Diesel fuel mixtures with high concentrations of biodiesel have been investigated to analyze the technical feasibility of their use in diesel cycle engines regarding thermal and oxidative properties. The results of combined techniques of oxidative stability, high Pressurized Differential Scanning Calorimetry (P-DSC), Calculated Cetane Index (CCI), and calorific power were used to verify the effect of the thermal-oxidative stability as a function of the percentage of biodiesel in the mixtures. The obtained results evidenced that the thermal and oxidative stability decreased with the addition of biodiesel from 50 to 5% v/v. Low stability fuels require rapid use as the oxidation compounds degrade the product and impair vehicle performance, as well as lead to corrosion and clogging problems in various mechanical systems.

Synthetic fuel production via gasification of residual biomass streams from the pulp and paper industry can be an opportunity for the mills to enable improved resource utilization and at the same time reduce the production of excess heat. This paper summarizes initial oxygen-blown gasification experiments with two bark residues from a European pulp and paper mill, i.e., a softwood bark and a hardwood bark. The gasification process was characterized by measuring syngas yields and process efficiency to find optimum operating conditions. In addition, impurities in the syngas and ash behavior were characterized. Maximum yields of CO and H2 were obtained from softwood bark and amounted to approximately 29 and 15 mol/kg fuel, respectively. Optimum cold gas efficiency was achieved at an oxygen stoichiometric ratio of λ = 0.40 and was approximately 76% and 70% for softwood bark and hardwood bark, respectively. Increased λ had a reducing effect on pollutants in the syngas, e.g., higher hydrocar... [more]

H2 production through dry reforming of methane (DRM) is a hot topic amidst growing environmental and atom-economy concerns. Loading Ni-based reducible mixed oxide systems onto a thermally stable support is a reliable approach for obtaining catalysts of good dispersion and high stability. Herein, NiO was dispersed over MOx-modified-γ-Al2O3 (M = Ti, Mo, Si, or W; x = 2 or 3) through incipient wetness impregnation followed by calcination. The obtained catalyst systems were characterized by infrared, ultraviolet−visible, and X-ray photoelectron spectroscopies, and H2 temperature-programmed reduction. The mentioned synthetic procedure afforded the proper nucleation of different NiO-containing mixed oxides and/or interacting-NiO species. With different modifiers, the interaction of NiO with the γ-Al2O3 support was found to change, the Ni2+ environment was reformed exclusively, and the tendency of NiO species to undergo reduction was modified greatly. Catalyst systems 5Ni3MAl (M = Si, W) comp... [more]

Developing simple and effective chemistry able to convert industrial waste streams into valuable chemicals is a primary contributor to sustainable development. Working in the context of biodiesel production, we found that plain bisulfate on silica (SSANa, 3.0 mmol/g) proved to be an optimal catalyst to convert glycerol into solketal. With the assistance of a proper anhydrification technique, isolated yields of 96% were achieved working in mild conditions, on 100 g scale.

When Saccharomyces cerevisiae undergoes heat stress it stimulates several changes that are necessary for its survival, notably in carbon metabolism. Notable changes include increase in trehalose production and glycolytic flux. The increase in glycolytic flux has been postulated to be due to the regulatory effects in upper glycolysis, but this has not been confirmed. Additionally, trehalose is a useful industrial compound for its protective properties. A model of trehalose metabolism in S. cerevisiae was constructed using Convenient Modeller, a software that uses a combination of convenience kinetics and a genetic algorithm. The model was parameterized with quantitative omics under standard conditions and validated using data collected under heat stress conditions. The completed model was used to show that feedforward activation of pyruvate kinase by fructose 1,6-bisphosphate during heat stress contributes to the increase in metabolic flux. We were also able to demonstrate in silico tha... [more]

The constant increase in greenhouse gases in the environment is forcing people to look for different ways to reduce such pollution. One of these ways is the use of biodiesel for road transport. Conventional biodiesel production involves the catalytic triglyceride transesterification process. When using homogeneous two-stage catalysis, it is difficult to purify the resulting product from the by-products formed, and the catalysts cannot be reused. In the case of heterogeneous catalysis, the process costs are increased due to separation and regeneration of the catalysts. To solve these problems of catalytic synthesis, a noncatalytic process has been recently studied that which takes place under supercritical conditions for an alcohol or other acyl receptor. In such biodiesel production, fatty feedstocks and alcohols are used as raw materials, with the synthesis taking place at supercritical conditions for alcohol, i.e., high temperature and pressure, thus making the process quite simple.... [more]

