Operators of commercial anaerobic digestion (AD) plants frequently note the challenge of transferring research results to an industrial setting, especially in matching well-controlled laboratory studies at a constant organic loading rate (OLR) with full-scale digesters subject to day-to-day variation in loadings. This study compared the performance of food waste digesters at fluctuating and constant OLR. In a long-term experiment over nearly three years, variable daily OLR with a range as wide as 0 to 10.0 g VS L−1 day−1 (weekly average 5.0 g VS L−1 day−1) were applied to one laboratory-scale digester, while a pair of control digesters was operated at a constant daily loading of 5.0 g VS L−1 day−1. Different schemes of trace elements (TE) supplementation were also tested to examine how they contributed to process stability. Variable loading had no adverse impact on biogas production or operational stability when 11 TE species were dosed. When TE addition was limited to cobalt and selen... [more]

Maize and wheat are two of the most widespread crops worldwide because of their high yield and importance for food, chemical purposes and livestock feed. Some of the residues of these crops (i.e., maize cob and wheat chaff) remain in the field after grain harvesting. In Europe, just maize cob and grain chaff could provide an annual potential biomass of 9.6 Mt and 54.8 Mt, respectively. Collecting such a biomass could be of interest for bioenergy production and could increase farmers’ income. Progress in harvest technology plays a key role in turning untapped by-products into valuable feedstocks. This article presents a study of the performance and the quality of the work of Harcob, an innovative system developed for maize cob collection. Furthermore, the feasibility of using the Harcob system to also harvest wheat chaff during wheat harvesting was also verified. The results showed that it was possible to harvest 1.72 t ha−1 and 0.67 t ha−1 of cob and chaff, respectively, without affect... [more]

The manuscript presents the possibilities of using selected Lean Management tools at a fast food restaurant located at the international airport terminal in Poland. Observations in other points of the company lasting for five years, made possible fair proposals for improvement of selected elements of production and work organization. The research part presents the results of application of such tools as value stream mapping (VSM), Kaizen, and 5S. The Lean Management method, chosen after careful analysis of the work system in the facility, contributed to the increase of work efficiency. Production times were shortened. Additionally, the possibility of reducing energy consumption, and thus the reduction of CO2 emissions associated with production, achieved without interfering with product quality was demonstrated. The timetable for device work was proposed. It was selected based on the analysis of the daily number of transactions compared with energy consumption. It should be emphasized... [more]

This paper analyses potential geothermal sites in North-East Croatia which is part of the Pannonian Basin System where a substantial geothermal potential was discovered during hydrocarbon exploration using the Multi-Criteria Decision-Making Tool specially developed for the purposes of the Horizon 2020 project: Multidisciplinary and multi-context demonstration of EGS exploration and Exploitation Techniques and potentials (H2020 MEET). Most of these sites use available geothermal energy potential for commercial purposes, mainly for balneology and more recently for agriculture and electricity generation. The case study involves five different geothermal locations chosen according to their geothermal potential, the current state of production and possible future development, including one oil field that is at the very end of its production life. Three potential final users’ types; agriculture demand, electricity generation demand and district heating have been evaluated for each of the fiv... [more]

The main objective of the Portuguese project “CONVERTE-Biomass Potential for Energy” is to support the transition to a low-carbon economy, identifying biomass typologies in mainland Portugal, namely agri-forest waste, energy crops and microalgae. Therefore, the aim was to design and construct a georeferenced (mapping) database for mainland Portugal, to identify land availability for the implementation of energy crops and microalgae cultures, and to locate agricultural and forestry production areas (including their residues) with potential for sustainable exploitation for energy. The ArcGIS software was used as a Geographic Information System (GIS) tool, introducing the data corresponding to the type of soil, water needs and edaphoclimatic conditions in shapefile and raster data type, to assess the areas for the implantation of the biomass of interest. After analysing the data of interest in each map in ArcGIS, the intersection of all maps is presented, suggesting adequate areas and pre... [more]

