The publication presents a picture of modern steelworks that is evolving from steelworks 3.0 to steelworks 4.0. The paper was created on the basis of secondary sources of information (desk research). The entire publication concerns the emerging opportunities for the development of the steel producers to Industry 4.0 and the changes already implemented in the steel plants. The collected information shows the support environment for changes in the steel sector (EU programs), the levels of evolution of steel mills, along with the areas of change in the steel industry and implemented investment projects. The work consists of a theoretical part based on a literature review and a practical part based on case studies. The work ends with a discussion in which the staged and segmented nature of the changes introduced in the analyzed sector is emphasized. Based on the three case studies described in the paper, a comparative analysis was conducted between them. When we tried to compare methods us... [more]

Auto-catalyzed hydrothermal pretreatment (A-HTP) and sulfuric-acid-catalyzed hydrothermal pretreatment (SA-HTP) were applied to quinoa stalks in order to reduce their recalcitrance towards enzymatic saccharification. Prior to pretreatment, quinoa stalks were extracted with either water or a 50:50 (v/v) ethanol−water mixture for removing saponins. Extraction with water or aqueous ethanol, respectively, led to removal of 52 and 75% (w/w) of the saponins contained in the raw material. Preliminary extraction of quinoa stalks allowed for a lower overall severity during pretreatment, and it led to an increase of glucan recovery in the pretreated solids (above 90%) compared with that of non-extracted quinoa stalks (73−74%). Furthermore, preliminary extraction resulted in enhanced hydrolysis of hemicelluloses and lower by-product formation during pretreatment. The enhancement of hemicelluloses hydrolysis by pre-extraction was more noticeable for SA-HTP than for A-HTP. As a result of the pretre... [more]

Latent thermal energy storage is regarded as an effective strategy to utilize solar energy and recover automotive waste heat. Based upon an enthalpy-porosity method, the influence characteristics and mechanism of fin location on phase change material melting behavior in vertical rectangular enclosures were explored numerically. The results show that as fin location increases, the melting time decreases before attaining the minimum at the fin location of 0.20 after which it increases and finally surpasses the no fin case, because (1) the influence range of fins for conduction is limited by the bottom surface when putting fins next to this surface, (2) the liquid flow resistance increases with moving fins up, and (3) mounting fins near the top surface accelerates melting at the upper part, facilitating thermal stratification formation and weakening natural convection. Nu is higher than the no fin case, i.e., Nu enhancement factor is a positive value, in the melting process for a lower fi... [more]

Biomass occupies a very important place among renewable energy sources, and the residual biomass recovery chain represents a sector of fundamental importance. Our work focused on the production of pellets by pruning residues from two of the most important woody crops in Italy: hazelnut and olive groves. We found a higher value of bulk density for the hazelnut pellet (581.30 kg m−3 vs. 562.38 kg m−3) and a higher value of length for the olive pellet (16.66 mm vs. 10.47 mm). The percentages of durability were very similar (98%). The low heating value and ash content of hazelnut and olive were 17.21 MJ kg−1 and 3.1%, and 16.83 MJ kg−1 and 2.5%. A higher concentration of Cu, Pb, and Ni was observed in the hazelnut. The contrary was observed for the concentration of Zn. N content was 0.77% and 1.24% for the hazelnut and the olive, respectively. The concentration of S was 0.00% for both. The quality parameters that do not meet current standards could be improved by mixing these materials wit... [more]

Natural gas hydrates (GHs) filling sand layer pores are the most promising GHs that can be produced via conventional mechanisms in deep-sea environments. However, the seismic tracking of such thin GH-bearing sand layers is subject to certain limitations. For example, because most GH-bearing sand layers are thin and sparsely interbedded with mud layers, conventional seismic data with a maximum resolution of ~10 m are of limited use for describing their spatial distribution. The 2010 Ulleung Basin drilling expedition identified a relatively good GH reservoir at the UBGH2-6 site. However, the individual GH-bearing sand layers at this site are thin and cannot therefore be reliably tracked using conventional seismic techniques. This study presents a new thin layer tracking method using stepwise seismic inversion and 3D seismic datasets with two different resolutions. The high-resolution acoustic impedance volume obtained is then used to trace thin layers that cannot be harnessed with conven... [more]

The properties and the applications of the main monocyclic aromatic hydrocarbons (benzene, toluene, ethylbenzene, styrene, and the three xylene isomers) and the industrial processes for their manufacture from fossil raw materials are summarized. Potential ways for their production from renewable sources with thermo-catalytic processes are described and discussed in detail. The perspectives of the future industrial organic chemistry in relation to the production of high-octane bio-gasolines and monocyclic aromatic hydrocarbons as renewable chemical intermediates are discussed.

