Metal halide perovskite solar cells (PSCs) are considered an effectual way to enhance photovoltaic (PV) properties, leading to low-cost and high efficiency. PSCs have experienced rapid improvement in the last ten years. The device’s energy production increases extensively in the presence of concentrated light. The use of concentrated optics in solar cells has spurred the PV industry towards tremendous research. Incorporating the concentrated optic into the PV system as a concentrated PV (CPV) means it can capture light effectively and operate at increased efficiencies under concentrated irradiance. This work addresses an initial assessment of the power conversion efficiency (PCE) enhancement of the ambient PSCs by externally integrating concentrated optics. Significantly, the concentrated optics exhibit ~90% of the PCE enhancement under the solar irradiance of 400 W/m2, whereas 16% of the PCE increase was observed when the solar irradiance changed to 1000 W/m2. During optics integratio... [more]

The paper presents the investigation of a prototype cold accumulator using water−ice latent heat for the cold storage process. The concept of the cold accumulator was based on a 200-L-capacity cylindrical storage tank in which spherical capsules filled with water were placed. Beds of polypropylene capsules with diameters of 80 mm, 70 mm, and 60 mm were used in the tests. The cold accumulator operated with a water−air heat pump. Based on the test results, the following parameters were calculated: the cooling capacity, cooling power, energy efficiency of the cold storage, and energy efficiency ratio (EER) of the accumulator. The obtained measurement results were described with mathematical relationships (allowing for measurement error) using criterial numbers and the developed “Research Stand Factor Number” (RSFN) index. It has been found that, for the prototype cold accumulator under investigation, the maximum values of the cooling capacity (17 kWh or 85.3 kWh per cubic meter of the acc... [more]

This study aims to investigate the thermal performance of PCM and PCM combined with nighttime natural (NV) and mechanical ventilation (MV) applied to a residential building located in eight cities of tropical rainforest climate zone (Af). The analysis was accomplished using numerical simulations and developing a unique methodology for selecting the PCM melting temperature based on the thermal comfort limits. The thermal performance of the PCM integrated building was quantitatively evaluated using the concept of peak temperature drop. Additionally, a novel indicator of Total Temperature Drop (TTD) was introduced to determine the overall impact of the PCM and PCM combined with NV/MV on the thermal comfort conditions inside the building. The results showed that PCM 28 was the most efficient in improving the thermal performance of the building located in the Af climate zone, achieving a TTD of up to 356 °C per year. The usage of PCM 28 combined with nighttime natural ventilation improved t... [more]

This article presents a method for detecting defects and assessing their size in soft magnetic composites (SMCs) based on magnetograms obtained from a magnetic field camera and a numerical analysis of the magnetic field around them. For the purpose of the experiment, toroidal samples of a metal−polymer composite were made, in which holes and gaps simulating defects were prepared. The magnetic camera allowed for registering the magnetic flux density image near the surface of the samples. As a result, magnetograms with information about the location and geometry of defects were obtained. A numerical analysis was used to investigate the influence of various factors, such as defect depth, its size and material permeability. Theoretical changes in magnetic field over defects stay in good agreement with measurements, which is a strong indication that surface field magnetograms can be useful in a quality assessment of the considered composites. The effectiveness and usefulness of the method i... [more]

In this paper, we present a mathematical model to predict the evolution of rock permeability depending on effective pressure during oil production. The model is based on the use of the results of well testing data from wells operating in the oil fields of the Perm−Solikamsk region in the north of the Volgo Ural oil and gas province. Dependences of the change in flow characteristics in the reservoir on the effective pressure were established. We performed a comparative assessment using permeability and effective pressure data that were normalized to dimensionless forms of k/ko and P/Po. The factors and their influence on the nature of the change in permeability from the reservoir pressure were determined. Depending on the type of rock, its composition, initial permeability, and bedding conditions, we determined the limits of variation of the constants in empirical equations describing the change in the permeability of rocks from the effective pressure. The mathematical model we develope... [more]

