A series of functionalized ferrocene derivatives carrying electron-donor and electron-withdrawing (hetero)aromatic substituents has been designed as potential alternative electrolyte redox couples for dye-sensitized solar cells (DSSC). The compounds have been synthesized and fully characterized in their optical and electrochemical properties. A general synthetic approach that implies the use of a microwave assisted Suzuki coupling has been developed to access a significative number of compounds. The presence of different electron-rich and electron-poor substituents provided fine tuning of optical properties and energy levels. HOMO and LUMO energy values showed that the substitution of one or two cyclopentadienyl rings of ferrocene can be successfully exploited to increase the maximum attainable voltage from a standard DSSC device using TiO2 as a semiconductor, opening the way to highly efficient, non-toxic, and cheap redox shuttles to be employed in solar energy technologies.

Thermal conversion of ash-rich fuels in fluidized bed systems is often associated with extensive operation problems caused by the high amount of reactive inorganics. This paper investigates the behavior of wheat straw lignin—a potential renewable fuel for dual fluidized bed gasification. The formation of coherent ash residues and its impact on the operation performance has been investigated and was supported by thermochemical equilibrium calculations in FactSage 7.3. The formation of those ash residues, and their subsequent accumulation on the surface of the fluidized bed, causes temperature and pressure fluctuations, which negatively influence the steady-state operation of the fluidized bed process. This paper presents a detailed characterization of the coherent ash residues, which consists mostly of silica and partially molten alkali silicates. Furthermore, the paper gives insights into the formation of these ash residues, dependent on the fuel pretreatment (pelletizing) of the wheat... [more]

A comprehensive analysis of combustion behaviour during cold, intermediately cold, warm and hot start stages of a diesel engine are presented. Experiments were conducted at 1500 rpm and 2000 rpm, and the discretisation of engine warm up into stages was facilitated by designing a custom drive cycle. Advanced injection timing, observed during the cold start period, led to longer ignition delay, shorter combustion duration, higher peak pressure and a higher peak apparent heat release rate (AHRR). The peak pressure was ~30% and 20% and the AHRR was ~2 to 5% and ±1% higher at 1500 rpm and 2000 rpm, respectively, during cold start, compared to the intermediate cold start. A retarded injection strategy during the intermediate cold start phase led to shorter ignition delay, longer combustion duration, lower peak pressure and lower peak AHRR. At 2000 rpm, an exceptional combustion behaviour led to a ~27% reduction in the AHRR at 25% load. Longer ignition delays and shorter combustion durations... [more]

Conditioning of lignocellulosic hydrolysates with sulfur oxyanions, such as dithionite, is one of the most potent methods to improve the fermentability by counteracting effects of inhibitory by-products generated during hydrothermal pretreatment under acidic conditions. The effects of pH, treatment temperature, and dithionite dosage were explored in experiments with softwood hydrolysates, sodium dithionite, and Saccharomyces cerevisiae yeast. Treatments with dithionite at pH 5.5 or 8.5 gave similar results with regard to ethanol productivity and yield on initial glucose, and both were always at least ~20% higher than for treatment at pH 2.5. Experiments in the dithionite concentration range 5.0−12.5 mM and the temperature range 23−110 °C indicated that treatment at around 75 °C and using intermediate dithionite dosage was the best option (p ≤ 0.05). The investigation indicates that selection of the optimal temperature and dithionite dosage offers great benefits for the efficient fermen... [more]

Monopiles supporting offshore wind turbines can experience permanent non-recoverable rotations (or displacements) during their lifetime due to the cyclic nature of hydrodynamic and aerodynamic loading exerted on them. Recent studies in the literature have demonstrated that conventional cyclic p−y curves recommended in different codes of practice (API-RP-2GEO and DNVGL-RP-C212) may not capture the effects of long-term cyclic loads as they are independent of the loading profile and the number of applied cycles. Several published methodologies based on laboratory scaled model tests (on sands) exist to determine the effect of cyclic lateral loads on the long-term behaviour of piles. The tests vary in terms of the pile behaviour (rigid or flexible pile), number of applied loading cycles, and the load profile (one-way or two-way loading). The best-fit curves provided by these tests offer practical and cost-efficient methods to quantify the accumulated rotations when compared to Finite Elemen... [more]

