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Records Added in March 2023
Records added in March 2023
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9944. LAPSE:2023.16251
A Proportional Digital Controller to Monitor Load Variation in Wind Turbine Systems
March 3, 2023 (v1)
Subject: Energy Systems
Keywords: blade system, load variation, monitoring, wind turbine
Monitoring the variation of the loading blades is fundamental due to its importance in the behavior of the wind turbine system. Blade performance can be affected by different loads that alter energy conversion efficiency and cause potential safety hazards. An example of this is icing on the blades. Therefore, the main objective of this work is to propose a proportional digital controller capable of detecting load variations in wind turbine blades together with a fault detection method. An experimental platform is then built to experimentally validate the main contribution of the article. This platform employs an automotive throttle device as a blade system emulator of a wind turbine pitch system. In addition, a statistical fault detection algorithm is established based on the point change methodology. Experimental data support our approach.
9945. LAPSE:2023.16250
Multiobjective Optimal Control of Wind Turbines: A Survey on Methods and Recommendations for the Implementation
March 3, 2023 (v1)
Subject: Energy Systems
Keywords: controller tuning, multiobjective optimal control, multiobjective optimization, multiobjective optimization algorithms, objective functions, wind turbines control
Advanced control system design for large wind turbines is becoming increasingly complex, and high-level optimization techniques are receiving particular attention as an instrument to fulfil this significant degree of design requirements. Multiobjective optimal (MOO) control, in particular, is today a popular methodology for achieving a control system that conciliates multiple design objectives that may typically be incompatible. Multiobjective optimization was a matter of theoretical study for a long time, particularly in the areas of game theory and operations research. Nevertheless, the discipline experienced remarkable progress and multiple advances over the last two decades. Thus, many high-complexity optimization algorithms are currently accessible to address current control problems in systems engineering. On the other hand, utilizing such methods is not straightforward and requires a long period of trying and searching for, among other aspects, start parameters, adequate objecti... [more]
9946. LAPSE:2023.16249
Periodic CO2 Injection for Improved Storage Capacity and Pressure Management under Intermittent CO2 Supply
March 3, 2023 (v1)
Subject: Energy Systems
Keywords: carbon capture and storage, Carbon Dioxide, cyclic and periodic injection, intermittent supply, pressure management, saline aquifer, storage capacity
Storing CO2 in geological formations is an important component of reducing greenhouse gases emissions. The Carbon Capture and Storage (CCS) industry is now in its establishing phase, and if successful, massive storage volumes would be needed. It will hence be important to utilize each storage site to its maximum, without challenging the formation integrity. For different reasons, supply of CO2 to the injection sites may be periodical or unstable, often considered as a risk element reducing the overall efficiency and economics of CCS projects. In this paper we present outcomes of investigations focusing on a variety of positive aspects of periodic CO2 injection, including pressure management and storage capacity, also highlighting reservoir monitoring opportunities. A feasibility study of periodic injection into an infinite saline aquifer using a mechanistic reservoir model has indicated significant improvement in storage capacity compared to continuous injection. The reservoir pressure... [more]
9947. LAPSE:2023.16248
A Low-Cost Monitoring Platform and Visual Interface to Analyse Thermal Comfort in Smart Building Applications Using a Citizen−Scientist Strategy
March 3, 2023 (v1)
Subject: Environment
Keywords: citizen science, IoT, mobile app, PMV, remote monitoring, thermal comfort
Smart building issues are critical for current energy and comfort managing aspects in built environments. Nevertheless, the diffusion of smart monitoring solutions via user-friendly graphical interfaces is still an ongoing issue subject to the need to diffuse a smart building culture and a low-cost series of solutions. This paper proposes a new low-cost IoT sensor network, exploiting Raspberry Pi and Arduino platforms, for collecting real-time data and evaluating specific thermal comfort indicators (PMV and PPD). The overall architecture was accordingly designed, including the hardware setup, the back-end and the Android user interface. Eventually, three distinct prototyping platforms were deployed for initial testing of the general system, and we analysed the obtained results for different building typologies and seasonal periods, based on collected data and users’ preferences. This work is part of a large educational and citizen science activity.
