In this study, we studied the drying process, grinding characteristics and physicochemical characteristics of broccoli sprouts (BS). The seeds of broccoli were germinated at 20 °C for 3 and 6 days. Then, the seeds were air- and freeze-dried, and the Page model was used for prediction of drying kinetics of broccoli sprouts. It was observed that the drying time of BS decreased about twofold as the air-drying temperature increased from 40 to 80 °C. An increasing the air-drying temperature from 40 to 80 °C decreased the drying time by approximately twofold. Freeze-drying of sprouts took the longest drying time. Germination of seeds significantly decreased the value of grinding energy requirements, and the ground sprouts exhibited a different grinding pattern in comparison to ground non-germinated seeds. In terms of color parameters, the highest lightness and yellowness were found for freeze-dried sprouts. Redness and yellowness of sprouts increased with an increase in the air-drying temper... [more]

This paper investigated the magnetohydrodynamic (MHD) mixed convection flow of Fe3O4-water ferrofluid over a nonlinearly moving surface. The present work focused on how the state of suction on the surface of the moving sheet and the effects of thermal radiation influence the fluid flow and heat transfer characteristics within the stagnation region. As such, a similarity solution is engaged to transform the governing partial differential equations to the ordinary differential equations. A collocation method, namely the bvp4c function in the MATLAB software solves the reduced system, numerically. Two different numerical solutions were identified for the cases of assisting and opposing flows. The stability analysis was conducted to test the stability of the non-uniqueness solutions. The increment of the thermal radiation effect affects the rate of heat transfer to decrease. The stability analysis conveyed that the upper branch solution is stable and vice versa for the other solution.

Carbon nanomaterials are widespread in the atmospheric aerosol as a result of the combustion processes and their extensive industrial use. This has raised many question about the potential toxicity associated with the inhalation of such nanoparticles, and its incorporation into the lung surfactant layer. In order to shed light on the main physical bases underlying the incorporation of carbon nanomaterials into lung surfactant layers, this work has studied the interaction at the water/vapor interface of carbon nanosheets (CN) with Langmuir monolayers of 1,2-Dipalmitoyl-sn-glycerol-3-phosphocholine (DPPC), with this lipid being the main component of lung surfactant layers and responsible of some of the most relevant features of such film. The incorporation of CN into DPPC Langmuir monolayers modifies the lateral organization of the DPPC at the interface, which is explained on the basis of two different effects: (i) particles occupy part of the interfacial area, and (ii) impoverishment of... [more]

It has been proven that polymer injection at early times is beneficial to offshore heavy oil recovery. It is of significant importance to optimize the polymer injection timing and decide the residual oil distribution after polymer flooding. Aiming at a specific offshore heavy oil reservoir in Bohai, China, the optimum polymer injection timing is investigated through laboratory experiments. The influence of polymer injection timing on oil displacement and remaining oil distribution is analyzed by combining macroscopic and microscopic flooding experiments. The results reveal that the optimum polymer injection timing should be close to the water breakthrough, i.e., just before the waterflooding front reaches the outlet of the core. In addition, the waterflooding front position is analytically solved by using the Buckley−Leverett method and verified by experimental results, which supply an approach to predict the polymer injection timing. When polymer is injected before the waterflood fron... [more]

Calculating hydrocarbon components solubility of natural gases is known as one of the important issues for operational works in petroleum and chemical engineering. In this work, a novel solubility estimation tool has been proposed for hydrocarbon gases—including methane, ethane, propane, and butane—in aqueous electrolyte solutions based on extreme learning machine (ELM) algorithm. Comparing the ELM outputs with a comprehensive real databank which has 1175 solubility points yielded R-squared values of 0.985 and 0.987 for training and testing phases respectively. Furthermore, the visual comparison of estimated and actual hydrocarbon solubility led to confirm the ability of proposed solubility model. Additionally, sensitivity analysis has been employed on the input variables of model to identify their impacts on hydrocarbon solubility. Such a comprehensive and reliable study can help engineers and scientists to successfully determine the important thermodynamic properties, which are key f... [more]