The study presents results of rheological tests and measurements of pressure drops occurring during the flow of aqueous solutions of a mixture of drag reducing surfactants: cocamidopropyl betaine (CAPB, zwitterionic surfactant) and cocamide DEA (nonionic surfactant) through straight pipes. Tests were carried out at different CAPB/DEA weight ratios and different total concentrations of surfactants in the solution. Rheological measurements demonstrate the formation of a shear-induced structure (SIS) in the temperature range below 10 °C, which provides evidence for the presence of wormlike micelles in CAPB/DEA solutions. Drag reduction was observed during the flow of CAPB/DEA solutions in the temperature range from 3 to 45 °C, however, above 25 °C the degree of drag reduction was markedly decreased. The lower temperature limit at which drag reduction occurs depends on the CAPB and DEA weight ratio in the solution. In the range of higher temperatures, during the flow of CAPB/DEA solutions... [more]

The high theoretical capacity of Bi2S3 shows high promise as a negative electrode material for energy storage devices. Herein, we investigate a facile, one-step chemical precipitation method using common organic solvents, such as acetone, ethanol, and isopropanol, for the synthesis of Bi2S3 nanostructures. The nanospherical Bi2S3 from acetone (Bi2S3-A) presents the most balanced electrochemical properties, exhibiting a high specific capacity of 181 mAh g−1 at 1 A g−1 and decent rate capability. Additionally, Bi2S3-A is used as a negative electrode in an aqueous hybrid system with an activated carbon positive electrode, demonstrating a capacitance of 86 F g−1, a specific energy of 7.6 Wh kg−1, and an initial capacity retention of 74% after 1000 cycles.

Perovskite solar cells (PVSC) have drawn increasing attention due to their high photovoltaic performance and low-cost fabrication with solution processability. A variety of methods have been developed to make uniform and dense perovskite thin films, which play a critical role on device performance. Herein, we demonstrate a polymer additive assisted approach with Polyamidoamine (PAMAM) dendrimers to facilitate the growth of uniform, dense, and ultra-smooth perovskite thin films. Furthermore, a lamp annealing approach has been developed to rapidly anneal perovskite films using an incandescent lamp, resulting in comparable or even better device performance compared to the control hotplate annealing. The facile polymer additive assisted method and the rapid lamp annealing technique offer a clue for the large-scale fabrication of efficient PVSCs.

The influence of the briquetting process on SO2 and NO release characteristics, combustion properties and kinetic characteristics during biomass combustion was investigated. Two biomass (Wheat straw and Tree bulk) and two obtained briquettes were analysed. The briquetting process helps to prevent the release of SO2 and NO. The experimental results show that once the biomass is made into a briquette, when the reaction temperature is 900 ∘C, the sulphur release ratio for TB was reduced from 34.7% to 4.3% and for WS was reduced from 12.4% to 1.6%. When the reaction temperature increases to 1000 ∘C, the sulphur release ratio for TB was reduced from 73.4% to 30.4%, for WS it was reduced from 58.4% to 10.2%. SEM micrographs show that the compact structure of the TB-Briquette and WS-Briquette reduce the rate of SO2 and NO release during combustion. The thermogravimetry confirmed that the combustion performance of WS-Briquette is the best, while the TB-Briquette is the worst. According to the... [more]

Coal seam gas (CSG), also known as coalbed methane (CBM), is an important source of gas supply to the liquefied natural gas (LNG) exporting facilities in eastern Australia and to the Australian domestic market. In late 2018, Australia became the largest exporter of LNG in the world. 29% of the country’s LNG nameplate capacity is in three east coast facilities that are supplied primarily by coal seam gas. Six geological basins including Bowen, Sydney, Gunnedah, Surat, Cooper and Gloucester host the majority of CSG resources in Australia. The Bowen and Surat basins contain an estimated 40Tcf of CSG whereas other basins contain relatively minor accumulations. In the Cooper Basin of South Australia, thick and laterally extensive Permian deep coal seams (>2 km) are currently underdeveloped resources. Since 2013, gas production exclusively from deep coal seams has been tested as a single add-on fracture stimulation in vertical well completions across the Cooper Basin. The rates and reserves... [more]

