Experimental studies of the effect of X-rays on the process of electrolytic deposition of composite coatings are reviewed in this paper. Particular emphasis will be on the applications of X-rays for both the modification of a structure and the mechanical characteristics of galvanic coatings. In particular, this research investigates the Co/SiO2 coatings deposited from aqueous solutions under the effect of X-rays. The results of extensive investigations into the dispersing ability of electrolytes with SiO2 nanoparticles and a mass rate of composite coatings Co/SiO2 indicates that the method of electroplating under the effect of X-rays during the process results in the intensification of diffusion in the electrolyte volume and creates dense, uniform coatings. This research demonstrates that exposure of an electrolytic cell to X-rays during the electroplating process of Co/SiO2 results in an orienting effect on the formation of crystal grains and allows for the creation of dense, morpholo... [more]

Spatial heating and cooking account for a significant fraction of global domestic energy consumption. It is therefore likely that hydrogen combustion will form part of a hydrogen-based energy economy. Catalytic hydrogen combustion (CHC) is considered a promising technology for this purpose. CHC is an exothermic reaction, with water as the only by-product. Compared to direct flame-based hydrogen combustion, CHC is relatively safe as it foregoes COx, CH4, and under certain conditions NOx formation. More so, the risk of blow-off (flame extinguished due to the high fuel flow speed required for H2 combustion) is adverted. CHC is, however, perplexed by the occurrence of hotspots, which are defined as areas where the localized surface temperature is higher than the average surface temperature over the catalyst surface. Hotspots may result in hydrogen’s autoignition and accelerated catalyst degradation. In this review, catalyst materials along with the hydrogen technologies investigated for CH... [more]

Two phase flow and horizontal well completion pose additional challenges for rate-transient analysis (RTA) techniques in under-saturated coal seam gas (CSG) reservoirs. To better obtain reservoir parameters, a practical workflow for the two phase RTA technique is presented to extract reservoir information by the analysis of production data of a horizontal well in an under-saturated CSG reservoir. This workflow includes a flowing material balance (FMB) technique and an improved form of two phase (water + gas) RTA. At production stage of a horizontal well in under-saturated CSG reservoirs, a FMB technique was developed to extract original water in-place (OWIP) and horizontal permeability. This FMB technique involves the application of an appropriate productivity equation representing the relative position of the horizontal well in the drainage area. Then, two phase (water + gas) RTA of a horizontal well was also investigated by introducing the concept of the area of influence (AI), which... [more]

For solar thermal harvesting, an experimental study was performed on the thermal absorption performance of water-based carbon nanotubes (CNTs), Cu, and Al2O3 nanofluids using a halogen lamp-based thermal radiation system. The effect of nanoparticle concentrations (0.01 wt.%, 0.1 wt.%, and 1 wt.%) on the nanofluid dispersion, stability, and thermal absorption characteristics was investigated, and a comparative analysis was performed for each type of nanofluid. All types of nanofluids increased the absorbance and electrical conductivity with increasing nanoparticle concentration, which contributed to improving the thermal absorption performance of nanofluids. The results showed that the thermal absorption performance was high in the order of carbon-based nanofluids (CNTs), metal-based nanofluids (Cu), and oxide-based nanofluids (Al2O3). In CNTs nanofluids, the thermal absorption performance expressed the time reduction rate, which was 12.8%, 16.3%, and 16.4% at 0.01 wt.%, 0.1 wt.%, and 1... [more]

The advancement of material technology has contributed to the variation of high-performance composites with good electrical insulation and mechanical properties. Their usage in electrical applications has grown since then. In Malaysia, the composite made of Glass Fiber Reinforced Polymer (GFRP) has been adopted for crossarm manufacturing and has successfully served 275 kV lines for a few decades. However, the combination of extreme conditions such as lightning transient and tropical climate can impose threats to the material. These issues have become major topics of discussion among the utilities in the Southeast Asian (SEA) region, and also in previous research. In Malaysia, more than 50% of total interruptions were caused by lightning. Limited studies can be found on the composite crossarm, especially on the square tube GFRP filled crossarm used in Malaysia. Therefore, this paper proposes to study the behavior of the particular GFRP crossarm, by means of its insulation characteristic... [more]

