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Records with Subject: Energy Systems
Showing records 6476 to 6500 of 9568. [First] Page: 256 257 258 259 260 261 262 263 264 Last
Smart Energy Management System: Design of a Smart Grid Test Bench for Educational Purposes
Oussama Laayati, Hicham El Hadraoui, Nasr Guennoui, Mostafa Bouzi, Ahmed Chebak
March 1, 2023 (v1)
Keywords: education, energy management, Optimization, PLC, remote laboratory, renewable energies, SCADA, smart grid
The presented article aims to design an educational test bench setup for smart grids and renewable energies with multiple features and techniques used in a microgrid. The test bench is designed for students, laboratory engineers, and researchers, which enables electrical microgrid system studies and testing of new, advanced control algorithms to optimize the energy efficiency. The idea behind this work is to design hybrid energy sources, such as wind power, solar photovoltaic power, hydroelectric power, hydrogen energy, and different types of energy storage systems such as batteries, pumped storage, and flywheel, integrating different electrical loads. The user can visualize the state of the components of each emulated scenario through an open-source software that interacts and communicates using OPC Unified Architecture protocol. The researchers can test and validate new solutions to manage the energy behavior in the grid using machine learning and optimization algorithms integrated i... [more]
Analogies in the Analysis of the Thermal Status of Batteries and Internal Combustion Engines for Mobility
Luigi Sequino, Ezio Mancaruso, Bianca Maria Vaglieco
March 1, 2023 (v1)
Keywords: battery, engine, experiments, Modelling, thermal analysis
Thermal management is an important research area for the automotive sector in order to make high-efficiency and low-impact future vehicles. The transition from internal combustion engines to battery systems in the automotive field requires new skills to be achieved in the shortest possible time. The well-consolidated knowledge of thermal management of engine systems can be rearranged to face new challenges regarding the thermal control of batteries. The present work aims to show the analogies between the thermal behavior of an engine component, such as the piston, and of a battery. The thermodynamic processes involved during the operation are described, experimentally investigated, and modeled. The external temperature of the piston window is measured once per cycle with a K-type sheathed thermocouple, while the surface temperature of the battery is detected via infrared imaging. An almost-fixed stabilization time of 500 s is observed for the engine while it varies with the current loa... [more]
Polyhumous Dystrophic Pit Lakes: Hydrographic and Hydrochemical Characteristics on the Example of Reservoirs in the Włoszczowska Basin, Central Poland
Tadeusz Molenda, Beata Kostka, Ireneusz Malik, Paweł Lejwoda, Wiktor Radziejowski, Joanna Kidawa
March 1, 2023 (v1)
Keywords: bog, dystrophy lake, humic lake, humic state index, hydrochemical dystrophy index, mine waters
The article presents the hydrographic and hydrochemical characteristics of post-exploitation reservoirs formed in peat excavations. Two natural bog lakes were selected as the control objects for the study. The research indicated that both the waters of post-exploitation peat reservoirs and natural bog lakes show low electrolytic conductivity (<100 µS/cm) and acidic water reaction (pH < 5.5). The concentration of major cations and anions is also very low. The concentration of calcium and magnesium does not exceed a few mg/L. Hydrochemically, all post-exploitation peat reservoirs are bi-ionic sulphate−calcium (SO42−-Ca2+). This distinguishes post-exploitation peat reservoirs from natural bog lakes in which multi-ion waters were found, for example, sulphate−chloride−calcium (SO42−-Cl−-Ca2+) and sulphate−calcium−sodium (SO42−-Ca2+-Na+). The calculated water humic state index (HSI) allowed the classifying of the examined reservoirs as polyhumous. The value of this index, in all reservoir... [more]
Deeper Understanding of Ternary Eutectic Carbonates/Ceria-Based Oxide Composite Electrolyte through Thermal Cycling
André Grishin, Manel Ben Osman, Haïtam Meskine, Valérie Albin, Virginie Lair, Michel Cassir, Armelle Ringuedé
March 1, 2023 (v1)
Keywords: carbonate eutectic/ceria composite, hybrid fuel cell electrolyte, MCFC, multi-ionic conductor, SOFC, thermal cycling, transport mechanisms
