Gas migration through fresh and hardened cement slurry is an ongoing problem in the oil industry. In order to eliminate this unfavourable phenomenon, research is being conducted on new compositions of slurries for gas wells. The article presents the results of research for slurries with low and high resistance to gas migration. The proper selection of the quantity and quality of components makes it possible to design slurry with the required static structural strength values. In addition, the cement sheath of such anti-migration slurry has low porosity and a very low proportion of large pore spaces. Additionally, the mechanical parameters do not decrease during long-term deposition in borehole-like conditions. By obtaining these results, it was possible to design slurry whose cement sheath has high corrosion resistance. The new slurry has a lower water-cement ratio. Additionally, GS anti-migration copolymer, anti-filter additive and latex are used. The presence of n-SiO2 aqueous soluti... [more]

The most relevant electrolytes used in commercial electrical double layer capacitors (EDLCs) are based on non-aqueous solvents as acetonitrile (ACN) and propylene carbonate (PC). However, these solvents are synthesized from non-renewable fossil feedstocks, making it desirable to develop more sustainable alternatives. To address this issue, in this work lactic acid was used to synthesize a panel of substances with small structural variation. The investigated products belong to the chemical family of ketals, and among them the 5-methyl-1,3-dioxolan-4-one (LA-H,H) was found to be the most suitable to prepare electrolytic solutions. Therefore, LA-H,H was combined with triethylmethylammonium tetrafluoroborate (TEMABF4), and analyzed in symmetrical EDLC. This electrolyte was thoroughly characterized by cyclic voltammetry, galvanostatic cycles and electrochemical impedance spectroscopy (EIS), disclosing competitive performances compared to PC-based electrolyte. The EDLC with LA-H,H/TEMABF4 di... [more]

The process and energy intensifications for the synthesis of glycerol carbonate (GC) from glycerol and dimethyl carbonate (DMC) using an eggshell-derived CaO heterogeneous catalyst were investigated. The transesterification reaction between glycerol and DMC was typically limited by mass transfer because of the immiscible nature of the reactants. By varying the stirring speed, it was observed that the mass transfer limitation could be neglected at 800 rpm. The presence of the CaO solid catalyst made the mass transport-limited reaction process more prominent. Mass transfer intensification using a simple kitchen countertop blender as an alternative to overcome the external mass transfer limitation of a typical magnetic stirrer was demonstrated. A lower amount of the catalyst and a shorter reaction time were required to achieve 93% glycerol conversion or 91% GC yield, and the turnover frequency (TOF) increased almost 5 times from 1.5 to 7.2 min−1 when using a conventional magnetic stirrer... [more]

This study examined the economy-wide effects of reallocating the biofuel subsidy to invest in transportation using a recursive dynamics computable general equilibrium model. The constructed model consists of 35 sectors, 42 commodities, and 3 institutions (household, government, and the rest of the world). Three scenarios were simulated. In the first scenario, the subsidy of gasohol and biodiesel is completely removed, whereas, in the second and third scenarios, half of the removed subsidy is reallocated to finance investment in road freight transportation and road public transportation. The simulation results show that reallocating the biofuel subsidy to invest in road public transportation can lead to the highest long-term economic growth and has the lowest impact on the consumer price index (CPI). All findings suggest that policymakers should maintain continuous investment in transportation and prioritize this investment policy over the fuel price distortion scheme.

Wind energy has seen an increase of almost 500 GW of installed wind power over the past decade. Renewable energy technologies have, over the years, been striving to develop in relation to capacity and size and, simultaneously, though with less focus on, the consequences and challenges that arise when the products achieve end-of-life (EoL). The lack of knowledge and possibilities for the recycling of fiber composites and, thus, the handling of EoL wind turbine blades (WTBs) has created great environmental frustrations. At present, the frustrations surrounding the handling are based on the fact that the most commonly used disposal method is via landfills. No recycling or energy/material recovery is achieved here, making it the least advantageous solution seen from the European Waste Commission’s perspective. The purpose of this research was thus to investigate the current recycling methods and to categorize them based on the waste materials. The opportunities were compared based on proce... [more]

A clearance gap (CG) between guide vanes (GVs) and facing plates exists at both ends of a Francis turbine and allows the opening angle to be adjusted for varying operating conditions. Leakage flow is induced through this gap due to the pressure difference between the two sides of the guide vanes. While some research works have used qualitative approaches to visualize and predict the strength of a leakage vortex (LV), this paper presents a method for quantifying vortices along a trajectory. In this paper, a prototype high-head Francis runner with specific speed of 85.4 is considered as a reference case. A systematic investigation across both space and time is carried out, i.e., analysis of the spatial temporal progression of LV for three operating conditions. While travelling from the CG to runner leading edge, LV evolution and trajectory data are observed and the values of vorticity and turbulent kinetic energy are calculated for the LV trajectory. Frequency spectrum analyses of pressu... [more]

