Biochar, which is a byproduct of gasification, is used in a wide range of fields such as water filtration, agriculture, and electronics, to name a few. The metals in the biomass were thought to end up either in the ash or distributed throughout the biochar. In this study, the goal was a more thorough characterization of biochar resulting from a single-stage downdraft gasifier. One of the first observations was that some metals actually localize into small (~25 micron diameter) metallic nodules on the biochar surface. Further analysis included ultimate and proximate analysis, Brunauer−Emmert−Teller (BET) analysis, and scanning electron microscopy X-ray spectroscopy (SEM-EDS). Biomass fuel included corn grains, soybeans, and wood pellets, with wood biochar showing the highest fixed carbon content, at 91%, and the highest surface area, at 92.4 m2/g. The SEM analysis showed that certain minerals, including potassium, phosphorus, calcium, iron, nickel, silicon, and copper, formed nodules wi... [more]

Expectation for renewable energy is increasing due to environmental pollution such as fossil fuel depletion, CO2 emission, and harmful gases. Therefore, in this study, extracted sugars of microalgae, which cause algal blooms and crude glycerol, a biodiesel industry byproduct, were used simultaneously to produce 2,3-BDO. The 2,3-BDO production using only extracted algal sugars was about 4.8 g/L at 18 h, and the production of 2,3-BDO using both extracted algal sugar and crude glycerol was about 7 g/L at 18 h. It was confirmed that the main culture with crude glycerol was increased 1.5-fold compared to the case of using only extracted algal sugars. In addition, four components of the main medium (ammonium sulfate, casein hydrolysate, yeast extract, and crude glycerol) were statistically optimized and the concentrations of the medium were 12, 16, 12, and 13 g/L, respectively. In addition, the final 2,3-BDO production was about 11g/L, which 1.6-fold higher than before the optimization proce... [more]

This paper presents a part of the study referring to exploring Energy Recovery from Municipal Solid Waste in Maramures County. In order to analyze the possibility of energetic recovery of municipal solid waste (MSW), data referring to the management system of MSW from Maramures county were cumulated and processed in a first stage in order to estimate the quantity of municipal solid waste and its composition, which might be recovered energetically. In the next stage, samples of municipal solid waste were collected from landfills, which were submitted to specific processing and analyses. The experimental data were processed and in the end the energy potential of municipal solid waste from Maramures county was found. This study will help stakeholders and those involved in waste management to assess the possibility of energy recovery. The analysis of the study concluded that municipal solid waste in Maramures County is a potential source of renewable energy.

Algorithms that compute locally optimal continuous designs often rely on a finite design space or on the repeated solution of difficult non-linear programs. Both approaches require extensive evaluations of the Jacobian Df of the underlying model. These evaluations are a heavy computational burden. Based on the Kiefer-Wolfowitz Equivalence Theorem, we present a novel design of experiments algorithm that computes optimal designs in a continuous design space. For this iterative algorithm, we combine an adaptive Bayes-like sampling scheme with Gaussian process regression to approximate the directional derivative of the design criterion. The approximation allows us to adaptively select new design points on which to evaluate the model. The adaptive selection of the algorithm requires significantly less evaluations of Df and reduces the runtime of the computations. We show the viability of the new algorithm on two examples from chemical engineering.

The startup process occurs frequently for pumped storage units. During this process, the rotating rate that changes rapidly and unsteady flow in runner cause the complex dynamic response of runner, sometimes even resonance. The sharp rise of stress and the large-amplitude dynamic stresses of runner will greatly shorten the fatigue life. Thus, the study of start-up process in turbine mode is critical to the safety operation. This paper introduced a method of coupling one dimensional (1D) pipeline calculation and three-dimensional computational dynamics (3D CFD) simulation to analyze transient unsteady flow in units and to obtain more accurate and reliable dynamic stresses results during start up process. According to the results, stress of the ring near fixed support increased quickly as rotating rate rose and became larger than at fillets of leading edge and band in the later stages of start-up. In addition, it was found that dynamic response can be caused by rotor stator interaction (... [more]