Due to a high conductivity of about 0.1 S·cm−1, Li-Na-K carbonate eutectic and Sm-doped ceria composite material is a good electrolyte candidate for hybrid fuel cells operating between 500 °C and 600 °C. The present paper aims at a deeper understanding of the species and mechanisms involved in the ionic transport through impedance spectroscopy and thermal analyses, in oxidizing and reducing atmospheres, wet and dry, and during two heating/cooling cycles. Complementary structural analyses of post-mortem phases allowed us to evidence the irreversible partial transformation of molten carbonates into hydrogenated species, when water and/or hydrogen are added in the surrounding atmospheres. Furthermore, this modification was avoided by adding CO2 in anodic and/or cathodic compartments. Finally, a mechanistic model of such composite electrical behavior is suggested, according to the surrounding atmospheres used. It leads to the conclusions that cells based on this kind of electrolyte would p... [more]
An Iterative Algorithm for the Estimation of Thermal Boundary Conditions Varying in Both Time and Space
Piotr Duda, Mariusz Konieczny
March 1, 2023 (v1)
Keywords: convective heat transfer coefficient estimation, inverse heat conduction problem, Levenberg-Marquardt algorithm, nonlinear estimation, steam boilers
The presented survey of the up-to-date state of knowledge indicates that despite the great number of works devoted to the issue in question, there is no simple method that allows the use of commercial programs for the identification of the transient thermal state in elements with a simple or complex shape. This paper presents an inverse method developed to estimate the convective heat transfer coefficient varying both in time and space on a vertical plate during its cooling. Despite the smaller number of measurement points and larger disturbance of measured temperatures compared to the data presented in the available literature, comparable results are obtained. The developed iterative algorithm is also applied to estimate the time- and space-dependent heat flux and the convective heat transfer coefficient in the steam boiler membrane waterwall. The analysed component has the form of the non-simply connected and complex shape domain Ω. Temperature-dependent thermophysical properties are... [more]
Parameter Studies on Hydraulic Fracturing in Brittle Rocks Based on a Modified Hydromechanical Coupling Model
Yulong Zhang, Yiping Zhang, Bei Han, Xin Zhang, Yun Jia
March 1, 2023 (v1)
Keywords: discrete element method, fluid injection rate, fluid viscosity, hydraulic fracturing, in situ stress, particle flow simulation
In this paper, we present a numerical study of hydraulic fracturing in brittle rock by using particle flow simulation. The emphasis is put on the influence of in situ stress, differential stress, fluid injection rate, fluid viscosity and borehole size on hydraulic fracturing behavior. To this end, an improved hydromechanical coupling model is first introduced to better describe fluid flow and local deformation of particle-based rocks. A series of parameter sensitivity studies are then conducted under the framework of particle flow simulation. Modelling results suggest that the breakdown pressure and time to fracture both linearly increase with confining stress, and hydraulic fracturing patterns present a distinct transition from brittle to ductile. Fluid injection rate and fluid viscosity have similar influences on hydraulic fracturing propagation, their value decrease leads to borehole pressure decrement and time to fracture prolongation. However, the former mainly controls the time t... [more]
State of the Art, Perspective and Obstacles of Ground-Source Heat Pump Technology in the European Building Sector: A Review
Davide Menegazzo, Giulia Lombardo, Sergio Bobbo, Michele De Carli, Laura Fedele
March 1, 2023 (v1)
Keywords: energy transition, ground coupled heat pump, ground source heat pump
In the European Union, 40% of the overall final energy consumption is attributable to the buildings sector. A reason for such data may be found considering that the great majority of the building stock is more than 40 years old. According to the European Commission, an interesting potential lies in the refurbishment of the building sector, and heat pump technology has been recognized as one of the most cost-effective solutions to tackle the environmental issue of this sector. Regarding heat pump technology, ground-source heat pumps (GSHPs) have been proven to be the most efficient solution on equal boundary conditions. Despite this, in most EU states’ markets, GSHPs hold only a small market share with respect to air-source heat pumps. In this paper, the state of art and possible future developments of GSHP technology have been reviewed together with a focus on the potential of such technology, most of all on the refurbishment of existing buildings, and on the obstacles to its spread. T... [more]
