The construction of nanostructured materials for their application in electrochemical processes, e.g., energy storage and conversion, or sensing, has undergone a spectacular development over the last decades as a consequence of their unique properties in comparison to those of their bulk counterparts, e.g., large surface area and facilitated charge/mass transport pathways. This has driven strong research on the optimization of nanostructured materials for the fabrication of electrochemical devices, which demands techniques allowing the assembly of hybrid materials with well-controlled structures and properties. The Layer-by-Layer (LbL) method is well suited for fulfilling the requirements associated with the fabrication of devices for electrochemical applications, enabling the fabrication of nanomaterials with tunable properties that can be exploited as candidates for their application in fuel cells, batteries, electrochromic devices, solar cells, and sensors. This review provides an u... [more]

The importance of developing efficient and environmentally friendly means of biomass conversion into bioenergy, biofuels, and valuable products is currently high in Poland. Accordingly, herein, two new energy and biofuel units are proposed, namely, POLpec and POLbp, which are used as reference sources for comparing energy consumption and biofuel production in other countries or regions in the world. One POLpec equals 4400 PJ (195.1 Mtoe), reflecting the annual primary energy consumption of Poland in 2020. Meanwhile, one POLbp equals 42 PJ (1.0 Mtoe), referring to the annual production of biofuels in Poland in 2020. Additionally, a new import−export coefficient β is proposed in the current study, which indicates the relationship between the import and export of an energy carrier. More specifically, the potential of biomass and organic waste to be converted into energy, biofuels, and valuable products has been analysed for the rural areas of Poland. Results show that the annual biomass a... [more]

Wearable thermoelectric generators (WTEGs) can incessantly convert body heat into electricity to power electronics. However, the low efficiency of thermoelectric materials, tiny terminal temperature difference, rigidity, and neglecting optimization of lateral heat transfer preclude WTEGs from broad utilization. In this review, we aim to comprehensively summarize the state-of-the-art strategies for the realization of flexibility and high normalized power density in thermoelectric generators by establishing the links among materials, TE performance, and advanced design of WTEGs (structure, heatsinks, thermal regulation, thermal analysis, etc.) based on inorganic bulk TE materials. Each section starts with a concise summary of its fundamentals and carefully selected examples. In the end, we point out the controversies, challenges, and outlooks toward the future development of wearable thermoelectric devices and potential applications. Overall, this review will serve to help materials scie... [more]

In order to make centrifugal blowers environmentally friendly, machines with a lighter weight and a more compact size are required. Thus, the axial length of the machine needs to be minimized within the diameter limit. However, in the design methodology, losses and thermal study become very significant; thus, losses increase significantly to achieve the desired output power when the volume is excessively reduced. Moreover, due to the machine’s compact size, heat is concentrated rapidly without adequate cooling. It might lead to a temperature rise of the critical part of the machine above the safe limit, such as winding, thereby affecting its lifespan. This study considers the 225 kW high-speed permanent magnet synchronous machine (HSPMSM) with the forced air cooling axial ventilation system (FACAVS) used in centrifugal blower applications. Firstly, four different analytical models (A2−A5) in the electromagnetic analysis are derived by minimizing the initial machine’s (A1) axial length... [more]

Two geopolymer foams were prepared from a thermally activated coal gangue containing kaolinite. As the foaming agent, aluminium powder and 36% hydrogen peroxide were used to obtain two levels of porosity. The materials’ high temperature performances were investigated: tensile and compressive strength evolution with temperature. This study shows that the mechanical performances of developed geopolymer foams are similar to foam concrete of the same apparent density. The geopolymer foams from coal gangue present stable mechanical performances up to 600 °C. When the glass transition temperature is achieved, sintering occurs and mechanical performance increases. SEM observations confirm the glass transition and densification of the matrix at temperatures above 800 °C. Moreover, the XRD measurements revealed a high amount of mullite that forms at 1000 °C that explained the observed strength increase. The synthesis of good-quality geopolymer foams from coal gangue and its application as a the... [more]

Transformer oil is conventionally used as an insulating liquid for the purpose of insulation and cooling in power transformers. The rise in the power demand has put stress on the existing insulation system used for power transmission. Nanotechnology provides an advanced approach to upgrade the conventional insulation system by producing nano-oil with enhanced dielectric characteristics. The aim of the study is to present the influence of area volume effect on the dielectric performance of mineral oil and its nanofluids. In this paper, nanofluids are prepared by dispersing two different concentrations of SiO2 nanoparticles in base transformer oil using a two-step method. The effect of area and volume is investigated on nanofluids in the laboratory using coaxial electrode configurations under different test conditions. The AC breakdown voltage and maximum electric stress is determined for the pure oil and nanofluids. The results show that the addition of SiO2 nanoparticles significantly... [more]

