Pneumatic conveying is widely used in coal mining. As the lowest conveying velocity of materials, the pickup velocity is the key to the study of gas−solid two-phase flow. In this study, the pickup velocity of pebble particles was experimentally investigated. When the particle size is 3−9 mm, the airflow velocity was found to suitably describe the results as a function of the pickup velocity and have a high correlation. When the swirl number is 0.2, the optimal swirl number was found for which the highest particle pickup ratio was observed. Based on four different methods, namely, visual observation, mass weighing, coefficient of difference analysis, and determination of the peak-average ratio of the pressure drop in the flow field to measure the pickup velocity of the spraying material, the results showed that the accuracy of the particle pickup velocity obtained through visual observation was the lowest, and when the mass−loss rate of the particle was selected as the measurement index... [more]

In industrial-scale biogas production from cereal straw, large quantities of solid fiber-rich digestate are produced as residual material. These residues usually contain high amounts of cellulose, hemicellulose and lignin and thus have potential for further utilization. However, they also contain impurities such as ammonia and minerals, which could negatively affect further utilization. Against this background, the present study investigates how this fibrous straw digestate can be fractionated by a combined hydrothermal and enzymatic treatment and what influence the impurities have in this process. Therefore, it is analyzed how the fractions cellulose, hemicellulose and lignin are modified by this two-stage treatment, using either raw digestate (including all impurities) or washed digestate (containing only purified fibers) as the substrate. For both substrates, around 50% of the hemicellulose is solubilized to xylans after 50 min of hydrothermal treatment using steam at 180 ∘C. Furthe... [more]

Harvesting atmospheric water by solar regenerated desiccants is a promising water source that is energy-efficient, environmentally clean, and viable. However, the generated amounts of water are still insignificant. Therefore, more intensive fundamental research must be undertaken involving experiments and modeling. This paper describes several experiments, which were conducted to predict and improve the behavior of water absorption/desorption by the Calcium Chloride (CaCl2) desiccant, where the uncertainty did not exceed ±3.5%. The absorption effect in a deep container was studied experimentally and then amplified by pumping air into the solution. The latter measured water absorption/desorption by a thin solution layer under variable ambient conditions. Pumping air inside deep liquid desiccant containers increased the water absorption rate to 3.75% per hour, yet when using a thin layer of the solution, it was found to have increased to 6.5% per hour under the same conditions. The maxim... [more]

Silica is considered one of the most prevalent components in the Earth’s shell and is synthesized for use in technological applications. Nevertheless, new methods for finding a better, cheaper, and more ecologically friendly supply of silica with less energy consumption are unavoidable. This study investigates whether nanopowders made from waste with a great silica amount (fly ash and glass) can be utilized as fillers in an epoxy glue to enhance its characteristics. Four different contents (5, 10, 15, and 20 wt%) of nano−fly ash, nanoglass, and nanosilica powder were introduced into the samples. Fourier transform infrared analysis, differential scanning calorimetry analysis, viscosity testing, and microhardness testing were conducted for nanoglass/epoxy and nano−fly ash/epoxy samples, which were compared with the silica/epoxy samples. Results indicated that the nanoglass and nano−fly ash powder have the same impact as nanosilica on the characteristics of epoxy. The hardness and viscosi... [more]

Long linear antennas for very low frequency radio transmissions, supported by aerostats, unanchored, and raised to high altitudes, present themselves as slow-moving, highly conductive disturbances in cloud layers, acquiring an electrical charge and being subjected to intense coronae. High electric field strength values around those objects increase the risk of lightning strikes, which could be disastrous to the mechanical structures of the balloon mission (both the antenna and the balloon) and the radio transmitter. This paper aims to investigate the inception of lightning strikes over two essential elements of such missions: a talc-covered latex (balloon material) and the model of the linear antenna, made of different materials. Based on the high-voltage experiments with the recorded electrical discharges, the properties, functions, and possible ameliorations of the talc cover are presented, as well as the basic characteristics of lightning forms around the very long antenna system, w... [more]

This paper introduces a fiber generator using PVDF with a high-performance lead-free piezoelectric ceramic as filler. The piezoelectric ceramic filler was Ba0.84Ca0.16Ti0.90Zr0.10O3 + CuO 0.25 wt% (BCTZC0.25) sintered at 1550 °C. The BCTZC0.25 has an improved high-energy conversion constant (d33 × g33). The fiber generator made of PVDF/BCTZC0.25 composite fiber showed 1.6 times better piezoelectric power generation performance compared to a pure PVDF fiber generator. The PVDF/BCTZC0.25 fiber generator produced an output voltage of 1.9 V at 4 Hz. Hence, we successfully demonstrated that a composite fiber generator that uses piezoelectric ceramics which are harmless to the human body can outperform a pure PVDF fiber generator.

