Trichlorophenols are on the US environmental protection agency’s list of priority pollutants due to their serious damage to water safety. With the aim of adsorbing the 2,4,6-trichlorophenol (2,4,6-TCP), Zn2+-Al3+-tartrate layered double hydroxides (Zn2+-Al3+-C4H4O62−-LDHs) adsorbent was synthesized via homogeneous precipitation method. X-ray powder diffraction (XRD), Fourier infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) were used to characterize Zn2+-Al3+-C4H4O62−-LDHs. The concentration of 2,4,6-TCP was determined using gas chromatography−mass spectrometry (GC-MS). Zn2+-Al3+-C4H4O62−-LDHs exhibited a good adsorption performance of 2,4,6-trichlorophenol, since a bigger layer spacing of Zn2+-Al3+-C4H4O62−-LDHs was obtained than that in Zn2+-Al3+-CO32−-LDHs. Adsorption parameters of adsorption temperature, contact time, adsorbent dosage, and solution pH were investigated, the initial concentration of 2,4,6-TCP was 2.0 g/L. Resp... [more]

Nowadays, plant-based proteins are gaining momentum due to their wide availability, good amino acid content, and their market appeal. Unfortunately, these molecules usually have low water solubility, affecting other functional characteristics, such as foaming and emulsification, opening technological opportunities for research. Some plant-based protein applications rely on adjustments to final formulations and changing these chemical structures to produce new protein ingredients is also a path widely used in recent research. These modifications can be classified as physical or chemical, the latter being the most popular, and hydrolysis is one of the more widely reported modifications. This review explores the application of chemical modifications to plant-based proteins to improve techno-functional properties, when applied as part of food formulations. In addition, acetylation and succinylation, as the second and third most used processes, are discussed, including a deep analysis of th... [more]

In mechanized rice harvesting, the performance of the cleaning device is one of the important factors that affect the overall efficiency of the combine-harvester. To study the influence of different parameters on the cleaning efficiency, the influence of airflow velocity and the inclination angle on the cleaning effect was analyzed. Both simulation and experimental results prove that the increase of airflow velocity and the inclination angle will reduce the impurity rate of rice and increase the entrainment loss rate. The addition of a vibrating sieve to the device reduces the trash rate of rice, but the entrained loss rate increases accordingly. After tilting the sieve surface by 10°, a reduction in both the impurity rate and the entrainment loss rate of rice was found in combination with the force analysis of the particles on the sieve surface. The effect of the device structure on the internal flow field distribution was analyzed by comparing the eddy viscosity and velocity flow lin... [more]

The mixture of water extracts from Tanacetum parthenium and Salix alba was studied in an ex vivo assessment of neurotoxicity constituted by isolated mouse cortex specimens challenged with K+ 60 mM Krebs−Ringer buffer (neurotoxicity stimulus). The effects of the mixture on lactate dehydrogenase (LDH), nitrite and serotonin levels were investigated. The phytochemical profile of the mixture was also evaluated. A docking approach was conducted to predict, albeit partially, the putative mechanism underlying the observed effects. The extracts displayed a good profile of polyphenolic compounds (22 chromatographic peaks detected), with caftaric acid and epicatechin being the prominent phenols. In isolated cortex, the association of T. parthenium and S. alba extracts was effective in reducing the K+ 60 mM-induced levels of LDH and nitrites, whereas the neurotoxicity stimulus-induced serotonin depletion was prevented by the treatment. Regarding the inhibition of serotonin catabolism, epicatechin... [more]

In this study, we assessed the coating of ‘Tommy Atkins’ mangoes with films containing chitosan and nano-silicon dioxide in terms of the effects on fruit parameters as an indicator of quality. After coating, the fruits were first stored at 13 ± 1 °C and 90−95% RH for 30 days, and then at 20 ± 2 °C and 70−75% RH for 5 days, which corresponds to the marketing period. The results showed that coating treatments significantly decreased the fruits’ weight loss and decay percentage compared to the uncoated control samples over the storage period. Additionally, all coated treatments delayed skin degreening, reduced endogenous ethylene production, suppressed respiration rate, and maintained the firmness, compared to untreated control fruit. Titratable acidity and vitamin C significantly decreased in all samples during storage, but this decrease was less pronounced in the coated fruits. Furthermore, coating can delay the increments in total soluble solids and total sugars while maintaining total... [more]