Solid Oxide Cells (SOCs) are under intensive development due to their great potential to meet the 2030 targets for decarbonization. One of their advantages is that they can work in reversible mode. However, in respect to durability, there are still some technical challenges. Although the quick development of experimental and modeling approaches gives insight into degradation mechanisms, an obligatory step that cannot be avoided is the performance of long-term tests. Taking into account the target for a commercial lifetime is 80,000 h, experiments lasting years are not acceptable for market needs. This work aims to develop accelerated stress tests (ASTs) for SOCs by the artificial aging of the fuel electrode via redox cycling, which follows the degradation processes of calendar aging (Ni coarsening and migration). However, it can cause irreversible damage by the formation of cracks at the interface anode/electrolyte. The advantages of the developed procedure are that it offers a mild le... [more]

For many applications, the possibility of controlling heat flow by “thermal switching” can be very beneficial. In previous work, we presented a novel approach for thermal switching using a water-loaded adsorbent as part of the evaporator of a heat pipe. The basic idea is that the adsorbent releases water upon exceeding a certain evaporator temperature and thus “activates” the heat pipe by providing the working fluid for thermal transport. In this work, we present an improved version of the heat switch. We found that an ordinary copper heat pipe (i.e., thermosyphon) with outer diameters common in heat pipe applications (10 mm) can be used as a base of the heat switch. The reversibility of the switching effect was proven. The location of heat input relative to the adsorbent position was optimized, leading to improved switching ratios of up to 36 as calculated from thermal resistance change between evaporator and condenser. Furthermore, the role of the insulation on thermal resistance and... [more]

The digital transformation of electrical substations relies on the communication protocols introduced in the IEC Std 61850. In particular, the Sampled Value data format is expected to be employed in an ever-increasing number of measurement applications and devices. In this context, National Metrological Institutes are required to develop calibration infrastructures capable of dealing with synchronous analog and digital input and output channels. In this paper, we characterize the performance of the METAS calibrator in terms of transmission latency and publishing rate stability. In particular, we discuss the feasibility of meeting the stringent requirements of meterological applications even in a non real-time operating system. To this end, an enhanced software library and measurement procedure are introduced. The proposed results confirm the quasi-deterministic behavior of the calibrator and proves its refined precision and stability with respect to commercial devices.

Energy performances of an innovative Temporary Housing Unit (THU), made of natural materials and developed for the Mediterranean area, were determined. Cork panels limit winter transmission losses, whereas bio-PCMs were applied to reduce cooling needs properly. Assuming a split system for air-conditioning purposes, simulations in EnergyPlus allowed for identifying the optimal configuration that minimizes the annual electric demand. Bio-PCM melting temperatures, locations inside the external walls and the PCM quantities were varied. An ideal melting temperature of 23 °C was identified, whereas a double PCM layer uniformly distributed in the external walls is recommended, mainly for the limitation of the cooling demands. Negligible differences in electric requirements have been observed between the continuous and the scheduled functioning of the split system. A PV generator installed on the available roof surface allows for covering the electric demands satisfactorily. Experimental tests... [more]

Determining the aging state of low-voltage nuclear power plant cables using a nondestructive and reliable condition monitoring technique is highly desirable as the cables experience multiple aging stresses during the service period. This paper deals with the implementation and investigation of such nondestructive techniques, which can detect the overall aging state of low-voltage instrumentation and control (I&C) cables, which are subjected to accelerated thermal aging. The dielectric spectroscopy, extended voltage response, and polarization−depolarization current as nondestructive electrical aging techniques were used for the investigation purpose, while the elongation at break was also adopted as a mechanical measurement and for comparison. Prominent variations in the electrical parameters for the insulation and jacket were observed, whereas the elongation at break for both materials also decreased under thermal aging. Based on the electrical techniques, aging markers were selected t... [more]

Today, as a result of the advancement of technology and increasing environmental problems, the need for clean energy has considerably increased. In this regard, hydrogen, which is a clean and sustainable energy carrier with high energy density, is among the well-regarded and effective means to deliver and store energy, and can also be used for environmental remediation purposes. Renewable hydrogen energy carriers can successfully substitute fossil fuels and decrease carbon dioxide (CO2) emissions and reduce the rate of global warming. Hydrogen generation from sustainable solar energy and water sources is an environmentally friendly resolution for growing global energy demands. Among various solar hydrogen production routes, semiconductor-based photocatalysis seems a promising scheme that is mainly performed using two kinds of homogeneous and heterogeneous methods, of which the latter is more advantageous. During semiconductor-based heterogeneous photocatalysis, a solid material is stim... [more]