Rechargeable power sources are an essential element of large-scale energy systems based on renewable energy sources. One of the major challenges in rechargeable battery research is the development of electrode materials with good performance and low cost. Carbon-based materials have a wide range of properties, high electrical conductivity, and overall stability during cycling, making them suitable materials for batteries, including stationary and large-scale systems. This review summarizes the latest progress on materials based on elemental carbon for modern rechargeable electrochemical power sources, such as commonly used lead−acid and lithium-ion batteries. Use of carbon in promising technologies (lithium−sulfur, sodium-ion batteries, and supercapacitors) is also described. Carbon is a key element leading to more efficient energy storage in these power sources. The applications, modifications, possible bio-sources, and basic properties of carbon materials, as well as recent developme... [more]

Thermal Energy Storage (TES) materials, such as Phase Change Materials (PCMs) are proven to enhance the energy efficiency in many fields, such as automotive and building sectors, which correspond to the most energy intensive ones. Shape-stabilized PCM and cascade PCM are procedures to overcome the most important barriers when PCMs are applied since PCMs need to be encapsulated for their technical use: the leakage of the liquid phase, corrosion, low heat transfer and narrow temperature of application. In the present study, a novel shape stabilized PCM with cascade performance (cascade shape stabilized phase change material, CSS-PCM) is synthesized via dissolution, which allows up to 60 wt.% of a paraffin-PCM in the final composition. The novel CSS-PCM is based on a biopolymer, the polycaprolactone (PCL), a low melting temperature polyester as polymeric matrix and RT27 and Micronal DS 5040 acting as PCM. To evaluate the performance of the new TES materials developed, several techniques h... [more]

In this study, a thermal energy storage tank filled with commercial phase change material flat slabs is investigated. The tank provides heat at around 15 °C to the evaporator of a seasonal thermal energy storage system developed under the EU-funded project SWS-Heating. A 2D numerical model of the phase changed material storage tank based on the finite control volume approach was developed and validated with experimental data. Based on the validated model, an optimization was performed to identify the number, type and configuration of slabs. The final goal of the phase change material tank model is to be implemented into the whole generic heating system model. A trade-off between results’ accuracy and computational time of the phase change material model is needed. Therefore, a comparison between a 2D implicit and 2D explicit scheme of the model was performed. The results showed that using an explicit scheme instead of an implicit scheme with a reasonable number of nodes (15 to 25) in t... [more]

The 2030 Agenda and Sustainable Development Goals (SDG) are both an engineering challenge and an opportunity. Clean energy (SDG 7), sustainable cities and communities (SDG 11), and climate action (SDG 13) represent an effort to manage, plan, and develop our buildings and infrastructure. The purpose of this study is to contribute to this challenge by analysing nanomaterials in marine environment structures, both urban and maritime. To do this, we have analyzed different regulations of concrete properties in various countries, defining the characteristics of the cement, coating, water/cement rating, and chloride effect; the difference in durability based on conventional reinforcements and nanomaterials; and use on highly sensitive elements, buildings in marine environments, rubble mound structures, crown walls, and gravity-based foundations for wind power facilities. Division into overhead, underwater, or splash zones entails the use of epoxy resins or silica fume matrices in percentages... [more]

The materials and the technology used to build the ground heat exchangers significantly affect the heat transfer performance of a geothermal system, in addition to the local geological and hydrogeological context. Among expense items such as the coupled heat pumps and the applied drilling technology, the heat exchangers play a key role in the shallow geothermal market. For this reason, they are usually made with plastic. Metal tubes are not widely used because of corrosion issues, which can compromise the reliability of the system over time. According to best practices, metal is an unfavorable choice if the pipes are not made of corrosion resistant alloys, such as stainless steel, but the overall performance is strongly related to the heat transfer efficiency. In this study, laser-flash technique is applied on carbon steel samples with anti-corrosion coatings and on corrosion resistant materials (stainless steel grades used for pipes), thus, allowing the comparison of their thermophysi... [more]