The Kumar model as a molecular model has achieved successful application. However, only 22 reactions limit its veracity and adaptability for feedstocks. A series of models with different degrees of integration of the free radical model and the molecular model has been proposed to enhance feedstock adaptability and simulation accuracy. An improved search engine algorithm, namely Improved PageRank (IPR), is provided and applied to calculate the importance of substances in Kumar model to screen the free-radical reaction network for efficient model selection. A methodology of optimal structure and model parameters chosen is applied to the target to improve the adaptability of the material and the accuracy of the model. Then, two cases with different feedstocks are demonstrated with industrial data to verify the correctness of the proposed approach and its wide feedstock adaptability. The proposed model demonstrates good performance: (1) The mean relative errors (MRE) of the K-R (Kumar and... [more]

Safety analysis is one of the important means to show compliance with airworthiness requirements. The traditional safety analysis methods are significantly dependent on analysts’ skills and experiences. A model-based safety analysis approach is proposed for typical fly-by-wire (FBW) systems based on the system development model built via Simulink, by which the response of system performances can be simulated. The safety requirements of the FBW system are defined by presenting the thresholds of system performance metrics, and the effects of failure conditions on aircraft safety are determined according to the system response simulation by injecting failures or failure combinations into the Simulink model. The Monte Carlo simulation method is used to calculate the probability of unsafe conditions, whose effects are determined by the system response simulation with fault injections. Finally, a case study is used to illustrate the effectiveness and advantages of our proposed approach.

This work aims to characterize a new method to recover low-manipulated human adipose tissue, enriched with adipose tissue-derived mesenchymal stem cells (ATD-MSCs) for autologous use in regenerative medicine applications. Lipoaspirated fat collected from patients was processed through Lipocell, a Class II-a medical device for dialysis of adipose tissue, by varying filter sizes and washing solutions. ATD-MSC yield was measured with flow cytometry after stromal vascular fraction (SVF) isolation in fresh and cultured samples. Purification from oil and blood was measured after centrifugation with spectrophotometer analysis. Extracellular matrix preservation was assessed through hematoxylin and eosin (H&E) staining and biochemical assay for total collagen, type-2 collagen, and glycosaminoglycans (GAGs) quantification. Flow cytometry showed a two-fold increase of ATD-MSC yield in treated samples in comparison with untreated lipoaspirate; no differences where reported when varying filter size... [more]

During mathematical representation of microbial cultures, it is normally assumed that changes in the environment produce instantaneous effects on growth. However, reports are available indicating that sometimes this may not be the case. This work studied the existence of delays on the response of a population of microalgae when subjected to changes in energy and carbon sources, and when exposed to a growth inhibitor. Results show that no appreciable delays exist when microalgae undergo changes in the incident light intensity. For changes in carbon source concentration (inorganic carbon), a small delay in the range of minutes was detected. Finally, when exposing microalgae to inhibitory concentrations of ammonia, a significant delay of several hours was observed.

This paper aims at studying the dynamic fluid evolution process of port plate pair of an axial piston pump. First of all, The Renormalization Group k-ε model (RNG k-ε model) is implemented to simulate the dynamic flow distribution and forecast the evolution of the internal vortex structure inside the valve plate chamber with different speeds of pistons and velocities of inlet fluid by using computational fluid dynamics software. Then, an equivalent amplification test model of a piston-valve plate is built up based on Reynolds similarity theory; the flow state of the piston-valve plate flow field is observed applied the particle image velocimetry (PIV) measuring technique. The resulting uniformity of numerical simulation and PIV measurement verifies that the RNG k-ε model can achieve high-precision prediction for the vortex structure inside the valve plate chamber. Through analysis of velocity contours and streamlines of the flow field, it can be found that vortices with different scale... [more]

