In view of the main problems of the condensing heat discharge modes of the existing underground air-conditioning system, the technical scheme of using phase change heat storage modules to improve the heat storage capacity of the reservoir is proposed. By establishing a 3D flow and transient heat transfer model of the phase change reservoir, the effects of thermal property parameters, package size and arrangement of the phase change heat storage modules on the heat storage performance of the phase change reservoir were quantitatively analyzed based on three indexes: heat storage capacity per volume Δq, guaranteed efficiency coefficient η and slope of temperature rise per unit load ε. The results show that when the phase change temperature is 29 °C (23 °C increased to 33 °C) and the latent heat value is 250 kJ/kg (100 kJ/kg increased to 250 kJ/kg), Δq (110.92 MJ/m3, 112.83 MJ/m3) and η (1.22, 1.24) under both conditions are at their most, respectively, indicating that the phase change te... [more]

Fractional-slot PMSM motors allow for obtaining high values of power density factors, but at the same time, they are characterized by high values of rotor losses—in the rotor core and permanent magnets. The main causes of rotor losses in this type of motor are subharmonics and a high content of higher harmonics in the distribution of the magnetomotive force MMF. The use of a solid rotor core simplifies the construction and technology of the rotor but eddy current losses in the core account for a significant percentage of the total rotor losses. It is well known that a laminated core reduces eddy currents, while for motors with an outer rotor, it complicates the construction and increases weight. Thus, the question arises about the necessity to use a laminated core in a high power density motor and the real benefits of this. The article presents a comparison of the motors with a solid rotor core and a laminated rotor core, considering the value of rotor losses, power density factor, eff... [more]

Polyacrylamide (PAM)/polyethyleneimine (PEI) gels doped with graphene oxide (GO) were prepared. Their structure and properties were systematically studied by X-ray diffraction (XRD), Fourier transition infrared spectrum (FT-IR), Raman spectroscopy, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and rheological experiments. The results showed that the graphene oxide (GO) nanosheets were significantly involved in the cross-linking reaction between the main agent (PAM) and the cross-linker (PEI), serving as multi-functional cross-linker and effective reinforcing nanofillers. Increasing the main agent and cross-linker content, the strength of gels was enhanced effectively. The GO could effectively adjust the strength and the gelation time to exhibit characteristics of weak gel, thanks to the improved three-dimensional honeycombed structure with controllable pore size. The DSC confirmed that the PAM/PEI/GO gel exhibited excellent thermal stability and did not d... [more]

A Mg65Ni20Cu5Y10 metallic glass was produced by melt spinning and was mixed with a 5 wt.% multiwall carbon nanotube additive in a high-energy ball mill. Subsequently, the composite mixture was exposed to high-pressure torsion deformation with different torsion numbers. Complimentary XRD and DSC experiments confirmed the exceptional structural and thermal stability of the amorphous phase against severe plastic deformation. Combined high-resolution transmission electron microscopy observations and fast Fourier transform analysis revealed deformation-induced Mg2Ni nanocrystals, together with the structural and morphological stability of the nanotubes. The electrochemical hydrogen discharge capacity of the severely deformed pure metallic glass was substantially lower than that of samples with the nanotube additive for several cycles. It was also established that the most deformed sample containing nanotubes exhibited a drastic breakdown in the electrochemical capacity after eight cycles.

With the continuous development and utilization of clean energy, the thermal utilization of solar energy is an important research direction. In view of the problems of the low utilization rate of solar heat in alpine regions of solar energy, an air-type vacuum-tube solar collector (AVSC) with air as the heat-exchange medium was designed. The vacuum tube of the solar heat collector adopted a double-pass spiral direct-current structure, and the vacuum tube had a built-in heat-storage rod. In order to test the heat collection performance of the designed air evacuated-tube solar collector, a heat collection performance test of the collector was conducted. The results showed that the average heat collection efficiency of the vacuum tube solar collector without phase-change heat-storage rods was 38%. The evacuated-tube solar collector using water as the heat transfer medium had an average heat collection efficiency of 58%. The average equivalent heat collection efficiency of the AVSC with a... [more]

Due to a high operating voltage and theoretical capacity, P2-type layered Mn-based metal oxides are considered to be promising cathodes in sodium-ion batteries, but their poor structural stability in the process of Na+ insertion/deinsertion severely hinders their practical application. Here, an interesting K+ pre-intercalation is used to expand the interlayer distance and enhance the electrochemical reversibility of KsFexAlyMnzO2. With a suitable K+ content, the optimized electrode shows a high specific capacity of 135 mAh g−1 at 0.1 C, a good rate capability of 80 mAh g−1 at 5 C and an excellent cycling performance of 76.4% capacity retention after 200 cycles at a high rate of 5 C. This work proves the feasibility of a K+ pre-intercalation strategy in a P2-type layered cathode.

