This paper presents the results of a comparative analysis of the dielectric strength of disconnecting vacuum interrupters operating on air and helium. The breakdown voltage Ud was measured in the pressure range from 8.0 × 10−4 Pa to 3.0 × 101 Pa for air and from 8.0 × 10−4 Pa to 7.0 × 102 Pa for helium, while varying the interelectrode distance from 1.0 to 5.0 mm. Dedicated laboratory workstations were used to determine the actual pressure values in the vacuum interrupters tested and to precisely measure and record the dielectric strength results of the test object. It was found that the helium-filled vacuum interrupter maintains its full dielectric strength in significantly larger pressure ranges, while the air-filled vacuum interrupter loses its insulating properties. Thus, it is possible to make vacuum interrupters based on the working medium associated with pure helium, with larger working pressure ratings. Under such conditions, it is easier to maintain the tightness of the device... [more]

ZnO nanorods are promising materials for many applications, in particular for UV detectors. In the present paper, the properties of high crystal quality individual ZnO nanorods and nanorod arrays grown by the self-catalytic CVD method have been investigated to assess their possible applicationsfor UV photodetectors. X-ray diffraction, Raman spectroscopy and cathodoluminescence investigations demonstrate the high quality of nanorods. The nanorod resistivity and carrier concentration in dark is estimated. The transient photocurrent response of both as grown and annealed at 550 °C nanorod array under UV illumination pulses is studied. It is shown that annealing increases the sensitivity and decreases the responsivity that is explained by oxygen out-diffusion and the formation of near surface layer enriched with oxygen vacancies. Oxygen vacancy formation due to annealing is confirmed by an increase of green emission band intensity.

In times of climate change and dwindling fossil resources, the need for sustainable renewable energy technologies gains importance, increasingly fast. However, the state of the art technologies are energy intensive in their production, like monocrystalline photovoltaic, or even consist of not recyclable composite material, in the case of wind turbine blades. Despite a lack in efficiency and stability, dye sensitized solar cells (DSSC) have a high potential to supplement the state of the art green energy technology in future. With low production costs and no necessity for toxic compounds DSSCs are a potential product, which could circulate in the loops of a circular economy. Therefore, with this paper, we provide the status of research on DSSC recycling and an outlook on how recycling streams could be realized in the future for glass-based DSSCs without toxic components. The overview includes work on using recycled material to build DSSCs and extending the life of a DSSC, e.g., through... [more]

During the construction of nuclear waste storage facilities, deep drilling, and geothermal energy development, high-temperature rocks are inevitably subjected to thermal shock. The physical and mechanical behaviors of granite treated with different thermal shocks were analyzed by non-destructive (P-wave velocity test) and destructive tests (uniaxial compression test and Brazil splitting test). The results show that the P-wave velocity (VP), uniaxial compressive strength (UCS), elastic modulus (E), and tensile strength (st) of specimens all decrease with the treatment temperature. Compared with air cooling, water cooling causes greater damage to the mechanical properties of granite. Thermal shock induces thermal stress inside the rock due to inhomogeneous expansion of mineral particles and further causes the initiation and propagation of microcracks which alter the mechanical behaviors of granite. Rapid cooling aggravates the damage degree of specimens. The failure pattern gradually tra... [more]

In this investigation, six groups of cemented coal gangue-fly ash backfill (CGFB) samples with varying amounts of kaolin (0, 10, 20, 30, 40, and 50%) instead of cement are prepared, and their mechanical properties are analyzed using uniaxial compression, acoustic emission, scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The uniaxial compressive strength, peak strain, and elastic modulus of CGFB samples decreased with the kaolin content. The average uniaxial compressive strength, elastic modulus, and peak strain of CGFB samples with 10% amount of kaolin are close to that of CGFB samples with no kaolin. The contribution of kaolin hydration to the strength of CGFB sample is lower than that of cement hydration, and the hydration products such as ettringite and calcium-silicate-hydrate gel decrease, thereby reducing strength, which mainly plays a role in filling pores. The contents of kaolin affect the failure characteristics of CGFB samples, wh... [more]