Microalgae are promising feedstock for the production of biodiesel and diverse medium- and high-value products such as pigments and polyunsaturated fatty acids. The importance of strain selection adapted to specific environments is important for economical purposes. We characterize here two microalgal strains, isolated from wastewater of shrimp cultivation ponds in Vietnam. Based on the 18S rDNA-ITS region, one strain belongs to the Eustigmatophyceae class and is identical to the Nannochloropsis salina isolate D12 (JX185299.1), while the other is a Chlorophyceae belonging to the Desmodesmus genus, which possesses a S516 group I intron in its 18S rDNA gene. The N. salina strain is a marine and oleaginous microalga (40% of dry weight (DW) at stationary phase) whole oil is rich in saturated fatty acids (around 45% of C16:0) suitable for biodiesel and contains a few percent of eicosapentaenoic acid (C20:5). The Desmodesmus isolate can assimilate acetate and ammonium and is rich in lutein.... [more]

This paper explores the feasibility of flexible biogas production by co-digestion of food waste and sewage sludge based on experiments and mathematical modeling. First, laboratory-scale experiments were carried out in variable operating conditions in terms of organic loading rate and feeding frequency to the digester. It is demonstrated that biogas production can achieve rapid responses to arbitrary feedings through co-digestion, and the stability of the anaerobic digestion process is not affected by the overloading of substrates. Compared with the conventional continuous mode, the required biogas storage capacity in flexible feeding mode can be significantly reduced. The optimum employed feeding organic loading rate (OLR) is identified, and how to adjust the feeding scheme for flexible biogas production is also discussed. Finally, a simplified prediction model for flexible biogas production is proposed and verified by experimental data, which could be conveniently used for demand-orie... [more]

This paper presents an analysis of selected qualitative characteristics of pellets produced from rape straw obtained from cultivations subjected to different fertilization treatments and from mixtures of straw selected for testing with crude glycerol obtained as a by-product from biodiesel production. The assessment focused on the following qualities of the obtained pellets: Moisture content, mechanical durability, heating value and main elements, that is, carbon, hydrogen, nitrogen, sulphur, chlorine and oxygen. The obtained results indicated that the different treatment regimens applied in spring rape cultivations had a significant impact on the physicochemical qualities of the straw. In terms of the heating value, traditional fertilization with multi-component fertilizer (NPK) yielded slightly lower chemical parameters (lower carbon content and heat of combustion) than in the case of straw obtained from the control sample and from the plot fertilized with digestate. Furthermore, in... [more]

Palm oil is one of the most consumed oils, one of whose refining steps is the removal of pigments and other substances using bleaching clay as adsorbent. Worldwide production of this oil was 70 million tons in 2017, requiring 1 t of clay to produce 1000 t of refined oil. The residual bleaching clay, having an oil fraction (12.70%) rich in phenolics, carotenoids and tocopherols, was extracted in this study with ethanol to obtain an antioxidant-rich palm oil bleaching extract (POBE), with the aim of using it as a natural antioxidant source. The POBE antioxidant capacity determined by the DPPH method corresponded to a 20.29% inhibition of radical formation. The POBE was also tested for its potential to enhance oxidative stability of passion fruit, pracaxi and Brazil nut oils used as reference oils, and compared to common synthetic antioxidants (tert-butylhydroquinone and propyl gallate), either separately as controls or in mixtures with them. Besides the increased oxidative stability of t... [more]

In large-scale arable farming, multiple sequential operations involving multiple machines must be carried out simultaneously due to restrictions of short time windows. However, the coordination and planning of multiple sequential operations is a nontrivial task for farmers, since each operation may have its own set of operational features, e.g., operating width and turning radius. Taking the two sequential operations—hoeing cultivation and seeding—as an example, the seeder has double the width of the hoeing cultivator, and the seeder must remain idle while waiting for the hoeing cultivator to finish two rows before it can commence its seeding operation. A flow-shop working mode can coordinate multiple machines in multiple operations within a field when different operations have different implement widths. To this end, an auto-steering-based collaborative operating system for fleet management (FMCOS) was developed to realize an in-field flow-shop working mode, which is often adopted by... [more]