Laboratory-synthesized specimens are employed for an experimental study on the mechanical properties of hydrate-bearing sediments (HBS) due to the difficulty of field coring. A representative synthesized sample for the analysis of the mechanical properties of HBS in the experimental study requires evenly distributed hydrates in the pores of the sample. However, a specimen made with an improper sand−water mixing method might have an uneven water distribution, resulting in an uneven hydrate distribution when applying the ice-seeding method for hydrate formation. This study adopted three kinds of methods to mix sand and water before forming hydrates and applied the low-field nuclear magnetic resonance (NMR) technique to investigate how these methods affect the hydrate distribution, further affecting the mechanical properties. To analyze the mechanical properties of HBS, we conducted drained triaxial tests. As shown in low-field NMR, when we compacted a sample of the sand−water mixture and... [more]

In this article, a novel frequency slot-based switchable antenna fabricated on flexible and nonflexible materials is presented for suitable reconfigurable radiations of Bluetooth, WiMAX, and upper WLAN applications. Initially, the performance of this structure was simulated using a CSTTM simulator and evaluated experimentally using a nonflexible FR4 structure. The same antenna was implemented on a flexible (jean) substrate with a relative permittivity of 1.7. The proposed textile antenna prototypes were fabricated by optimal dimensions of an E-shaped slot with a variation on the shape of the ground layer, integrated using a crossed T-shaped strip with ON/OFF switchable state operations. The proposed antenna prototype is compact (20 × 20 mm2), providing switchable radiations with tri bands, has frequencies ranged at 2.36−2.5 GHz for Bluetooth, 3.51−3.79 GHz and 5.47−5.98 GHz for the distinct bands of WiMAX and WLAN, respectively, as well as part of UWB operations.

Building integrated photovoltaics is one of the key technologies when it comes to electricity generation in buildings, districts or urban areas. However, the potential of building façades for the BIPV system, especially in urban areas, is often neglected. Façade-mounted building integrated photovoltaics could contribute to supply the energy demand of buildings in dense urban areas with economic feasibility where the availability of suitable rooftop areas is low. This paper deals with the levelised cost of electricity (LCOE) of building integrated photovoltaic systems (BIPV) in the capitals of all the European member state countries plus Norway and Switzerland and presents a metric to investigate a proper subsidy or incentive for BIPV systems. The results showed that the average LCOE of the BIPV system as a building envelope material for the entire outer skin of buildings in Europe is equal to 0.09 Euro per kWh if its role as the power generator is considered in the economic calculation... [more]

Smart WiFi thermostats, when they first reached the market, were touted as a means for achieving substantial heating and cooling energy cost savings. These savings did not materialize until additional features, such as geofencing, were added. Today, average savings from these thermostats of 10−12% in heating and 15% in cooling for a single-family residence have been reported. This research aims to demonstrate additional potential benefit of these thermostats, namely as a potential instrument for conducting virtual energy audits on residences. In this study, archived smart WiFi thermostat measured temperature data in the form of a power spectrum, corresponding historical weather and energy consumption data, building geometry characteristics, and occupancy data were integrated in order to train a machine learning model to predict attic and wall R-Values, furnace efficiency, and air conditioning seasonal energy efficiency ratio (SEER), all of which were known for all residences in this st... [more]

In this work, the diffusion process of sodium (Na) in molybdenum (Mo) thin films while it was deposited on soda lime glass (SLG) was studied. A small amount of oxygen was present in the chamber while the direct-current (DC) magnetron sputtering was used for the deposition. The substrate temperatures were varied to observe its effect. Such molybdenum films, with or without oxidations, are often used in thin film solar cells, either as back contact or as hole transport layers. Secondary ion mass spectrometry (SIMS) was used to quantify the concentration of the species. A grain diffusion mechanistic model incorporating the effect of grain and grain boundary geometrical shape and size was developed. The model was used to provide an in-depth theoretical analysis of the sodium diffusion in molybdenum thin films that lead to the measured SIMS data. It was observed that not only diffusion coefficients should be considered when analyzing diffusion processes in thin films but also the ratio of g... [more]