This paper proposes a new technique to engineer the Fin channel in vertical GaN FinFET toward a straight and smooth channel sidewall. Consequently, the GaN wet etching in the TMAH solution is detailed; we found that the m-GaN plane has lower surface roughness than crystallographic planes with other orientations, including the a-GaN plane. The grooves and slope (Cuboids) at the channel base are also investigated. The agitation does not assist in Cuboid removal or crystallographic planes etching rate enhancement. Finally, the impact of UV light on m and a-GaN crystal plane etching rates in TMAH has been studied with and without UV light. Accordingly, it is found that the m-GaN plane etching rate is enhanced from 0.69 to 1.09 nm/min with UV light; in the case of a-GaN plane etching, UV light enhances the etching rate from 2.94 to 4.69 nm/min.

The installation of rooftop PV systems in residential buildings and dwellings has increased rapidly in the past decade, and these systems have become a major source of renewable energy in many countries. This paper presents a new method of estimating the potential of rooftop PV systems to meet energy demands in residential districts by introducing a roof suitability factor. The method of assessment is based on an online tool called SunSPot, which uses a solar radiation heat map layer of building roofs and the PVSYST solar performance software. A sample of 400 houses from four suburbs considered in the Sydney City Council 2030 sustainability plan was selected to conduct the performance analysis of rooftop PV systems and develop a formula that can estimate the suburban annual energy production. The results show that if the dwelling roofs in residential suburbs could be covered by PV arrays it would produce enough electricity to exceed the local electricity demand and, in some suburbs, a... [more]

Direct steam generation is a promising alternative to conventional heat transfer fluids for solar thermal power plants using linear concentrators because water and steam do not have thermal and chemical stability problems. The novelty of this study, an energy and exergy (2E) analysis, was that it was performed on several configurations of a conceptual direct steam generation solar power plant with optimized Fresnel reflectors in Agua Prieta, Mexico coupled with a regenerative steam Rankine power cycle to quantify their efficiency and establish a reference for future implementation of this technology in concentrated solar power plants in Mexico. The thermal model was assumed to be a 1D steady-state flow and validated against results in the literature. It was then applied directly to a case study to determine the size of the solar field. The design point was the lowest solar irradiance day, and evaluating the solar multiple with the highest solar irradiance, taking care not to oversize t... [more]

The development of a one-dimensional (1D) phenomenological model for biomass gasification in downdraft reactors is presented in this study; the model was developed with the aim of highlighting the main advantages and limits related to feedstocks that are different from woodchip, such as hydro-char derived from the hydrothermal carbonization of green waste, or a mix of olive pomace and sawdust. An experimental validation of the model is performed. The numerically evaluated temperature evolution along the reactor gasifier is found to be in agreement with locally measured values for all the considered biomasses. The model captures the pressure drop along the reactor axis, despite an underestimation with respect to the performed measurements. The producer gas composition resulting from the numerical model at the exit section is in quite good agreement with gas-chromatograph analyses (12% maximum error for CO and CO2 species), although the model predicts lower methane and hydrogen content i... [more]

The article presents the results of research on the vibroacoustic response of internal combustion engines mounted in a vehicle. The vehicles studied belong to popular models, which became available in successive versions. Each group included vehicles of the same model of an older generation (equipped with a naturally aspirated engine) and of a newer generation, including downsized (and turbocharged) engines. Tests in each group were carried out under repeatable conditions on a chassis-load dynamometer. The vibrations were measured using single-axis accelerometers mounted on the steering wheel, engine, and driver’s head restraint mounting. The primary purpose of the study was to verify whether the new generations of vehicles equipped with additional high-speed elements (compressors) generate additional harmonics (especially those within the range potentially affecting travel comfort and human health) and whether there are significant changes in the distribution of spectral power density... [more]

The subject of the article is a new method that I have developed for calculating a multi-asset break-even for multi-assortment production, extended by a percentage threshold and a current sales ratio (which was missing in previously published methods). The percentage threshold provides unambiguous information about the economic health of a company. As a result, it became possible to use it in practice to evaluate the activities of economic entities (mines) and to perform modelling and optimisation of production plans based on different variants of customer demand scenarios. The publication addresses the complexity of the problem of determining the break-even in multi-assortment production. Moreover, it discusses the practical limitations of previous methods and demonstrates the usefulness of the proposed method on the example of hard coal mines.