9948. LAPSE:2023.16247
Adaptive Laboratory Evolution for Multistress Tolerance, including Fermentability at High Glucose Concentrations in Thermotolerant Candida tropicalis
March 3, 2023 (v1)
Subject: Biosystems
Keywords: adaptive laboratory evolution, Candida tropicalis, fermentability at high glucose concentrations, fermenting yeast, multistress tolerance
, a xylose-fermenting yeast, has the potential for converting cellulosic biomass to ethanol. Thermotolerant C. tropicalis X-17, which was isolated in Laos, was subjected to repetitive long-term cultivation with a gradual increase in temperature (RLCGT) in the presence of a high concentration of glucose, which exposed cells to various stresses in addition to the high concentration of glucose and high temperatures. The resultant adapted strain demonstrated increased tolerance to ethanol, furfural and hydroxymethylfurfural at high temperatures and displayed improvement in fermentation ability at high glucose concentrations and xylose-fermenting ability. Transcriptome analysis revealed the up-regulation of a gene for a glucose transporter of the major facilitator superfamily and genes for stress response and cell wall proteins. Additionally, hydropathy analysis revealed that three genes for putative membrane proteins with multiple membrane-spanning segments were also up-regulated. From the... [more]
9949. LAPSE:2023.16246
Fly Ash as an Ingredient in the Contaminated Soil Stabilization Process
March 3, 2023 (v1)
Subject: Environment
Keywords: encapsulation, hazardous waste, physicochemical stabilization, remediation, VOC
Fly ash is the main by-product of coal combustion characterized by a large specific surface area. In addition to oxides, it also contains unburned coal and trace elements. This study aimed to investigate the possibility of using fly ash from pit-coal combustion (CFA) for the treatment of benzene-contaminated soil (S). The CFA was used as a mixture with Portland cement (PC) (70% PC + 30% CFA). The soil was treated with a PC-CFA mixture in amounts of 40, 60, and 80% of soil mass. During the process, the concentration of benzene was monitored with the flame-ionization detector. Produced monoliths (S+(PC-CFA)x) were tested for compressive strength and capillary water absorption. The experiment confirmed that the PC-CFA mixture limited benzene emission. The highest reduction in benzene concentration (34−39%) was observed for samples treated with the PC-CFA mixture in an amount of 80% (S+(PC-CFA)80). The average compressive strength of monoliths S+(PC-CFA)40, S+(PC-CFA)60, and S+(PC-CFA)80 w... [more]
9950. LAPSE:2023.16245
Energy Security in Danger? A Comparative Analysis of Oil and Copper Supply
March 3, 2023 (v1)
Subject: Energy Systems
Keywords: copper, crude oil, energy security, GARCH, renewable energy sources (RES)
This study aims to examine energy security in terms of crude oil and copper supply. While oil remains the leading energy commodity globally, copper is crucial for many new technologies, foremost for RES. Therefore, both oil and copper are extremely important for current and future energy security. This article contains a bivariate methodological approach to a comparative analysis of oil and copper supply: determining supply security with an Index of security of supply, and examines price stability with generalized autoregressive conditional heteroscedasticity (GARCH) models. This research provides evidence that there are many differences but also significant similarities between these two completely different commodities in terms of both supply security and price stability. Facing the future for RES, significant demand may cause a threat to energy security on a previously unknown scale. Therefore this instability, both supply- and price-related, appears to be the main threat to future... [more]
9951. LAPSE:2023.16244
Evaluation of Prediction Models for the Physical Properties in Fire-Flooding Exhaust Reinjection Process
March 3, 2023 (v1)
Subject: Process Design
Keywords: equations of state, fire-flooding exhaust, MAPE, physical properties, reinjection process
The reinjection of the fire-flooding exhaust is a novel disposal process for handling the exhaust produced by the in-situ combustion technology. For reasonable process design and safe operation, it is of great significance to select an optimum property calculation method for the fire-flooding exhaust. However, due to the compositional particularity and the wide range of operating parameters during reinjection, the state equations in predicting the exhaust properties over the wide range of operating parameters have not been studied clearly yet. Hence, this paper investigates the applicability of several commonly-used equations of state, including the Soave−Redlich−Kwong equation, Peng−Robinson equation, Lee−Kesler−Plocker equation, Benedict−Webb−Rubin−Starling equation, and GERG-2008 equations. Employing Aspen Plus software, the gas densities, compressibility factors, volumetric coefficients, and dew points for five exhaust compositions are calculated. In comparison with the experimenta... [more]
