One of the ways used to reduce the emission of carbon dioxide and other harmful substances is the implementation of biomass co-firing processes with coals. Such processes have been implemented for many years throughout many countries of the world, and have included using existing high-power coal boilers. Despite numerous experiments, there are still no analyses in the literature allowing for their generalization. The purpose of this paper is to determine the generalized energy and ecological characteristics of dust steam boilers co-firing hard coal with biomass. The energy characteristics determined in the paper are the dependence of the gross energy efficiency of boilers on such decision parameters as their efficiency and the share of biomass chemical energy in fuel. However, the ecological characteristics are the dependence of emission streams: CO, NO, SO2, and dust on the same decision parameters. From a mathematical point of view, the characteristics are approximation functions bet... [more]

Bioenergy plays a major role as a renewable energy source in the European Union. Solid biomass is derived mainly as wood from forests and wood processing plants. Willow plantations set up on marginal lands can be a supplementary source of wood for energy generation. This study aimed to determine the energy value of yield and the thermophysical properties and elemental composition of the biomass of 7-year rotation willow harvested on marginal soil. Three varieties and three clones were cultivated in the Eko-Salix system on three marginal soils in northern Poland: riparian, alluvial soil, classified as heavy complete humic alluvial soil (Obory); organic, peat−muck soil formed from peat (Kocibórz); very heavy mineral clay soil (Leginy). Favourable conditions for obtaining high energy value biomass were at Kocibórz and Obory with a high groundwater level. The energy value of biomass at Leginy was lower than at Kocibórz and Obory (by 33% and 26%, respectively). The Ekotur variety had the si... [more]

This paper reports the performance of a spark ignition engine using gasoline blended with an upgraded bio-oil rich in aromatics and ethanol. This upgraded bio-oil was obtained using a two-step catalytic process. The first step comprised an in-situ catalytic pyrolysis process with CaO in order to obtain a more stable deoxygenated organic fraction, while the second consisted of a catalytic cracking of the vapours released using ZSM-5 zeolites to obtain an aromatics-rich fraction. To facilitate the mixture between bio-oil and gasoline, ethanol was added. The behaviour of a stationary spark ignition engine G12TFH (9600 W) was described in terms of fuel consumption and electrical efficiency. In addition, gaseous emissions and polycyclic aromatic hydrocarbon (PAH) concentrations were determined. Trial tests suggested that it is possible to work with a blend of gasoline, ethanol and bio-oil (90/8/2 vol%, herein named G90E8B2) showing similar fuel consumption than pure gasoline (G100) at the s... [more]

Solid recovered fuel (SRF) residue, which is leftovers from the SRF manufacturing process, usually is discarded in landfill because of its low heating value and high ash and moisture content. However, it could be used as a fuel after mechanical and biological treatment. Gasification experiments were conducted on treated SRF residue (TSRFR) to assess the viability of syngas production. Efforts were also made to improve the gasification performance by adding low-cost natural minerals such as dolomite and lime as bed material, and by blending with biomass waste. In the case of additive mineral tests, dolomite showed better performance compared to lime, and in the case of biomass blends, a 25 wt% pine sawdust blend with TSRFR showed the best performance. Finally, as an appropriate condition, a combined experiment was conducted at an equivalence ratio (ER) of 0.2 using a 25 wt% pine sawdust blend with TSRFR as a feedstock and dolomite as the bed material. The highest dry gas yield (1.81 Nm3... [more]

Short rotation woody crops (SRWC) like shrub willow are highly productive biomass resources of interest for energy and fuel applications. Hot water extraction (HWE) as an upgrading tool to enable the use of willow biomass in pellet applications has been proposed, and is of increasing interest. This study treats willow and mixes of willow and conventional mixed hardwood feedstock with HWE in a tumbling laboratory reactor to elucidate the effects of time, temperature, feedstock mixes, and other process considerations (water:biomass ratio, presteaming, counter-current processing) on mass removals and other extraction outcomes (e.g., sugar, acetate, and furan yields). Results demonstrated alignment of extraction outcomes with P-factor from 155 °C to 175 °C, with a good compromise of removed mass and co-product potential in the range from 575−800 P-factor. The preferred condition was chosen as 575 P-factor. HWE of mixes of willow and hardwood feedstocks showed a linear response of extractio... [more]