Technological advancement is accompanied by excessive consumption of fossil fuels and affluent uses of chemical substances in many sectors, including transportation and manufacturing companies, and so on. Being an exhaustible resource, the excessive use of fossil fuels and of chemical substances may lead to a serious energy crisis in the long run, and it may additionally impose environmental pollution. Attempts have been made in the solution of such serious issues from every nook and corner. Nonetheless, no method has been found to be a panacea in waste water treatment and subsequent beneficiaries. One of the attempts in the solution to such issues is the application of photocatalytic technology, which could serve as a dual function in environmental remediation and clean energy production. A photocatalytic fuel cell is a tool developed for the recovery of energy from organic wastes. A rational cell construction needs the fabrication of photoelectrodes, the design of a photoanode and a... [more]

Adsorption equations are important to analyze the pore size distribution (PSD) of shale and the adsorption behavior on it. However, the accurate description of nitrogen adsorption on shale by current adsorption equations is difficult to achieve due to the heterogeneous pore structure of shale. In our study, new adsorption isotherms that can properly depict the adsorbed amount of nitrogen were built for shale rocks considering both the processes of nitrogen adsorption and the cylindrical pore shape property of shale. When performing a regression analysis on five sets of experimental adsorption data using the developed adsorption equations, the R-square ranged from 0.739 to 0.987. Based on the pore shape determined by adsorption−desorption curves, the distinct R-square indicated that our equation is not valid for shale samples with ink-bottle pores and pores formed by schistose materials, but that it is suitable for shale samples with cylindrical pores and slit pores. Meanwhile, we preci... [more]

High-temperature superconductor (HTS) bulks have shown very promising potential for industrial applications due to the ability to trap much higher magnetic fields compared to traditional permanent magnets. In rotating electrical machines, the magnetic field is a combination of alternating and rotating fields. On the contrary, all studies on electromagnetic characterization of HTS presented in the literature so far have only focused on alternating AC magnetic fields and alternating AC loss due to the unavailability of robust experimental techniques and analytical models. This paper presents a numerical investigation on the characterization of HTS bulks subjected to rotating magnetic fields showing AC loss, current density distribution in three-dimensional axes, and trapped field analysis. A three-dimensional numerical model has been developed using H-formulation based on finite element analysis. An HTS cubic sample is magnetized and demagnetized with two-dimensional magnetic flux densit... [more]

Nowadays, the ever-growing energy demands, the associated greenhouse gas emissions, and the exhaustible nature of fossil fuels are the biggest challenges of our industrial world [...]

Additive manufacturing offers several opportunities for thermoelectric energy harvesting systems. This new manufacturing approach enables customized leg geometries, minimized thermal boundary resistances, less retooling, reduced thermoelectric material waste, and strong potential to manipulate microstructure for higher values of figure of merit. Although additive manufacturing has been used to fabricate thin thermoelectric films, there has been comparatively limited demonstrations of additive manufacturing for bulk thermoelectric structures. This review provides insights about the current progress of bulk thermoelectric material and device additive manufacturing. Each additive manufacturing technique used to produce bulk thermoelectric structures is discussed in detail along with future directions and challenges.

The paper presents the results of laboratory tests regarding the impact of accelerated thermal ageing of cellulose−aramid insulation samples saturated with electrical-insulating synthetic ester on the polarization and depolarization current characteristics being analyzed in the time domain. In the tests, electro-technical paper from DuPontTM was used, commercially designated as NOMEX®910. Laboratory-accelerated ageing consisted of heating with air a supply of samples of not-impregnated cellulose−aramid insulation for a specified time at specified temperatures. The temperatures and the warming time were selected so as to faithfully represent the degree of the thermal degradation of the cellulose fibers that takes place during normal operation of the material in power transformers. To determine the described impact of the ageing process in the insulation samples on the dielectric properties, the Polarization and Depolarization Method was applied. In the measurements, the MIC-15k1 high re... [more]

Belt conveyors are presently the most common transportation machines used in surface and underground mining [...]