This paper represents the results of experimental studies of physical modeling of the underground coal gasification process in terms of implementation of design and technological solutions aimed at intensification of a gasification process of thin coal seams. A series of experimental studies were performed in terms of a stand unit with the provided criteria of similarity to field conditions as well as kinetics of thermochemical processes occurring within a gas generator. Hard coal (high volatile bituminous coal) was selected as the raw material to be gasified, as that coal grade prevails in Ukrainian energy balance since it is represented by rather great reserves. Five blow types were tested during the research (air, air−steam, oxygen−steam, oxygen−enriched, and carbon dioxide and oxygen). As a result, the effect of tightness of a gas generator on the quantitative and qualitative parameters of coal gasification while varying the blow by reagents and changing the pressure in a reaction... [more]

The verification of the blasting parameters of Ammonium Nitrate Fuel Oil (ANFO) with the addition of microstructured charcoal (MC) produced by destructive wood distillation was performed. Additional investigation of specific surface and pore distribution by the nitrogen adsorption of the two granulations of MC was also carried out. High-resolution scanning electron microscopy was used for morphology evaluation and revealed smoothening of the initially developed external surface of carbon with intensive milling. In addition, the analysis of the thermal properties of the studied samples (TG/DSC) indicated that the size of the microstructured charcoal additives influenced the decomposition temperature of the prepared materials. The explosives containing microstructured charcoal grains of −90 μm underwent decomposition at lower temperatures in comparison with those containing higher sizes of microstructure charcoal grains (−1.18 mm), for which the decomposition temperature reached 292 °C.... [more]

The corrosiveness of biodiesel affects the fuel processing infrastructure and different parts of an internal combustion (IC) engine. The present study investigates the corrosion behaviour of automotive materials such as stainless steel, aluminium, cast iron, and copper in 20% (B20) and 30% (B30) by volume second-generation Jatropha biodiesel using an immersion test. The results were compared with petro-diesel (B0). Various fuel properties such as the viscosity, density, water content, total acid number (TAN), and oxidation stability were investigated after the immersion test using ASTM D341, ASTM D975, ASTM D445, and ASTM D6751 standards. The morphology of the corroded materials was investigated using optical microscopy and scanning electron microscopy SEM), whereas the elemental analysis was carried out using energy-dispersive X-ray spectroscopy (EDS). The highest corrosion using biodiesel was detected in copper, while the lowest was detected in stainless steel. Using B20, the rate of... [more]

Hundreds of geothermal wells have been drilled in Hungary to exploit Pannonian Basin sandstones for district heating, agriculture, and industrial heating projects. Most of these sites suffer from reinjection issues, limiting efficient use of this vast geothermal resource and imposing significant extra costs for the required frequent workovers and maintenance. To better understand the cause of this issue requires details of reservoir rock porosity, permeability, and mineralogy. However, publicly available data for the properties of reservoir rocks at geothermal project sites in Hungary is typically very limited, because these projects often omit or limit data acquisition. Many hydrocarbon wells in the same rocks are more extensively documented, but their core, log, or production data are typically decades old and unavailable in the public domain. Furthermore, because many Pannonian sandstone formations are poorly consolidated, coring was always limited and the collected core often unsui... [more]

Methanol synthesis from carbon dioxide (CO2) may contribute to carbon capture and utilization, energy fluctuation control and the availability of CO2-neutral fuels. However, methanol synthesis is challenging due to the stringent thermodynamics. Several catalysts mainly based on the carrier material Al2O3 have been investigated. Few results on MgO as carrier material have been published. The focus of this study is the carrier material MgO. The caustic properties of MgO depend on the caustification/sintering temperature. This paper presents the first results of the activity of a Cu/MgO catalyst for the low calcining temperature of 823 K. For the chosen calcining conditions, MgO is highly active with respect to its CO2 adsorption capacity. The Cu/MgO catalyst showed good catalytic activity in CO2 hydrogenation with a high selectivity for methanol. In repeated cycles of reactant consumption and product condensation followed by reactant re-dosing, an overall relative conversion of CO2 of 76... [more]