Two bimetallic Fe-Cu and Fe-Ca oxygen carriers were studied for chemical looping gasification (CLG) of biomass. The SEM results indicated that there was no obvious agglomeration on the bimetallic Fe-Cu oxygen carrier supported on Al2O3 and Fe-Ca oxygen carrier after five redox cycles while agglomeration occurred on CuO supported on Al2O3 due to the low melting point of CuO. The XRD results indicated the presence of copper-ferrite and calcium-ferrite phases in the bimetallic materials. The two bimetallic oxygen carriers can be re-oxidized with air to form a crystalline that is similar to the fresh materials. The Fe-Ca oxide became active at 360 °C which was lower than 380 °C for the Fe-Cu oxygen carrier. The high thermal stability and redox reactivity of bimetallic Fe-Cu and Fe-Ca oxygen carriers make the bimetallic oxygen carriers more suitable for recycling during CLG. The method for preparing Fe-Cu oxygen carriers had no significant impact on biomass conversion efficiency but had sig... [more]

Microalgae can be a future source of biomass with a wide range of applications, including its use to solve current environmental issues. One of the main variables for microalgal cultivation is the light supply: (i) its intensity that often does not present a uniform spatial distribution inside the culture; (ii) photoperiod; and (iii) spectrum. Therefore, this study aims to evaluate the growth of the microalgae Chlorella vulgaris in a tubular photobioreactor with compound parabolic collectors (CPCs) under outdoor conditions. The effect of ultraviolet and visible radiation on biomass productivity and nutrients (nitrogen and phosphorus) uptake was assessed. The maximum biomass productivity was (5 ± 1) × 10−3 g·L−1·h−1, and the specific growth rates ranged from (1.1 ± 0.3) × 10−2 to (2.0 ± 0.6) × 10−2 h−1. Regarding nutrient uptake, initial removal rates of (0.9 ± 0.4) mg N·L−1·h−1 for nitrogen and (0.17 ± 0.04) mg P·L−1·h−1 for phosphorus were reached. These values increased with visible... [more]

Organic Rankine Cycle (ORC) turbogenerators are a well-established technology to recover from medium to ultra-low grade heat and generate electricity, or heat and work as cogenerative units. High firmness, good reliability and acceptable efficiency guarantee to ORCs a large range of applications: from waste heat recovery of industrial processes to the enhancement of heat generated by renewable resources like biomass, solar or geothermal. ORC unit coupled with biomass boiler is one of the most adopted arrangements. However, despite biomass renewability, it is mandatory to evaluate the environmental impact of systems composed by boilers and ORCs taking into account the entire life cycle. To this purpose, the authors perform a life cycle assessment of a commercially available 150 kW cogenerative ORC unit coupled with a biomass boiler to assess the global environmental performance. The system is modelled in SimaPro using different approaches. Results show that the most impacting processes... [more]

For biomass compaction, it is important to determine all aspects of the process that will affect the quality of pellets and briquettes. The low bulk density of biomass leads to many problems in transportation and storage, necessitating the use of a compaction process to ensure a solid density of at least 1000 kg·m−3 and bulk density of at least 600 kg·m−3. These parameters should be achieved at a relatively low compaction pressure that can be achieved through the proper preparation of the raw material. As the compaction process includes a drying stage, the aim of this work is to determine the influence of the drying temperature of pine biomass in the range of 60−140 °C on the compaction process. To determine whether this effect is compensated by the moisture, compaction was carried out on the material in a dry state and on the materials with moisture contents of 5% and 10% and for compacting pressures in the 130.8−457.8 MPa range. It was shown that drying temperature affects the specif... [more]

The agricultural sector can play an important role in the transformation of the energy economy in Poland. Special attention in this paper has been paid to the development of the agricultural biogas market in Poland. The considerations mainly concern organizational and economic aspects. Agricultural biogas plant represents the circular cycle of matter and energy. It enables the establishment of low-carbon, resource-efficient links between the agriculture and energy sectors. This is an important element of the circular economy, where waste from agricultural production and the agri-food industry, coming from renewable resources, is transformed into goods with a higher added value. The social and economic needs of the present generation and future generations are considered. The paper presented the characteristics of the Polish market, i.e., the number of entities, the number and location of plants, as well as the production volumes. Analyses were performed in the area of raw materials use... [more]

