Water vapor sorption in salt hydrates is a promising method to realize seasonal solar heat storage. Several of these materials have already shown promising performance for this application. However, a significant bottle neck for applications is the low thermal conductivity. In this study, several fabrication methods of the fixation of salts and their hydrates on metals to overcome the problem are presented. The products are analyzed concerning the hydration states, the corrosion behavior, the chemical compatibility, and the mechanical stability.

The solar absorption efficiency of water as a base-fluid can be significantly improved by suspending nanoparticles of various materials in it. This experimental work presents the photo thermal performance of water-based nano-fluids of graphene oxide (GO), zinc oxide (ZnO), copper oxide (CuO), and their hybrids under natural solar flux for the first time. Nanofluid samples were prepared by the two-step method and the photothermal performance of these nanofluid samples was conducted under natural solar flux in a particle concentration range from 0.0004 wt % to 0.0012 wt %. The photothermal efficiency of water-based 0.0012 wt % GO nanofluid was 46.6% greater than that of the other nanofluids used. This increased photothermal performance of GO nanofluid was associated with its good stability, high absorptivity, and high thermal conductivity. Thus, pure graphene oxide (GO) based nanofluid is a potential candidate for direct absorption solar collection to be used in different solar thermal e... [more]

One of the most interesting perspectives for the development of concentrated solar power (CSP) is the storage of solar energy on a seasonal basis, intending to exploit the summer solar radiation in excess and use it in the winter months, thus stabilizing the yearly production and increasing the capacity factor of the plant. By using materials subject to reversible chemical reactions, and thus storing the thermal energy in the form of chemical energy, thermochemical storage systems can potentially serve to this purpose. The present work focuses on the identification of possible integration solutions between CSP plants and thermochemical systems for long-term energy storage, particularly for high-temperature systems such as central receiver plants. The analysis is restricted to storage systems potentially compatible with temperatures ranging from 700 to 1000 °C and using gases as heat transfer fluids. On the basis of the solar plant specifications, suitable reactive systems are identifie... [more]

The South African coalmining industry has a rich and long history and contributes significantly to the economic wellbeing of the country. Despite its importance in developing the economy, the industry is causing severe environmental challenges. For example, Emalahleni, a city situated in the Mpumalanga Province in South Africa, has been exposed for over a century to the continuous mining of coal. Challenges experienced include the sterilisation of land due to underground fires, water pollution, surface collapse, and acidification of topsoil. Previous work by the researchers formulated a conceptual framework aimed at addressing some of these challenges. In an extension of this work, the authors comprehensively enhance the preliminary framework on the strength of a set of qualitative propositions coupled with a parallel, exploratory survey. Interviews among various stakeholders were conducted, aimed at enhancing the components of the framework, followed by a focus group to validate the a... [more]

As the heating demands of buildings drop considerably, the use of solar walls makes increasing sense. One of the obstacles to the development of such walls is their need for on-site implementation by specialized companies. On the other hand, a storage wall is generally composed of heavy materials with high inertia, which prevents prefabrication of the solar component. To avoid this problem and allow for solar walls to be prefabricated in the factory, a novel approach to replacing this heavy wall with a lighter storage wall incorporating phase change materials (PCM) has been proposed. This paper aims to demonstrate the impact of PCM on the thermal energy performance once they have been integrated into the storage wall of the composite Trombe wall. Addressed herein will be the heat transfer exchange inside a house located in the northern part of France, where a composite Trombe wall has been fitted without PCM. Three configurations will be investigated—(1) the model house without the sol... [more]

Graphene is a new generation material, which finds potential and practical applications in a vast range of research areas. It has unrivalled characteristics, chiefly in terms of electronic conductivity, mechanical robustness and large surface area, which allow the attainment of outstanding performances in the material science field. Some unneglectable issues, such as the high cost of production at high quality and corresponding scarce availability in large amounts necessary for mass scale distribution, slow down graphene widespread utilization; however, in the last decade both basic academic and applied industrial materials research have achieved remarkable breakthroughs thanks to the implementation of graphene and related 1D derivatives. In this work, after briefly recalling the main characteristics of graphene, we present an extensive overview of the most recent advances in the development of the Li-ion battery anodes granted by the use of neat and engineered graphene and related 1D... [more]