The main reason for the limited usage of biodiesel is it tends to oxidize when exposed to air. It is anticipated that the addition of an antioxidant along with graphene nano particle improves combustion of diesel-biodiesel blend. In the present research biodiesel made from the transesterification of waste cooking oil is used. Three synthetic antioxidants butylated hydroxytoluene (BHT), 2(3)-t-butyl-4-hydroxyanisole (BHA) and tert butylhydroquinone (TBHQ) along with 30 ppm of graphene nano particle were added at a volume fraction of 1000 ppm to diesel−biodiesel blends (B20). The performance and emission tests were performed at constant engine speed of 1500 rpm. Because of the inclusion of graphene nano particles, surface area to the volume ratio of the fuel is augmented enhancing the mixing ability and chemical responsiveness of the fuel during burning causing superior performance, combustion and emission aspects of compression ignition engine. The results revealed that there was a slig... [more]

Energy and exergy (EnE) efficiencies are considered the most important parameters to compare the performance of various thermal systems. In this paper, an analysis was carried out for EnE efficiencies of a flat plate solar collector (FPSC) using four different kinds of nanofluids as flowing mediums, namely, Al2O3/water, MgO/water, TiO2/water, and CuO/water, and compared with water as a flowing medium (traditional base fluid). The analysis considered nanofluids made of nanomaterials’ volume fractions of 1−4% with water. The volume flow rates of nanofluids and water were 1 to 4 L/min. The solar collector′s highest EnE efficiency values were obtained for CuO/water nanofluid among the four types of nanofluids mentioned above. The EnE efficiencies of the CuO nanofluid-operated solar collector were 38.21% and 34.06%, respectively, which is significantly higher than that of water-operated solar collectors. For the same volume flow rate, the mass flow rate was found to be 15.95% higher than wa... [more]

This work aims to study the drying of clay ceramic materials with arbitrary shapes theoretically. Advanced phenomenological mathematical models based on lumped analysis and their exact solutions are presented to predict the heat and mass transfers in the porous material and estimate the transport coefficients. Application has been made in hollow ceramic bricks. Different simulations were carried out to evaluate the effect of drying air conditions (relative humidity and speed) under conditions of forced and natural convection. The transient results of the moisture content and temperature of the brick, and the convective heat and mass transfer coefficients are presented, discussed and compared with experimental data, obtaining a good agreement. It was found that the lower the relative humidity is and the higher the speed of the drying air is, the higher the convective heat and mass transfer coefficients are at the surface of the brick and in the holes, and the faster the moisture removal... [more]

Knowing the properties of vernacular materials is crucial to heritage conservation and to develop innovative solutions. Reed, considered to be a carbon-neutral and a carbon dioxide sink material, has been used for centuries for diverse uses. Its high availability and properties made it a popular building material, including in Portuguese vernacular architecture. An experimental investigation was conducted to evaluate the physical performance, thermal performance, and durability of the reed found in Portugal since the characterisation of this material was not found in previous studies. The influence of geometric characteristics and the presence of nodes on these properties were also analysed, and the results showed that they are irrelevant. The studied reeds were found to have an adequate thermal performance to be used as thermal insulation. Their thermal resistance (1.8 m2·°C/W) and thermal conductivity (0.06 W/m·°C) are under the requirements defined by Portuguese regulations on therm... [more]

Ultrathin Cu(In,Ga)Se2 (CIGS) absorber layers of 550 nm were grown on Ag/AlOx stacks. The addition of the stack resulted in solar cells with improved fill factor, open circuit voltage and short circuit current density. The efficiency was increased from 7% to almost 12%. Photoluminescence (PL) and time resolved PL were improved, which was attributed to the passivating properties of AlOx. A current increase of almost 2 mA/cm2 was measured, due to increased light scattering and surface roughness. With time of flight—secondary ion mass spectroscopy, the elemental profiles were measured. It was found that the Ag is incorporated through the whole CIGS layer. Secondary electron microscopic images of the Mo back revealed residuals of the Ag/AlOx stack, which was confirmed by energy dispersive X-ray spectroscopy measurements. It is assumed to induce the increased surface roughness and scattering properties. At the front, large stains are visible for the cells with the Ag/AlOx back contact. An a... [more]