In this research, the idea of multicomponent, one-vessel cleaning of syngas through simultaneous dedusting and adsorption is described. Data presented were obtained with the use of a pilot-scale 60 kWth fixed-bed GazEla reactor, coupled with a dry gas cleaning unit where mineral sorbents are injected into raw syngas at 500−650 °C, before dedusting at ceramic filters. The research primarily presents results of the application of four calcined sorbents, i.e., chalk (CaO), dolomite (MgO−CaO), halloysite (AlO−MgO−FeO), and kaolinite (AlO−MgO) for high-temperature (HT) adsorption of impurities contained in syngas from gasification of biomass. An emphasis on data regarding the stability of the filtration process is provided since the addition of coating and co-filtering materials is often necessary for keeping the filtration of syngas stable, in industrial applications.

Agriculture can provide biomass for bioproducts, biofuels and as energy feedstock with a low environmental impact, derived from carbohydrate, protein and oil annual crops, as well from lignocellulosic crops. This paper presents the thermophysical and chemical features of camelina and crambe straw depending on nitrogen fertilisation rate with a view to their further use in a circular bioeconomy. A two-factorial field experiment was set up in 2016, with camelina and crambe as the first factor and the N fertilizer rate (0, 60 and 120 kg·ha−1·N) as the second factor. Ash content in crambe straw (6.97% d.m.) was significantly higher than in camelina straw (4.79% d.m.). The higher heating value was higher for the camelina (18.50 MJ·kg−1·d.m.) than for the crambe straw (17.94 MJ·kg−1·d.m.). Sulphur content was also significantly higher in camelina than in crambe straw. An increase in nitrogen content with increasing fertilisation rate was visible in the straw of both species (from 1.19 to 1.3... [more]

Sugarcane harvesting requires a significant amount of energy and time to manage dry leaves after the harvesting process. Therefore, the objective of this study was to minimize the energy requirement to process the cane and dry leaves’ harvesting (CDLH) for sugarcane while, at the same time, maximizing sugar production from cane and energy from dry leaves in Sri Lanka. The CDLH was conceptualized using a novel approach to optimize sugarcane harvesting to maximize biomass supply for energy production while reducing supply chain sugar-loss. The CDLH was investigated for manual harvesting capacity, energy consumption, sugar loss, and biomass energy potential. It was observed that CDLH consumed higher energy compared to the present practices of harvesting. However, the energy used for fieldwork was reduced because of the shifting of cane chopping and cleaning from the field to the factory. Low bulk density of the harvested cane of the CDLH system had a higher energy requirement in transport... [more]

Bioenergy accounts for 61.7% of all renewable energy sources, with solid fuels accounting for 43% of this amount. Poplar plantations can deliver woody biomass for energy purposes. A field experiment with poplar was located in the north-east of Poland on good quality soil formed from medium loam. The study aimed to determine the yield, the energy value of the yield and the thermophysical properties and elemental composition of the biomass of four poplar clones harvested in two consecutive 4-year harvest rotations. The highest biomass energy value was determined in the UWM 2 clone in the second harvest rotation (231 GJ ha−1·year−1). This value was 27−47% lower for the other clones. The biomass quality showed that poplar wood contained high levels of moisture and low levels of ash, sulphur, nitrogen and chlorine. This indicates that poplar can be grown in the north-east of Poland and that it gives a yield with a high energy value and beneficial biomass properties from the energy generatio... [more]

In this review, we focus on the literature that described the various unit operations in a process design flowsheet of biorefineries. We begin by establishing the accepted definitions of a biorefinery, go on to describe how to categorize biorefineries, and finally review the literature on biorefinery process designs by listing the unit operation in each process design. Distinguishing biorefineries based on feedstock, the types of processing units, and the products emanating from the biorefinery are discussed.