This article aims to develop a proton exchange membrane (PEM) electrolyzer emulator. This emulator is realized through an equivalent electrical scheme. It allows taking into consideration the dynamic operation of PEM electrolyzers, which is generally neglected in the literature. PEM electrolyzer dynamics are reproduced by the use of supercapacitors, due to the high value of the equivalent double-layer capacitance value. Steady-state and dynamics operations are investigated in this work. The design criteria are addressed. The PEM electrolyzer emulator is validated by using a 400-W commercial PEM electrolyzer. This emulator is conceived to test new DC-DC converters to supply the PEM ELs and their control as well, avoiding the risk to damage a real electrolyzer for experiment purposes. The proposed approach is valid both for a single cell and for the whole stack emulation.

Propylene glycol, also known as 1,2 propanediol, is one of the most important chemicals in the industry. It is a water-soluble liquid, considered by the U.S. Food and Drug Administration as safe to manufacture consumer products, including foodstuffs, medicines, and cosmetics. This chemical has essential properties, such as solvent, moisturizer, or antifreeze, in addition to a low level of toxicity. This paper aims to present the selection, simulation, and dimensioning of a trickle bed reactor at a laboratory scale. The sizing was validated with other authors. Two predictive models have been considered for reactor modeling, intrinsic kinetics and coupled intrinsic kinetics, along with mass transfer equations and the wetting of the catalyst particles. The model was implemented using Aspen Custom Modeler® (20 Crosby Dr. Bedford, MA 01730, EE. UU.) to study the reactor behavior in terms of conversion. The results show the profiles of different variables throughout the reactor and present h... [more]

Muscular tissue regeneration may be enhanced in vitro by means of mechanical stimulation, inducing cellular alignment and the growth of functional fibers. In this work, a novel bioreactor is designed for the radial stimulation of porcine-derived diaphragmatic scaffolds aiming at the development of clinically relevant tissue patches. A Finite Element (FE) model of the bioreactor membrane is developed, considering two different methods for gripping muscular tissue patch during the stimulation, i.e., suturing and clamping with pliers. Tensile tests are carried out on fresh and decellularized samples of porcine diaphragmatic tissue, and a fiber-reinforced hyperelastic constitutive model is assumed to describe the mechanical behavior of tissue patches. Numerical analyses are carried out by applying pressure to the bioreactor membrane and evaluating tissue strain during the stimulation phase. The bioreactor designed in this work allows one to mechanically stimulate tissue patches in a radial... [more]

The output generations of renewable energy sources (RES) depend basically on climatic conditions, which are the main reason for their uncertain nature. As a result, the performance and security of distribution systems can be significantly worsened with high RES penetration. To address these issues, an analytical study was carried out by considering different penetration strategies for RES in the radial distribution system. Moreover, a bi-stage procedure was proposed for optimal planning of RES penetration. The first stage was concerned with calculating the optimal RES locations and sites. This stage aimed to minimize the voltage variations in the distribution system. In turn, the second stage was concerned with obtaining the optimal setting of the voltage control devices to improve the voltage profile. The multi-objective cat swarm optimization (MO-CSO) algorithm was proposed to solve the bi-stages optimization problems for enhancing the distribution system performance. Furthermore, th... [more]

Climate changes will have a huge impact on society, one that cannot be truly predicted. However, what is known is that our dependence on fossil feedstock for energy, fuel and chemical production will need to shift towards more biobased and circular feedstock. This paper describes part of an important technology development that uses biogenic and plastic-containing waste streams for the co-production of aromatics with fuels and/or chemicals. This paper captures the first decade of this technology development from idea towards a large Process Demonstration Unit operated and validated within a large gasification R&D infrastructure. The scale-up was successful, with supporting tools to optimize and identify the limits of the technology. Benzene and toluene are directly removed from the product gas with 97% and 99% efficiency, respectively. The next steps will be to include this development in larger piloting and demonstrations for the co-production of aromatics from biomass gasification (b... [more]

