LAPSE:2023.24097
Published Article
LAPSE:2023.24097
Development of Rubber Seed Shell−Activated Carbon Using Impregnated Pyridinium-Based Ionic Liquid for Enhanced CO2 Adsorption
Nawwarah Mokti, Azry Borhan, Siti Nur Azella Zaine, Hayyiratul Fatimah Mohd Zaid
March 27, 2023
Abstract
In this study, rubber seed shell was used for the production of activated carbon by chemical activation using an ionic liquid, [C4Py][Tf2N] as an activating agent. Sample RSS-IL 800 shows the highest specific surface area of 393.99 m2/g, a total pore volume of 0.206 cm3/g, and a micropore volume of 0.172 cm3/g. The performance of AC samples as an adsorbent for CO2 was also studied using a static volumetric technique evaluated at a temperature of 25 °C and 1 bar pressure. The CO2 adsorption capacity for sample RSS-IL 800 was 2.436 mmol/g, comparable with reported data from the previous study. Results also show that the CO2 adsorption capacity decreased at a higher temperature between 50 and 100 °C and increased at elevated pressure due to its exothermic behavior. The Langmuir model fits the adsorption data well, and the isosteric heat of adsorption proved that the physisorption process and exothermic behavior occur.
Keywords
activated carbon (AC), carbonization, CO2 adsorption capacity, pyridinium-based ionic liquid, rubber seed shell (RSS)
Suggested Citation
Mokti N, Borhan A, Zaine SNA, Mohd Zaid HF. Development of Rubber Seed Shell−Activated Carbon Using Impregnated Pyridinium-Based Ionic Liquid for Enhanced CO2 Adsorption. (2023). LAPSE:2023.24097
Author Affiliations
Mokti N: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Perak 32610, Malaysia
Borhan A: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Perak 32610, Malaysia; HICoE, Centre for Biofuel and Biochemical Research, Institute of Self-Sustainable Building, Department of Chemical Engineering, Universiti Teknologi P
Zaine SNA: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Perak 32610, Malaysia; Centre of Innovative Nanostructures & Nanodevices, Universiti Teknologi PETRONAS, Seri Iskandar, Perak 32610, Malaysia
Mohd Zaid HF: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Perak 32610, Malaysia; Centre of Innovative Nanostructures & Nanodevices, Universiti Teknologi PETRONAS, Seri Iskandar, Perak 32610, Malaysia
Journal Name
Processes
Volume
9
Issue
7
First Page
1161
Year
2021
Publication Date
2021-07-04
ISSN
2227-9717
Version Comments
Original Submission
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PII: pr9071161, Publication Type: Journal Article
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LAPSE:2023.24097
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https://doi.org/10.3390/pr9071161
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Mar 27, 2023
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