Rural areas of developing countries often have poor energy infrastructure and so rely on a very local supply. A local energy supply in rural Uganda frequently has problems such as limited accessibility, unreliability, a high expense, harmful to health and deforestation. By carbonizing waste biomass streams, available to those in rural areas of developing countries through a solar resource, it would be possible to create stable, reliable fuels with more consistent calorific values. An energy demand calculator is reported to assess the different energy demands of various thermochemical processes that can be used to create biofuel. The energy demand calculator then relates the energy required to the area of solar collector required for an integrated system. Pyrolysis was shown to require the least amount of energy to process 1 kg of biomass when compared to steam treatment and hydrothermal carbonization (HTC). This was due to the large amount of water required for steam treatment and HTC.... [more]

The paper presents the results of a study on chemical composition of ashes from three types of waste biomass in terms of fertilizer usefulness. Waste from the process of corn grain drying, including corn cobs, corn grains and corn husk and their mixtures in the ratio 4:1 (v/v) were examined. The study proved that corn grain was the material with the highest concentration of macroelements among those studied (P—21,452 ppm, K—25,970 ppm, S—5911 ppm) and the mixture of corn cobs with corn grains (Ca—81,521 ppm). When microelements were considered, the highest concentration was recorded for corn cobs (Cu—207 ppm, Mn—844 ppm, Zn—857 ppm) and corn husk (Fe—15,100 ppm). The analysis of toxic elements in the ashes of the biomass studied showed their highest concentration in corn husk ash (Ni—494 ppm, Cr—301 ppm, Pb—42.7 ppm, As—4.62 ppm). The analysis showed that regardless of the type of biomass studied, all ashes were strongly enriched (in relation to the average soil content) with phosphoru... [more]

In this study, lignin with fine structures and facile enzymatic saccharifying residue were successively dissociated based on the lignin-first biomass deconstruction strategy. In the lignin-first process, aldehyde-protected lignin fractions were firstly isolated by acid-catalyzed dioxane extraction in the presence of formaldehyde (FA) and acetaldehyde (AA) and then analyzed by advanced nuclear magnetic resonance (NMR) spectroscopy and gel permeation chromatography (GPC). The optimized hydrogenolysis of the extracted lignin (LFA and LAA) resulted in a high yield (42.57% and 33.00%) of lignin monomers with high product selectivity (mainly 2,6-dimethoxy-4-propylphenol) (39.93% and 46.61%). Moreover, the cellulose-rich residues were saccharified into fermentable glucose for bioethanol production. The glucose yield of the substrate (RAA) reached to 75.12%, which was significantly higher than that (15.4%) of the substrate (RFA). In short, the lignin-first biomass deconstruction by adding AA i... [more]

In search of guaranteeing global energy requirements, waste from different agricultural, forestry and industrial sources is presented as a renewable and sustainable energy source. The manufacture of solid fuels from biomass based on the densification of this to improve its mechanical and energy properties is one of the mechanisms of viable energy production from the technical-economic point of view. The biomass mixture is one of the topics currently researched, in which various factors can affect the final behavior of the briquettes. In this research the influence on the mechanical properties of briquettes obtained from the mixture between two biomasses is studied: rice husk and pine sawdust. A mixed factorial experimental factorial design is used, in which the process temperature, the proportion of the rice husk biomass over the total mass, and the compaction time are defined as experimental factors. Experimental statistical models are obtained that partially explain the behavior of s... [more]

The presented work is focused on biomass thermochemical conversion with integrated CO2 capture. The main aim of this study was the in-depth investigation of the impact of pyrolysis temperature (500, 600 and 700 °C) and CaO sorbent addition on the chemical and physical properties of obtained char and syngas. Under the effect of the pyrolysis temperature, the properties of biomass chars were gradually changed, and this was confirmed by examination using thermal analysis, scanning electron microscopy, X-ray diffraction, and porosimetry methods. The chars were characterised by a noticeable carbon content (two times at 700 °C) resulting in a lower O/C ratio. The calculated combustion indexes indicated the better combustible properties of chars. In addition, structural morphology changes were observed. However, the increasing pyrolysis temperature resulted in changes of solid products; the differences of char properties were not significant in the range of 500 to 700 °C. Syngas was analysed... [more]