In the context of wave resource assessment, the description of wave climate is usually confined to significant wave height and energy period. However, the accurate joint description of both linear and directional wave energy characteristics is essential for the proper and detailed optimization of wave energy converters. In this work, the joint probabilistic description of wave energy flux and wave direction is performed and evaluated. Parametric univariate models are implemented for the description of wave energy flux and wave direction. For wave energy flux, conventional, and mixture distributions are examined while for wave direction proven and efficient finite mixtures of von Mises distributions are used. The bivariate modelling is based on the implementation of the Johnson−Wehrly model. The examined models are applied on long-term measured wave data at three offshore locations in Greece and hindcast numerical wave model data at three locations in the western Mediterranean, the Nort... [more]

The rise of personalised and highly complex drug product profiles necessitates significant advancements in pharmaceutical manufacturing and distribution. Efforts to develop more agile, responsive, and reproducible manufacturing processes are being combined with the application of digital tools for seamless communication between process units, plants, and distribution nodes. In this paper, we discuss how novel therapeutics of high-specificity and sensitive nature are reshaping well-established paradigms in the pharmaceutical industry. We present an overview of recent research directions in pharmaceutical manufacturing and supply chain design and operations. We discuss topical challenges and opportunities related to small molecules and biologics, dividing the latter into patient- and non-specific. Lastly, we present the role of process systems engineering in generating decision-making tools to assist manufacturing and distribution strategies in the pharmaceutical sector and ultimately em... [more]

Ethyl ester production from palm fatty acid distillate (PFAD) with ethanol in the presence of sulfuric acid and potassium hydroxide was performed in a continuous three-step process using the ultrasound clamps and an ultrasonic probe. The ultimate goal was to produce biodiesel from the PFAD. In the first and second esterification steps, 16 units of a 400 W ultrasound clamp (20 kHz) were attached 100-m apart along each tubular reactor. In the third transesterification step, a 1000-W ultrasonic homogenizer (18 kHz) was used in a 100-mL continuous reactor. A composite central design of experiments and the response surface methodology (RSM) were used to develop predictive models and identify the optimal conditions of each step based on the purities of ethyl ester. The optimal conditions in the first step were 46.1 vol.% ethanol, 1.4 vol.% sulfuric acid, and purity 66.68 wt.% ethyl ester. In the second step, the optimized conditions were 57 vol.% ethanol, and 2.1 vol.% sulfuric acid, purity... [more]

In recent years, liposomes have gained increasing attention for their potential applications as drug delivery systems in the pharmaceutic, cosmetic and food industries. However, they have a tendency to aggregate and are sensitive to degradation caused by several factors, which may limit their effectiveness. A promising approach to improve liposomal stability is to modify liposomal surfaces by forming polymeric layers. Among natural polymers, chitosan has received great interest due to its biocompatibility and biodegradability. This review discussed the characteristics of this combined system, called chitosomes, in comparison to those of conventional liposomes. The coating of liposomes with chitosan or its derivatives improved liposome stability, provided sustained drug release and increased drug penetration across mucus layers. The mechanisms behind these results are highlighted in this paper. Alternative assembly of polyelectrolytes using alginate, sodium hyaluronate, or pectin with c... [more]

Biodiesel is one the most sought after alternate fuels in the current global need for sustainable and renewable energy sources due to their lower emissions and no major modification requirement to existing engines. However, the performance and productivity of the biodiesel production process are significantly dependent on the process parameters. In this regard, a novel hybrid genetic programming-gray wolf optimizer approach for the process optimization of biodiesel production is proposed in this paper. For an illustration of the proposed approach, kinematic viscosity is expressed as a symbolic regression metamodel to account for the influence of catalyst concentration, reaction temperature, alcohol-to-oil molar ratio, and reaction time. Then, the genetic programming-based symbolic regression metamodel is used as an objective function by the gray wolf optimizer to optimize the process parameters. The obtained results show that the proposed approach is simple, accurate, and robust.