Membrane and Electrochemical Based Technologies for the Decontamination of Exploitable Streams Produced by Thermochemical Processing of Contaminated Biomass
Dimitrios Koutsonikolas, George Karagiannakis, Konstantinos Plakas, Vasileios Chatzis, George Skevis, Paola Giudicianni, Davide Amato, Pino Sabia, Nikolaos Boukis, Katharina Stoll
March 1, 2023 (v1)
Keywords: decontamination, electrochemical oxidation, electrocoagulation, fast pyrolysis, membrane gas absorption, microfiltration, supercritical water gasification
Phytoremediation is an emerging concept for contaminated soil restoration via the use of resilient plants that can absorb soil contaminants. The harvested contaminated biomass can be thermochemically converted to energy carriers/chemicals, linking soil decontamination with biomass-to-energy and aligning with circular economy principles. Two thermochemical conversion steps of contaminated biomass, both used for contaminated biomass treatment/exploitation, are considered: Supercritical Water Gasification and Fast Pyrolysis. For the former, the vast majority of contaminants are transferred into liquid and gaseous effluents, and thus the application of purification steps is necessary prior to further processing. In Fast Pyrolysis, contaminants are mainly retained in the solid phase, but a part appears in the liquid phase due to fine solids entrainment. Contaminants include heavy metals, particulate matter, and hydrogen sulfide. The purified streams allow the in-process re-use of water for... [more]
Knowledge and Skills Development in the Context of the Fourth Industrial Revolution Technologies: Interviews of Experts from Pennsylvania State of the USA
Sebastian Saniuk, Sandra Grabowska, Wieslaw Grebski
March 1, 2023 (v1)
Keywords: energy consumption, Fourth Industrial Revolution, human factors, Industry 5.0, knowledge and skills of engineers, sustainable production and consumption
Fourth industrial revolution is the introduction of ICT (mostly IoT) in industry and elsewhere, which enables the creation of cyber-physical systems, i.e., digital twins of reality. The application of widespread digitization of processes brings changes in terms of increased efficiency of processes, increased flexibility of production, and the possibility of realizing prosocial and pro-ecological goals, such as sustainable development, sustainable production and consumption, and reducing the consumption of increasingly expensive energy. Nowadays, the high autonomy of cyber-physical systems and benefits to society are expected by including human factors within the Industry 5.0 concept. Implementing the Fourth Industrial Revolution technologies and meeting the expectations of sustainable development also means new challenges for the knowledge and skills of industry employees, mainly engineers implementing modern solutions. Hence, the article’s aim is to identify the critical knowledge and... [more]
Synthesis of Chitosan Derivatives and Their Inhibition Effects on Methane Hydrates
Yue Zhang, Zhi Li, Xiaodeng Yang, Tianduo Li
March 1, 2023 (v1)
Keywords: chitosan, derivatives, kinetics hydrate inhibitors, methane hydrate
In recent years, the study of natural polymer products such as methane hydrate inhibitors has attracted more and more attention in the scientific research field. In order to achieve environmentally friendly and economical methane hydrate inhibitors with high activity, four chitosan derivatives were successfully synthesized and their methane hydrate inhibition effects were compared with chitosan (CS) and carboxymethyl chitosan (CMCS). Under the conditions of 6 MPa, 1 °C and 400 rpm, the induction time of methane hydrate was prolonged by 7.3 times with the addition of 0.1 wt% CS. It was found that chitosan with high hydrophobicity could effectively prevent methane gas from entering the water solution and reduce the driving force of methane hydrates, resulting in the extension of hydrate induction time. The hydrate inhibition effect of CMCS could be improved by the introduction of hydroxypropyl-3-trimethylamine and N-2-hydroxypropyl-3-isooctyl ether groups based on the enhancement of the... [more]
Process-Product Interdependencies in Lamination of Electrodes and Separators for Lithium-Ion Batteries
Ruben Leithoff, Arian Fröhlich, Steffen Masuch, Gabriela Ventura Silva, Klaus Dröder