Combined heat and power systems dedicated to micro-scale applications are currently increasing in popularity. The use of such systems is beneficial from the standpoint of increasing the usage of renewable energy, increasing energy efficiency and reducing CO2 emissions into the atmosphere. This paper shows two examples of prototypical micro-cogeneration systems powered by biomass. In the first, smaller one, electricity is generated in thermoelectric generators using heat from the wood-fired stove. The second one is equipped with a 100 kWt batch boiler and operates according to a modified Rankine cycle. The energy and ecological analysis were conducted and discussed, including selected aspects of heat and power generation and gaseous pollutant emission. Measurements were performed using a dedicated control and measurement station with a PLC controller. As was shown, thermoelectric generators operated respectively with the power of 22.5 We in the case of the air-cooled unit and 31.2 We in... [more]

Boil-off gas (BOG) disposal in liquefied natural gas (LNG) tankers has long been considered inevitable owing to the constant vaporization of the LNG in the storage tanks, but results in energy waste and environmental pollution. To address these challenges, we developed a re-liquification system that can condense the BOG and return it to the storage tank. The re-liquification system was modeled, and a case study was conducted to evaluate the viability of the system. The energy waste, which was quantified by tonnes of oil equivalent (TOE), greenhouse-gas emissions in tonnes of carbon dioxide (TCO2), and cost reduction in millions of U.S. dollars (MUSD), was evaluated for five different tanker cruising speeds. The re-liquification system significantly reduced the average TOE, TCO2, and cost by up to 9120.40 TOE/year, 19,474.33 TCO2/year, and 1.9765 MUSD/year, respectively, for five different tanker speeds with multi-stage compression.

This study aims to test the effects of changes in international crude oil prices on changes in crude oil and hydropower use from 1965 to 2016. We suggest a cointegration relationship between the consumption of coal, crude oil, and hydropower and the real crude oil price. The real price is weakly exogenous for the long-run relationship and has impacted energy consumption accordingly. The long-run crude oil price elasticity of oil use is 0.460. Our estimate suggests a positive oil price−oil use relationship in China, which is dramatically different from many previous studies but is consistent with a few past studies. The growth in external oil prices may lead to a long-run increase in hydropower use in China, with a long-run price elasticity of 0.242. The long-run crude oil price elasticity of coal use is −0.930. Hence, increased oil and hydropower use could make up the energy supply−demand gap left over by the decreased coal use. Strictly planned domestic fuel prices and rapidly growing... [more]

With an ever-increasing release of harmful greenhouse gases into the environment, there is an ongoing search for a renewable source of energy to replace the current means of producing energy. One promising source is from methanotrophic bacteria, which uses methane as its primary carbon source to produce valuable byproducts including lipids. These lipids could be used in the production of biofuels and other important industrial chemicals including plastics and surfactants. The use of methanotrophs would lower the amount of methane in the atmosphere from two sides, in the growth and cultivation of methanotrophs and in the replacement of conventional fossil fuels. The development of such a system requires a good understanding of the bacteria responsible and the steps of growth/culturing and extraction. An integrated system that uses every product of methanotrophic growth could impact multiple markets and help make this technique economically feasible as well as provide the groundwork for... [more]

Overdischarge often occurs during the use of battery packs, owing to cell inconsistency in the pack. In this study, the overdischarge behavior of 2.9 Ah cylindrical NCM811 [Li(Ni0.8Co0.1Mn0.1)O2] batteries in an adiabatic environment was investigated. A higher overdischarge rate resulted in a faster temperature increase in the batteries. Moreover, the following temperatures increased: Tu, at which the voltage decreased to 0 V; Ti, at which the current decreased to 0 A; and the maximum temperature during the battery overdischarge (Tm). The following times decreased: tu, when the voltage decreased from 3 to 0 V, and ti, when the current decreased to 0 A. The discharge capacity of the batteries was 3.06−3.14 Ah, and the maximum discharge depth of the batteries was 105.51−108.27%. Additionally, the characteristic overdischarge behavior of the batteries in a high-temperature environment (55 °C) was investigated. At high temperatures, the safety during overdischarging decreased, and the amou... [more]