When designing the cement slurry for casing string cementing in geothermal boreholes, the appropriate thermal conductivity is selected. In the zone of geothermal water, where thermal energy is collected, cement slurry is used, from which the cement sheath has high thermal conductivity. On the other hand, the remaining part of the opening is sealed with slurry, from which the cement sheath will reduce thermal energy losses through appropriate thermal insulation. Cement slurry with appropriate thermal insulation includes light insulating materials. However, the use of such additives is very problematic as they are fractionated due to their low density. Therefore, measures should be taken to prevent fractionation of the cement slurry for sealing geothermal boreholes. This article presents the results of research on fractionation of cement slurries for sealing geothermal boreholes. 12 slurries were used for the tests. Six of them are based on class A cement, and six based on class G cement... [more]

Plaster has, from ancient times, been used as a decorative material. However, the advances in materials engineering such as thermal and moisture control provide new opportunities. Superabsorbent polymers (SAPs) have been found to possess passive moisture control that may find utilization in modern buildings. However, the main drawback is associated with a limited number of applicable SAPs due to mechanical strength loss. In this regard, concurrent utilization of cellulose fibers may provide additional benefits linked with the reinforcing of plaster structure and preservation of superior hygric properties. In this regard, this study investigates the combined effect of SAP and cellulose fibers on the material properties of cement-lime plaster in terms of its mechanic, thermal, and hygric properties. To access the capability of such modified plasters to control the interior moisture fluctuations, the moisture buffering value is determined. Obtained results show the effect of both applied... [more]

This paper discusses a 1D one-dimensional mathematical model for the thermoelasticity problem in a two-layer plate. Basic equations in dimensionless form contain both temperature and displacement. General solutions of homogeneous equations (displacement and temperature equations) are assumed to be a linear combination of Trefftz functions. Particular solutions of these equations are then expressed with appropriately constructed sums of derivatives of general solutions. Next, the inverse operators to those appearing in homogeneous equations are defined and applied to the right-hand sides of inhomogeneous equations. Thus, two systems of functions are obtained, satisfying strictly a fully coupled system of equations. To determine the unknown coefficients of these linear combinations, a functional is constructed that describes the error of meeting the initial and boundary conditions by approximate solutions. The minimization of the functional leads to an approximate solution to the problem... [more]

In the present work, structural and catalytic characterization was performed on La0.6Sr0.4MnO3 (LSM) nanofibers. The LSM nanofibers were obtained using the electrospinning technique. For comparison, LSM powders with identical composition were characterized as well. The LSM powders were prepared through a self-combustion citrate-based procedure. SEM, EDX, XRD, and BET investigations were carried out on both LSM nanofibers and powders, pointing out the different structural features. The LSM nanofibers showed a higher surface area than the LSM powders and a lower presence of strontium oxide on the surface. Results of the H2-Temperature Programmed Reduction (TPR) tests showed evidence of a higher reactivity of the nanofibers compared to the powders. The catalytic characterization was performed utilizing a methane oxidation activity test, revealing a better catalytic performance of the LSM nanofibers: at 800 °C. The methane conversion achieved with the LSM nanofibers was 73%, which compared... [more]

This paper aims to provide technical insights on the aerodynamic characterization activities performed in the field of the H2020 STRATOFLY project, for the Mach 8 waverider reference configuration. Considering the complexity of the configuration to be analyzed at conceptual/preliminary design stage, a build-up approach has been adopted. The complexity of the aerodynamic model increases incrementally, from the clean external configuration up to the complete configuration, including propulsion systems elements and flight control surfaces. At each step, the aerodynamic analysis is complemented with detailed mission analysis, in which the different versions of the aerodynamic databases are used as input for the trajectory simulation. eventually, once the contribution to the aerodynamic characterization of flight control surfaces is evaluated, stability and trim analysis is carried out. The comparison of the results obtained through the different mission analysis campaigns clearly shows tha... [more]