Lignin is a natural polymer, one that has an abundant and renewable resource in biomass. Due to a tendency towards the use of biochemicals, the efficient utilization of lignin has gained wide attention. The delignification of lignocellulosic biomass makes its fractions (cellulose, hemicellulose, and lignin) susceptible to easier transformation to many different commodities like energy, chemicals, and materials that could be produced using the biorefinery concept. This review gives an overview of the field of lignin separation from lignocellulosic biomass and changes that occur in the biomass during this process, as well as taking a detailed look at the influence of parameters that lead the process of dissolution. According to recent studies, a number of ionic liquids (ILs) have shown a level of potential for industrial scale production in terms of the pretreatment of biomass. ILs are perspective green solvents for pretreatment of lignocellulosic biomass. These properties in ILs enable... [more]

This research involved studying the physico-chemical parameters of fly ash derived from the combustion of 100% biomass in bubbling and circulating fluidized bed boilers of two large energy plants in Poland. Chemical composition revealed that ash contains substantial amounts of CaO (12.86−26.5%); K2O (6.2−8.25%); MgO (2.97−4.06%); P2O5 (2−4.63%); S (1.6−1.83%); and micronutrients such as Mn, Zn, Cu, and Co. The ash from the bubbling fluidized bed (BFB) was richer in potassium, phosphorus, CaO, and micronutrients than the ash from the circulating fluidized bed (CFB) and contained cumulatively less contaminants. However, the BFB ash exceeded the threshold values of Cd to be considered as a liming amendment. Additionally, according to our European Community Bureau of Reference (BCR) study Pb and Cd were more mobile in the BFB than in the CFB ash. Except for a low nitrogen content, the ash met the minimum requirements for mineral fertilizers. Acute phytotoxicity revealed no inhibition of th... [more]

Microwave heating offers a lot of advantages compared to conventional heating methods in the chemical reactions field due to its positive effects on reaction time and selectivity. Dielectric properties, and in particular permittivity, of substances and mixtures, are important for the optimization of microwave heating processes; notwithstanding this, specific databases are poor and far from being complete, and in the scientific literature very little data regarding these properties can be found. In this work, impedance measurements were carried out using a specially designed system to get the real and imaginary parts of the dielectric constant. The apparatus was tested in the estimation of permittivity of water−ethanol and water−NaCl mixtures, varying their composition to obtain a wide range of permittivity values. The results were compared to literature data and fitted with available literature models to verify the correspondence between them, finding that permittivity dependence on mi... [more]

Solid-free drilling fluid is a matter of cardinal significance in the course of Coal bed Methane (CBM) reservoir drilling. This study evaluated the performance of solid-free CBM drilling fluid in central Hunan. Three types of surfactants, namely TX-10 (nonionic), HSB1618 (zwitterionic) and penetrant T (anionic), were added in basic fluid at various concentrations of 0.05, 0.10 and 0.15% (m/m). This study comprised of drilling fluid rheology, sample mineral analysis, sample nuclear magnetic resonance (NMR) scanning, sample wettability, and sample surface micro characteristics tests. The results show that TX-10 and HSB1618 enhance the rheological properties of drilling fluid, such as yield point and gel strength. Penetrant T has opposite effect on it. It was found that the minimum American Petroleum Institute (API) filtration is only 0.3 mL. This study adopted a new method using laser particle size analyzer to evaluate suspension performance. Based on the surface micro characteristics of... [more]