In low-voltage grids with a wide spread of domestic and/or small commercial consumers, mostly single-phase, problems can appear due to unbalanced power consumption between the different phases. These problems are mainly caused due to voltage unbalances between phases and the increase in distribution losses. This phenomenon occurs more frequently at the end of highly radial grids and can be stressed by the installation of renewable generators next to the consumers. Amongst the various techniques that have been proposed to solve this problem, this article explores the use of a D-STATCOM, presenting and testing a new method for the optimal location of this type of D-FACT. The developed method starts from a detailed analysis of the existing voltage unbalances in a distribution network and identifies the optimal location of the D-STATCOM (i.e., the one that reduces these unbalances while reducing energy losses). The developed method has been successfully tested for one year at four real Eur... [more]

Liquid fuels obtained in refining crude oil are one of the most important energies in economic activity. The domestic wholesale market for liquid fuels is of decisive importance for price formation in the national economy. The noncompetitive behavior of the market players at this level of the distribution chain can significantly affect all downstream price levels and the producer−consumer surplus balance. Therefore, the competitiveness of this market should be screened and assessed regularly, especially when significant external factors change. This article attempts to evaluate the impact of structural changes on the global market of crude oil and energy products after the outbreak of the COVID-19 pandemic on the competitiveness of the wholesale fuel market in Poland. Using asymmetry of the reaction of product prices to changes in the prices of inputs as a marker of noncompetitive behavior and the NARDL model as a test specification, the price paths of market players before and after t... [more]

Turbulent combustion modelling in internal combustion engines (ICEs) is a challenging task. It is commonly synthetized by incorporating the interaction between chemical reactions and turbulent eddies into a unique term, namely turbulent flame speed sT. The task is very complex considering the variety of turbulent and chemical scales resulting from engine load/speed variations. In this scenario, advanced turbulent combustion models are asked to predict accurate burn rates under a wide range of turbulence−flame interaction regimes. The framework is further complicated by the difficulty in unambiguously evaluating in-cylinder turbulence and by the poor coherence of turbulent flame speed (sT) measurements in the literature. Finally, the simulated sT from combustion models is found to be rarely assessed in a rigorous manner. A methodology is presented to objectively measure the simulated sT by a generic combustion model over a range of engine-relevant combustion regimes, from Da = 0.5 to Da... [more]

The main goal of setting energy efficiency priorities is to find ways to reduce energy consumption without harming consumers and the environment. The renovation of buildings can be considered one of the main aspects of energy efficiency in the European Union (EU). In the EU, only 5% of the renovation projects have been able to yield energy-saving at the deep renovation level. No other study has thus far ranked the EU member states according to achieved results in terms of increased usage in renewable sources, a decrease in energy usage and import, and reduction in harmful gas emissions due to energy usage. The main purpose of this article is to perform a comparative analysis of EU economies according to selected indicators related to the usage of renewable resources, energy efficiency, and emissions of harmful gasses as a result of energy usage. The methodological contribution of our study is related to developing a complex and robust research method for investment efficiency assessmen... [more]

An improved high step-down DC-DC converter for charging the batteries in an electric vehicle application is proposed in this paper. It adopts the topology of the conventional full-bridge converter, which has a coupled inductor current-doubler rectifier as the secondary side of the transformer. In addition, four power switches are driven using a phase-shifting technique. The proposed converter can achieve a high step-down voltage with low-voltage stress on the rectifier diodes. In addition, the coupled inductor current-doubler rectifier of the secondary side can reduce the ripple current and losses of the secondary side to achieve high efficiency. Furthermore, the proposed converter can overcome the drawbacks of the conventional full-bridge converter, such as switching loss caused by high switching frequency, duty-cycle loss, voltage stress, and numerous components, and can increase the efficiency with the soft-switching technique. A 600 W laboratory prototype of the proposed converter... [more]

Community renewable energy (CRE) has recently been proposed as one of the effective policy tools to make a community sustainable and to strengthen this association. CRE is, however, not widespread yet in Thailand, and evidence-based research on CRE in the country is rather scarce. This paper aims to investigate the characteristics of CRE in Thailand to identify the key factors affecting its implementation. Data were collected through semi-structured interviews and document analysis for 26 active CRE projects in Thailand. Results show that the characteristics of CRE in Thailand are rooted in the geographical location of a community. A legal structure was created from a pre-existing group to implement a CRE project. The primary motivation for implementing CRE is sustainable development of a community. We examined essential factors separated into two groups—internal and external factors—in reference to CRE in developed nations. We highlight several issues concerning the further developmen... [more]

Based on threshold regression models, this paper analyzes the effect of economic growth on energy intensity by using panel data from 21 developed countries from 1996 to 2015. Results show that a 1% increase in GDP per capita can lead to a 0.62−0.78% reduction in energy intensity, implying economic growth can significantly reduce energy intensity. The extent of the reduction in energy intensity varies depending on the economic development stages represented by key influencing factors including energy mix in consumption, urbanization, industrial structure, and technological progress. Specifically, the reduction in energy intensity due to economic growth can be enhanced with relatively more renewable energy consumption and more urban population until a threshold point, where the enhancement disappears. On the other hand, the extent of the energy intensity reduction due to economic growth can be weakened with relatively more tertiary industry activities and more research and development (R... [more]