This article presents the application of a novel system for the treatment of fruit and vegetable waste (FVW) using the combination of treatment by the application of the liquid fraction to an anaerobic hydrolytic bioreactor and a constructed wetland. The batch-fed anaerobic bioreactor (AB) had an average organic loading rate of 44 g COD/L-d and a hydraulic residence time (HRT) of 24 h for the degradation of the liquid fraction of the FVW with an average COD removal of 55%. Subsequently, the constructed wetlands (CWs) were fed a subsurface vertical flow of the effluent from the AB by stepwise concentration increments from 1 to 12 g COD/L and a HRT = 72 h until the limit conditions of the operation were identified. For the tropical ornamental species of the CWs in red volcanic gravel (RVG) and RVG + polyethylene (PE) supports, the monoculture of Hippeastrum rutilum and Spathiphyllum wallisii presented removals of COD, Tot-P, and TKN of 90%, 80%, and 85%, respectively. The polycultures wi... [more]

The aim of this study was to explore the impact of aqueous ozone technology on maintaining grapefruit flavor and freshness by minimizing the occurrence of postharvest deterioration. During the 2018 and 2019 seasons, Star Ruby grapefruit fruits were treated with 0.3 and 0.6 ppm aqueous ozone for 5 and 10 min after harvest at water temperatures of 5 °C and 15 °C, respectively. The fruits were stored for 40 days at 8 ± 1 °C with 85−90% relative humidity. The results revealed that all the ozonated water treatments reduced physiological weight loss, disease infection, and decay, as well as providing long-term protection to the fruits throughout storage. The best treatment for preserving the postharvest quality was 0.6 ppm ozonated water at 5 °C for 5 min, which successfully delayed ripening while concurrently preserving the TSS/acid ratios, total phenolics, and antioxidant activity. Overall, aqueous ozone treatment is a promising example of a treatment that is beginning to be utilized on a... [more]

This paper is concerned with the real-time configuration of fault detection systems by exploiting an gradient optimization scheme. It is known that industrial processes may often encounter some uncertainties or changes of operating points and environment, which would lead to an unsatisfactory fault detection result. To handle this problem, a real-time (or online) configuration strategy is introduced, which plays an important role in ensuring the efficiency of the fault detection method without a high industrial cost. In this paper, a gradient-based iterative optimization scheme is taken into account for the real-time configuration implementation. By utilizing the gradient-based iterative algorithm to minimize the K-gap between the residual generator and the current system, the parameters of the residual generator can be configured from the online input/output data. Based on this, real-time configuration of the residual generator parameters is achieved and, correspondingly, the fault de... [more]

Gas dispersion in non-Newtonian fluids is encountered in a broad range of chemical, biochemical, and food industries. Mechanically agitated vessels are commonly employed in these processes because they promote high degree of contact between the phases. However, mixing non-Newtonian fluids is a challenging task that requires comprehensive knowledge of the mixing flow to accurately design stirred vessels. Therefore, this review presents the developments accomplished by researchers in this field. The present work describes mixing and mass transfer variables, namely volumetric mass transfer coefficient, power consumption, gas holdup, bubble diameter, and cavern size. It presents empirical correlations for the mixing variables and discusses the effects of operating and design parameters on the mixing and mass transfer process. Furthermore, this paper demonstrates the advantages of employing computational fluid dynamics tools to shed light on the hydrodynamics of this complex flow. The liter... [more]

Driven by energy shortages and climate concerns, the electric vehicles are popular around the world with their energy-saving and environmentally friendly advantages. As electric vehicle batteries (EVBs) mainly use lithium batteries, and the batteries’ performance decreases with the increase of charging times, a large number of batteries are entering the end-of-life (EoL) stage. Recycling and reuse of EVBs are effective ways to reduce environmental pollution and promote resources utilization and is now a top priority. Building a recycling network is the foundation of battery recycling. However, there are few studies on battery recycling networks and the construction of recycling networks is expensive, which impedes the sustainable development of electric vehicles. Based on this, recycling network design is critical for EVB recycling. This paper first analyzes three strategies to deal with used batteries: remanufacturing, reuse, and recycling materials. Secondly, an EVB recycling network... [more]