Biopharmaceuticals are currently becoming one of the fastest growing segments of the global pharmaceutical industry, being used in practically all branches of medicine from disease treatment to prevention. Virus-like particles (VLP) hold tremendous potential as a vaccine candidate due to their anticipated immunogenicity and safety profile when compared to inactivated or live attenuated viral vaccines. Nevertheless, there are several challenges yet to be solved in the development and manufacturing of these products, which ultimately can increase time to market. Suchlike virus-based products, the development of a platform approach is often hindered due to diversity and inherent variability of physicochemical properties of the product. In the present work, a flow-through chromatographic purification strategy for hepatitis C VLP expressed using the baculovirus-insect cell expression system was developed. The impact of operational parameters, such as residence time and ionic strength were s... [more]

Municipal solid waste (MSW) gasification could be a novel method that shows the various advantages over traditional MSW treatments in China. Other research concluded that MSW gasification was operating by the assistant heat, and the gasification may occur under medium temperature. So, this study is aimed to investigate MSW gasification and pyrolysis behavior and analyze the syngas evolution and reaction mechanism. The MSW samples were collected in daily life and the experiments were carried out in a fixed tubular reactor below 650 °C. The effects of medium temperature and oxygen content on syngas quality were elucidated in depth. The results have shown that temperature can promote the syngas quality in the range of 550−650 °C, because the increasing temperature strengthens the reaction rate. The oxygen content should be controlled in a certain range, or oxidation reactions will be more prominent during gasification. The optimal gasification condition in this study was obtained at 650 °... [more]

The toxic pollutants phenol and cyanide in the bio-treated effluent of coking wastewater still need advanced treatment to meet environmental requirements. In this study, activated carbon prepared from municipal sludge and bamboo waste (SBAC) was used for simultaneous adsorption of phenol and cyanide from bio-treated effluent of coking wastewater. The results showed that the optimum removal efficiencies of volatile phenol (69.7%) and total cyanide (80.1%) were observed at a SBAC dosage of 8 g/L, a pH value of 8.0, and a contact time of 80 min. The physical and chemical properties of SBAC were analyzed using Brunauer−Emmett−Teller (BET) surface area (SBET), scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. SBAC had high SBET (289.58 m2/g) and rich mesoporous structure (average pore diameter of 3.688 nm), and carboxylic groups on SBAC surfaces were enhanced due to the addition of bamboo waste. In addition, a kinetic model of pseudo-first-order fitted... [more]

As interest in the modularization and intensification of chemical processes continues to grow, more research must be directed towards the modeling and analysis of these units. Intensified process units such as polymer membrane reactors pose unique challenges pertaining to design and operation that have not been fully addressed. In this work, a novel approach for modeling membrane reactors is developed in AVEVA’s Simcentral Simulation Platform. The produced model allows for the simulation of polymer membrane reactors under nonisothermal and countercurrent operation for the first time. This model is then applied to generate an operability mapping to study how operating points translate to overall unit performance. This work demonstrates how operability analyses can be used to identify areas of improvement in membrane reactor design, other than just using operability mapping studies to identify optimal input conditions. The performed analysis enables the quantification of the Pareto front... [more]

This article describes the use of the electrical conductivity for measuring bed expansion in a continuous anaerobic biofilm reactor in order to prevent the exit of support material from the reactor with the consequent loss of biomass. The substrate used for the tests is obtained from a two-stage anaerobic digestion (AD) process at the pilot scale that treats the liquid fraction of fruit and vegetable waste (FVW). Tests were performed with the raw substrate before anaerobic treatment (S1), the effluent from the hydrolysis reactor (S2), and the effluent from the methanogenic reactor (S3) to evaluate its effect on the electrical conductivity values and its interaction with colonized support material. The tests were carried out in a 32 L anaerobic inverse fluidized bed reactor (IFBR), which was inoculated with colonized support material and using two industrial electrodes at different column positions. The results with the previously digested samples (S2 and S3) were satisfactory to detect... [more]