Organosolv pre-treatments aiming to selectively remove and depolymerise lignin and hemicellulose and yield an easily digestible cellulose fraction are one of the potential options for industrial implementation within the biorefinery concept. However, the use of high temperatures and/or high catalyst concentrations is still hindering its wide adoption. In this work, mild temperature organosolv processes (140 °C) that were either non-catalysed or catalysed with sulphuric or acetic acid were compared to standard similar conditions using ethanol-based organosolv for both wheat straw (WS) and eucalyptus wood residues (ERs) as agricultural and forestry-derived model raw materials, respectively. The experimental results demonstrated that high cellulose purities could be obtained for the catalysed ethanol-based processing of the WS, which resulted in high saccharification yields (>80%), conversely to the non-catalysed process, which only reached values close to 70%. For eucalyptus residues (ER... [more]

The inherent low thermal conductivity of phase change materials (PCMs) serious limits the thermal performance of latent heat thermal energy storage (LHTES) systems. In this study, the author proposed two operating modes (inside heating/outside cooling and inside cooling/outside heating)and designed seven fin configurations to improve the thermal performance and flexibility of the triple-tube LHTES unit. A transient two-dimensional numerical model was established to study the energy storage, release and simultaneous storage and release processes, and local and global entropy generation was analyzed. A comprehensive evaluation was used to propose the optimal combination of operating mode and fin configuration. Considering various performances, the combination of the operation mode of inside cooling/outside heating and the staggered fin configuration shortened the total time by 66.6% and increased the heat transfer rate by 5.6%, providing the best performance in both the continuous and si... [more]

The importance of biogas in the energy mix in Poland and Latvia is very low. In Poland, 306 million m3 of biogas is produced annually, and in Latvia, 56 million m3. The share of energy from agricultural biogas in Latvia is 1.6%, and in Poland, only 0.12%. This study analyzed the impact of the structure on CO2 emissions from agricultural biogas production in Latvia and Poland. The emission was determined in accordance with the EU directive. The structure of substrates was dominated by those from the second generation, i.e., manure and food waste. In Latvia, it was 70%, and in Poland, 78%. The manure share was 45% and 24%, respectively. The anaerobic digestion of manure guarantees high GHG savings thanks to the avoided emissions from the traditional storage and management of raw manure as organic fertilizer. The level of emissions from the production of agricultural biogas was calculated for the variant with the use of closed digestate tanks, and it was about 10−11 g CO2/MJ, which is com... [more]

One of the unconventional, innovative ways of using biomass is using it as a component of high-energy material. According to conceptual assumptions, biomass can act as an energy carrier in modified high-energy materials-explosives (EX). Modification of the composition of the explosive requires the development of a method of introducing an additional component and changes its explosive and operational parameters (including safety). Thermodynamic calculation programs allow you to model the predicted energetic parameters of an explosive in order to select prospective compositions without the need to carry out a large number of costly and time-consuming field tests. This enables more effective design of new explosives compositions by narrowing down the scope of field tests using the “in situ” method. The use of renewable biomass as a corrector of EX properties may be a pro-environmental approach and reduces the production costs of the product. The thermodynamic simulations performed showed... [more]

In recent years, DC power supply and distribution technology plays an increasingly significant role in power supply and distribution systems with a low loss and large power supply radius. However, the corresponding DC distribution network protection electric devices cannot satisfy the needs of the existing DC power supply and distribution network. Based on this, in this article, an intelligent/energy-efficient DC leakage protection circuit breaker based on two-phase magnetic nanomaterials and detection and control technology is proposed. Firstly, the core of an intelligent/energy-efficient DCCB is composed of two-phase magnetic nanomaterials, and the mathematical modeling process, preparation and processing method of two-phase magnetic nanomaterials are given. Secondly, the DC leakage detection technology is studied by fluxgate technology, and the design process of magnetic rings, winding and detection circuit is given. Thirdly, the simulation and experiment results of the detection sy... [more]

Although they are of significant importance for environmental applications, the industrialization of photocatalytic techniques still faces many difficulties, and the most urgent concern is cost control. Natural minerals possess abundant chemical inertia and cost-efficiency, which is suitable for hybridizing with various effective photocatalysts. The use of natural minerals in photocatalytic systems can not only significantly decrease the pure photocatalyst dosage but can also produce a favorable synergistic effect between photocatalyst and mineral substrate. This review article discusses the current progress regarding the use of various mineral classes in photocatalytic applications. Owing to their unique structures, large surface area, and negatively charged surface, silicate minerals could enhance the adsorption capacity, reduce particle aggregation, and promote photogenerated electron-hole pair separation for hybrid photocatalysts. Moreover, controlling the morphology and structure... [more]