March 1, 2023 (v1)
Keywords: battery production, greyscale analysis, high potential test, lamination, lithium-ion batteries, quality control
In today’s cell production, the focus lies on maximizing productivity while maintaining product quality. To achieve this, the lamination of electrode and separator is one key process technology, as it bonds the electrode and separator to form mechanically resilient intermediate products. These mechanically resilient intermediates are necessary to enable high throughput processes. Although the lamination process has significant effects on the electrochemical performance of battery cells, it has not been sufficiently researched with regard to its process-product interdependencies. Therefore, this paper addresses the investigation of these interdependencies and proposes three characterization methods (grey scale analysis, high potential tests, electrochemical cycling and C-rate tests). The results of the three methods show that the lamination process with its process parameters (lamination temperature, lamination pressure and material feed rate) has an influence on both the properties of... [more]
Deploying Taller Turbines in Complex Terrain: A Hill Flow Study (HilFlowS) Perspective
Sonia Wharton, Kathryn Foster
March 1, 2023 (v1)
Keywords: Altamont, complex terrain, hub-height, lidar, rotor-disk, wind energy, wind profile
Terrain-induced flow acceleration is presented for the summertime, peak power season at Lawrence Livermore National Laboratory’s Site 300 for the Hill Flow Study (HilFlowS). HilFlowS, designed as an adjunct field campaign to the Department of Energy’s Second Wind Forecasting Improvement Project (WFIP2), provides wind profile observations at a second location in complex terrain for validating numerical atmospheric model simulations and for better understanding flow behavior over hills for wind power generation. One unique feature of HilFlowS was the inclusion of an undergraduate university student who helped plan and execute the experiment as well as analyze wind data from two remote sensing laser detection and ranging (lidar) instruments deployed along parallel ridgelines. HilFlowS examines the trend of building higher into the atmosphere for the purpose of increasing wind turbine power production and evaluates the wind resource in the Altamont Pass Region of Northern California for a... [more]
Development of a Predicting Model for Calculating the Geometry and the Characteristic Curves of Pumps Running as Turbines in Both Operating Modes
Silvio Barbarelli, Vincenzo Pisano, Mario Amelio
March 1, 2023 (v1)
Keywords: experimental test, optimization procedure, predicting model, pumps as turbines
This article is part of a scientific research project dedicated to the study of plants generating electricity from hydraulic sources by exploiting the technology of inverted flow centrifugal pumps, also known as PAT. The main purpose is to provide a contribution to the methodologies already existing in the literature, creating a one-dimensional model capable of predicting the characteristic curves of the machine, in both operating modes, without knowing its geometry. The first part of the work is therefore focused on the description of the fluid dynamic model, capable of determining the losses in the various sections of the machine, using different calculation approaches. The development of this model was carried out using a set of six centrifugal pumps, measured at the DIMEG Department of the University of Calabria and at the University of Trento. For this range of pumps, the characteristic curves were therefore obtained, both in pump and turbine operation. The second part of this wor... [more]
Momentum-Dependent Cosmic Ray Muon Computed Tomography Using a Fieldable Muon Spectrometer
Junghyun Bae, Stylianos Chatzidakis
March 1, 2023 (v1)
Keywords: cosmic ray muons, muon momentum, muon spectrometer, muon tomography
Cosmic ray muon tomography has been recently explored as a non-destructive technique for monitoring or imaging dense well-shielded objects, classically not achievable with traditional tomographic methods. As a recent example of technology transition from high-energy physics to real-world engineering applications, cosmic ray muon tomography has been used with various levels of success in nuclear nonproliferation. However, present muon detection systems have no momentum measurement capabilities and recently developed muon-based radiographic techniques rely only on muon tracking. This unavoidably reduces resolution and requires longer measurement times thus limiting the widespread use of cosmic ray muon tomography. Measurement of cosmic ray muon momenta has the potential to significantly improve the efficiency and resolution of cosmic ray muon tomography. In this paper, we propose and explore the use of momentum-dependent cosmic ray muon tomography using multi-layer gas Cherenkov radiator... [more]