IaaS (Infrastructure as a Service) is a well-known computing service, which provides infrastructures over the cloud without owning real hardware resources. This is attractive as resources can be scaled up and down instantly according to the user’s computing demands. Customers of such services would like to adjust the utilization policy promptly by considering the charge of the service, but an instantaneous response is not possible as it takes several hours or even a couple of days for cloud service providers to inform the billing information. In this article, we present an instant cost estimation model for estimating the cost of public cloud resources. Specifically, our model estimates the cost of IaaS by monitoring the usage of resources on behalf of virtual machine instances. As this is performed by generating a user-side metering daemon, it is very precise and thus similar to the resource usage evaluated by the cloud service provider. To validate our model, we run PC laboratory serv... [more]

Microwave (MW) heating of supported metal nanoparticles (NPs) presents attractive effects on catalysis such as the rapid heating processes and the enhancement of the reaction rate. Improving the heating property of the NPs, which act as the catalytic active sites, the MW effects will become more significant. Here we show a systematic study about the supported Pt NPs structure to improve the MW heating property. We found that the drastic heating was induced by a percolated Pt NPs structure, where the conduction electrons move around in the two-dimensional network. On the other hand, no heating was observed in an isolated Pt NPs system with the confined electrons. We conclude that the percolation of the Pt NPs giving the network structure is one of the important key factors for the efficient MW heating. The optimized Pt NPs catalyst leads to the dramatic MW effects on catalytic reactions.

The increasing trends in gas emissions have had direct adverse impacts on human health and ecological habitats in the world. A variety of technologies have been deployed to mitigate the release of such gases, including CO2, CO, SO2, H2S, NOx and H2. This special issue on gas-capture processes collects 25 review and research papers on the applications of novel techniques, processes, and theories in gas capture and removal.

When internal flows go through a valve with a small opening degree, high-speed jet flows are induced, which causes the erosion of the valve core and affects the stability of the flow field. Setting guiding plates in the valve behind the valve core has the function of reducing the adverse effect of high-speed jet flows. In this work, numerical simulations were carried out to investigate the effect of the guiding plate on flow and resistance coefficient, velocity and pressure distributions and flow stability downstream of the valve. The number of guiding plates was changed from 0 to 3 and the opening degree was varied from 0 to 100% at intervals of 10%. A guiding plate with holes in it plays the role of bypassing and guiding flow. Under the action of the guiding plate, the flow coefficient obviously decreases, the gap flow between the valve core and the valve wall in the top of the valve are modified, and the gap flow even disappeared in the valve with 3 guiding plates. It was found that... [more]

The piston-cylinder pair is the key friction pairs in the piston pump. Its performance determines the volume efficiency of piston pump. With the increase of load pressure, the leakage at the clearance of piston-cylinder pair will also increase. In order to reduce leakage, the clearance of the piston-cylinder pair of the ultra-high pressure piston pump is smaller than that of the medium-high pressure piston pump. In order to explore whether the piston will stuck in the narrow gap, it is necessary to study the oil film characteristics of the piston-cylinder pair under the condition of ultra-high pressure, so as to provide a theoretical basis for the optimal design of the piston-cylinder pair of ultra-high pressure axial piston pump. In this paper, an ultra-high pressure axial piston pump is taken as the research object, and its structural characteristics are analyzed. The mathematical model of the oil film thickness of the piston-cylinder pair is established by using the cosine theorem i... [more]

The concentration of volatile fatty acids (VFAs) is one of the most important measurements for evaluating the performance of anaerobic digestion (AD) processes. In real-time applications, VFAs can be measured by dedicated sensors, which are still currently expensive and very sensitive to harsh environmental conditions. Moreover, sensors usually have a delay that is undesirable for real-time monitoring. Due to these problems, data-driven soft sensors are very attractive alternatives. This study proposes different data-driven methods for estimating reliable VFA values. We evaluated random forest (RF), artificial neural network (ANN), extreme learning machine (ELM), support vector machine (SVM) and genetic programming (GP) based on synthetic data obtained from the international water association (IWA) Benchmark Simulation Model No. 2 (BSM2). The organic load to the AD in BSM2 was modified to simulate the behavior of an anaerobic co-digestion process. The prediction and generalization perf... [more]