9952. LAPSE:2023.16243
Integrated Estimation of a Cyber-Physical System’s Sustainability
March 3, 2023 (v1)
Subject: Environment
Keywords: cyber-physical system, effectiveness, integrated estimation, key-point indicators, Sustainability
Currently, in conditions of Industry 4.0, the use of cyber-physical systems in various fields is becoming widespread. This article is devoted to the problem of estimating CPS sustainability in the context of modern challenges faced by decision makers and IT developers in order to ensure effective proactive business process management using this innovative technology. The purpose of the research is to propose and substantiate a methodology for estimating CPS sustainability to ensure the reliability and strength of its elements, their interrelationships and interaction, as well as the effective functioning and development of this system in conditions of high dynamism and uncertainty of the external environment. In this study, we used methods of integral evaluation, synthesis, expert assessments, dynamic analysis, and systematic approach, and coined the term ‘CPS sustainability’. Our study showed that negative risks, external and internal threats may have a significant adverse impact on C... [more]
9953. LAPSE:2023.16242
Development of Combined Load Spectra for Offshore Structures Subjected to Wind, Wave, and Ice Loading
March 3, 2023 (v1)
Subject: Energy Systems
Keywords: arctic conditions, damage model, ice-induced vibrations, low-temperature fatigue, Markov chain method, offshore wind turbine support structures, omission level, rainflow counting, stress-time sequence
Fixed offshore wind turbines continue to be developed for high latitude areas where not only wind and wave loads need to be considered but also moving sea ice. Current rules and regulations for the design of fixed offshore structures in ice-covered waters do not adequately consider the effects of ice loading and its stochastic nature on the fatigue life of the structure. Ice crushing on such structures results in ice-induced vibrations, which can be represented by loading the structure using a variable-amplitude loading (VAL) sequence. Typical offshore load spectra are developed for wave and wind loading. Thus, a combined VAL spectrum is developed for wind, wave, and ice action. To this goal, numerical models are used to simulate the dynamic ice-, wind-, and wave-structure interaction. The stress time-history at an exemplarily selected critical point in an offshore wind energy monopile support structure is extracted from the model and translated into a VAL sequence, which can then be u... [more]
9954. LAPSE:2023.16241
Using Transfer Learning to Build Physics-Informed Machine Learning Models for Improved Wind Farm Monitoring
March 3, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: informed machine learning, performance monitoring, simulation-based neural networks, transfer learning
This paper introduces a novel, transfer-learning-based approach to include physics into data-driven normal behavior monitoring models which are used for detecting turbine anomalies. For this purpose, a normal behavior model is pretrained on a large simulation database and is recalibrated on the available SCADA data via transfer learning. For two methods, a feed-forward artificial neural network (ANN) and an autoencoder, it is investigated under which conditions it can be helpful to include simulations into SCADA-based monitoring systems. The results show that when only one month of SCADA data is available, both the prediction accuracy as well as the prediction robustness of an ANN are significantly improved by adding physics constraints from a pretrained model. As the autoencoder reconstructs the power from itself, it is already able to accurately model the normal behavior power. Therefore, including simulations into the model does not improve its prediction performance and robustness... [more]
9955. LAPSE:2023.16240
Preparation, Properties and Application of Gel Materials for Coal Gangue Control
March 3, 2023 (v1)
Subject: Materials
Keywords: acrylic acid, chitosan, coal gangue, gel–foam
In order to solve the problem of the spontaneous combustion of coal gangue, a coal gangue fire-extinguishing material of gel−foam was developed. The foaming agent was screened by the Waring blender method with varying foam amounts, and the superabsorbent foam stabilizer was synthesized by free radical polymerization. Moreover, the gel−foam was used in a spontaneous combustion of coal gangue mountain field practice. The results showed that when the mass fraction of sodium dodecyl sulfonate and coconut oil amide propyl betaine was 0.6% and 4:6, the foaming amount was as high as 1500 mL. When the mass ratio of chitosan to acrylic acid was 1:6, the neutralization degree was 80%, the cross-linking agent was 0.8%, and the initiator was 0.01%, the water absorption of the synthesized superabsorbent foam stabilizer reached 476 mL/g. The synthesized gel−foam was tested in a spontaneous combustion coal gangue hill in a certain area, and no reburning sign was found within one month.