Colloidal dye-sensitized photocatalysis is a promising route toward efficient solar fuel production by merging properties of catalysis, support, light absorption, and electron mediation in one. Metal-organic frameworks (MOFs) are host materials with modular building principles allowing scaffold property tailoring. Herein, we combine these two fields and compare porous Zr-based MOFs UiO-66-NH2(Zr) and UiO-66(Zr) to monoclinic ZrO2 as model colloid hosts with co-immobilized molecular carbon dioxide reduction photocatalyst fac-ReBr(CO)3(4,4′-dcbpy) (dcbpy = dicarboxy-2,2′-bipyridine) and photosensitizer Ru(bpy)2(5,5′-dcbpy)Cl2 (bpy = 2,2′-bipyridine). These host-guest systems demonstrate selective CO2-to-CO reduction in acetonitrile in presence of an electron donor under visible light irradiation, with turnover numbers (TONs) increasing from ZrO2, to UiO-66, and to UiO-66-NH2 in turn. This is attributed to MOF hosts facilitating electron hopping and enhanced CO2 uptake due to their innate... [more]

Nowadays, batteries for electric vehicles are expected to have a high energy density, allow fast charging and maintain long cycle life, while providing affordable traction, and complying with stringent safety and environmental standards. Extensive research on novel materials at cell level is hence needed for the continuous improvement of the batteries coupled towards achieving these requirements. This article firstly delves into future developments in electric vehicles from a technology perspective, and the perspective of changing end-user demands. After these end-user needs are defined, their translation into future battery requirements is described. A detailed review of expected material developments follows, to address these dynamic and changing needs. Developments on anodes, cathodes, electrolyte and cell level will be discussed. Finally, a special section will discuss the safety aspects with these increasing end-user demands and how to overcome these issues.

Due to environmental concerns, the role of renewable sources for petroleum-based products has become an invaluable research topic. One possibility of achieving this goal is the Fischer−Tropsch synthesis (FTS) based on sustainable raw materials. Those materials include, but are not limited to, synthesis gas from biomass gasification or hydrogen through electrolysis powered by renewable electricity. In recent years, the utilisation of CO2 as carbon source for FTS was one main R&D topic. This is one of the reasons for its increase in value and the removal of its label as being just exhaust gas. With the heavy product fraction of FTS, referred to as Fischer−Tropsch waxes (FTW), being rather limited in their application, catalytic upgrading can help to increase the economic viability of such a process by converting the waxes to high value transportation fuels and lubricating oils. In this paper, the dewaxing of FTW via hydroisomerisation and hydrocracking was investigated. A three phase fix... [more]

The power conversion efficiency (PCE) of organic photovoltaics (OPVs) has exceeded 18% with narrow bandgap, non-fullerene materials Y6 or its derivatives when used as an electron acceptor. The PCE improvement of OPVs is due to strong photon harvesting in near-infrared light range and low energy loss. Meanwhile, ternary strategy is commonly recognized as a convenient and efficient means to improve the PCE of OPVs. In this review article, typical donor and acceptor materials in prepared efficient OPVs are summarized. From the device engineering perspective, the typical research work on ternary strategy and tandem structure is introduced for understanding the device design and materials selection for preparing efficient OPVs.