Agriculture affects both the quantity and the quality of water available for other purposes, which becomes problematic, especially during increasingly frequent severe droughts. This requires tapping into the resources that are typically neglected. One such resource is a by-product of anaerobic digestion, in which moisture content typically exceeds 90%. Application of hydrothermal carbonization process (HTC) to this residue could partially remove organic and inorganic material, improve dewatering, decrease the overall solid mass, sanitize the digestate, change its properties, and eliminate problems related with emissions of odors from the installation. However, a significant gap still exists in terms of the dewatering of the hydrochars and the composition of the effluents. This work presents results of experimental investigation focused on the removal of organic compounds from the HTC effluent. Results of qualitative and quantitative analysis of liquid by-products of HTC of the agricult... [more]

The optimum nitrogen concentration for media supplementation and strain dominance are aspects of key importance to the industrial production of ethanol with a view to reducing costs and increasing yields. In this work, these two factors were investigated for four ethanologenic Saccharomyces cerevisiae strains (CLQCA-INT-001, CLQCA-INT-005, CLQCA-10-099, and UCLM 325), selected from the screening of 150 isolates, mostly from Ecuadorian yeast biodiversity. The effect of nitrogen concentration was assessed in terms of cellular growth, glucose consumption and ethanol production, and the yeast strains’ dominance was evaluated in continuous co-fermentation with cellular recycling by mitochondrial DNA analyses. Among the four selected yeast strains under study, CLQCA-INT-005 presented the highest glucose consumption at a nitrogen supplement concentration as low as 0.4 g·L−1, attaining an ethanol yield of up to 96.72% in 24 h. The same yeast strain was found to be highly competitive, showing a... [more]

In this study, an energy consumption model of a decanter centrifuge was proposed, in particular for a technologically evolved machine equipped with an electromechanical recovery system. This model should be suitably coupled with an auto-adaptive controlling technique used to accurately manage the olive oil process. To achieve this goal, a solid physical and theoretical basis that simple to implement is required. To date there have only been limited scientific studies modelling energy consumption applied to the machines used in olive oil extraction processes. Therefore, the model was developed using fluid dynamic analysis and physical constraints to give it a solid basis. It was then simplified sufficiently for future implementation in automatic machine systems. The empirical model was validated through power measurements conducted in two harvesting seasons under varying operating conditions. The model estimates the power absorbed by the bowl and that produced and recovered by the screw... [more]

The cultivation of plants in greenhouses currently plays a role of primary importance in modern agriculture, both for the value obtained with the products made and because it favors the development of highly innovative technologies and production techniques. An intense research effort in the field of energy production from renewable sources has increasingly led to the development of greenhouses which are partially covered by photovoltaic elements. The purpose of this study is to present the potentiality of an innovative prototype photovoltaic greenhouse with variable shading to optimize energy production by photovoltaic panels and agricultural production. With this prototype, it is possible to vary the shading inside the greenhouse by panel rotation, in relation to the climatic conditions external to the greenhouse. An analysis was made for the solar radiation available during the year, for cases of completely clear sky and partial cloud, by considering the 15th day of each month. In t... [more]

The olive orchard cultivation in Mediterranean countries results in huge amounts of lignocellulosic biomass residues. One of the main residues are olive leaves. Olive leaves contain high concentrations of bioactive antioxidant compounds like oleuropein and luteolin-7-glucoside. The production of biactive compounds from olive leaves requires treatments capable of breaking the lignocellulosic structure. Current research focuses on use of inexpensive, quick, and not harmful to the environment treatments, searching a more simplified large-scale operation approach. Recently, advances in applied chemistry have led to possible new emerging industrial techniques like ultrasound-assisted extraction (UAE). This technology is a promising candidate as a green treatment solution for olive leaves utilization in a biorefinery. However, this application goes through prior optimization of technique and operating conditions. The goal of this study was to optimize the extraction of oleuropein and luteoli... [more]