In the past decades, carbon dioxide (CO2) emissions have become an important issue for many researchers and policy makers. The focus of scientists and experts in the area is mainly on lowering the CO2 emission levels. In this article, panel data is analyzed with an econometric model, to estimate the impact of renewable energy, biofuels, bioenergy efficiency, population, and urbanization level on CO2 emissions in European Union (EU) countries. Our results underline the fact that urbanization level has a negative impact on increasing CO2 emissions, while biofuels, bioenergy production, and renewable energy consumption have positive and direct impacts on reducing CO2 emissions. Moreover, population growth and urbanization level are negatively correlated with CO2 emission levels. The authors’ findings suggest that the public policies at the national level must encourage the consumption of renewable energy and biofuels in the EU, while population and urbanization level should come along wit... [more]

The aquathermolysis process is widely considered to be one of the most promising approaches of in-situ upgrading of heavy oil. It is well known that introduction of metal ions speeds up the aquathermolysis reactions. There are several types of catalysts such as dispersed (heterogeneous), water-soluble and oil soluble catalysts, among which oil-soluble catalysts are attracting considerable interest in terms of efficiency and industrial scale implementation. However, the rock minerals of reservoir rocks behave like catalysts; their influence is small in contrast to the introduced metal ions. It is believed that catalytic aquathermolysis process initiates with the destruction of C-S bonds, which are very heat-sensitive and behave like a trigger for the following reactions such as ring opening, hydrogenation, reforming, water−gas shift and desulfurization reactions. Hence, the asphaltenes are hydrocracked and the viscosity of heavy oil is reduced significantly. Application of different hyd... [more]

Using biodiesel in diesel engines is beneficial for reducing emissions of carbon monoxide (CO), hydrocarbons (HC) and particulate matters (PM). Biodiesel is usually produced from vegetable oils or animal fats. When produced from plant oil or woody plant sources, biodiesel can reduce a significant amount of carbon dioxide on a life cycle basis. The objective of this study is to produce biodiesel from a non-conventional woody plant source that is, crude tall oil, which is a dark brown viscous liquid extracted and processed in wood pulping plants. It contains a high percentage of fatty acids. From raw crude tall oil, tall oil fatty acids were separated and were successfully used for the production of biodiesel in this study. Although biodiesel produces lower CO, HC and PM than petroleum diesel fuel, it produces higher oxides of nitrogen (NOx) emissions in diesel engines. Water emulsifications of diesel-biodiesel blends are investigated in a direct injection (DI) diesel engine in this work... [more]

Thermal energy storage systems help to couple thermal energy generation and process demand in cogeneration facilities. One single deposit with two design temperatures and one main temperature step in sensible thermal energy storage define the thermocline systems. Performance of one high size real thermocline thermal energy storage system is analysed. Starting from temperature and mass flow rate data registered by the plant control system, one advanced thermodynamic analysis is performed. The quality of heat storage is analysed in terms of evaluation of the stratification in the thermocline zone. The temperature data registered at 21 positions is extended by displacement analysis generating detailed profiles. Fraction of recoverable heat, thermocline width, stratification indices based on energy and exergy analysis, and mean temperature gradients in the thermocline region are calculated. These parameters are monitored under real operation conditions of the plant. The calculated paramete... [more]

In order to improve the accuracy of numerical simulation, a new heat transfer model is developed by using a modular approach in the Anstalt für Verbrennungskraftmaschinen (AVL)-Boost software. The improved heat transfer model mainly considers the effects of the swirl and boiling heat transfer inside the engine. In addition, a chemical kinetics mechanism including 475 reactions and 134 species is employed to predict the combustion of diesel engines fueled with biodiesel. The result shows that the boiling heat transfer will occur, especially in the high-temperature area. Analysis shows that the improved model is reliable and its precision is increased. Finally, the perturbation method is employed to investigate the relatively important inputs as the complex nonlinear function with a lot of output data and input data produced by the improved model. The relative effects of different parameters such as EGR, injection mass, injection timing, compression ratio, inlet air pressure, fuel inject... [more]

This article introduces a novel laboratory-scale process for the electrochemical synthesis of hydrogen peroxide (H2O2). The process aims at an energy-efficient, decentralized production, and a mathematical optimization of it is presented. A dynamic, zero-dimensional mathematical model of the reactor is set up in Aspen custom modeler®. The proposed model constitutes a reasonable compromise between complexity and convergence. After thoroughly determining the reaction kinetics by adjustment to experimental data, the reactor unit is embedded in an Aspen Plus® flowsheet in order to investigate its interaction with other unit operations. The downstream contains another custom module for membrane distillation. Electricity appears as a resource in the process, and optimization shows that it reaches product purities of up to 3 wt.-%. Both the process optimization and the adjustment of the reaction kinetics are treated as multi-criteria optimization (MCO) problems.