In the current research work, palladium (Pd) nanoparticles were electrochemically deposited on a nitrogen doped montmorillonite (CNx-MMT) support using the underpotential deposition (UPD) method. The prepared Pd based composite electrode was studied as an electrocatalyst for methanol fuel oxidation. The catalysts and the supporting materials montmorillonite, acid activated montmorillonite, and nitrogen doped montmorillonite (MMT, HMMT and CNx-HMMT) were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS) and electrochemical characterization by cyclic voltammetry (CV). The results indicated that Pd supported on CNx-HMMT possesses enhanced electrocatalytic activity and stability compared to commercial Pd/C, which was attributed to its higher electrochemical surface area (ECSA) (23.00 m2 g−1). The results demonstrated the potential application of novel Pd/CNx-HMMT compo... [more]

The building sector is known to have a significant environmental impact, considering that it is the largest contributor to global greenhouse gas emissions of around 36% and is also responsible for about 40% of global energy consumption. Of this, about 50% takes place during the building operational phase, while around 10−20% is consumed in materials manufacturing, transport and building construction, maintenance, and demolition. Increasing the necessity of reducing the environmental impact of buildings has led to enhancing not only the thermal performances of building materials, but also the environmental sustainability of their production chains and waste prevention. As a consequence, novel thermo-insulating building materials or products have been developed by using both locally produced natural and waste/recycled materials that are able to provide good thermal performances while also having a lower environmental impact. In this context, the aim of this work is to provide a detailed... [more]

A theoretical analysis of the influence of temperature and nanoparticle concentration on free convection heat transfer from a horizontal tube immersed in an unbounded nanofluid was presented. The Nusselt (Nu) number and heat transfer coefficient were parameters of the intensity of the convective heat transfer. For free convection, the Nu number was a function of the Rayleigh (Ra) number and Prandtl (Pr) number. The Rayleigh (Ra) number and Prandtl (Pr) number were functions of the thermophysical properties of nanofluids. The thermophysical properties of nanofluids varied with temperature and nanoparticle concentration. Therefore, an analysis was conducted to evaluate the effects on the performance of nanofluids due to variations of thermal conductivity, viscosity, thermal expansion, density, and specific heat, which are functions of nanoparticle concentration and temperature. Water- and ethylene glycol (EG)-based nanofluids with dispersed alumina (Al2O3) nanoparticles at mass concentra... [more]

High temperature and overheating of photovoltaic panels lead to efficiency losses and eventual degradation. For solar PV systems, this is a significant impediment for achieving economic viability. In this study, a novel Window-Integrated Concentrated Photovoltaic (WICPV) system is proposed for window integration. This offers high (50%) transparency and is fabricated and characterised indoors at an irradiance of 1000 Wm−2. Its electrical performance is tested (a) without applied cooling (i.e., under natural ventilation) and (b) with a heat sink to accommodate passive cooling media. The results are compared to study the effects of reduction in operating temperature on system performances. The effectiveness of a sensible cooling medium (water) and two latent heat removal media, phase change materials (or PCMs, RT50 and RT28HC), is investigated. This paper reports the passive temperature regulation of this WICPV at ambient testing conditions. The results demonstrate an increase in electric... [more]

The generation and use of energy are significant contributors to CO2 emissions. Globally, approximately 30% to 40% of all energy consumption can be directly or indirectly linked to buildings. Nearly half of energy usage in buildings is linked to maintaining the thermal comfort of the inhabitants. Therefore, finding solutions that are not only technically but also economically feasible is of utmost importance. Though much research has been conducted to address this issue, most solutions are still costly for developing countries to implement practically. This study endeavors to find a less expensive yet straightforward methodology to achieve thermal comfort while conserving energy. This study takes a broader view of multiple habitat-related CO2 emission issues in developing regions and describes a hybrid solution to address them. New technologies and innovative concepts are being globally examined to benefit from the considerable potential of PCMs and their role in thermal energy storage... [more]