Cementitious grouts are being developed for use as sealing and support matrices (SSMs) in deep borehole disposal (DBD) where temperatures do not exceed 190 °C. They will seal radioactive waste containers into the bottom 2 km of holes drilled up to 5 km deep into the crystalline basement. The temperature and pressure is likely to be similar to those in hydrocarbon and geothermal energy wells, where grout placement and durability are affected. This paper reviews the potential cementing systems suitable for this application and explains why a single solution of a formulation of Class G oil well cement, silica flour, water, fluid loss additive, and retarding admixture has been selected. This type of formulation has been used extensively for over 100 years in well cementing. It should provide the short-term performance and durability required for an SSM, maintaining the seal around the waste packages within the disposal zone long after the boreholes are sealed back to the surface, and thus... [more]

Algae biorefinery is gaining much attention for the sustainable production of value-added products (e.g., biofuels, protein supplements etc.) globally. The current study aimed to investigate the relationship between lipid production and bacteria growth by an initial microalgae Chlorella vulgaris density culture in seafood wastewater effluent (SWE). According to our results, the initial C. vulgaris concentration in SWE influenced lipid accumulation. The concentration ranged from 25−35 mg·L−1 which corresponds to SWE’s chemical oxygen demand concentration of 365.67 ± 3.45 mg·L−1. A higher microalgae growth rate and lipid content of 32.15 ± 1.45% was successfully attained. A higher lipid content, approximately double, was observed when compared to the control (16.8 ± 0.5%). Moreover, this study demonstrates that bacteria inhibited microalgae growth as the initial cell density stepped over 35 mg·L−1, which also affected lipid accumulation. This study shows an optimal lipid accumulation att... [more]

In recent years, industries in the suburb have retrofitted their power supply units with solar power supply systems. Using solar power supply systems for various applications, such as food processing, enables energy expense saving. A promising opportunity in the food industry is solar-powered Pulsed Electric Field (PEF) used in the treatment of fruits and their by-products. For this application, a converter is proposed in this paper with a combination of a passive switched inductor cell and a switched capacitor cell. Furthermore, the derived topology possesses an extendable feature. This topology generates high voltage repetitive pulses with a single semiconductor switch and a reduced component count. Dynamic study of the converter is also performed with the derivation of the transfer function. Cost effective, reliable, and simple circuitry are the critical features of this topology. The circuit topology can generate high voltage pulses by increasing the number of switched inductors an... [more]

Biogas production is the most important and promising alternative for replacing fossil fuels in an environmentally friendly manner. Along with the many renewable energy sources available, biogas production occupies an irreplaceable position due to the undeniable availability of biomass and the need to manage agro-commercial waste. The article reviews the current state of technology used in the production of biogas for selected European examples in terms of methane fermentation efficiency and actual energy production. The novelty of the article is its description of innovative trends that have great potential to play an important role in this field in the near future. The development of the biogas industry in Europe is evident, although the dynamics vary from country to country. Different models are presented, which are based on the different types of feedstock used for biogas production and the proportion of substrates used in co-digesters. Of course, Germany is the undisputed pioneer... [more]

The aim of the study was to determine the effect of selected reaction parameters—temperature (37−57 °C), pH (5.8−7.9), substrates ratio (sucrose/sorbitol 0.5/1.5 to 1.5:0.5 (m/m)), and the presence of NaCl—on the course of fructosyl-sorbitol synthesis with an enzyme preparation (11 760 U/100 g of sucrose) containing fructosyltransferase and β-d-fructofuranosidase from Aspergillus niger. A mixture of at least three fructosyl sorbitol derivatives was obtained: two mono-fructosyl and one di-fructosyl. The highest content of all sorbitol derivatives combined was 2.7 g/100 mL for pH 6.8−6.9, and the sucrose/sorbitol ratio was 1:1. Increasing the reaction temperature from 37 to 57 °C reduced the time required to reach the maximum product content from 5 to 2 h, while the concentration did not increase. The addition of NaCl (0.63 M) extended the reaction time from 2 to 5 h and slightly lowered the maximum concentration of sorbitol derivatives (from 2.74 to 2.6 g/100 mL).