There is growing recognition that the degradation of plastics in the environment is a serious problem. This study investigated and reported on the feasibility of removing end-of-life plastics from circulating in the environment. The specific example focuses on non-recyclable plastics found in a waste diversion program for compostable materials, known as the Green Bin Program. The purpose of this study was to identify and quantify the types of polymers in this stream, as well as to determine if it could be successfully turned into char without separation of its components. The measurements show that polyethylene (72 wt.%), polypropylene (14 wt.%) and polyethylene terephthalate (12 wt.%) are the main constituents of this stream, with minor contributions from polybutylene adipate terephthalate (PBAT), polyvinyl alcohol (PVA), poly methyl methacrylate (PMMA), polystyrene (PS), Nitrile rubber and Nylon. Samples of the as-received waste containing plastics and fibrous material were subjected... [more]

Nanofluids as heat transfer fluids have been acquiring popularity ever since their beginning. Therefore, the refrigeration research could not keep itself away from the ever-rising horizon of nanofluid applications. On the other hand, nanofluid stability remains the critical bottleneck for use. A significant reduction in nanofluids’ performance can derivate from instability phenomena. Looking to industrial applications, nanofluid long-term stability and reusability are crucial requisites. Nanoparticles’ deposits induce microchannel circuit obstruction, limiting the proper functioning of the device and negating the beneficial characteristics of the nanofluid. The aggregation and sedimentation of the particles may also determine the increased viscosity and pumping cost, and reduced thermal properties. So, there is a need to address the features of nanofluid starting from realization, evaluation, stabilization methods, and operational aspects. In this review, investigations of nanorefriger... [more]

Although the conversion of lignocellulosic biomass into bio-oil with high yield/quality through hydrothermal liquefaction (HTL) is promising, it still faces many challenges. In this study, a Fex-Co(1-x)/Al2O3 catalyst was prepared with the coprecipitation method and low-content ethanol was used as the cosolvent for the HTL of poplar. The results showed that the Fex-Co(1-x)/Al2O3 catalyst significantly promoted the yield and energy recovery rate (ERR) of bio-oil compared with the control (10% ethanol content). At 260 °C for 30 min, 60Fe-40Co/Al2O3 had the best catalytic effect, achieving the highest bio-oil yield (67.35%) and ERR (93.07%). As a multifunctional bimetallic catalyst, Fex-Co(1-x)/Al2O3 could not only increase the degree of hydrogenation deoxidization of the product but also promote the diversity of phenolic compounds gained from lignin. The bio-oil obtained from HTL with Fex-Co(1-x)/Al2O3 as catalyst contained lower heterocyclic nitrogen, promoting the transfer of more bio-... [more]

The interpretation of subsurface fluid flow features in seismic reflection data is a key part of identifying the presence of hydrocarbon and active petroleum systems. Currently, this kind of study is mainly conducted utilizing offshore seismic reflection data with very limited cases utilizing onshore seismic reflection data. In addition, the Alamein basin is an area of prolific study in onshore Egypt, with most related studies concentrating on basin analysis and reservoir characterization. Therefore, in our study we aimed to make practical and effective use of onshore seismic reflection data with seismic attribute analysis to describe seismic facies, delineating and interpreting subsurface fluid flow features. The relatively vertical V-shaped and pipe or concave-up-shaped features with distorted reflections inside them are revealed through the analysis of variance, sweetness, chaos, instantaneous frequency and the RMS amplitude of seismic attributes. These subsurface fluid flow feature... [more]

The economic activity of businesses and the living standards of the population are largely dependent on inflation. Here, energy prices are of particular importance. Energy is what offers a competitive edge to economies. Therefore, many energy sectors still remain under state control. However, the fuel market is free although highly concentrated. The primary objective of this study was to determine the impact of fuel price changes on inflation in Poland. The research was based on causality models and regression models including asymmetry correction. The flow path was analyzed of price impulses from the basic raw material (i.e., crude oil) through wholesale diesel prices to inflation. The study demonstrates that with each successive stage of raw material processing, price volatility proves to be weaker. However, the final effect is still significant: inflation is largely shaped by energy carriers and, here, specifically by fuel prices. Such results have serious implications for the state... [more]

The high frequency PWM voltage pulses from a two-level six-switch inverter produce a common-mode voltage in an electric machine’s windings, a fraction of which appears on the machine shaft due to electrostatic (capacitive) coupling. When the shaft voltage exceeds the dielectric strength of the bearing lubricating grease, electric discharge machining (EDM) electrostatic discharges occur within the bearing, which can lead to premature failure. According to pulsed dielectric theory, the breakdown voltage across a dielectric increases with an increase in voltage slew rate (dv/dt). Therefore, the faster voltage rise times of wide bandgap devices are expected to produce higher magnitude shaft voltages and EDM bearing currents. This paper presents circuit modeling of EDM currents and compares the shaft voltage and bearing current amplitudes of silicon- and silicon carbide-based PWM inverters through experimental measurements and a statistical analysis using probability density functions. The... [more]