Drilling volumes should be increased in order to increase hydrocarbon production, but this is impossible without the usage of high-quality drilling tools made of modern structural materials. The study has to analyze the design, technological and operational methods to increase the performance of drilling tools made of various materials and has highlighted prospects of technological method applications. The scientific novelty of the study consists in the development of a new analytical model of PDC drill bit−well interaction. The developed model takes into account the drill bit manufacturing errors in the form of bit body−nipple axes misalignment on the drill bit strength. This result makes it possible to determine the permissible manufacturing errors to provide safe operation of the drill bit. It is established that there is an additional transverse force that presses the drill bit to the well wall in the rock due to manufacturing errors. It is determined that the magnitude of this cla... [more]

In this study, cold and thermal storage systems were designed and manufactured to operate in combination with the water chiller air-conditioning system of 105.5 kW capacity, with the aim of reducing operating costs and maximizing energy efficiency. The cold storage tank used a mixture of water and 10 wt.% glycerin as a phase-change material (PCM), while water was used as heat transfer fluid (HTF). The cold storage heat exchanger was made of polyvinyl chloride (PVC). On the other hand, the thermal storage tank used water as the storage fluid with a capacity of 50 L of hot water per hour. The thermal storage did not use a pump for water transfer through the heat exchanger, so as to save energy and operating costs. In this paper, the operating parameters of the cold and thermal storage tanks are shown according to the results of experimental research, including the temperatures of cooling and heating load, heat transfer fluid, and cold storage material during the discharge process, as wel... [more]

This paper presents an environmental impact assessment of the entire cycle of existence of the tube-vacuum solar collector prototype. The innovativeness of the solution involved using a phase change material as a heat-storing material, which was placed inside the collector’s tubes-vacuum. The PCM used in this study was paraffin. The system boundaries contained three phases: production, operation (use phase), and disposal. An ecological life cycle assessment was carried out using the SimaPro software. To compare the environmental impact of heat storage, the amount of heat generated for 15 years, starting from the beginning of a solar installation for preparing domestic hot water for a single-family residential building, was considered the functional unit. Assuming comparable production methods for individual elements of the ETC and waste management scenarios, the reduction in harmful effects on the environment by introducing a PCM that stores heat inside the ETC ranges from 17 to 24%. T... [more]

Photovoltaic (PV) power systems are increasingly being used as renewable power generation sources. Quasi-Z-source inverters (qZSI) are a recent, high-potential technology that can be used to integrate PV power systems into AC networks. Simultaneously, concerns regarding the stability of PV power systems are increasing. Converters reduce the damping of grid-connected converter systems, leading to instability. Several studies have analyzed the stability and dynamics of qZSI, although the characterization of qZSI-PV system dynamics in order to study transient interactions and stability has not yet been properly completed. This paper contributes a small-signal, state-space-averaged model of qZSI-PV systems in order to study these issues. The model is also applied to investigate the stability of PV power systems by analyzing the influence of system parameters. Moreover, solutions to mitigate the instabilities are proposed and the stability is verified using PSCAD time domain simulations.

A new type of Fresnel array has been devised and constructed as an answer to the need to reduce the investment costs of solar thermal collectors, without jeopardizing their efficiency in capturing solar radiation at high temperatures. The array of mirror bands is fixed onto a horizontal platform, which rotates around a virtual vertical axis, so that the sun is in the extrapolated vertical plane of symmetry of the array. The receptor central line is also placed in said plane, and it is physically made of at least one tube at each side of the plane. The geometrical relation between the mirrors and the receptor is therefore fixed. The platform rotates with the same speed as that of the sunlight’s azimuthal component. On the contrary, the angle of incidence of the sunlight on the mirrors changes as the sun rises and declines in its daily apparent motion, but this effect does not disturb the radiation concentration kinematics, although it induces a shift along the receptor. This is a new co... [more]

Photovoltaic modules during sunny days can reach temperatures 35 °C above the ambient temperature, which strongly influences their performance and electrical efficiency as power losses can be up to −0.65%/°C. To minimize and control the PV panel temperature, the scientific community has proposed different strategies and innovative approaches, one of them through passive cooling with phase change materials (PCM). However, further investigation, including the effects of geometric shape, insulation, phase change temperature, ambient temperature, and solar radiation on the PV module power output and efficiency, needs further optimization and research. Therefore, the current work aims to investigate several system configurations and different PCMs (RT42, RT31, and RT25) and compare the system with and without insulation through computational fluid dynamic (CFD) tools. The final goal is to optimise and control the temperature of PV modules and evaluate their system efficiency and energy gene... [more]