In this research, the graphene was grown directly on the Si(100) surface at 600 °C temperature using an anode layer ion source. The sacrificial catalytic cobalt interlayer assisted hydrocarbon ion beam synthesis was applied. Overall, two synthesis process modifications with a single-step graphene growth at elevated temperature and two-step synthesis, including graphite-like carbon growth on a catalytic Co film and subsequent annealing at elevated temperature, were applied. The growth of the graphene was confirmed by Raman scattering spectroscopy and X-ray photoelectron spectroscopy. The atomic force microscopy and scanning electron microscopy were used to study samples’ surface morphology. The temperature, hydrocarbon ion beam energy, and catalytic Co film thickness effects on the structure and thickness of the graphene were investigated. The graphene growth on Si(100) by two-step synthesis was beneficial due to the continuous and homogeneous graphene film formation. The observed resul... [more]

Within this article, the nonlinear vibration control of the rotor active magnetic bearings system is tackled utilizing the integral resonant controller for the first time. Two integral resonant controllers are proposed to mitigate the system lateral oscillations in the horizontal and vertical directions. Based on the suggested control technique, the whole system dynamical model is derived as a two-degree-of-freedom nonlinear system (i.e., rotor system) coupled linearly to two first-order filters (i.e., the integral resonant controllers). The nonlinear autonomous system that governs the oscillation amplitudes of the controlled system as a function of the control parameters is extracted by applying perturbation analysis. The obtained autonomous system showed that the linear damping coefficients of the rotor system are functions of the control gains, feedback gains, and internal loop feedback gains of the coupled controller. Accordingly, the sensitivity of the rotor oscillation amplitudes... [more]

The vanadium redox flow battery (VRFB) is a promising and commercially available technology that poses advantageous features for stationary energy storage. A key component of the VRFB in terms of cost and system efficiency is the membrane. In recent years, anion exchange membranes (AEMs) have gained interest in VRFB research as they in general exhibit lower vanadium crossover due to a more substantial Donnan exclusion effect. In this study, a low-resistance flow cell was developed and the electrochemical performance of Aemion™ anion exchange membranes AF1-HNN5-50-X, AF1-HNN8-50-X and AF1-ENN8-50-X were compared against commonly used cation exchange membranes, Nafion® 211 and 212. The VRFB using AF1-ENN8-50-X exhibited superior performance versus Nafion® 212 regarding cycling efficiency and rate performance. However, relatively high and comparable capacity losses were observed using both membranes. NMR analysis showed no sign of chemical degradation for AF1-ENN8-50-X by immersion in VO2... [more]

A novel endo-β-1,4-mannanase gene was cloned from a novel actinomycetes, Nonomuraea jabiensis ID06-379, isolated from soil, overexpressed as an extracellular protein (47.8 kDa) in Streptomyces lividans 1326. This new endo-1,4-β-mannanase gene (manNj6-379) is encoded by 445-amino acids. The ManNj6-379 consists of a 28-residue signal peptide and a carbohydrate-binding module of family 2 belonging to the glycoside hydrolase (GH) family 5, with 59−77% identity to GH5 mannan endo-1,4-β-mannanase. The recombinant ManNj6-379 displayed an optimal pH of 6.5 with pH stability ranging between 5.5 and 7.0 and was stable for 120 min at 50 °C and lower temperatures. The optimal temperature for activity was 70 °C. An enzymatic hydrolysis assay revealed that ManNj6-379 could hydrolyze commercial β-mannan and biomass containing mannan.