A super high-head Francis turbine with a gross head of nearly 700 m was designed with computational fluid dynamics (CFD) simulation and laboratory tests. Reduced-scale (1:3.7) physical and numerical models of the real-scale prototype were created to investigate the hydraulic performance. According to the CFD analysis, a strong rotor−stator interaction (RSI) between guide vanes and runner blades is observed as a result of the high-speed tangential flow towards runner created by the super high water head as well as the small gaps between the radial blades. At the designed best efficiency point (BEP), there is no significant flow recirculation inside the flow passage and minor loss occurs at the trailing edge of the stay vanes and guide vanes. Maximum velocity is observed at runner inlets due to flow acceleration through the narrow passages between the guide vanes. The elbow-shaped draft tube gradually decreases the flow velocity to keep the kinetic energy loss at a minimum. The laborator... [more]

In the last years, an increasing number of countries has been affected by water shortage. Seawater desalination driven by solar energy, which is usually available in arid regions, might be a solution to satisfy the freshwater demand. In this study, the feasibility of a stand-alone multi-effect desalination (MED) plant driven by solar energy for an isolated community was studied. The system was made up of a solar field, a MED unit, and a thermal storage that mitigated solar energy fluctuations. Simulations with different top brine temperature and inclination and number of the solar panels were carried out in Matlab and Aspen Plus on an hourly basis by considering one typical meteorological year for ambient temperature and solar radiation. Two different sources of electrical energy were considered: A photovoltaic (PV) field and a diesel generator. The results were compared from an energetic and economic point of view, by considering the adoption of plastic as a material for MED heat exch... [more]

Recently, use of supercapacitors as energy storage systems has attracted considerable attention. However, the literature is scarce of information about the optimization of hybrid systems, using supercapacitors as the main energy storage system. In our study, we focused step-by-step on the engineering concept of a photo-rechargeable energy storage system based on silicon solar cells and supercapacitors. In the first step, based on commercially available elements, we designed a solar charger and simulated its work in idealized conditions. Secondly, we designed appropriate electronic connections and control systems, allowing for the charging−discharging process of the energy storage system. After constructing three type of demonstrators of solar energy charger, we tested it. The novel design allowed us to achieve total available energy from solar panel energy conversion up to 93%.

As one of the main businesses in Jeju-do in South Korea, specialized local products are grown in greenhouses. For greenhouse farming, it is preferable to use geothermal heat pump systems for energy conservation because of the stable temperature of the ground. In the same manner, heat pumps using underground air is recommended for greenhouse farming since underground air can easily be obtained from porous volcanic rocks in Jeju-do. However, direct usage of the underground air is not feasible for planting in the greenhouse or livestock care because the underground air is relatively humid and its temperature is low. For the present study, the heating performance of an air-to-water heat pump which used underground air as a heat source for greenhouse farming during the winter was assessed through measurements. In addition, the economic impact of the air-to-water heat pump (AWHP) was compared with a conventional air heater. According to the results, an AWHP can save more than 70% of the tota... [more]

Hydrogen-based engines are progressively becoming more important with the increasing utilization of hydrogen and layouts (e.g., onboard reforming systems) in internal combustion engines. To investigate the possibility of HICE (hydrogen fueled internal combustion engine), such as an engine with an onboard reforming system, which is introduced as recent technologies, various operating areas and parameters should be considered to obtain feasible hydrogen contents itself. In this study, a virtual hydrogen-added compressed natural gas (HCNG) model is built from a modified 11-L CNG (Compressed Natural Gas) engine, and a response surface model is derived through a parametric study via the Latin hypercube sampling method. Based on the results, performance and emission trends relative to hydrogen in the HCNG engine system are suggested. The operating conditions are 1000, 1300, and 1500 rpm under full load. For the Latin hypercube sampling method, the dominant variables include spark timing, exc... [more]