In this work, hydrolysis lignin with nickel compounds deposited on the surface was prepared. The resulting material was introduced into the process of carbon dioxide assisted conversion and the catalytic activity of the deposited nickel compounds in this reaction was evaluated. Use of the obtained catalytic system increases CO2 conversion by more than 30% in the temperature range 450−800 °C. After the conversion process, the material was subjected to a study using a variety of physico-chemical analysis methods (TEM, SEM-EDX, and X-ray phase analysis). Physico-chemical methods of analysis of a sample calcined at 300 °C to decompose nickel nitrate revealed NiO nanoparticles with an average particle size of 16.9 nm.

Characterization of stress-dependent single-phase and multiphase fluid transport in fractured geo-materials is essential for a wide range of applications, including CO2 sequestration, energy storage, and geo-energy extraction. However, pivotal studies on capillarity and multiphase fluid flow in deformable rock fractures are surprisingly sparse. In this study, we initially investigated the hydro-mechanical properties of an intact mixed-wet Calumet carbonate from the Waterways formation (Alberta) under isothermal conditions (40 °C). Then, we conducted core-flooding experiments using water and N2 to assess changes in the aperture, absolute permeability, relative permeability, and capillary pressure of an artificially fractured Calumet core in response to changes in effective confining stress during loading (0−10 MPa) and unloading (10−3 MPa). We quantified the fracture’s non-linear closure and hysteresis effect during the cyclic loading−unloading processes. We found that porosity and abso... [more]

Capacitance−resistance models (CRMs) are semi-analytical methods to estimate the production rate of either an individual producer or a group of producers based on historical observed production and injection rates using material balance and signal correlations between injectors and producers. Waterflood performance methods are applied to evaluate the waterflooding performance effect and to forecast the development index on the basis of Buckley−Leverett displacement theory and oil−water permeability curve. In this case study, we propose an approach that combines a capacitance−resistance model (CRM) modified by increasing the influence radius on the constraints and a waterflood performance equation between oil cut and oil accumulative production to improve liquid and oil production prediction ability. By applying the method, we can understand the waterflood performance, inter-well connectivities between injectors and producer, and production rate fluctuation better, in order to re-just t... [more]

The influence of high-rank coal’s pore characteristics on the physical properties, gas-bearing properties, and exploitation of coal reservoirs is becoming more and more prominent. How to establish the classification to describe the pore networks combining quantitative and qualitative characteristics has emerged as a major problem, which may offer a scientific foundation to deepen the understanding of this issue. In this research, the structure and fractal characteristics of reservoir pores were determined after analyzing 20 high-rank coal samples from Xinjing Coal Mine in the Qinshui Basin with the application of the high-pressure mercury intrusion method (HPMI) and argon ion polishing−field emission scanning electron microscopy (AIP−FESEM). The results show that the tested coal samples were bipolar distributed, with transitional pores and micropores dominating the pore volume, followed by macropores. The Menger sponge fractal models manifested two or three distinct straight-line segme... [more]

The currently reported bottom water sealing materials and fracturing technologies can hardly simultaneously achieve the high production and low water cut of gas reservoirs due to the complexity of various formation conditions. Therefore, without controlling the fracturing scale and injection volume, a kind of polylactide polymer water plugging material with a density of 1.15−2.0 g/cm3 is developed, which can be used to seal the bottom water of a gas−water differential layer by contact solidification with water and automatic degradation with natural gas. This technology can not only fully release the production capacity of the gas reservoir but also effectively control water production and realize the efficient fracturing development of the target gas reservoir. Laboratory test results show that the smart plugging agent has a bottom water plugging rate of 100%, and the low-density plugging agent has a dissolution rate of 96.7% in methane gas at 90 °C for 4 h and a dissolution rate of 97... [more]

The aim of the proposed paper is to harmonize the Jiles−Atherton (J−A) static hysteresis loop models presented by different authors at different publication dates. The reviewed papers, which explain the hysteresis loop model of magnetic materials originally developed by Jiles are taken into consideration due to their different variable nomenclature and even physical meaning. Inconsistency between Jiles’ referenced works is shown and the consequences are presented as differences between BH curve behaviors and, on the application level, as differences in calculated static hysteresis losses. The harmonization of J−A hysteresis models is presented and confirmed by numerical calculations and measured data.