An absorption air-conditioning system is a good choice for green buildings. It has the superiority in the utilization of renewable energy and the refrigerant is environment-friendly. However, the performance of the traditional absorption system has been restricted by the energy waste in the thermal regeneration process. Capacitive deionization (CDI) regeneration is proposed as a potential method to improve system efficiency. In the new method-based air-conditioning system, strong absorbent solutions and pure water are acquired with the joint work of two CDI units. Nevertheless, the practical CDI device is composed of a lot of CDI units, which is quite different from the theoretical model. To reveal the performance of multiple CDI units, the model of the double/multi-stage CDI system has been developed. Analysis has been made to expose the influence of some key parameters. The results show the double-stage system has better performance than the single-stage system under certain conditio... [more]

This study aimed to improve the adsorption capacity of activated carbon (AC) towards naphthalene (NAP) in aqueous solutions. Starch-based AC (SAC) and pulverized coal-based AC (PCAC) were prepared in a one-pot procedure by activation with oleic acid and KOH under microwave heating. Brunauer−Emmett−Teller (BET) specific surface areas reached 725.0 and 912.9 m2/g for in situ modified SAC (O-SAC1) and PCAC (O-PCAC1), respectively. π−π bond, H-bond, and hydrophobic effects were directly involved in the NAP adsorption process. Batch adsorption data were well fitted by pseudo-second order kinetics and the Freundlich isotherm model. As compared to ACs prepared with only KOH activation, NAP adsorption capacities of PCAC and SAC prepared by the one-pot method increased by 16.9% and 13.7%, respectively. Influences of varying factors were investigated in column adsorption of NAP using O-SAC1 and O-PCAC1. Based on breakthrough curves analysis, the larger column height (H), lower flow rate (Q0), an... [more]

A critical review on the synthesis, characterization, and modeling of polymer grafting is presented. Although the motivation stemmed from grafting synthetic polymers onto lignocellulosic biopolymers, a comprehensive overview is also provided on the chemical grafting, characterization, and processing of grafted materials of different types, including synthetic backbones. Although polymer grafting has been studied for many decades—and so has the modeling of polymer branching and crosslinking for that matter, thereby reaching a good level of understanding in order to describe existing branching/crosslinking systems—polymer grafting has remained behind in modeling efforts. Areas of opportunity for further study are suggested within this review.

The aim of this study was to investigate the influence of biomass micronization on energy production using a converted aircraft turbine AI-20. The test system was constructed in such a way to ensure continuous operation for a given period of time and was equipped in a chopper, a flail mill, and a micronizer. The turbine had the ability to produce energy from solid biomass and as well conventional fuels. The most energy was obtained from absolutely dry sunflower husk (17.27 MJ/kg) and the least from Poplar (7.82 MJ/kg). Miscanthus, wheat straw, and hay (approximately 17 MJ/kg) showed high values of energy production. In addition, the thermal decomposition of wheat straw at 350 and 450 °C was studied using the Py-GC/MS technique in a helium atmosphere to determine the gaseous compounds formed during biomass gasification under anaerobic conditions. The results obtained indicate the formation of compounds classified as phenols (vanillin, hydroxymethylfurfural).

More than 1.2 billion kW wind and solar power generation will be integrated in China by 2030. The new provincial renewable portfolio standard, officially implemented in 2020, establishes an efficient bridge between rapid capacity growth and limited accommodation capability. A data-driven prospect analysis framework was proposed to evaluate the activated potential under two kinds of nearby accommodation approaches and to explore the completion prospect of this new obligated quota from provincial levels. Empirical results illustrate diverse prospects across regions. Particularly, it is hard for two kinds of provinces to complete their obligated quotas merely via the single nearby accommodation approach: The first one is close to renewable energy resources but lacks flexible peak regulation capability in Northeast and Northwest China, and the other is close to the nationwide load center but lacks nearby integration from renewables in Southeast, North, and Middle China. Therefore, the path... [more]

Enzymatic biodiesel production has attracted tremendous interest due to its well-recognized advantages. However, high enzyme costs limit the application of enzymatic processes in industrial production. In the past decade, great improvements have been achieved in the lab and the industrial scale, and the production cost of the enzymatic process has been reduced significantly, which has led to it being economically competitive compared to the chemical process. This paper summarizes the progress achieved in enzymatic biodiesel research and commercialization, including reducing enzyme cost, expanding low-quality raw materials, and novel reactor designs. The advantages and disadvantages of different enzymatic processes are also compared.