In this study, a targeted oxygen-enrichment technology was proposed to enhance coal combustion in an ironmaking blast furnace. The coal flow and combustion characteristics under targeted oxygen-enrichment were investigated using the computational fluid dynamics (CFD) method. The results showed that oxygen utilization and coal burnout were significantly increased under targeted oxygen-enrichment. The coal burnout at 24% O2 concentration was 86.29%, which was the maximum and indicated an increase of 13.13%. However, the cooling effect of room-temperature oxygen had some adverse effects on coal combustion. Given this, the effect of coal particle temperature on coal combustion was investigated based on targeted oxygen-enrichment. The coal combustion process was further enhanced. The coal burnout at a 600 K particle temperature and 25% oxygen concentration was 91.12% and had an increase of 17.96%, which was the maximum.

The mixed collector can improve low rank coal flotation efficiency, but its synergistic mechanism needs to be further explored. In this paper, oleic acid-dodecane (OA-D), oleic acid (OA), and dodecane (D) were employed to treat the low rank coal for revealing new synergistic mechanism of the mixed collector. First the surface free energy of the coal, the surface free energy of coal-water and coal-water-coal were calculated. Then wetting heat measurement, X-ray Photoelectron Spectroscopy (XPS) and FTIR were used to analyze synergistic mechanism of the mixed collector in depth. The results showed that OA-D obtained a higher combustible recovery than using OA and D, respectively. The essence of synergetic mechanism of OA-D was that they formed a relatively ordered “supramolecular structure” on the low rank coal surface, especially there were hydrophobic and van der Waals forces between the oleic acid chain and the dodecane chain that can promote the formation of a continuous collector fil... [more]

The potential for utilizing industrial waste heat for district heating is enormous. There is, however, often a temporal mismatch between the waste heat availability and the heating demand, and typically fossil-based peak boilers are used to cover the remaining heat demand. This study investigates the potential of applying a thermal energy storage tank at the district heating supply system at Mo Industrial Park in Norway, where waste heat from the off-gas of a ferrosilicon production plant is the main heating source. To cover peak heating demands, boilers based on CO gas, electricity, and oil are applied. The reduction in peak heating costs and emissions is evaluated as a function of tank size for two different scenarios: (1) a scenario where CO gas, which is a byproduct from another nearby industry, is the main peak heating source; and (2) a scenario where no CO gas is available, and electricity is the main peak heating source. The highest economic viability is obtained with the smalle... [more]

This study examines the applicability of the ice storage systems in the small commercial refrigerated showcases through experimental analysis. R-404A is used as the working fluid and various influence of parameter settings and improvements, are discussed in details. In the ice storage system, the condenser is changed from air-cooling (refrigeration mode) to an immersion type that is placed in an ice storage tank, the corresponding condensing temperature and pressure are reduced appreciably. This increased the efficiency and can effectively reduce the peak power consumption. The reduction of the condensing temperature and pressure increased the coefficient of performance (COP) from 3.6 (refrigeration mode) to 6.35 (melting mode), effectively enhancing the refrigeration efficiency. The results indicated that the ice storage system could effectively increase the coefficient of performance from 3.6 to 6.35 during ice melting when compared to the conventional refrigeration system. It also c... [more]

Energy storage is a key solution to supply renewable electricity on demand and in particular batteries are becoming attractive for consumers who install PV panels. In order to minimize their electricity bill and keep the grid stable, batteries can combine applications. The daily match between PV supply and the electricity load profile is often considered as a determinant for the attractiveness of residential PV-coupled battery systems, however, the previous literature has so far mainly focused on the annual energy balance. In this paper, we analyze the techno-economic impact of adding a battery system to a new PV system that would otherwise be installed on its own, for different residential electricity load profiles in Geneva (Switzerland) and Austin (U.S.) using lithium-ion batteries performing various consumer applications, namely PV self-consumption, demand load-shifting, avoidance of PV curtailment, and demand peak shaving, individually and jointly. We employ clustering of the hous... [more]