The paper presents an innovative method for smoothing fluctuations of heat flux, using the thermal energy storage unit (TES Unit) with phase change material and Artificial Neural Networks (ANN) control. The research was carried out on a pilot large-scale installation, of which the main component was the TES Unit with a heat capacity of 500 MJ. The main challenge was to smooth the heat flux fluctuations, resulting from variable heat source operation. For this purpose, a molten salt phase change material was used, for which melting occurs at nearly constant temperature. To enhance the smoothing effect, a classical control system based on PID controllers was supported by ANN. The TES Unit was supplied with steam at a constant temperature and variable mass flow rate, while a discharging side was cooled with water at constant mass flow rate. It was indicated that the operation of the TES Unit in the phase change temperature range allows to smooth the heat flux fluctuations by 56%. The tests... [more]

A diamond’s color grading is a dominant property that determines its market value. Its color quality is dependent on the light transmittance through the diamond and is largely influenced by nitrogen contamination, which induces a yellow/brown tint within the diamond, as well as by structural defects in the crystal (in rare cases boron contamination results in a blue tint). Generally, spectroscopic instrumentation (in the infrared or UV−visible spectral range) is used in industry to measure polished and rough diamonds, but the results are not accurate enough for precise determination of color grade. Thus, new methods should be developed to determine the color grade of diamonds at longer wavelengths, such as microwave (MV). No difference exists between rough and polished diamonds regarding stray light when the MW frequency is used. Thus, several waveguides that cover a frequency range of 3.95−26.5 GHz, as well as suitable resonator mirrors, have been developed using transmission/reflecti... [more]

In view of potential uses in short-term thermochemical heat storage by sorption of water vapor, the capacity to release a sufficient heat amount at the appropriate rate of a Prussian blue analogue (PBA) containing hexacyanocobaltate vacancies has been compared with those of 13X type zeolites possessing Na+, Ce3+, Ce4+, or Tb3+ extra-framework compensating cations. The extended structural and surface characterization demonstrated good reproducibility of the preparation procedures performed on a 10-g scale. The adsorbents were tested under dynamic conditions of gas flow with the aid of either a gas flow calorimeter (120 mL h−1 helium flow) to measure the amount and rate of the integral heat release or a laboratory-scale test rig (15,000 to 22,800 mL h−1 nitrogen flow) to monitor the outlet temperature of nitrogen heated by adsorption. For a regeneration temperature of 353 K and a partial H2O pressure of 2.8 kPa in helium, the PBA sample yielded an integral heat ranging between 900 and 10... [more]

Degradation of electrode microstructure is one of the key factors affecting long term performance of Solid Oxide Fuel Cell systems. Evolution of a multiphase system can be described quantitatively by the change in its interfacial energy. In this paper, we discuss free energy of a microstructure to showcase the anisotropy of its evolution during a long-term performance experiment involving an SOFC stack. Ginzburg Landau type functional is used to compute the free energy, using diffuse phase distributions based on Focused Ion Beam Scanning Electron Microscopy images of samples taken from nine different sites within the stack. It is shown that the rate of microstructure evolution differs depending on the position within the stack, similar to phase anisotropy. However, the computed spatial relation does not correlate with the observed distribution of temperature.

A special element of road safety research is accidents at the interface of the road and rail system. Due to their low share in the total number of incidents, they are not a popular subject of analyses but rather an element of collective studies, whereas the specificity of the road−rail accidents requires a separate characteristic, allowing, on the one hand, to categorize these types of incidents, and on the other, to specify the factors that affect them, along with an assessment of the strength of this impact. It is important to include in such analyses all potential predictors, both qualitative and quantitative. Moreover, the literature considers most often a number of accidents while, according to the authors, it does not fully reflect the scale of the danger. A better evaluation would be the victim’s degree of injury. Therefore, the purpose of this article is to assess the likelihood of occurrence of various effects of road−rail accidents in the aspect of selected factors. Due to th... [more]