Sectoral Analysis of the Fundamental Criteria for the Evaluation of the Viability of Wave Energy Generation Facilities in Ports—Application of the Delphi Methodology
Raúl Cascajo, Rafael Molina, Luís Pérez-Rojas
March 1, 2023 (v1)
Keywords: clean energy, Renewable and Sustainable Energy, SDG, Wave Energy, wave energy converter
Nearly 40% of the world’s population lives within 100 kilometres of the coast with the risk that this implies in terms of exposure to the effects of climate change. Ocean energy, according to the IPCC (Intergovernmental Panel on Climate Change) in 2019, has been identified as one of the measures for mitigating these effects. In addition, ocean energy can play an essential role in achieving some of the SDGs (Sustainable Development Goals) set at the Paris Climate Summit in 2015, namely SDG 7 (clean and affordable energy) and SDG 13 (climate action) and could have a substantial impact on others such as SDG 1 (poverty eradication), SDG 2 (end hunger), SDG 5 (gender equality), SDG 6 (universal energy access), SDG 8 (promote sustainable economic growth), SDG 9 (build resilient infrastructure), SDG 14 (sustainable conservation of oceans and seas) and SDG 17 (promote sustainable development cooperation). There are several projects under development around the world aimed at extracting energy... [more]
An Electro-Thermal Model for LFP Cells: Calibration Procedure and Validation
Michele Barbieri, Massimo Ceraolo, Giovanni Lutzemberger, Claudio Scarpelli
March 1, 2023 (v1)
Keywords: battery, experimental, lithium, model, test
Lithium batteries for energy storage systems are a prominent solution for both stationary and mobile applications. Electro-thermal modelling of the cell is a useful tool for monitoring voltage and temperature in order to predict battery behaviour especially in cases of critical operative conditions. This paper provides a modelling approach focusing on the calibration of parameters of an electro-thermal model for large prismatic LFP lithium cells. The designed model is tuned by means of experimental tests that identify a set of parameters that are function of a cell’s state-of-charge and temperature. The model outputs are voltage, cell surface, and internal temperature profiles, which are validated against experimental data referring to realistic working conditions, even providing an intense level of thermal stress. The model accuracy is marked by a voltage mean average error lower than 1% and a mean cell surface temperature deviation lower than 1 K.
Out-of-Step Prediction Using DQN-Based Disturbance Observer and Its RTDS Verification
Sun Jick Yang, Nebiyeleul Daniel Amare, Jun Woo Kim, Young Ik Son
March 1, 2023 (v1)
Keywords: internal model-based disturbance observer, power system protection, real-time digital simulator, reinforcement learning, single machine infinite bus system, synchronous out-of-step detection
Despite having extensive research dedicated towards designing methodologies for synchronous out-of-step detection, the risk posed by a large-scale power blackout still makes power system protection an active research area. In recent decades, multiple out-of-step detection techniques such as impedance-based relays and equal-area criterion-analysis-based methods have been widely adopted. However, these conventional techniques have been known to suffer from drawbacks that may be attributed to the inherent assumptions of their foundational design principles. Therefore, to alleviate some of the problems faced in the currently adopted techniques, researchers have been studying the implementation of estimation algorithms for synchronous out-of-step detection. Aiming to contribute to this research area, this paper proposes a synchronous out-of-step detection algorithm that uses a deep Q-network-based disturbance observer, robust to measurement noise. Using the disturbance estimation provided b... [more]
Firefly Algorithm-Based Optimization of the Additional Energy Yield of Bifacial PV Modules
Ibukun Damilola Fajuke, Atanda K. Raji
March 1, 2023 (v1)
Keywords: additional energy yield, bifacial PV module, Firefly Algorithm, Renewable and Sustainable Energy