9956. LAPSE:2023.16239
Critical Assessment of Feed-In Tariffs and Solar Photovoltaic Development in Vietnam
March 3, 2023 (v1)
Subject: Energy Policy
Keywords: feed-in tariffs, levelized cost of electricity, photovoltaic, solar policy, Vietnam
Vietnam became the world’s third largest market for solar photovoltaic energy in 2020. Especially after the Vietnamese government issued feed-in tariffs for grid-connected solar photovoltaic systems, the installed capacity of solar photovoltaic applications exploded in 2019. From studies carried out in the relevant literature, it can be said that support policies are highly important for the initial development of the renewable energy industry in most countries. This is especially true in emerging countries such as Vietnam. This paper reviews the feed-in tariffs issued and deployed in different regions of Vietnam for grid-connected solar photovoltaic applications. Moreover, the paper takes a closer look at the costs of electricity production from these systems in relation to the feed-in tariffs issued in Vietnam. The results show that the gap between the levelized cost of electricity and the feed-in tariff for solar photovoltaic electricity is relatively high, particularly in regions w... [more]
9957. LAPSE:2023.16238
Agent-Based Modelling of Urban District Energy System Decarbonisation—A Systematic Literature Review
March 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: agent-based modelling, agent-based simulation, district energy system, net-zero energy district, positive energy district, systematic literature review, urban energy system
There is an increased interest in the district-scale energy transition within interdisciplinary research community. Agent-based modelling presents a suitable approach to address variety of questions related to policies, technologies, processes, and the different stakeholder roles that can foster such transition. However, it is a largely complex and versatile methodology which hinders its broader uptake by researchers as well as improved results. This state-of-the-art review focuses on the application of agent-based modelling for exploring policy interventions that facilitate the decarbonisation (i.e., energy transition) of districts and neighbourhoods while considering stakeholders’ social characteristics and interactions. We systematically select and analyse peer-reviewed literature and discuss the key modelling aspects, such as model purpose, agents and decision-making logic, spatial and temporal aspects, and empirical grounding. The analysis reveals that the most established agent-b... [more]
9958. LAPSE:2023.16237
Analysis of Air Pollution around a CHP Plant: Real Measurements vs. Computer Simulations
March 3, 2023 (v1)
Subject: Environment
Keywords: 3D spatial analysis, air quality modeling, air quality monitoring, dispersion of pollutants, outdoor air quality, PM1.0, PM10, PM2.5, SO2, VOC
This study examines the concentrations of air pollution in the vicinity of a combined heat and power plant (CHP) and a communication route, using computer modeling of pollutant dispersion and spatial analysis based on real measurements in the city of Łódź, Poland, Europe. The research takes into account the concentrations of particulate matter (PM10, PM2.5, PM1.0) and gaseous pollutants (SO2 and VOC) in winter and summer. The spatial distribution of pollutants is discussed, including the presence of areas with increased accumulations of pollutants. Because atmospheric air has no natural boundaries, when analyzing any location, not only local sources of pollution, but also background pollution, should be analyzed. A clear difference was observed between the concentrations of pollutants in the summer and winter seasons, with significantly higher concentrations in the winter (heating) period. The impacts of road transport, individual heating systems, and combined heat and power plants wer... [more]
9959. LAPSE:2023.16236
Synthesis of V2O5/Single-Walled Carbon Nanotubes Integrated into Nanostructured Composites as Cathode Materials in High Performance Lithium-Ion Batteries
March 3, 2023 (v1)
Subject: Materials
Keywords: carbon nanotubes, hybrid cathodes, lithium-ion batteries, nanocomposite materials, vanadium pentoxide, xerogel
Vanadium pentoxide (V2O5)-anchored single-walled carbon nanotube (SWCNT) composites have been developed through a simple sol−gel process, followed by hydrothermal treatment. The resulting material is suitable for use in flexible ultra-high capacity electrode applications for lithium-ion batteries. The unique combination of V2O5 with 0.2 wt.% of SWCNT offers a highly conductive three-dimensional network. This ultimately alleviates the low lithium-ion intercalation seen in V2O5 itself and facilitates vanadium redox reactions. The integration of SWCNTs into the layered structure of V2O5 leads to a high specific capacity of 390 mAhg−1 at 0.1 C between 1.8 to 3.8 V, which is close to the theoretical capacity of V2O5 (443 mAhg−1). In recent research, most of the V2O5 with carbonaceous materials shows higher specific capacity but limited cyclability and poor rate capability. In this work, good cyclability with only 0.3% per cycle degradation during 200 cycles and enhanced rate capability of 1... [more]