The purpose of this paper is to explore the challenges of an old low-standard urban district with a strong historical and cultural heritage and propose more sustainable renovation solutions, acceptable for the residents and municipality. The challenges of physical renovation or refurbishment are complex due to poor condition of the buildings, municipal ownership and governance, mixed management with community and low rents, which are insufficient to cover the costs. The paper discusses the proposed solutions of living standards, supported by the research in two directions: (i) available resources and reuse of materials, (ii) developing a renovation guidance for inhabitants from the building physics perspective, including indoor environment quality. Challenges related to energy efficiency are addressed from the decision-making perspective to overcome the barrier of lack of motivation to invest in energy-efficient measures at the individual and community level. The interdisciplinary appr... [more]

The exploitation of bioenergy plays a key role in the process of decarbonising the economic system. Huge efforts have been made to develop bioenergy and other renewable energy systems, but it is necessary to investigate the costs and problems associated with these technologies. Soil consumption and, in particular, soil sealing are some of these aspects that should be carefully evaluated. Agricultural biogas plants (ABPs) often remove areas dedicated to agricultural activities and require broad paved areas for the associated facilities. This study aimed to (i) assess the surfaces destined to become facilities and buildings in ABPs, (ii) correlate these surfaces with each other and to the installed powers of the plants, and (iii) estimate the consumption of soil in bioenergy applications in Italy. Two hundred ABPs were sampled from an overall population of 1939, and the extents of the facilities were measured by aerial and satellite observations. An ABP with an installed power of 1000 kW... [more]

Developing renewable energy, especially solar energy related, is of great importance for securing our future energy society. Steam generation in nanofluids based on solar radiation has been increasingly studied. It has been determined that the efficiency of steam generation is significantly enhanced when nanoparticles are seeded into the fluid owing to their unique radiative heat transfer performance. The nanoparticles trap solar energy inside the fluid and convert it into thermal form, which dramatically accelerates the steam generation process. In this study, we experimentally investigated different nanofluids that directly absorb solar energy to generate steam. Ag nanofluid, Au nanofluid and MWCNT nanofluid with different concentration have been carefully investigated. We analyzed the temperature increase and steam generation combined with the calculation of the efficiency factor from radiative heat transfer. The heating power and steam generation power of different nanofluids and t... [more]

Polyimide is a high-performance engineering polymer with outstanding thermomechanical properties. Because of its inherent fire-retardant properties, polyimide nanocomposite is an excellent material for packaging electronic devices, and it is an attractive electrode material for batteries and supercapacitors. The fire-retardant behavior of polyimide can be remarkably improved when polyimide is reinforced with multilayered graphene sheets. Differential scanning calorimetry and thermogravimetric analysis were used to study the heat of decomposition and gravimetric decomposition rate, respectively, of polyimide-graphene nanocomposites. Polyimide/graphene nanocomposites containing 10, 20, 30, 40, and 50 wt.% of multilayered graphene sheets were heated at a rate of 10 and 30 °C/min in air and in nitrogen atmosphere, respectively. The rate of mass loss was found to remarkably decrease by up to 198% for nanocomposites containing 50 wt.% of graphene. The enthalpy change resulting from the decom... [more]

Cu(In,Ga)Se2 (or CIGS) thin films and devices were fabricated using a modified three-stage process. Using high deposition rates and a low temperature during the process, a copper chloride vapor treatment was introduced in between the second and third stages to enhance the films properties. X-ray diffraction and scanning electron microscopy demonstrate that drastic changes occur after this recrystallization process, yielding films with much larger grains. Secondary ion mass spectrometry shows that the depth profile of many elements is not modified (such as Cu, In and Se) while others change dramatically (such as Ga and Na). Because of the competing effects of these changes, not all parameters of the solar cells are enhanced, yielding an increase of 15% in the device efficiency at the most.

The exploitation of power inductors outside their linear region in switching converters can be achieved by raising the current until a decrease in the inductance can be noticed. This allows using a smaller magnetic core, increasing the power density of the converter. On the other hand, a detailed description of the magnetization curve including the temperature is required. Since this information is often not included in the inductor’s datasheets, this paper shows how to identify the behavior of an inductor when it is operated up to saturation and its temperature rises. In order to characterize the inductor in real operating conditions, a dedicated measurement rig was developed. It consists of a switching converter that encompasses the inductor under test and is controlled by a virtual instrument developed in LabVIEW. The characterization system was tested by retrieving the inductance and the magnetization curves vs. current for two commercial inductors at core temperatures up to 105 °C... [more]