A solar bifacial photovoltaic (PV) module is designed so that it permits the addition of the back electrode to the prevailing silicon PV on the front side. Hence, it has the ability to harvest energy using its front and back faces. This study presents an optimization model for calculating the extra energy yield (EY) that can be harvested from the backside of a bifacial PV module using the Firefly Algorithm (FA). Mathematical modelling of the various parameters that influence the extra EY of the backside of a bifacial module was carried out using SIMULINK. Moreover, the mathematical model of the EY of the module was also carried out and then optimized using FA. The optimization model was confined to two orientation states namely the vertical south−north and vertical east−west at Ogbomosho (8.1227° N, 4.2436° E), Nigeria, with different values of albedo and mounting heights. The simulation result shows that the vertical east−west oriented modules outperform the vertical south−north orien... [more]
Energy Cell Simulation for Sector Coupling with Power-to-Methane: A Case Study in Lower Bavaria
Robert Bauer, Dominik Schopf, Grégoire Klaus, Raimund Brotsack, Javier Valdes
March 1, 2023 (v1)
Keywords: energy cell simulation, Energy Storage, energy systems modeling, Power-to-Methane, Renewable and Sustainable Energy, sector coupling
In this study, the possibility of sector coupling with biological Power-to-Methane to support and stabilize the energy transition of the three major sectors of electricity, heat, and gas was addressed. For this purpose, the energy cell simulation methodology and the Calliope tool were utilized for energy system optimization. This combination provides detailed insights into the existing dependencies of consumers and fossil and renewable energy suppliers on a local scale. In this context, Power-to-Methane represents an efficient technology for quickly and effectively exploiting unused electricity potential for various sectors and consumers. It was found that, even in regions with low wind levels, this surplus electricity potential already exists and depends on various influencing factors in very different ways. The solar influence on these potentials was considered in connection with gas-fired cogeneration plants for district heating. It was found that the current heat demand for distric... [more]
Research on Oil Mist Leakage of Bearing in Hydropower Station: A Review
Jie Sun, Yuquan Zhang, Bin Liu, Xinfeng Ge, Yuan Zheng, Emmanuel Fernandez-Rodriguez
March 1, 2023 (v1)
Keywords: engineering measures, hydropower station, multi-phase flow and mass transfer problems, numerical simulation, oil mist leakage, oil throwing
Hydropower is a clean and renewable energy, fundamental to the attainment of a sustainable society. Despite its efficacy and success, there is a need to address the hydroelectric stations’ oil throwing and mist leakage, resulting in the deterioration of the generating units, water, and biodiversity. The conventional engineering measures to deal with oil mist leakage include: the reduction in the operating pad and oil temperature, optimization of the oil circulation loop in the oil tank, improvement of the sealing performance, and design of the oil mist emission device. However, the problem of oil mist leakage of bearings is complex, intractable, and cannot be solved by only one method. Numerical simulation can help to solve the oil mist problem and make up for the shortage of engineering measures. Yet, the mass transfer, involving multi-component and multi-phase flow, becomes a limitation for many numerical studies. As a result, this paper seeks to integrate the solutions by reviewing... [more]
Thermal Abuse Tests on 18650 Li-Ion Cells Using a Cone Calorimeter and Cell Residues Analysis
Maria Luisa Mele, Maria Paola Bracciale, Sofia Ubaldi, Maria Laura Santarelli, Michele Mazzaro, Cinzia Di Bari, Paola Russo
March 1, 2023 (v1)
Keywords: cone calorimeter, DSC, lithium-ion cell, over-discharge, SEM-EDS, SoC, thermal runaway, XRD
Lithium-ion batteries (LIBs) are employed when high energy and power density are required. However, under electrical, mechanical, or thermal abuse conditions a thermal runaway can occur resulting in an uncontrollable increase in pressure and temperature that can lead to fire and/or explosion, and projection of fragments. In this work, the behavior of LIBs under thermal abuse conditions is analyzed. To this purpose, tests on NCA 18,650 cells are performed in a cone calorimeter by changing the radiative heat flux of the conical heater and the State of Charge (SoC) of the cells from full charge to deep discharge. The dependence of SoC and radiative heat flux on the thermal runaway onset is clearly revealed. In particular, a deep discharge determines an earlier thermal runaway of the cell with respect to those at 50% and 100% of SoC when exposed to high radiative heat flux (50 kW/m2). This is due to a mechanism such as an electrical abuse. Cell components before and after tests are investi... [more]