The refurbishment of the building stock is a key strategy towards the achievement of the climate and energy goals of the European Union. This study aims at evaluating the energy and environmental impacts associated with retrofitting a residential apartment to improve its vertical envelope thermal insulation. Two insulation materials, stone wool and cellulose fibers, are compared. The life cycle assessment methodology is applied assuming 1 m2 of retrofitted vertical envelope as functional unit. Moreover, to estimate the net energy and environmental benefits achievable in the retrofitted scenario compared with the non-retrofitted one, a second analysis is performed in which the system boundaries are expanded to include the building operational phase, and 1 m2 of walkable floor per year is assumed as reference. The results show that the use of cellulose fibers involve lower impacts in most of the assessed categories compared to stone wool, except for abiotic resource depletion. In detail,... [more]

The presence of different pollutants in recycled plastics is reviewed in this article. The desirable circular economy of plastics should be linked to the availability of clean recycled plastics with a non-significant and small to nil amount of substances of concern. Different researchers found polycyclic aromatic hydrocarbons (PAHs) and Persistent Organic Pollutants (POPs), such as brominated flame retardants (BFRs), pesticides, dioxins and furans (PCDD/Fs and PBDD/Fs) in plastic recyclates. This represents an added difficulty to the effective recycling process of plastics that reduces the demand for energy and materials, in addition to posing a great environmental danger since they represent a vector of accumulation of the contaminants that will finally appear in the most unexpected products. Life Cycle Analysis of the plastic wastes recycling process indicates a great saving of energy, water and CO2 emissions.

The research project Fraunhofer Cluster of Excellence “Programmable Materials” aims to develop new materials that can change their properties according to defined boundaries. This article describes the development and use of a novel programmable phase change material (PCM) for latent heat storage applications. At the moment, these PCMs have a programmable trigger mechanism incorporated that activates the crystallization of the material as a reaction to a defined stimulus so that the stored heat is released. In future development stages, programmability is to be integrated on the material level. The latent heat storage that is based on PCMs can be recharged by using the energy of the sun. As an example, for a possible application of such a material, the use of a novel programmable PCM in greenhouses to support heating energy reduction or to reduce the risk of frost is explained. Using the hygrothermal simulation tool WUFI® Plus, the effects in greenhouse constructions without and with c... [more]

The article investigated the possibility of reusing heat resistant glass cullet to improve the mechanical properties of high-temperature composites. This is an excellent recycled aggregate that may be used as a substitute for alumina cement, and for fine natural aggregate in the production of concrete based on hydraulic binder. The experimental programme comprised of strength testing conducted on 40 × 40 × 160 mm cuboidal samples. The model mixture was modified by filler that comprised glass recyclate, amounting to 5%, 10%, and 15% of the mass of gravel and cement. Given the degree of glass grounding, use was made of two fractions, 0/4 and 0/0.125 mm. Six modified mixtures were produced. Tests were then carried out on their selected physical and mechanical properties as well as the impact of temperature, topography, and chemical composition exerted on the composite. Next, the progress and development of compressive strength and flexural strength after 14 and 28 days of curing were stud... [more]

Signs of wetness in housing are a significant obstacle to the renovation and energy rehabilitation of old and energy-intensive heritage buildings, especially in cold climates. Thus, in order to avoid the numerous possibilities of degradation caused by the moisture transfer phenomena in the building envelope, the a disruptive aeraulic process, which focuses on the ventilation of an air gap between the thermal insulation and the wet wall, has been designed and its assessed. This system avoids the presence of liquid water at the wall surface by maintaining the hygrothermal balance within the wet wall. This enables the mechanical durability of the supporting structure, the absence of biological activity and/or frost and, hence, the durability of the thermal insulation. These issues are investigated through a case study based on a real site. Over a year of measurements, the wet wall was constantly maintained in hygroscopic balance, around 90% RH, guaranteeing the preservation of its mechani... [more]