This paper deals with the pyrolysis conversion of synthetic waste materials into noble fuels, i.e., heating oils, gasoline, diesel, and carbon. The following article presents the principle and use of pyrolysis conversion of waste tires and plastics. The core of the paper is the determination of energy properties of noble fuels obtained from pyrolysis conversion and the possibility of their real use in industry. The aim of this paper is a technical-economic evaluation of the use of waste pyrolysis in practice in the Slovak Republic. Unlike various methods of waste management, there are also more efficient methods, which primarily have a positive effect on the ecology of our Earth and at the same time can be effectively used for the production of alternative fuels. One of these methods is the pyrolysis conversion of synthetic waste materials into noble fuels. It is an ecological, waste-free, economical, and economical disposal of waste with a full recovery of its energy and material comp... [more]

An application of latent heat thermal energy storage systems with phase change materials seems to be unavoidable in the present world. The latent heat thermal energy storage systems allow for storing excessive heat during low demand and then releasing it during peak demand. However, a phase change material is only one of the components of a latent heat thermal energy storage system. The second part of the latent heat thermal energy storage is a heat exchanger that allows heat transfer between a heat transfer fluid and a phase change material. Thus, the main aim of this review paper is to present and systematize knowledge about the heat exchangers used in the latent heat thermal energy storage systems. Furthermore, the operating parameters influencing the phase change time of phase change materials in the heat exchangers, and the possibilities of accelerating the phase change are discussed. Based on the literature reviewed, it is found that the phase change time of phase change material... [more]

In order to study the axial compression performance of the T-shaped multi-cavity concrete-filled steel tube shear wall, first, three specimens were designed to perform the axial compression test. Then three-dimensional finite element analysis by the ABAQUS software was used to obtain the axial bearing capacity of the shear wall with different parameters. According to the results of the finite element model, the computational diagram in the limit state was obtained. The diagram was simplified into the core concrete in the non-enhanced area that was not constrained by the steel tube and the core concrete in the enhanced area that was uniformly constrained by the steel tube. Finally, a new practical equation for calculating the axial bearing capacity of a multi-cavity concrete-filled steel tubular shear wall was deduced and proposed based on the theory of ultimate equilibrium. The calculation results of the proposed equation were in good agreement with the finite element results, and the... [more]

Grouting reinforcement plays an important role in repairing fractures and improving the strength of the surrounding rock. To address practical engineering challenges such as caving and chip off-falling of surrounding rock in deep roadways, normal splitting was adopted to prefabricate fractures on rock samples gathered from underground coal mines. This was done to better match the rock fracture specimen with actual conditions. Based on the elementary unit of a fracture surface, systematic experiments were conducted on the tensile properties of rock fractures after grouting reinforcement, and the shear properties were studied after considering the presence of gas. As per the results, the tensile strength of rock fractures increased with the increase in viscosity of grout, but the overall tensile strength was relatively low. The overall tensile effect of surrounding rock was improved less by grouting approach. When the presence of fracture gas in grouting was considered, the peak shear st... [more]

Biomass remains one of the most important materials for the production of renewable energy in the European Union. Willow can be one of the sources of biomass, and its production can also be profitable on soils with low quality. A proper selection of raw material for energy production should be based not only on the cost effectiveness or crop yield, but also on the environmental impact and the cost it incurs. The aim of this work was to evaluate the external environmental costs of the production of willow chips of seven willow genotypes, produced for energy generation on marginal cropping lands. The environmental external costs of chips production were estimated against the amount of emissions calculated according to the LCA method (ReCiPe Midpoint) and its monetary value. The external environmental cost of willow chips production amounted to €212 ha−1 year−1, which constituted 23% of the total production cost of willow chips. The external cost of production of 1 Mg d.m. of willow chips... [more]