Technology-Agnostic Assessment of Wave Energy System Capabilities
Pablo Ruiz-Minguela, Jesus M. Blanco, Vincenzo Nava, Henry Jeffrey
March 1, 2023 (v1)
Keywords: commercial attractiveness, design domains, drivers, metrics, requirements, stakeholders, systems engineering, technical achievability, technology-agnostic
Developing new wave energy technologies is risky, costly and time-consuming. The large diversity of concepts, components and evaluation criteria creates a vast design space of potentially feasible solutions. This paper aims to introduce a novel methodology for the holistic assessment of wave energy capabilities in various market applications based on sound Systems Engineering methods. The methodology provides a consistent hierarchy of performance metrics relevant to the given system of reference, design activity and development stage under consideration as a means to scrutinise wave energy requirements. Full traceability of system requirements and performance metrics is then facilitated by multi-criteria decision tools and aggregation logic, respectively. The qualitative assessment in the case studies has resulted in very different rankings of System Drivers and Stakeholders for the two market applications considered. However, the Stakeholder Requirements and Functional Requirements pr... [more]
Editorial on Special Issues of Development of Unconventional Reservoirs
Reza Rezaee
March 1, 2023 (v1)
The energy transition to renewable energy is inevitable since fossil fuels are a finite source [...]
Microbial Electrolysis Cell as a Diverse Technology: Overview of Prospective Applications, Advancements, and Challenges
Devi Radhika, Archana Shivakumar, Deepak R. Kasai, Ravindranadh Koutavarapu, Shaik Gouse Peera
March 1, 2023 (v1)
Keywords: challenges, energy generation, hydrogen peroxide, hydrogen/biohydrogen production, methane, microbial electrolysis cell, pollutant removal
Microbial electrolysis cells (MECs) have been explored for various applications, including the removal of industrial pollutants, wastewater treatment chemical synthesis, and biosensing. On the other hand, MEC technology is still in its early stages and faces significant obstacles regarding practical large-scale implementations. MECs are used for energy generation and hydrogen peroxide, methane, hydrogen/biohydrogen production, and pollutant removal. This review aimed to investigate the aforementioned uses in order to better understand the different applications of MECs in the following scenarios: MECs for energy generation and recycling, such as hydrogen, methane, and hydrogen peroxide; contaminant removal, particularly complex organic and inorganic contaminants; and resource recovery. MEC technology was examined in terms of new concepts, configuration optimization, electron transfer pathways in biocathodes, and coupling with other technologies for value-added applications, such as MEC... [more]
Performance Comparison of LMNO Cathodes Produced with Pullulan or PEDOT:PSS Water-Processable Binders
Alessandro Brilloni, Francesco Marchesini, Federico Poli, Elisabetta Petri, Francesca Soavi
March 1, 2023 (v1)
Keywords: electronically conducting polymer, lithium-ion battery cathode, LMNO, PEDOT:PSS, pullulan, water processable binder
The aim of this paper is to demonstrate lithium metal battery cells assembled with high potential cathodes produced by sustainable processes. Specifically, LiNi0.5Mn1.5O4 (LMNO) electrodes were fabricated using two different water-processable binders: pullulan (PU) or the bifunctional electronically conductive poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT:PSS). The cell performance was evaluated by voltammetric and galvanostatic charge/discharge cycles at different C-rates with 1M LiPF6 in 1:1 (v:v) ethylene carbonate (EC):dimethyl carbonate (DMC) (LP30) electrolyte and compared to that of cells assembled with LMNO featuring poly(vinylidene difluoride) (PVdF). At C/10, the specific capacity of LMNO-PEDOT:PSS and LMNO-PU were, respectively, 130 mAh g−1 and 127 mAh g−1, slightly higher than that of LMNO-PVdF (124 mAh g−1). While the capacity retention at higher C-rates and under repeated cycling of LMNO-PU and LMNO-PVdF electrodes was similar, LMNO-PEDOT:PSS featured su... [more]
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