The sustainable development of the energy sector through the implementation of renewable energy (RE) technology has been a primary concern for the government of Malaysia since the 1990s. Developing RE technology in rural areas is also one of the most important energy strategies. One of the most important requirements for the successful adoption of renewable energy technology is the public acceptance of this technology. This article examines the public acceptance of RE (wind and solar) technologies among rural residents in Mersing, Malaysia. This study is conducted in conjunction with the development of the hybrid wind−solar RE generation system for the Marine Ecosystem Research Centre (EKOMAR), which located in Mersing. To investigate the public acceptance of RE technologies, two surveys were conducted, before and after the installation of the hybrid wind−solar RE generation system. The findings revealed that RE innovations, such as wind and solar energy, were well known among 54.7% an... [more]

This paper investigates the bottom-hole pressure (BHP) performance of a fractured well with multiple radial fracture wings in a coalbed methane (CBM) reservoir with consideration of stress sensitivity. The fluid flow in the matrix simultaneously considers adsorption−desorption and diffusion, whereas fluid flow in the natural fracture system and the induced fracture network obeys Darcy’s law. The continuous line-source function in the CBM reservoir associated with the discretization method is employed in the Laplace domain. With the aid of Stehfest numerical inversion technology and Gauss elimination, the transient BHP responses are determined and analyzed. It is found that the main flow regimes for the proposed model in the CBM reservoir are as follows: linear flow between adjacent radial fracture wings, pseudo-radial flow in the inner region or Stimulated Reservoir Volume (SRV), and radial flow in outer region (un-stimulated region). The effects of permeability modulus, radius of SRV,... [more]

The limitation of fossil fuel uses and GHG (greenhouse gases) emissions reduction are two of the main objectives of the European energy policy and global agreements that aim to contain climate changes. To this end, the building sector, responsible for important energy consumption rates, requires a significant improvement of its energetic performance, an obtainable increase of its energy efficiency and the use of renewable sources. Within this framework, in this study, we analysed the economic feasibility of a stand-alone photovoltaic (PV) plant, dimensioned in two configurations with decreasing autonomy. Their Net Present Value at the end of their life span was compared with that of the same plant in both grid-connected and storage-on-grid configurations, as well as being compared with a grid connection without PV. The analysis confirms that currently, for short distances from the grid, the most suitable PV configuration is the grid-connected one, but also that the additional use of a... [more]

This paper discusses three methods of modulation for a single-phase isolated matrix converter. The matrix converter is combined with a transformer integration to perform power decoupling control in order to reduce the number of component and capacitor volumes. Due to the reason of (i) Alternating current (AC/AC) direct conversion and (ii) transformer integration, obtaining a clean sinusoidal grid current waveform in the modulation of matrix converter (MC) is important. Three methods of modulation are compared in terms of control complexity, quality waveform, and inductive-capacitive-inductive (LCL) filter sizing. The principal control of each method is described. Finally, a prototype was tested to verify the validity and the effectiveness of grid current control and power decoupling in the spoken circuit structure.

According to the International Energy Agency (IEA)’s forecast, China will fully electrify its railway system by 2050. However, the development of electrified railways is limited in the weak areas of China’s power grid. To surpass these limitations, we turn our attention to new railway energy sources, among which the most suitable is photovoltaic power generation. To evaluate the feasibility of integrating railway systems and photovoltaic power generation in China, this paper analyzes the geographical conditions and railway layout of China, gives a potential method for evaluating railway asset energy transformation measures and asset energy transformations that are suitable for China’s national conditions, and proposes an application of railway system energy transformation on this basis. Then, this method is used to evaluate the potential of a substation section of the Lanxin high-speed railway in China for reference. The results show that the green energy potential and scheduling poten... [more]