It is well known that cheese yield and quality are affected by animal genetics, milk quality (chemical, physical, and microbiological), production technology, and the type of rennet and dairy cultures used in production. Major differences in the same type of cheese (i.e., hard cheese) are caused by the rennet and dairy cultures, which affect the ripening process. This review aims to explore current technological advancements in animal genetics, methods for the isolation and production of rennet and dairy cultures, along with possible applications of microencapsulation in rennet and dairy culture production, as well as the challenge posed to current dairy technologies by the preservation of biodiversity. Based on the reviewed scientific literature, it can be concluded that innovative approaches and the described techniques can significantly improve cheese production.

During the alcoholic fermentation of grape sugars, wine yeast produces a range of secondary metabolites that play a critical role in the aroma profile of wines. One of the most impactful yeast-modified compound families, particularly in white wines, are the ‘fruity’ polyfunctional thiols, which include 3-mercaptohexan-1-ol (3-MH) and 4-mercapto-4-methylpentan-2-one (4-MMP). While the formation and stylistic contribution of these thiols have been extensively researched in white wines, little is known about the conditions leading to their formation in red wines. In this study, we explored the ability of yeast strains to modulate the release of these aroma compounds during the fermentation of two red musts. In laboratory-scale Pinot Noir fermentations, the formation of 3-MH strongly correlated with yeast β-lyase activity, particularly with the presence of certain genotypes of the flavour-releasing gene IRC7. Subsequent production of Grenache wine at the pilot scale, with detailed composit... [more]

Heavy metals mainly enter tea from the soil. In this study, stratified soil samples were collected, at a depth of 0−60 cm, using a soil drill in An-tea plantations. Speciation of As, Cd, Cr, Cu, Ni, Pb, and Zn was determined using the European Community Bureau of Reference sequential extraction method, and the heavy metal concentrations in the extracts were determined by inductively coupled plasma−mass spectrometry. Compared with other soil layers, the mean Cd, Cu, Pb, and Zn concentrations were highest in the 0−20 cm layer, the Ni concentrations were highest in the 20−40 cm layer, and the As and Cr concentrations were highest in the 40−60 cm layer. The mean contributions of the non-residual fractions, including the acid-soluble, reducible, and oxidizable fractions, to the total concentrations were higher than those of the residual fraction for Cr, Cu, and Ni at all depths in soil from a flat area, as well as for Cd and Zn at all depths in soil from a sloping area. The contributions of... [more]

In order to clarify the characteristics of fine-grained sedimentary lithofacies and the depositional models in lacustrine environments of the Chang 7 Member of the Upper Triassic Yanchang Formation in the Ordos Basin, we focus on the lacustrine lithofacies classification and controlling factors. Based on the typical field sections of the southern Ordos Basin, combined with the methods of organic geochemical analysis, polarizing microscopic observation, XRD and elemental geochemistry, we summarize the main controlling factors of the lithofacies under different sedimentary environments and establish the sedimentary model under different sedimentary backgrounds. Results show that the Chang 7 Member of the Ordos Basin includes six major lithofacies types, i.e., quasi-laminated clayey shale facies, blocky silty mudstone facies, quasi-laminated silty shale facies, laminated silty shale facies, blocky mixed mudstone facies, and laminated argillaceous siltstone facies. Al2O3, MgO, CaO, Na2O, K... [more]

A high load of inorganics in raw lignocellulosic biomass is known to inhibit the yield of bio-oil and alter the chemical reactions during fast pyrolysis of biomass. In this study, palm kernel shell (PKS), an agricultural residue from palm oil production, and two other woody biomass samples (mahogany (MAH) sawdust and iroko (IRO) sawdust) were pretreated with distilled water or an acidic solution (either acetic, formic, hydrochloric (HCl) or sulfuric acid (H2SO4)) before fast pyrolysis in order to investigate its effect on the primary products and pyrolysis reaction pathways. The raw and pretreated PKS, MAH and IRO were pyrolysed at 600 °C and 5 s with a micro-pyrolyser connected to a gas chromatograph−mass spectrometer/flame ionisation detector (GC-MS/FID). Of the leaching solutions, HCl was the most effective in removing inorganics from the biomass and enhancing the primary pyrolysis product formed compared to the organic acids (acetic and formic acid). The production of levoglucosan... [more]