Polymeric surfactant flooding is an effective method to improve oil recovery, and the stability of the emulsion is closely related to the effect of surfactant flooding. The preparation method for a surfactant-stabilized emulsion is relatively simple, and the emulsion produced by the existing device cannot simulate the real formation conditions. To better simulate the emulsification of polymeric surfactant during formation and to study the influencing factors of emulsion stability, a new sieve plate rotary emulsification device was used to prepare emulsions instead of the traditional high-speed shear emulsifier, and the stability of emulsions prepared by different methods was compared. The parameters of the device were optimized by determining the water content, particle size, and Turbiscan Stability Index TSI (stability parameter) of the emulsion. The factors affecting the stability of the emulsion were studied by using the optimized experimental device. The results showed that the opt... [more]

In this paper, the impact of the back contact barrier on the performance of Cu (In, Ga) Se2 solar cells is addressed. This effect is clearly visible at lower temperatures, but it also influences the fundamental parameters of a solar cell, such as open-circuit voltage, fill factor and the efficiency at normal operation conditions. A phototransistor model was proposed in previous works and could satisfactorily explain specific effects associated with the back contact barrier, such as the dependence of the saturated current in the forward bias on the illumination level. The effect of this contribution is also studied in this research in the context of metastable parameter drift, typical for Cu (In, Ga) Se2 thin-film solar cells, as a consequence of different bias or light soaking treatments under high-temperature conditions. The impact of the back contact barrier on Cu (In, Ga) Se2 thin-film solar cells is analyzed based on experimental measurements as well as numerical simulations with T... [more]

Molecule radiation can be used as a tool to study colder regions in switching arc plasmas like arc fringes in contact to walls and ranges around current zero (CZ). This is demonstrated in the present study for the first time for the case of ablation-dominated high-current arcs as key elements of self-blast circuit breakers. The arc in a model circuit breaker (MCB) in CO2 with and an arc in a long nozzle under ambient conditions with peak currents between 5 and 10 kA were studied by emission and absorption spectroscopy in the visible spectral range. The nozzle material was polytetrafluoroethylene (PTFE) in both cases. Imaging spectroscopy was carried out either with high-speed cameras or with intensified CCD cameras. A pulsed high-intensity Xe lamp was applied as a background radiator for the broad-band absorption spectroscopy. Emission of Swan bands from carbon dimers was observed at the edge of nozzles only or across the whole nozzle radius with highest intensity in the arc center, de... [more]

Wall-stabilized arcs dominated by nozzle−ablation are key elements of self-blast circuit breakers. In the present study, high-current arcs were investigated using a model circuit breaker (MCB) in CO2 as a gas alternative to SF6 (gas sulfur hexafluoride) and in addition a long polytetrafluoroethylene nozzle under ambient conditions for stronger ablation. The assets of different methods for optical investigation were demonstrated, e.g., high-speed imaging with channel filters and optical emission spectroscopy. Particularly the phase near current zero (CZ) crossing was studied in two steps. In the first step using high-speed cameras, radial temperature profiles have been determined until 0.4 ms before CZ in the nozzle. Broad temperature profiles with a maximum of 9400 K have been obtained from analysis of fluorine lines. In the second step, the spectroscopic sensitivity was increased using an intensified CCD camera, allowing single-shot measurements until few microseconds before CZ in the... [more]

Improving the efficiency of well drilling process in a reservoir is directly related to subsequent well flow rates. Drilling of deviated and horizontal wells is often accompanied by an increase in pressure losses due to flow resistance caused by small size of the annular space. An important role in such conditions is played by the quality of borehole cleaning and transport capacity of drilling fluid, which is directly related to the rheological parameters of the drilling fluid. The main viscosifiers in modern drilling fluids are polymer reagents. They can be of various origin and structure, which determines their features. This work presents investigations that assess the effect of various polymers on the rheological parameters of drilling fluids. Obtained data are evaluated taking into account the main rheological models of fluid flow. However, process of fluid motion during drilling cannot be described by only one flow model. Paper shows experimentally obtained data of such indicator... [more]