Climate change, other environmental impacts due to increased energy use worldwide, and the exhaustion of energy resources are some of the major challenges facing today’s society. Considering this, this paper assesses the importance of biomass-based heating and hot-water systems in the achievement of more sustainable buildings. Using a simplified calculation method, we jointly analyzed the potential operational cost savings and reduction of CO2 emissions that would be achieved when the traditional energy model, based on the use of fossil fuels, is replaced by biomass-based heating systems. Evidence stems from a case study in public buildings in the province of Pontevedra, in the northwest of Spain. The results of this research not only show a huge impact on CO2 emission reduction just by adapting the kind of fuel use, but also considerable annual cost reduction without compromising activity development and workers’ comfort. Thus, the findings obtained should encourage governments to sup... [more]

The main objective of the Portuguese project “CONVERTE-Biomass Potential for Energy” is to support the transition to a low-carbon economy, identifying biomass typologies in mainland Portugal, namely agri-forest waste, energy crops and microalgae. Therefore, the aim was to design and construct a georeferenced (mapping) database for mainland Portugal, to identify land availability for the implementation of energy crops and microalgae cultures, and to locate agricultural and forestry production areas (including their residues) with potential for sustainable exploitation for energy. The ArcGIS software was used as a Geographic Information System (GIS) tool, introducing the data corresponding to the type of soil, water needs and edaphoclimatic conditions in shapefile and raster data type, to assess the areas for the implantation of the biomass of interest. After analysing the data of interest in each map in ArcGIS, the intersection of all maps is presented, suggesting adequate areas and pre... [more]

While filtration, chlorination, and UV drinking water treatments are commonplace, globally an estimated 1.2 billion people continue to boil their drinking water over inefficient biomass fires instead because it allows them to use available resources paired with a time-tested and trusted method. Although boiling water is culturally well-established, there is vast potential to improve human health, environmental impact, and efficiency by leveraging the fact that a significant reduction in pathogenic microorganisms occurs at temperatures well below boiling through a process known as pasteurization. This paper presents the evaluation of a community-scale, biomass-powered, flow-through water pasteurization system that was designed to heat water to the temperature required for pasteurization to occur before recuperating heat while cooling treated water down to a safe-to-handle temperature. The system is then compared to other common thermal treatment methods including batch-boiling over open... [more]

Lithium iron orthosilicate (LFS) cathode can be prepared via the polyol-assisted ball milling method with the incorporation of carbon derived from eggshell membrane (ESM) for improving inherent poor electronic conduction. The powder X-ray diffraction (XRD) pattern confirmed the diffraction peaks without any presence of further impure phase. Overall, 9 wt.% of carbon was loaded on the LFS, which was identified using thermogravimetric analysis. The nature of carbon was described using parameters such as monolayer, and average surface area was 53.5 and 24 m2 g−1 with the aid of Langmuir and Brunauer−Emmett−Teller (BET) surface area respectively. The binding energy was observed at 285.66 eV for C−N owing to the nitrogen content in eggshell membrane, which provides more charge carriers for conduction. Transmission electron microscopy (TEM) images clearly show the carbon coating on the LFS, the porous nature of carbon, and the atom arrangements. From the cyclic voltammetry (CV) curve, the ra... [more]

This work aims to study the influence of an oxidant agent on syngas quality. A series of tests using air and steam as oxidant agents have been performed and the results compared with those of a pyrolysis test used as a reference. Tests were carried out at Sapienza University of Rome, using an updraft reactor. The reactor was fed with hazelnut shells, waste biomass commonly available in some parts of Italy. Temperature distribution, syngas composition and heating value, and producible energy were measured. Air and steam gasification tests produced about the same amount of syngas flow, but with a different quality. The energy flow in air gasification had the smallest measurement during the experiments. On the contrary, steam gasification produced a syngas flow with higher quality (13.1 MJ/Nm3), leading to the best values of energy flow (about 5.4 MJ/s vs. 3.3 MJ/s in the case of air gasification). From the cold gas efficiency point of view, steam gasification is still the best solution,... [more]