9960. LAPSE:2023.16235
Evolution of Solar Energy in Chile: Residential Opportunities in Arica and Parinacota
March 3, 2023 (v1)
Subject: Energy Policy
Keywords: distributed generation, energy policy, solar energy
Chile has set itself to achieve Greenhouse Gas emission neutrality, with at least 70% of electricity coming from renewable energy sources by 2050. To this end, institutional and regulatory frameworks have been improved, resulting in significant progress in medium and large-scale projects. However, solar energy production at residential level and its surplus injection to all distribution networks has been very limited. This paper analyzes the evolution of the regulatory energy policies in Chile in order to contrast it with an economic evaluation of residential projects. The analysis focuses on the city of Arica, one of the highest potential regions in terms of solar energy within the country. There, a particularly low penetration of residential solar energy usage has been observed. Based on the current situation, projections are made for Arica in 2050, through the identification of barriers and opportunities on a residential scale development. According to some recommendations, there is... [more]
9961. LAPSE:2023.16234
Effects of Plateau Environment on Combustion and Emission Characteristics of a Plateau High-Pressure Common-Rail Diesel Engine with Different Blending Ratios of Biodiesel
March 3, 2023 (v1)
Subject: Environment
Keywords: biodiesel, combustion and emission characteristics, internal combustion engine, plateau environment
Taking a plateau high-pressure common-rail diesel engine as the research model, a model was established and simulated by AVL FIRE according to the structural parameters of a diesel engine. The combustion and emission characteristics of D, B20, and B50 diesel engines were simulated in the plateau atmospheric environment at 0 m, 1000 m, and 2000 m. The calculation results show that as the altitude increased, the peak in-cylinder pressure and the cumulative heat release of diesel decreased with different blending ratios. When the altitude increased by 1000 m, the cumulative heat release was reduced by about 5%. Furthermore, the emission trend of NO, soot, and CO was to first increase and then decrease. As the altitude increased, the mass fraction of NO emission decreased. As the altitude increased, the mass fractions of soot and CO increased. Additionally, when the altitude was 0 m and 1000 m, the maximum temperature, the mass fraction of OH, and the fuel−air ratio of B20 were higher and... [more]
9962. LAPSE:2023.16233
Sizing, Optimization, and Financial Analysis of a Green Hydrogen Refueling Station in Remote Regions
March 3, 2023 (v1)
Subject: Energy Systems
Keywords: economic analysis, FCEV, Fuel Cells, HRS, Hydrogen, hydrogen storage, Renewable and Sustainable Energy
Hydrogen (H2) can be a promising energy carrier for decarbonizing the economy and especially the transport sector, which is considered as one of the sectors with high carbon emissions due to the extensive use of fossil fuels. H2 is a nontoxic energy carrier that could replace fossil fuels. Fuel Cell Electric Vehicles (FCEVs) can decrease air pollution and reduce greenhouse gases when H2 is produced from Renewable Energy Sources (RES) and at the same time being accessible through a widespread network of Hydrogen Refueling Stations (HRSs). In this study, both the sizing of the equipment and financial analysis were performed for an HRS supplied with H2 from the excess electrical energy of a 10 MW wind park. The aim was to determine the optimum configuration of an HRS under the investigation of six different scenarios with various numbers of FCEVs and monthly demands, as well as ascertaining the economic viability of each examined scenario. The effect of the number of vehicles that the ins... [more]
9963. LAPSE:2023.16232
Assessing Feature Importance for Short-Term Prediction of Electricity Demand in Medium-Voltage Loads
March 3, 2023 (v1)
Subject: Energy Management
Keywords: artificial neural networks, feature assessment, intelligent distribution networks, phidelta diagrams, prediction of electricity consumption, smart grid
The design of new monitoring systems for intelligent distribution networks often requires both real-time measurements and pseudomeasurements to be processed. The former are obtained from smart meters, phasor measurement units and smart electronic devices, whereas the latter are predicted using appropriate algorithms—with the typical objective of forecasting the behaviour of power loads and generators. However, depending on the technique used for data encoding, the attempt at making predictions over a period of several days may trigger problems related to the high number of features. To contrast this issue, feature importance analysis becomes a tool of primary importance. This article is aimed at illustrating a technique devised to investigate the importance of features on data deemed relevant for predicting the next hour demand of aggregated, medium-voltage electrical loads. The same technique allows us to inspect the hidden layers of multilayer perceptrons entrusted with making the pr... [more]
9964. LAPSE:2023.16231