This paper provides a theoretical framework to explore how the support policies for renewable energies can promote rent-seeking incentives in private firms. We develop a political economy of rent-seeking that considers the link between the regulatory decisions of political agents and the potential scope of socially wasteful pursuits. We argue that systematic public support schemes bring rent-seeking as a perception shared by entrepreneurs that influencing political allocations of resources is an essential and potentially preferable source of private profit than other for-profit economic avenues. As evidence of our claims, the framework is applied to the case of Spain to illustrate the economic effects of support policies on the production and distribution of renewable energy. We find rent-seeking behavior in Spain’s renewable energy industry, and precisely that: (i) political regulations have induced market concentration and rent-seeking in renewable energy firms, (ii) these firms have... [more]

In this study, carbon nanotubes (CNTs) were used as cathodes for lithium−oxygen (Li−O2) batteries to confirm the effect of oxygen functional groups present on the CNT surface on Li−O2 battery performance. A coating technology using atomic layer deposition was introduced to remove the oxygen functional groups present on the CNT surface, and ZnO without catalytic properties was adopted as a coating material to exclude the effect of catalytic reaction. An acid treatment process (H2SO4:HNO3 = 3:1) was conducted to increase the oxygen functional groups of the existing CNTs. Therefore, it was confirmed that ZnO@CNT with reduced oxygen functional groups lowered the charging overpotential by approximately 230 mV and increased the yield of Li2O2, a discharge product, by approximately 13%. Hence, we can conclude that the ZnO@CNT is suitable as a cathode material for Li−O2 batteries.

Methanolysis of vegetable oils in the presence of homogeneous catalysts remains the most important process for producing biodiesel. However, there is still a lack of accurate description of the reaction kinetics. This is in part due to the complexity of the reacting system in which a large number of interconnected reactions take place simultaneously. In this work, attention is focused on the biphasic character of the reaction medium, formed by two immiscible liquid phases. The behavior of the phases is investigated regarding their physicochemical properties, mainly density and mutual solubility of the components, as well as composition. In addition, two kinetic models with different level of complexity regarding the biphasic character of the reaction medium have been developed. It has been found that a heterogeneous model considering the presence of the two phases and the distribution of the several compounds between them is indispensable to get a good description of the process in ter... [more]

In response to the uncertainty of extreme climate change, energy consumption structure has been actively adjusted globally. Based on panel data of 101 countries or regions from 2006 to 2019, a panel data model with fixed effects is used to analyze the heterogeneous impacts of extreme climate risks on global consumption transition. The results show that extreme climate change has promoted the transition of the energy structure, reduced the consumption of fossil energy, and increased the consumption of renewable energy. Meanwhile, there are heterogeneous impacts of extreme climate change risks on the energy transition when different countries suffering from extreme weather conditions. Areas with high levels of economic development and coastal countries are more inclined to respond to climate change through energy transition. It is further confirmed that, under the impact of business cycle and oil price fluctuations, economic recession and falling oil prices will strengthen the correlatio... [more]

To ensure optimum working conditions for lithium-ion batteries, a numerical study is carried out for three-dimensional temperature distribution of a battery liquid cooling system in this work. The effect of channel size and inlet boundary conditions are evaluated on the temperature field of the battery modules. Based on the thermal behavior of discharging battery obtained experimental measurements, two temperature control strategies are proposed and studied. The results show that the channel width of the cooling plates has a great influence on the maximum temperature in the battery module. It is also revealed that increasing inlet water flow rate can significantly improve the heat transfer capacity of the battery thermal management system, while the relationship between them is not proportional. Lowering the inlet temperature can reduce the maximum temperature predicted in the battery module significantly. However, this will also lead to additional energy consumed by the cooling system... [more]

For energy supply in the Arctic regions, hybrid systems should be designed and equipped to ensure a high level of renewable energy penetration. Energy systems located in remote Arctic areas may experience many peculiar challenges, for example, due to the limited transport options throughout the year and the lack of qualified on-site maintenance specialists. Reliable operation of such systems in harsh climatic conditions requires not only a standard control system but also an advanced system based on predictions concerning weather, wind, and ice accretion on the blades. To satisfy these requirements, the current work presents an advanced intelligent automatic control system. In the developed control system, the transformation, control, and distribution of energy are based on dynamic power redistribution, dynamic control of dump loads, and a bi-directional current transducer. The article shows the architecture of the advanced control system, presents the results of field studies under th... [more]