Proppant is an essential material in hydraulic fracturing, and it can support artificial fractures for a long time. However, few people have applied proppant and conductive materials in the in-situ modification of shale oil. Here, we developed a graphene and resin coated (GRC) proppant with electrically conductive properties. The electrical conductivity of the GRC proppant improved by four orders of magnitude. The GRC proppant has a 54.58% improvement in suspension and 22.75% increase in settlement time at 0.25 wt% concentration compared with uncoated proppant. The GRC proppant’s adhesion reached 68.34 nN under 1 μN load force, increasing by 63.13% compared to uncoated proppant. This new electrically conductive proppant can be used as a conductive carrier to improve the efficiency of electric heating in in-situ modification technology of shale oil.

This article presents rheological models of fluids used in the drilling practice. It discusses the principles of determining drilling fluid rheological parameters based on data acquired from measurements by means of viscometers used in the drilling practice. The authors propose the application of the three-parameter Vom Berg and Hahn−Eyring models not used in the drilling industry so far. Necessary relationships have been developed for these models, which enable the determination of rheological parameters. In order to account for the influence of different flow conditions on the value of drilling fluid rheological parameters, the approach proposing the determination of rheological parameters of a given three-parameter model separately for low shear rates and high shear rates has been suggested. A practical application of the methodology proposed in this paper for determining the rheological parameters of the three-parameter Vom Berg and Hahn−Eyring models is presented using real drilli... [more]

Enzyme-induced carbonate precipitation (EICP) is a new biogeotechnical ground improvement technique that uses calcium carbonate (CaCO3) formed by biochemical processes to increase soil strength and stiffness. In this paper, crude urease extracted from soybeans was employed to catalyze the precipitation of CaCO3 in sand. To optimize the urease extraction efficiency, factors affecting the soybean crude urease extraction, including the powdered soybean particle size, concentration, soaking time, and soaking temperature, were addressed. This paper also provided further insight regarding the impact of the urease activity of soybean crude extract on the chemical conversion efficiency and the biocementation performance in EICP. The findings revealed that the powdered soybean concentration and the particle size were the two most important factors affecting the urease activity of the soybean crude extract. The enzyme activity utilized in the EICP process might further lead to different reactant... [more]

In underground projects such as mining and tunneling, the presence of coal rock columns plays a certain supporting role, and the instability of coal rock columns is often related to their size and shape of presence. Therefore, in order to investigate the compressive damage characteristics and damage evolution law of rocks of different sizes, uniaxial compression tests were conducted on sandstones with different height−diameter ratios to explore the mechanical properties and damage characteristics of sandstones with different height−diameter ratios, analyze the connection between acoustic emission ringing count rate, accumulated energy, peak frequency, and b-value changes and height−diameter ratio, and analyze the evolution law of sandstones during damage based on damage variables, and draw the following conclusions. As the height-to-diameter ratio increases, the less affected by the end effect, the rock strength shows a nonlinear decreasing trend, and the decreasing trend becomes slow.... [more]

(1) Background: Gas hydrates are historically notable due to their prevalence and influence on operational difficulties in the oil and gas industry. Recently, new technologies involving the formation of gas hydrates to accomplish various applications have been proposed. This has created new motivation for the characterization of rheological and mechanical properties and the study of molecular phenomena in gas hydrates systems, particularly in the absence of oil and under pre-nucleation conditions. (2) Methodology: This work reviews advances in research on the promotion, inhibition, rheology, and mechanical properties of gas hydrates obtained through an integrated material synthesis-property characterization-multi-scale theoretical and computational platform at McGill University. (3) Discussion: This work highlights the findings from previous experimental work by our group and identifies some of their inherent physical limitations. The role of computational research methods in extending... [more]

Use of nanoparticles as a method for enhancing oil recoveries has become an attractive prospect. Experimental evidence has shown that this technique possesses the ability to improve recoveries via wettability alteration and interfacial tension reduction amongst other strategies. In this study, we analyze the potential of nanoparticles employed in coreflood experiments. Low concentration acid was added to aid in the dispersion of the nanoparticles in the brine by protecting them from being aggregated, while enhancing the stimulation of the tight porous media. Electrokinetics was also implemented following a sequential as well as a simultaneous approach to further stimulate the fluids injected, controlling their mobility, and therefore, increasing the depth of penetration within the porous media. Several coreflood experiments were carried out on highly heterogeneous carbonate samples of Middle Eastern origin with permeabilities of around 0.1 mD. Zeta potential measurements were conducted... [more]

Over the past decade, hydrothermal carbonization (HTC) has emerged as a promising thermochemical pathway for treating and converting wet wastes into fuel, materials, and chemicals [...]