In this study, a new type of hydrophobic cationic polyacrylamide P (AM-DMC-DABC) (PADD) was synthesized by ultrasonic (US)-initiated polymerization, which is used for the separation and removal of coal mine wastewater. The acrylamide (AM), methacryloyloxyethyl trimethyl ammonium chloride (DMC) and acryloyloxyethyl dimethylbenzyl ammonium chloride (DABC) were used as monomers to prepare). The factors that affecting the US initiated polymerization of PADD were analyzed. Fourier transform infrared spectroscopy (FT-IR), 1H nuclear magnetic resonance (1H NMR) and scanning electron microscopy (SEM) were used to characterize the chemical structure, thermal decomposition performance and surface morphology of the polymers. FT-IR and 1H NMR results showed that PADD was successfully synthesized. In addition, irregular porous surface morphology of PADD were observed by SEM analysis. Under the optimum conditions (pH = 7.0, flocculant dosage = 16.0 mg/L), the excellent flocculation performance (turb... [more]

In the present study, four natural textiles (cotton, linen, wool, and silk) were dyed with 14 naturally extracted dyes, and pancreatin enzyme was used in the dyeing process. The effects of pancreatin enzyme and its buffer on naturally dyed textile samples were evaluated. Two concentrations of pancreatin enzyme and buffer were used as pretreatments for dyed textiles. Proteinic fabrics showed the highest relative color strength (RCS) values of 137.23% and 132.2% when the pancreatin enzyme was applied on wool and silk dyed with pomegranate skin and bloodroot at concentrations A and B, respectively. Linen fiber dyed with catechu tree showed the highest total color difference (TCD) values with buffer (6.83) and pancreatin enzyme A (5.7) and B (6.3). This shows that there were no side effects of the pancreatin enzyme on the studied dyed textiles. By high-performance liquid chromatography (HPLC) analysis, the root extract from madder showed the presence of salicylic acid (1758.91 mg/kg extrac... [more]

Biomass pyrolysis and polypropylene (PP) pyrolysis in a stirred tank reactor exhibited different heat transfer phenomena whereby heat transfer in biomass pyrolysis was driven predominantly by heat radiation and PP pyrolysis by heat convection. Therefore, co-pyrolysis could exhibit be expected to display various heat transfer phenomena depending on the feed composition. The objective of the present work was to determine how heat transfer, which was affected by feed composition, affected the yield and composition of the non-polar fraction. Analysis of heat transfer phenomena was based on the existence of two regimes in the previous research in which in regime 1 (the range of PP composition in the feeds is 0−40%), mass ejection from biomass particles occurred without biomass particle swelling, while in regime 2 (the range of PP composition in the feeds is 40−100%), mass ejection was preceded by biomass particle swelling. The co-pyrolysis was carried out in a stirred tank reactor with heat... [more]

Titanium-bearing electric furnace slag (TEFS) was prepared from vanadium titanomagnetite and leached with sulfuric acid. The Ti leaching rate of vanadium titanomagnetite TEFS is significantly lower than that of ilmenite TEFS. The impurity content in vanadium titanomagnetite TEFS is higher than that in ilmenite TEFS. This might be one of the main factors resulting in the low leaching rate of Ti, so the leaching behaviors of various impurities under different conditions (temperature, acid/solid weight ratio, particle size, and initial sulfuric acid concentration) were investigated. The following trends were observed under different leaching conditions: The leaching rate of Fe increased rapidly and reached equilibrium quickly, that of Si increased quickly in the early stage and then decreased in the later stage, that of Ca increased initially and reached equilibrium later, and the leaching rates of Mg and Al increased gradually until the equilibrium was reached. The leaching rate of Fe wa... [more]