A novel energetic co-crystal composed of hydrazinium 3-nitro-1,2,4-triazol-5-one (HNTO) and ammonium nitrate (AN), as a composite solid propellant oxidizer, was recently developed to substitute either pure ammonium perchlorate (AP) or nitrate. Unfortunately, the thermodynamic properties of this co-crystal or even the pure HNTO are not available in the open literature. Therefore, in this work, the low-temperature heat capacities of HNTO and HNTO·AN co-crystal were measured in the temperature range from 213.15 K to 378.15 K using differential scanning calorimetry. By fitting the heat capacity data, the thermodynamic functions ΔH298.15K, ΔG298.15K, and ΔS298.15K were derived. In addition, the standard molar energies of combustion ΔcU° of HNTO and HNTO·AN co-crystal were determined, and from the combustion results, the standard molar enthalpies of combustion ΔcHmo and formation ΔfHmo of these energetic compounds were derived at T = 298.15 K. The set of thermochemical data has been proposed... [more]

In order to explore the development characteristics and influencing factors of microscale pores in lacustrine organic-rich muddy shale, this study selected five shale samples with different mineral compositions from the Qingshankou Formation in the Songliao Basin. The oil content and mineralogy of the shale samples were obtained by pyrolysis and X-ray diffraction analysis, respectively, while the porosity of the samples was computed by micro-CT imaging. Next, based on the CT images, the permeability of each sample was calculated by the Avizo software. Results showed that the continuous porosity of Qingshankou shale in the Songliao Basin was found between 0.84 and 7.79% (average 4.76%), the total porosity between 1.87 and 12.03% (average 8.28%), and the absolute permeability was calculated between 0.061 and 2.284 × 10−3 μm2. The total porosity of the samples has a good positive correlation with the continuous porosity and permeability. This means higher values of total porosity suggeste... [more]

Using thermal insulation materials to reduce energy loss in buildings is a key action. For reducing the building’s energy use, firstly, the internal unheated spaces (attics, cellars) should be insulated, followed by the insulation of the external walls, and changing the doors and windows. Finally, the building can be completed with the renovation/maintenance of its service systems. Newly designed and constructed buildings are subject to increasingly strict regulations, which highlight the minimization and elimination of wasteful energy use and the resulting emissions of harmful substances. Therefore, the use of thermal insulation is the first step in making buildings more energy efficient. In this editorial, seven articles covering thermal insulation possibilities and topics are highlighted. This paper reflected on the use of thermal insulations both for internal and external applications. This editorial also promotes the use of super insulation materials such as aerogels and vacuum in... [more]

One of the by-products of a mechanical-biological waste treatment plant is the under-sieve fraction, which requires separation prior to further processing of municipal mixed waste. This stream usually follows the fate of landfilling. Instead, it could be introduced to the hydrothermal carbonization (HTC) process to improve its fuel properties and become solid recovered fuel. The organic fraction and high moisture content (approximately 26%) of under-sieve fraction are favorable properties for the HTC process. In this study, hydrochars, the solid product of HTC, were produced at 200 and 220 °C with residence times of 1, 4, and 8 h. The main aim of this investigation was to establish the influence of different process parameters on hydrochars’ fuel properties. Thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) were employed in the analyses. The results confirmed the positive effects of hydrothermal carbonization on the... [more]

This paper presents an overview of the emerging trends in the development of electrical generators for large wind turbines. To describe the developments in the design of electrical generators, it is necessary to look at the conversion system as a whole, and then, the structural and mechanical performances of the drive train need to be considered. Many drive train configurations have been proposed for large wind turbines; they should ensure high reliability, long availability and reduced maintainability. Although most installed wind turbines are geared, directly driven wind turbines with permanent magnet generators have attracted growing interest in the last few years, which has been in parallel to the continuous increase of the per unit turbine power. The aim of this work is to present the recent commercial designs of electrical generators in large wind turbines. Both the strengths and weaknesses of the existing systems are discussed. The most emerging technologies in high-power, low-s... [more]

This paper presents the influence of selected flame retardant additives on heat release rate and thermokinetics properties of epoxy materials made of epoxy resin—Epidian 5. The epoxy resin underwent flame retardant modification with the use of organophosphorus compounds (Roflam F5, Roflam B7) and Al(OH)3, Mg(OH)2. The fire characteristics of the analysed epoxy resin were determined using the cone calorimeter method, and thermal analysis of epoxy resin and the surface morphology of the analysed epoxy materials was with the use of an SEM microscope with an EDS attachment. The lowest value of the heat release rate was recorded for hardened epoxy resin containing one component additive 5% by weight of Mg(OH)2, as well as two component additive 10% by weight of Roflam F5 and 5% by weight of Al(OH)3. Moreover, the initial temperature of thermal decomposition of phase I of the modified epoxy resin samples with Mg(OH)2 (sample 5M) or organophosphorus compounds and Mg(OH)2 (samples 5B + 10M and... [more]

In this work, both pyrochar and activated carbon were prepared by physical activation (i.e., saturation and superheated) by involving a thermal agent as a comparison. The effects of three agents on the pore development of activated carbon from a new material, Calliandra calothyrsus, were observed in detail. The BET surface area and the iodine index of the prepared activated carbon were used as pyrochar selection. Proximate, ultimate, XRD, FTIR, TGA, and SEM were used to characterize the physical and chemical properties of the product. Pyrochar pores were found to develop significantly at 350 °C, indicated by an increase in the BET surface area and iodine index. Pyrochar from a temperature of 350 °C was then selected as a precursor of activated carbon. S−SS and SS−S activated carbon samples were declared to have the highest iodine index (870 mg/g) and the highest BET surface area (642 m2/g), respectively. The pore distribution data showed that the superheated agent widened the pore and... [more]