In this paper, we examine the energy efficiency performance of the Belt and Road Initiative (BRI) countries using a newly developed panel data stochastic frontier model that allows for estimation of both persistent and transient efficiency while controlling for random country effects and noise. By this, we contribute to the energy economic literature by providing a complete picture of the level of persistent, transient, and total energy efficiency estimates from a cross country perspective for a panel of 48 BRI countries during the period 1990−2015. Adding that there is little evidence to support energy efficiency convergence in the energy economic literature, we went further to check whether energy efficiency converges in the BRI countries. The results show that (1) persistent efficiencies are much lower than transient efficiencies, suggesting that the energy problem in the BRI countries is more of a structural issue; (2) while energy efficiency varies widely across the countries, hig... [more]

There is a significant interaction between wind and earthquakes for large-scaled wind turbines due to an aeroelastic effect. This study evaluates the accuracy of an uncoupled method extensively utilized to analyze the seismic response of wind turbines at the operational state. Initially, the oscillation of the blade for the National Renewable Energy Laboratory (NREL) 5 MW wind turbine excited by wind and wind-earthquake combination, respectively, is compared using the fully coupled method to verify the assumption in this uncoupled method. Subsequently, the influence of ground motions on the aerodynamic loadings of the rotor is discussed to evaluate the interaction between wind and earthquake loads. In addition, the accuracy of the uncoupled method is assessed by comparing the analysis results of the coupled and uncoupled methods, where different mean wind speed and equivalent aerodynamic damping ratio are considered. The results indicate that the oscillation velocity of blades and thru... [more]

Photovoltaic systems have been explored as a solution to meet the growing demand for electricity from a clean and renewable source. However, the low energy conversion efficiency of photovoltaic panels is one of the critical factors that hinder the competitiveness of this energy source concerning the others. An effective way to improve the efficiency of photovoltaic systems is by using solar trackers. The tracking strategy most used in photovoltaic plants employs algorithms to calculate the Sun position. This work presents energy generation estimation applying six algorithms in horizontal single-axis solar tracking: the Solar Position Algorithm (SPA) and Grena 1−5 algorithms. The aim is to evaluate the influence of these algorithms on energy generation. For all simulated locations, comparing to an ideal scenario, the SPA presented the best energy generation results. However, the other algorithms showed negligible differences between themselves, which allows us to conclude that any of th... [more]

This research put forth exergy-based economic and sustainability analyses of a (J85-GE-5H) military turbojet engine (TJE). Firstly, sustainability, conventional exergoeconomic and advanced exergoeconomic cost analyses were executed utilizing kerosene fuel according to real engine working circumstances. The engine was likewise investigated parametrically, considering H2 fuel utilization. The sustainable economic analysis assessment of the TJE was finally actualized by comparing the acquired outcomes for both fuels. The entire engine’s unit exergy cost of product (cPr) with kerosene was determined 76.45 $/GJ for the military (MIL) process mode (PM), whereas it was computed 94.97 $/GJ for the afterburner (AB) PM. Given the use of H2, the cPr increased to 179 and 288 $/GJ for the aforementioned two modes, seriatim. While the sustainability cost index (SCI) values were obtained 52.86 and 78.84 $/GJ for the MIL and AB PM, seriatim, they became 128 and 244 $/GJ when considering H2. Consequent... [more]

The pump turbine is prone to stall when running at part-load operation. Stalls would cause a hump-like head characteristic curve, low-frequency high-amplitude pressure pulsation, and surge or resonance in the system. There is a lack of efficient methods for pump turbine stall suppression. The traditional blade hydrodynamic optimization method has limited effect and would influence the other characteristics. As the essence of stall is flow separation, forming a severe backflow vortex, a “Groove Method” is put forward and employed to suppress stall in a pump turbine with the full consideration of the mechanical structure, flow field, and pressure field. Both experiments and calculations are carried out to test the effectiveness of this new method. Furthermore, its deep mechanisms are revealed. This method can weaken the head hump to a certain extent and reduce the pressure pulse amplitude induced by stall. Meanwhile, the performance at the design operating point is not disturbed much.