Phase change materials (PCM) utilization in energy storage systems represents a point of interest and attraction for the researchers to reduce greenhouse gas emissions. PCM have been used widely on the interior or exterior walls of the building application to optimize the energy consumption during heating and cooling periods. Meanwhile, ground source heat pump (GSHP) gained its popularity because of the high coefficient of performance (COP) and low running cost of the system. However, GSHP system requires a stand-by heat pump during peak loads. This study will present a new concept of energy piles that used PCM in the form of enclosed tube containers. A lab-scaled foundation pile was developed to examine the performance of the present energy pile, where three layers of insulation replaced the underground soil to focus on the effect of PCM. The investigation was conducted experimentally and numerically on two identical piles with and without PCM. Moreover, a flow rate parametric study w... [more]

The growing interest in developing applications for the storage of thermal energy (TES) is highly linked to the knowledge of the properties of the materials that will be used for that purpose. Likewise, the validity of representing processes through numerical simulations will depend on the accuracy of the thermal properties of the materials. The most relevant properties in the characterization of phase change materials (PCM) are the phase change enthalpy, thermal conductivity, heat capacity and density. Differential scanning calorimetry (DSC) is the most widely used technique for determining thermophysical properties. However, several unconventional methods have been proposed in the literature, mainly due to overcome the limitations of DSC, namely, the small sample required which is unsuitable for studying inhomogeneous materials. This paper presents the characterization of two commercial paraffins commonly used in TES applications, using methods such as T-history and T-melting, which... [more]

With the increasing needs of clean water supplies, the use of biomass wastes and residues for environmental remediation is essential for environmental sustainability. In this study, the residues from winery and citrus juice industries, namely grape skin and orange peel, respectively, were first converted to hydrochars by hydrothermal carbonization (HTC) and then a cationic dye (methylene blue) adsorption was studied on hydrochars. Hydrochars from both feedstocks were produced at three different temperatures (180, 220, and 250 °C) and a fixed residence time (1 h) to evaluate the hydrochar’s performance on the dye adsorption. The hydrochars were characterized in terms of their pH, pH at point of zero charge (pHPZC), surface functionalities, and surface area. A batch adsorption study of the dye was carried out with variable adsorbate concentration, pH, and temperature. Two adsorption isotherms namely Langmuir and Freundlich models were fitted at 4, 20, and 36 °C. The thermodynamic propert... [more]

Oil well cleanup fluids (pre-flushes) are intermediate fluids pumped ahead of the cement slurry; they are able to clean the well walls by removing the filter cake formed by the drilling fluid, and leave the surface water-wet. This work’s main objective was to use biodegradable microemulsion systems as cleanup fluids in order to reduce the environmental impact. Three microemulsion systems were formulated, each composed of an oil phase, a surfactant and three different aqueous phases: glycerol, glycerol:water (mass ratio 1:1), and fresh water. The results show that all microemulsion systems were effective with 100% filter cake removal, with a removal time of less than 60 s. The wettability test and fluid compatibility analyses exhibited advantageous performances, without phase separation, variations in viscosity, gelation, or flocculation. The compressive strength and X-ray diffractometry (XRD) analysis showed the influence of the glycerol on the cement slurry properties, with the compre... [more]

In this study, we examined the influence of microstructured charcoal (MC) when added to ammonium nitrate fuel oil (ANFO) samples. We performed a study that investigated ANFOs structure, crystallinity, and morphology by utilizing infrared spectroscopy (IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM), respectively. MC characteristics were probed by Raman spectroscopy and SEM analysis. SEM analysis indicated how fuel oil (FO) covered ammonium nitrate prill. Moreover, the surface of the MC was covered by specific microfibers and microtubes. The disordered graphitic structure of the MC was also confirmed by Raman spectroscopy. Simulation of blasting properties revealed that the addition of MC should decrease blasting parameters like heat explosion, detonation pressure, and detonation temperature. However, the obtained differences are negligible in comparison with the regular ANFO. All analyses indicated that MC was a good candidate as an additive to ANFO.