Wide band gap (WBG) power electronic devices, such as silicon carbide metal−oxide−semiconductor field-effect transistors (SiC MOSFETs) and gallium−nitride high-electron-mobility transistors (GaN HEMTs) have been widely used in various fields and occupied a certain share of the market with rapid momentum, owing to their excellent electrical, mechanical, and thermal properties. The reliability of WBG power electronic devices is inseparable from the reliability of power electronic systems and is a significant concern for the industry and for academia. This review attempts to summarize the recent progress in the failure mechanisms of WBG power electronic semiconductor chips, the reliability of WBG power electronic packaging, and the reliability models for predicting the remaining life of WBG devices. Firstly, the typical structures and dominant failure mechanisms of SiC MOSFETs and GaN HEMTs are discussed. This is followed by a description of power electronic packaging failure mechanisms a... [more]

The conversion and utilization of carbon dioxide (CO2) have dual significance for reducing carbon emissions and solving energy demand. Catalytic reduction of CO2 is a promising way to convert and utilize CO2. However, high-performance catalysts with excellent catalytic activity, selectivity and stability are currently lacking. High-throughput methods offer an effective way to screen high-performance CO2 reduction catalysts. Here, recent advances in high-throughput screening of electrocatalysts for CO2 reduction are reviewed. First, the mechanism of CO2 reduction reaction by electrocatalysis and potential catalyst candidates are introduced. Second, high-throughput computational methods developed to accelerate catalyst screening are presented, such as density functional theory and machine learning. Then, high-throughput experimental methods are outlined, including experimental design, high-throughput synthesis, in situ characterization and high-throughput testing. Finally, future directi... [more]

Wood is one of the basic building materials. It is a completely biodegradable raw industrial commodity, the resources of which, with proper forest management, are virtually inexhaustible. Additionally, its acquisition and processing does not require large inputs of fossil fuels. At the same time, forest areas which we obtain wood from neutralize the negative effects of producing and acquiring other raw materials, as one hectare of pine forest (the most popular in Poland) can absorb approx. 20−30 tons of CO2. Wood is characterised by low thermal and electrical conductivity, having simultaneously high sound insulation, which perfectly meets the requirements of the present market and its regulations. This study aimed at verifying the technical parameters of wood, i.e., its bending strength, with the use of an innovative method of the correlation between the bending strength measured along and across wood fibres. The procedure was envisaged as effective for testing the strength of beams in... [more]

Fly ash from waste incineration and waste poplar bark from furniture manufacturing are domestic wastes. In this study, fly ash and poplar bark were used as raw materials to prepare activated carbon via carbonization, steam activation and reagent modification. The effects of the raw material mixing ratio, carbonization temperature, activator concentration and modifier concentration on the physicochemical properties of the semi-coke and activated carbon were investigated through experiments. The experiment showed that when the carbonization temperature was 300 °C, the steam concentration was 20%, the mixing ratio of the poplar bark and fly ash (B:F) was 5:1, and the modifier was 6% K2CO3 reagent and 9% CaCl2. The prepared activated carbon had a better yield, specific surface area and pore structure, and had an abundant surface functional group structure. This paper points out the direction for the industrial directional production of activated carbon adsorbents with excellent physical an... [more]

Passive solutions in buildings have recently been rediscovered because they allow the rational use of solar radiation, which promotes energy savings. Thermal energy gained from the sun may be stored in the form of sensible heat in accumulative solid materials in a building envelope. This paper proposes an innovative solar air heater that captures and accumulates solar energy during the day and releases it during the night. The analyzed system is based on inexpensive ceramic modules, which can be used to construct thermal storage walls or solar chimneys in modern buildings. Both configurations have been tested experimentally and by a numerical model in ArCADia BIM software. Experiments have been carried out in laboratory conditions using a specially developed prototype. Among other parameters, power transferred from the solar air heater to the ventilation air in different conditions has been analyzed. When airflow was set to 150 m3/h, the maximum power observed under stable working cond... [more]

Using solar panels is one of the cleanest ways to generate electricity ever created by mankind. The efficiency of rapidly expanding solar panels decreases during their lifetime for several reasons, such as photodegradation, hot spots, potentially induced degradation, etc. Dirt and debris accumulation on the surface of the solar panels can also significantly contribute to their performance degradation due to the diminishing of the solar radiation reaching their active surfaces. Numerous degradation mitigation methods are cited in the literature. This article briefly outlines these basic measures.