We studied the hydrogen adsorption on the surface of a covalently bonded bilayer borophene-graphene heterostructure decorated with Pt, Ni, Ag, and Cu atoms. Due to its structure, the borophene-graphene bilayer combines borophene activity with the mechanical stability of graphene. Based on the density functional theory calculations, we determined the energies and preferred adsorption sites of these metal atoms on the heterostructure’s borophene surface. Since boron atoms in different positions can have different reactivities with respect to metal atoms, we considered seven possible adsorption positions. According to our calculations, all three metals adsorb in the top position above the boron atom and demonstrate catalytic activity. Among the metals considered, copper had the best characteristics. Copper-decorated heterostructure possesses a feasible near-zero overpotential for hydrogen evolution reaction. However, the borophene-graphene bilayer decorated with copper is unstable with re... [more]

Investigating the key factors that impact fluid rheology and proppant static settling velocity in high viscosity friction reducers (HVFRs) is a critical aspect for successful proppant transport in hydraulic fracture treatment. In this study, the rheological properties of HVFRs were tested at various temperature ranges (i.e., 25, 50, 75, and 100 °C) and different HVFR concentrations (i.e., 1, 2, 4, and 8 gpt). Three sizes of spherical particle diameters (i.e., 2, 4, and 6 mm) were selected to measure the static settling velocity. The fracture fluid was tested in two fracture models: an unconfined glass model and a confined rectangular model with two fracture widths (7 and 10 mm). The settling velocity in the confined and unconfined models was measured using an advanced video camera. HVFR results exhibited acceptable thermal stability even at higher temperatures, also the viscosity and elasticity increased considerably with increasing concentration. Increasing the temperature cut the fri... [more]

The technologies of cutting the cores of electric machines change the magnetic properties and the loss of the electrical sheets used, affecting the machine’s parameters, mainly power losses and efficiency. This is particularly important in the case of induction motors, which are a significant consumer of electricity. Therefore, the problem of increasing their efficiency is important from the point of view of environmental impact. The article presents a method of approximating a material’s magnetic properties based on the results of measurements carried out with specimens of various widths. The presented method allows for an approximate representation of the changes in the structure of the material caused by the cutting technology. It is used in the analytical method for calculating motor parameters, and gives results that are in good agreement with the measurement. This method can determine the operating parameters of electrical machines of various sizes and rated powers.

In loop heat pipes (LHPs), wick materials and their structures are important in achieving continuous heat transfer with a favorable distribution of the working fluid. This article introduces the characteristics of loop heat pipes with different wicks: (i) sintered stainless steel and (ii) ceramic. The evaporator has a flat-rectangular assembly under gravity-assisted conditions. Water was used as a working fluid, and the performance of the LHP was analyzed in terms of temperatures at different locations of the LHP and thermal resistance. As to the results, a stable operation can be maintained in the range of 50 to 520 W for the LHP with the stainless-steel wick, matching the desired limited temperature for electronics of 85 °C at the heater surface at 350 W (129.6 kW·m−2). Results using the ceramic wick showed that a heater surface temperature of below 85 °C could be obtained when operating at 54 W (20 kW·m−2).

This study used the subcritical hydrothermal liquefaction technique (SHLT) in the co- liquefaction of process rejects at a wastepaper-based paper mill (PRWPM) and waste soybean oil (WSO) for the production of biofuels and bio-char material. PRWPM emits complicated waste composed of cellulose, hemicellulose, lignin, and plastic from sealing film. The waste is produced from the recycled paper process of a mill plant located in central Taiwan. The source of WSO is the rejected organic waste from a cooking oil factory located in north Taiwan. PRWPM and WSO are suitable for use as fuels, but due to their high oxygen content, their use as commercial liquid fuels is not frequent, thus making deoxygenation and hydrogenation necessary. The temperature and pressure of SHLT were set at 523−643 K and 40−250 bar, respectively. The experimental conditions included solvent ratios of oil−water, temperature, reaction time, and ratios of solvent to PRWPM. The analysis results contained approximated comp... [more]