The goal of this study was to determine the concentrations of 16 PAHs (PAH16) naphthalene—Nap, acenaphthylene—Anl, acenaphthene—Ane, fluorene—Flu, phenanthrene—Phen, anthracene—Ant, fluoranthene—Flt, pyrene—Pyr, benz[a]anthracene—BaA, chrysene—Chry, benzo[b]fluoranthene—BbF, benzo[k]fluoranthene—BkF, benzo[a]pyrene—BaP, indeno[1,2,3-cd]pyrene—InP, dibenz[a,h]anthracene—DahA and benzo[g,h,i]perylene—BghiP) in Slavonska slanina traditionally smoked bacon over open fire and industrially smoked on a smoke generator with a heated plate. In the samples of Slavoska slanina smoked in a traditional manner, the presence of 11 out of 16 analyzed PAHs was determined (Nap, Anl, Ane, Fln, Ant, Phen, Flt, BaA, Pyr, BbF, BkF). In the samples smoked in industrial conditions, only 2 out of 16 (Nap, Anl) were quantified. In the samples smoked with open fire (the traditional method), PAH4 (BaA, BaP BbF, Chry) concentations were as follows: 14.84 μg kg−1 in the middle, 10.60 μg kg−1 on the surface and 17.3... [more]

Beer production has over a thousand-year tradition, but its development in the present continues with the introduction of new technological and technical solutions. The methods for modeling and optimization in beer production through an applied analytical approach have been discussed in the present paper. For this purpose, the parameters that are essential for the main processes in beer production have been considered—development of malt blends, guaranteeing the main brewing characteristics; obtaining wort through the processes of mashing, lautering and boiling of wort; fermentation and maturation of beer. Data on the mathematical dependences used to describe the different stages of beer production (one-factor experiments, modeling of mixtures, experiment planning, description of the kinetics of microbial growth, etc.) and their limits have been presented, and specific research results of various authors teams working in this field have been cited. The independent variables as well as... [more]

In view of the problems existing in the process of agricultural machinery selection, such as inadequate decision-making information, strong subjectivity and quantification difficulty of the index weight assignment, and accuracy deficiency of the selection results, a model on the selection of agricultural machinery based on the improved CRITIC-entropy weight and GRA-TOPSIS method was established in this study. Through analysis, based on the construction of a comprehensive evaluation index system for the selection of agricultural machinery, the combined weight value was determined by combining the weights obtained using the improved CRITIC method and the weights obtained using the entropy weight method. The grey relational analysis method was also combined with the TOPSIS method. The power machinery combination with 88.2 and 73.5 kW of the 68th Regiment of the Fourth Division of Xinjiang Production and Construction Corps was used as an example for verification to determine the optimal po... [more]

It is a concern that microplastics have been discovered in the food sources and water that we consume. This research was to evaluate the methods to isolate microplastics from organisms and how much of the environment of New Zealand (NZ), which is one of the least polluted countries, is contaminated by microplastics. New Zealand green-lipped mussels (Perna canaliculus) are considered to be an important product in the NZ food industry. For this reason, the existence of microplastics in these were investigated. Tarakihi fish (Nemadactylusmacropterus) consume food near the bottom of ocean, so this fish can be an indicator of the contamination of microplastics denser than water. In addition, bottled water, tap water and sea salt samples were also investigated. To isolate solid particles in an animal body, its tissues were chemically digested. It was found that 10% (w/w) potassium hydroxide (KOH) was a practical digestive protocol on biological tissues since polymers such as polyethylene ter... [more]

A Steam generator is a crucial device of a nuclear power plant. Control performance of the steam generator level control system is key to its normal operation. To improve its performance, the control system parameters should be optimized by utilizing a proper optimization method. Furthermore, the method’s efficiency is critical for its operability in the actual plant. However, the steam generator level process is a complex process, with high nonlinearity and time-varying properties. Traditional parameters tuning methods are experience-based, cumbersome, and time-consuming. To address the challenge, a systemic data-driven optimization methodology based on the model-free optimization with a revised simplex search method was proposed. Rather than the traditional controller parameter tuning method, this method optimizes the control system directly by using control performance measurements. To strengthen its efficiency, two critical modifications were incorporated into the traditional simpl... [more]

Forest fires are one of the strongest natural phenomena, occurring both for natural and man-made reasons. Forest fires entail not only economic losses, but also affect the ecological, biological and demographic picture of the region of its origin and far beyond its borders. Around the world, work is underway to develop effective methods for predicting the impact of a forest fire on the environment, the speed and direction of propagation and impact on various infrastructure facilities near the wildland−urban interface (WUI). The purpose of the work is to review recent and significant research works on the physical and chemical processes in wooden construction materials during WUI fires. As a result of the analysis of literary sources, works devoted to the modeling and experimental study of various physical and chemical processes, namely, the impact of forest fires on residential and industrial facilities, heat and mass transfer in structural materials, drying processes, pyrolysis, and i... [more]