Thermodynamics and Kinetic Modeling of the ZnSO4·H2O Thermal Decomposition in the Presence of a Pd/Al2O3 Catalyst
March 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Pd catalyst, thermal decomposition kinetics, zinc sulfate
The sulfur−iodine thermochemical water-splitting cycle is a promising route proposed for hydrogen production. The decomposition temperature remains a challenge in the process. Catalysts, such as Pd supported on Al2O3, are being considered to decrease reaction temperatures. However, little is known regarding the kinetic behavior of such systems. In this work, zinc sulfate thermal decomposition was studied through non-isothermal thermogravimetric analysis to understand the effect of a catalyst within the sulfur−iodine reaction system context. The findings of this analysis were also related to a thermodynamic assessment. It was observed that the presence of Pd/Al2O3 modified the reaction mechanism, possibly with some intermediate reactions that were suppressed or remarkably accelerated. The proposed model suggests that zinc sulfate transformation occurred in two sequential stages without the Pd-based material. Activation energy values of 238 and 368 kJ·mol−1 were calculated. In the presen... [more]
9965. LAPSE:2023.16230
Integrative Smart Grids’ Assessment System
March 3, 2023 (v1)
Subject: Energy Policy
Keywords: comprehensive assessment systems, COVID-19, efficiency, evaluation, indicators, policymakers, smart grid, system approach
The COVID-19 pandemic has significantly affected the energy sector. The new behavior of industrial and non-commercial consumers changes the energy consumption model. In addition, the constraints associated with the coronavirus crisis have led to environmental effects from declining economic activity. The research is based on evidence from around the world showing significant reductions in emissions and improved air quality. This situation requires rethinking the energy development strategy, particularly the construction of smart grids as a leading direction of energy development. Evaluating the efficiency of smart grids is a vital tool for disseminating successful experience in improving their management. This paper proposes an approach to a comprehensive assessment of smart grids based on a comparative analysis of existing methods, taking into account the changes that need to be considered after the experience gained from the COVID-19 pandemic. The approach provides an accurate set of... [more]
9966. LAPSE:2023.16229
Process Simulations and Experimental Studies of CO2 Capture
March 3, 2023 (v1)
Subject: Modelling and Simulations
Carbon dioxide, whose global emissions into the atmosphere have reached a maximum of about 36 billion tons per year (compared to the 6 billion tons emitted in 1950), is considered by far the main greenhouse gas (GHG) [...]
9967. LAPSE:2023.16228
[NiFe]-(Oxy)Sulfides Derived from NiFe2O4 for the Alkaline Hydrogen Evolution Reaction
March 3, 2023 (v1)
Subject: Materials
Keywords: alkaline hydrogen evolution reaction, electrocatalysis, Hydrogen, oxysulfide
The development of noble-metal-free electrocatalysts is regarded as a key factor for realizing industrial-scale hydrogen production powered by renewable energy sources. Inspired by nature, which uses Fe- and Ni-containing enzymes for efficient hydrogen generation, Fe/Ni-containing chalcogenides, such as oxides and sulfides, received increasing attention as promising electrocatalysts to produce hydrogen. We herein present a novel synthetic procedure for mixed Fe/Ni (oxy)sulfide materials by the controlled (partial) sulfidation of NiFe2O4 (NFO) nanoparticles in H2S-containing atmospheres. The variation in H2S concentration and the temperature allows for a precise control of stoichiometry and phase composition. The obtained sulfidized materials (NFS) catalyze the hydrogen evolution reaction (HER) with increased activity in comparison to NFO, up to −10 and −100 mA cm−2 at an overpotential of approx. 250 and 450 mV, respectively.
9968. LAPSE:2023.16227
Electrochemically Enhanced Deposition of Scale from Chosen Formation Waters from the Norwegian Continental Shelf
March 3, 2023 (v1)
Subject: Environment
Keywords: electro-deposition, formation water, mineral scale, well plugging
Reservoir formation waters typically contain scaling ions which can precipitate and form mineral deposits. Such mineral deposition can be accelerated electrochemically, whereby the application of potential between two electrodes results in oxygen reduction and water electrolysis. Both processes change the local pH near the electrodes and affect the surface deposition of pH-sensitive minerals. In the context of the plugging and abandonment of wells, electrochemically enhanced deposition could offer a cost-effective alternative to the established methods that rely on setting cement plugs. In this paper, we tested the scale electro-deposition ability of six different formation waters from selected reservoirs along the Norwegian continental shelf using two experimental setups, one containing CO2 and one without CO2. As the electrochemical deposition of scaling minerals relies on local pH changes near the cathode, geochemical modelling was performed to predict oversaturation with respect to... [more]
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