The study examines the implications of educating prosumers regarding Internet of Things (IoT) use and monitoring to reduce power consumption in the home and encourage energy conservation, sustainable living, and behavior change. Over 15 months, 125 households and household owners received training regarding IoT plug equipment, usage monitoring, and energy reduction. A face to face survey was then conducted regarding power consumption reductions, frequency of monitoring, and user satisfaction compared to the previous year. The study found that participating households used around 5% less energy compared to average households. The reduction rate was found to have increased when more appliances were connected to smart plugs and their power usage was monitored more frequently. Power usage also fell in a greater level when participants were more satisfied with being given smart plugs and related education. Moreover, energy reduction rates increase when smart plugs were used for cooling and... [more]

Modern electrical grids are transitioning from a centralized generation architecture to an architecture with significant distributed, intermittent generation. This transition means that the formerly sharp distinction between energy producers (utility companies) and consumers (residences, businesses, etc.) are blurring: end-users both produce and consume energy, making energy management and public policy more complex. The goal of the Open Power Quality (OPQ) project is to design and implement a low cost, distributed power quality sensor network that provides useful new forms of information about modern electrical grids to producers, consumers, researchers, and policy makers. In 2019, we performed a pilot study involving the deployment of an OPQ sensor network at the University of Hawaii microgrid for three months. Results of the pilot study validate the ability of OPQ to collect accurate power quality data in a way that provides useful new insights into electrical grids.

In this work, the dynamic combustion characteristics in a scramjet engine were investigated using three diagnostic data analysis methods: DMD (Dynamic Mode Decomposition), STFT (Short-Time Fourier Transform), and CEMA (Chemical Explosive Mode Analysis). The data for the analyses were obtained through a 2D numerical experiment using a DDES (Delayed Detached Eddy Simulation) turbulence model, the UCSD (University of California at San Diego) hydrogen/oxygen chemical reaction mechanism, and high-resolution schemes. The STFT was able to detect that oscillations above 50 kHz identified as dominant in FFT results were not the dominant frequencies in a channel-type combustor. In the analysis using DMD, it was confirmed that the critical point that induced a complete change of mixing characteristics existed between an injection pressure of 0.75 MPa and 1.0 MPa. A combined diagnostic analysis that included a CEMA was performed to investigate the dynamic combustion characteristics. The difference... [more]

Vehicle platooning has been proposed as one of the potential technologies for intelligent transport systems to improve transportation and energy efficiency in urban cities. Despite extensive studies conducted on the platooning of heavy-duty trucks, literature on the analysis of urban vehicle platoons has been limited. To analyse the impact of platooning in urban environments, this paper studies the influence of intervehicle distance, platoon size and vehicle speed on the drag coefficient of the vehicles in a platoon using computational fluid dynamics (CFD). Two vehicle models—a minibus and a passenger car—are analysed to characterise the drag coefficients of the respective platoons. An analysis of energy consumption is conducted to evaluate the energy savings with platooning using a longitudinal dynamics simulation. The results showed a reduction in the average drag coefficient of the platoon of up to 24% at an intervehicle distance of 1 m depending on the number of vehicles in the pla... [more]

Prussian Blue analogues (PBAs) are a promising class of electrode active materials for batteries. Among them, copper nitroprusside, Cu[Fe(CN)5NO], has recently been investigated for its peculiar redox system, which also involves the nitrosyl ligand as a non-innocent ligand, in addition to the electroactivity of the metal sites, Cu and Fe. This paper studies the dynamics of the electrode, employing surface sensitive X-ray Photoelectron spectroscopy (XPS) and bulk sensitive X-ray absorption spectroscopy (XAS) techniques. XPS provided chemical information on the layers formed on electrode surfaces following the self-discharge process of the cathode material in the presence of the electrolyte. These layers consist mainly of electrolyte degradation products, such as LiF, LixPOyFz and LixPFy. Moreover, as evidenced by XAS and XPS, reduction at both metal sites takes place in the bulk and in the surface of the material, clearly evidencing that a self-discharge process is occurring. We observe... [more]