Predicting the time series of 10.7-cm solar radio flux is a challenging task because of its daily variability. This paper proposed a non-linear method, a convolutional and recurrent neural network combined model to achieve end-to-end F10.7 forecasts. The network consists of a one-dimensional convolutional neural network and a long short-term memory network. The CNN network extracted features from F10.7 original data, then trained the feature signals in the long short-term memory network, and outputted the predicted values. The F10.7 daily data during 2003−2014 are used for the testing set. The mean absolute percentage error values of approximately 2.04%, 2.78%, and 4.66% for 1-day, 3-day, and 7-day forecasts, respectively. The statistical results of evaluating the root mean square error, spearman correlation coefficient shows a superior effect as a whole for the 1−27 days forecast, compared with the ordinary single neural network and combination models.

SUMOylation is a reversible covalent process between a small ubiquitin-like modifier (SUMO) and its target protein and has become a crucial regulator of protein functions. Here, we report that Bombyx mori nucleopolyhedrovirus (BmNPV) may take advantage of the host SUMOylation system to enhance its own replication, similar to many other viruses. Both the knockdown of BmSUMO by RNAi and chemical blocking by ginkgolic acid both impaired BmNPV replication. Using site mutation and pull-down assays, we found that lysine K70 of the protein kinase-interacting protein (PKIP), which is conserved in all Alphabaculoviruses, was modified by SUMO. Mutation of K70 in PKIP led to its translocation from the cytoplasm to the nucleus. Knockout and rescue experiments showed that the rescue of PKIP mutant virus with wild-type PKIP restored BmNPV replication to the normal level, but this was not true for the K70R mutation. Altogether, these results show that SUMOylation of PKIP plays a key role in BmNPV rep... [more]

We consider one-step and two-step simple models of anaerobic digestion that are able to adequately capture the main dynamical behaviour of the full anaerobic digestion model ADM1. We do not consider specific growth functions. We only require them to satisfy certain qualitative assumptions. These assumptions are satisfied for concave growth functions, but they are also satisfied for a large class of growth functions found in many applications. We consider the maximisation of the biogas production with respect to the operating parameters of the model, which are the dilution rate and the substrate input concentration. We give the best operating conditions and we describe them as a subset of the set of operating parameters. Our models incorporate biomass decay terms, corresponding to maintenance. Numerical plots with specified growth functions and biological parameters illustrate the obtained results.

Wheat alpha-amylase/trypsin inhibitors remain a subject of interest considering the latest findings showing their implication in wheat-related non-celiac sensitivity (NCWS). Understanding their functions in such a disorder is still unclear and for further study, the need for pure ATI molecules is one of the limiting problems. In this work, a simplified approach based on the successive fractionation of ATI extracts by reverse phase and ion exchange chromatography was developed. ATIs were first extracted from wheat flour using a combination of Tris buffer and chloroform/methanol methods. The separation of the extracts on a C18 column generated two main fractions of interest F1 and F2. The response surface methodology with the Doehlert design allowed optimizing the operating parameters of the strong anion exchange chromatography. Finally, the seven major wheat ATIs namely P01083, P17314, P16850, P01085, P16851, P16159, and P83207 were recovered with purity levels (according to the targete... [more]

Date palm fruits (Phoenix dactylifera) contain high levels of fructose and glucose sugars. These natural sugar forms are healthy, nutritional and easily assimilate into human metabolism. The successful production of soluble date sugar powder from nutritious date fruits would result in a new food product that could replace the commercial refined sugar. In this work, a novel process technology based on the supercritical extraction of sugar components from date pulp was modeled and simulated using Aspen Plus software. The process model consisted of three main steps that were individually simulated for their optimal working conditions as follows: (a) freeze-drying of the date pulp at −42 °C and 0.0001 bar; (b) supercritical extraction of the sugar components using a 6.77 wt.% water mixed CO2 solvent system at a pressure of 308 bar, temperature of 65 °C, and CO2 flow rate of 31,000 kg/h; and (c) spray-drying of the extract using 40 wt.% Gum Arabic as the carrier agent and air as drying medi... [more]