Steam accumulation is one of the most effective ways of thermal energy storage (TES) for the solar thermal energy (STE) industry. However, the steam accumulator concept is penalized by a bad relationship between the volume and the energy stored; moreover, its discharge process shows a decline in pressure, failing to reach nominal conditions in the turbine. From the economic point of view, between 60% and 70% of the cost of a steam accumulator TES is that of the pressure vessel tanks (defined as US$/kWhth). Since the current trend is based on increasing hours of storage in order to improve dispatchability levels in solar plants, the possibility of cost reduction is directly related to the cost of the material of pressure vessels, which is a market price. Therefore, in the present paper, a new design for steam accumulation is presented, focusing on innovative materials developed specifically for this purpose: two special concretes that compose the accumulation tank wall. Study of dosages... [more]

This paper deals with research into pool boiling critical heat flux (CHF) of water−Al2O3, water−TiO2 and water−Cu nanofluids on horizontal stainless steel tubes. The experiments were conducted under atmospheric pressure. Nanoparticles were tested at concentrations of 0.001%, 0.01%, 0.1% and 1% by weight. Ultrasonic vibration was used in order to stabilize the dispersion of the nanoparticles. Although dispersants were not used to stabilize the suspension, the solutions tested showed satisfactory stability. Experimental measurements were performed with stainless steel tubes of three outside diameters: 1.6, 3 and 5 mm. Enhancement of CHF was observed to be independent of the concentration and material of the nanoparticles and tube diameter, with simultaneous heat transfer degradation. Built up during the boiling process, nanolayers improve substantially the heating surface wettability. A correlation is suggested for the CHF prediction during pool boiling of nanofluids.

Lithium-ion (Li-ion) batteries have emerged as a promising energy source for electric vehicle (EV) applications owing to the solution offered by their high power, high specific energy, no memory effect, and their excellent durability. However, they generate a large amount of heat, particularly during the fast discharge process. Therefore, a suitable thermal management system (TMS) is necessary to guarantee their performance, efficiency, capacity, safety, and lifetime. This study investigates the thermal performance of different passive cooling systems for the LTO Li-ion battery cell/module with the application of natural convection, aluminum (Al) mesh, copper (Cu) mesh, phase change material (PCM), and PCM-graphite. Experimental results show the average temperature of the cell, due to natural convection, Al mesh, Cu mesh, PCM, and PCM-graphite compared with the lack of natural convection decrease by 6.4%, 7.4%, 8.8%, 30%, and 39.3%, respectively. In addition, some numerical simulations... [more]

The thermal performance of a phase change energy storage building envelope with the ventilated cavity was evaluated. CaCl2·6H2O-Mg(NO3)2·6H2O/expanded graphite (EG) was employed to combined with the building for year-round management. The energy consumption caused by the building under different influence parameters was evaluated numerically. The results indicated that CaCl2·6H2O-8wt %Mg(NO3)2·6H2O/EG should be installed on the south wall for the heating season, while CaCl2·6H2O-2wt %Mg(NO3)2·6H2O/EG should be integrated on the roof for the cooling season. When the air layer was ventilated and the south wall was coated with the solar absorbing coating, the room could save approximately 30% of energy consumption. Moreover, the energy consumption increased with an increase in the air layer thickness, and the air layers played a different role in the building envelope. The optimal value of the flow rate between air layer 2, air layer 3, and the room was 0.09 m3/s. To reduce the energy con... [more]

This particular research was conducted with the aim of describing the impact of a rotating nanoliquid on an elasting surface. This specific study was carried out using a two-phase nanoliquid model. In this study engine oil is used as the base fluid, and two forms of nanoparticles are used, namely, titanium oxide and zinc oxide (TiO2 and ZnO). Using appropriate similarity transformations, the arising system of partial differential equations and the related boundary conditions are presented and then converted into a system of ordinary differential equations. These equations are numerically tackled using powerful techniques. Graphs for nanoparticle rotation parameter and volume fraction for both types of nanoparticles present the results for the velocity and heat transfer features. Quantities of physical significance are measured and evaluated, such as local heat flux intensity and local skin friction coefficients at the linear stretching surface. Numerical values for skin friction and lo... [more]

In this paper, a strategy for reducing the electromagnetic interferences induced by power lines on metallic pipelines is proposed and numerically investigated. The study considers a set of steel conductors interposed between the power line and the pipeline. Different shapes of conductor cross sections and different magnetic permeabilities are considered, to identify the solution exhibiting the greatest mitigation efficiency for the same amount of material. The investigation is carried out by means of a quasi-3D finite element analysis. Results show that the main mechanism responsible for the mitigation is constituted by the currents induced in the screening conductors by the power line. Hence, a high magnetic permeability can have a detrimental effect since it reduces the skin depth to values below the size of the screening conductor. In this case, a reduction of the screening current and in the mitigation efficiency is observed. Nevertheless, the study shows that the use of strip-shap... [more]