The solubility in triple water-salt systems containing NdCl3, PrCl3, YCl3, TbCl3 chlorides, and water-soluble fullerenol C60(OH)24 at 25 °C was studied by isothermal saturation in ampoules. The analysis for the content of rare earth elements was carried out by atomic absorption spectroscopy, for the content of fullerenol—by electronic spectrophotometry. The solubility diagrams in all four ternary systems are simple eutonic, both consisting of two branches, corresponding to the crystallization of fullerenol crystal-hydrate and rare earth chloride crystal-hydrates, and containing one nonvariant point corresponding to the saturation of both solid phases. On the long branches of C60(OH)24*18H2O crystallization, a C60(OH)24 decreases by more than 2 orders of magnitude compared to the solubility of fullerenol in pure water (salting-out effect). On very short branches of crystallization of NdCl3*6H2O, PrCl3*7H2O, YCl3*6H2O, and TbCl3*6H2O, the salting-in effect is clearly observed, and the so... [more]

Gasification is a promising technology for the conversion of mixed solid waste like refuse-derived fuel (RDF) and municipal solid waste (MSW) into a valuable gas consisting of H2, CO, CH4 and CO2. This work aims to identify the basic challenges of a single-stage batch gasification system related to tar and wax content in the producer gas. RDF was first gasified in a simple semi-batch laboratory-scale gasification reactor. A significant yield of tars and waxes was received in the produced gas. Waxes were analyzed using gas chromatography-mass spectrometry (GC-MS) and nuclear magnetic resonance (NMR) spectrometry. These analyses indicated the presence of polyethylene and polypropylene chains. The maximum content of H2 and CO was measured 500 sec after the start of the process. In a second series of experiments, a secondary catalytic stage with an Ni-doped clay catalyst was installed. In the two-stage catalytic process, no waxes were captured in isopropanol and the total tar content decre... [more]

Energy generation and its utilization is bound to increase in the following years resulting in accelerating depletion of fossil fuels, and consequently, undeniable damages to our environment. Over the past decade, despite significant efforts in renewable energy realization and developments for electricity generation, carbon dioxide emissions have been increasing rapidly. This is due to the fact that there is a need to go beyond the power sector and target energy generation in an integrated manner. In this regard, energy systems integration is a concept that looks into how different energy systems, or forms, can connect together in order to provide value for consumers and producers. Cogeneration and trigeneration are the two most well established technologies that are capable of producing two or three different forms of energy simultaneously within a single system. Integrated energy systems make for a very strong proposition since it results in energy saving, fuel diversification, and s... [more]

An indirect evaporative cooling system combining with thermoelectric cooling technology (i.e., TIEC system) is proposed, in which a counter-flow plate-fin indirect evaporative cooler is inserted with thermoelectric cooling (i.e., TEC) modules. In hot and humid climate, condensation may occur on the dry channel surface of the cooler. For the TIEC system, with the aid of TEC technology, the surface temperature of the dry channel can be much lower than that of a traditional indirect evaporative cooler, thus, the condensation from the primary air is more likely to take place. A numerical model of this novel TIEC system is developed with specifically taking condensation from primary air into account. Detailed performance analysis of the TIEC system is carried out. Analytical results found that the condensation from primary air reduces the dew point effectiveness by up to 45.0% by weakening the sensible heat transfer but increases the coefficient of performance by up to 62.2% by increasing t... [more]

Industrial hydraulic turbines, a kind of small-scaled turbine in a more compact and flexible application, are frequently used in hydrogen cracking, synthesis ammonia, and circulating water field. Besides the energy recovery efficiency, the working stability at variable speed situations is a critical issue, since its rotation speed changes with the flow parameters of the upstream. In this paper, a conventional turbine was numerically investigated under three different rotation speeds and its best efficiency points (BEPs). The velocity profiles, blade load, pressure fluctuation, and vibration features were discussed to form a comprehensive evaluation of turbine stability. The numerical results were validated through turbine external characteristic and vibration tests. The results indicate that the pressure pulsation and vibrations increase when it deviates from the rated rotation speed, but the relatively low flowrate point behaves better than the large point in the aspect of turbine sta... [more]

-Octanol, as an oxygenated fuel, is considered as one of the most promising alternative fuels, owing to advantages such as its low hygroscopic nature, high cetane number, and high energy content. However, the introduction of n-octanol leads to a higher viscosity and latent heat of evaporation (LHOE), affecting the combustion and emission performances of compression ignition (CI) engines. This study sheds light on the effect of injection pressures (IPs, ranging from 60 to 160 MPa) on the combustion and emission performances of a turbocharged CI engine, in conjunction with n-octanol/diesel blends. According to the proportion of oxygen content, the test fuels contain pure diesel (N0), N2.5 (2.5% oxygen content in the blending fuels), and N5 (5% oxygen content in the blending fuels). The results indicate that the blending fuels have little influence on the in-cylinder pressure, ignition delay (ID), and CA50, but they improve the brake thermal efficiency (BTE). In terms of emissions, with t... [more]

This Special Issue on “Process Modeling in Pyrometallurgical Engineering” consists of 39 articles, including two review papers, and covers a wide range of topics related to process development and analysis based on modeling in ironmaking, steelmaking, flash smelting, casting, rolling operations, etc [...]