LAPSE:2020.0205
Published Article
LAPSE:2020.0205
Drastic Microwave Heating of Percolated Pt Metal Nanoparticles Supported on Al2O3 Substrate
February 12, 2020
Microwave (MW) heating of supported metal nanoparticles (NPs) presents attractive effects on catalysis such as the rapid heating processes and the enhancement of the reaction rate. Improving the heating property of the NPs, which act as the catalytic active sites, the MW effects will become more significant. Here we show a systematic study about the supported Pt NPs structure to improve the MW heating property. We found that the drastic heating was induced by a percolated Pt NPs structure, where the conduction electrons move around in the two-dimensional network. On the other hand, no heating was observed in an isolated Pt NPs system with the confined electrons. We conclude that the percolation of the Pt NPs giving the network structure is one of the important key factors for the efficient MW heating. The optimized Pt NPs catalyst leads to the dramatic MW effects on catalytic reactions.
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Keywords
conductive network, metal nanoparticles, microwave heating, percolated structure, supported catalyst system
Subject
Suggested Citation
Ano T, Maitani MM, Sato Y, Tsubaki S, Wada Y. Drastic Microwave Heating of Percolated Pt Metal Nanoparticles Supported on Al2O3 Substrate. (2020). LAPSE:2020.0205
Author Affiliations
Ano T: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan [ORCID]
Maitani MM: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan
Sato Y: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan
Tsubaki S: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan [ORCID]
Wada Y: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan
Maitani MM: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan
Sato Y: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan
Tsubaki S: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan [ORCID]
Wada Y: Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, E4-3, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8552, Japan
Journal Name
Processes
Volume
8
Issue
1
Article Number
E72
Year
2020
Publication Date
2020-01-05
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr8010072, Publication Type: Journal Article
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Published Article
LAPSE:2020.0205
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External Link
doi:10.3390/pr8010072
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[v1] (Original Submission)
Feb 12, 2020
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Feb 12, 2020
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https://psecommunity.org/LAPSE:2020.0205
Original Submitter
Calvin Tsay
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