The thermal diffusivity of building materials is an extremely important parameter influencing the subsequent thermal comfort of building users. By definition, thermal diffusivity describes how quickly heat from a hot source can flow through a material. Therefore, this parameter includes both the thermal conductivity and the heat capacity of the material. This parameter is often neglected in heat-related calculations which, in the case of dynamic problems, leads to unreliable results. It should be taken into account that heat flows through all materials at a finite speed. On the other hand, knowing the correct thermal diffusivity value of building materials, it is possible to accurately determine the internal parameters in rooms over time. There are several methods for determining thermal diffusivity, most of which are destined to determine this property in laboratories. The aim of the present research is to show how the thermal diffusivity of materials can be determined in existing bui... [more]

Groundwater velocity has significant effects on the formation of a frozen curtain during freezing. In order to study the influence of the velocity on a frozen curtain, a large physical model test platform was established for double-pipe freezing. Based on this platform, freezing tests for different velocities were carried out. Quartz sand was selected as a similar material. The freezing temperature of the saturated sand layer was found by analyzing the results of the nuclear magnetic resonance (NMR). Based on the study of the thermal physical properties of the sand layer, the freezing test results were analyzed, and the results showed that the flow led to the differential development of the temperature between the upstream and downstream sections of the freezing pipes. Moreover, the larger the velocity, the greater the difference. The flow prolonged the overlapping time of the frozen curtains. Additionally, the flow slowed down the development of the frozen curtain area and the frozen... [more]

Valorization of industrial low-value side-streams are of great interest, contributing to boosts in the circular economy. In this context, lignin side-streams of the pulp and paper industry were oxypropylated to produce biobased polyols and tested in the synthesis of rigid polyurethane (RPU) foams. E. globulus lignins, namely a lignin isolated from an industrial Kraft black liquor and depolymerized lignins obtained as by-products of an oxidation process, were used. RPU foams, synthesized with 100% lignin-based polyols and using a 1.1 NCO/OH ratio, were characterized concerning apparent density, morphology, thermal conductivity, thermal stability, and heat release rate (HRR). Foams containing the lignin-based polyols presented densities varying from 44.7 to 112.2 kg/m3 and thermal conductivity in the range of 37.2−49.0 mW/mK. For the reference foam (sample produced with 100% wt. Daltofoam TP 32015 polyol), values of 70.9 kg/m3 and 41.1 mW/mK were obtained, respectively. The achieved resu... [more]

Latent heat thermal energy storage systems (LHTES) are useful for solar energy storage and many other applications, but there is an issue with phase change materials (PCMs) having low thermal conductivity. This can be enhanced with fins, metal foam, heat pipes, multiple PCMs, and nanoparticles (NPs). This paper reviews nano-enhanced PCM (NePCM) alone and with additional enhancements. Low, middle, and high temperature PCM are classified, and the achievements and limitations of works are assessed. The review is categorized based upon enhancements: solely NPs, NPs and fins, NPs and heat pipes, NPs with highly conductive porous materials, NPs and multiple PCMs, and nano-encapsulated PCMs. Both experimental and numerical methods are considered, focusing on how well NPs enhanced the system. Generally, NPs have been proven to enhance PCM, with some types more effective than others. Middle and high temperatures are lacking compared to low temperature, as well as combined enhancement studies. A... [more]

Progression in the field of insulating materials for power transformers and other high voltage devices is visible regardless of the type of insulation: solid, liquid, or gas [...]

The dynamically developing energy sector forces technologists to create new materials that meet the increasingly higher mechanical, chemical, and electrical requirements. The paper relates to the method of reducing the energy consumption of the plasma nitriding process of austenitic steels. The method proposed by the authors involves the modification of nitriding technology in glow plasma. It consists of introducing perforated screens between the anode and nitrided surface made of a material with a composition similar to the processed material and the use of an HF power supply with controlled mean current generating negative voltage peaks of about 1000 V. Nitriding is carried out in a nitrogen-hydrogen atmosphere. The processed material has a negative potential in relation to the surrounding plasma and strongly negative in relation to the vacuum chamber jacket. The actual treatment is preceded by ionic cleaning of the surface of the detail and heating it to the temperature that activat... [more]

The chemical and petrochemical sector relies on fossil fuels and feedstocks, and is a major source of carbon dioxide (CO2) emissions. The techno-economic potential of 20 decarbonisation options is assessed. While previous analyses focus on the production processes, this analysis covers the full product life cycle CO2 emissions. The analysis elaborates the carbon accounting complexity that results from the non-energy use of fossil fuels, and highlights the importance of strategies that consider the carbon stored in synthetic organic products—an aspect that warrants more attention in long-term energy scenarios and strategies. Average mitigation costs in the sector would amount to 64 United States dollars (USD) per tonne of CO2 for full decarbonisation in 2050. The rapidly declining renewables cost is one main cause for this low-cost estimate. Renewable energy supply solutions, in combination with electrification, account for 40% of total emissions reductions. Annual biomass use grows to... [more]