The evolution of bio-based composites in the building industry is strongly linked with the growing demand for sustainable development, which is relevant nowadays. Hemp shives are a large group of organic residues that are obtained in the process of oil extraction as well as straw processing. These residues could be utilized along with a binder as constituents in the manufacture of bio-based building composites. This study is focused on the impact of density and relative humidity on the effective thermal conductivity of hemp shive-based bio-composites with a magnesium binder. For this reason, a series of samples with variable densities was manufactured and subjected to conditioning in a climatic chamber at a constant temperature and different relative humidity settings. As soon as samples were stabilized, the guarded hot plate method was applied to determine their thermal conductivities. Before each measurement, great care was taken during sample preparation to ensure minimum moisture l... [more]

Metal-Organic Frameworks have attracted profound attention the latest years for use in environmental applications. They can offer a broad variety of functions due to their tunable porosity, high surface area and metal activity centers. Not more than ten years ago, they have been applied experimentally for the first time in energy storage devices, such as batteries. Specifically, MOFs have been investigated thoroughly as potential materials hosting the oxidizing agent in the cathode electrode of several battery systems such as Lithium Batteries, Metal-Ion Batteries and Metal-Air Batteries. The aim of this review is to provide researchers with a summary of the electrochemical properties and performance of MOFs recently implemented in battery cathodes in order to provide fertile ground for further exploration of performance-oriented materials. In the following sections, the basic working principles of each battery system are briefly defined, and special emphasis is dedicated to MOF-based... [more]

As an innovative technology, the impedance-based technique has been extensively studied for the structural health monitoring (SHM) of various civil structures. The technique’s advantages include cost-effectiveness, ease of implementation on a complex structure, robustness to early-stage failures, and real-time damage assessment capabilities. Nonetheless, very few studies have taken those advantages for monitoring the health status and the structural condition of wind turbine structures. Thus, this paper is motivated to give the reader a general outlook of how the impedance-based SHM technology has been implemented to secure the safety and serviceability of the wind turbine structures. Firstly, possible structural failures in wind turbine systems are reviewed. Next, physical principles, hardware systems, damage quantification, and environmental compensation algorithms are outlined for the impedance-based technique. Afterwards, the current status of the application of this advanced techn... [more]

In recent decades, global electricity consumption has rapidly increased, and worldwide electricity demand is expected to follow the same trend [...]

Three vanadium-based catalysts were used to remove high concentrations of nitrogen oxides, and the catalysts’ performance of de-NOx and anti-H2O under the high concentrations of NOx were investigated. The V-Mo-W/TiO2 catalysts were tested under 1500 mL/min gas flow (GHSV = 500 h−1, 2.4% NO2, 4.78% NH3, 13% O2, 4% H2O, 5% CO2) and characterized by BET, SEM, EDS, XRD, XPS, H2-TPR, and NH3-TPD; then, their physical and chemical properties were analyzed. The results showed that under the influence of H2O, the NOx conversion of the V-Mo-W/TiO2 catalysts remained above 97% at 200−280 °C indicating that the catalysts had high catalytic activity and strong water resistance. The analysis of the characterization results showed that the larger specific surface area of the catalyst, the higher acid content, stronger redox ability, and higher V4+ and V3+ content were the reasons for the high NOx conversion. The surface area decreased and the microstructure become smoother after the reaction, which... [more]

Natural gas, biogas, and refinery gas all include H2S, which has adverse effects not only on the environment and human health but also on the equipment and catalysts that are employed in the relevant processes. H2S is removed from the aforementioned gases using a variety of techniques in order to fulfill the necessary sales criteria and for reasons of safety. The adsorption method stands out among various other approaches due to its straightforward operation, high level of efficiency, and low overall cost. This technique makes use of a variety of adsorbents, such as metal-organic frameworks (MOFs), activated carbon, and zeolites. The use of zeolite-based adsorbents is by far the most common of these various types. This is due to the specific properties of zeolite-based adsorbents, which include a high adsorption capacity, the ability to be regenerated, a high temperature stability, a diversity of types, the possibility of modification, high efficiency, and low cost. In addition, resear... [more]