Solar energy is a potential source for a thermal power generation system. A direct vapor generation solar organic Rankine cycle system using phase change material storage was analyzed in the present study. The overall system consisted of an arrangement of evacuated flat plate collectors, a phase-change-material-based thermal storage tank, a turbine, a water-cooled condenser, and an organic fluid pump. The MATLAB programming environment was used to develop the thermodynamic model of the whole system. The thermal storage tank was modeled using the finite difference method and the results were validated against experimental work carried out in the past. The hourly weather data of Karachi, Pakistan, was used to carry out the dynamic simulation of the system on a weekly, monthly, and annual basis. The impact of phase change material storage on the enhancement of the overall system performance during the charging and discharging modes was also evaluated. The annual organic Rankine cycle effi... [more]

When the load of Circulating Fluidized Bed (CFB) boiler changes dynamically, the accumulation and consumption of residual char causes a large inertia and hysteresis in the boiler combustion system. Therefore, accurate estimation of the residual char in the boiler is of great significance to the control system and improve the combustion efficiency. Based on the Computational Particles Fluid Dynamics (CPFD) method, a numerical simulation of the variable load process of CFB boiler was carried out, and the dynamic changes of the residual char inventory were analyzed by combining the coal feed, ash discharge, and furnace calorific value. The results showed that after CFB boiler reached stable operation, the residual char fluctuated from 11,000 kg to 16,000 kg, accounting for about 3.7% of the total bed material, and the residual char was in a dynamic balance. During the load-up phase, the average residual char was 17,500 kg, and during the load-down phase, the average residual char was 15,0... [more]

Spray impingement on smooth and heated surfaces is a highly complex thermofluid phenomenon present in several engineering applications. The combination of phase Doppler interferometry, high-speed visualization, and time-resolved infrared thermography allows characterizing the heat transfer and fluid dynamics involved. Particular emphasis is given to the use of nanofluids in sprays due to their potential to enhance the heat transfer mechanisms. The results for low nanoparticle concentrations (up to 1 wt.%) show that the surfactant added to water, required to stabilize the nanofluids and minimize particle clustering, affects the spray’s main characteristics. Namely, the surfactant decreases the liquid surface tension leading to a larger wetted area and wettability, promoting heat transfer between the surface and the liquid film. However, since lower surface tension also tends to enhance splash near the edges of the wetted area, the gold nanospheres act to lessen such disturbances due to... [more]

The organic fraction of waste is increasingly used for biogas production. However, the fermentation process used for this purpose also produces waste in the form of digestate in addition to biogas. Its liquid fraction can, among other things, be a source of water, but its recovery requires many advanced technological processes. Among the first in the treatment train is usually coagulation/chemical precipitation. Its application changes properties, including the size and zeta potential (ζ) of the fractions that have to be removed in subsequent processes. Changes in particle size distribution and ζ potential occurring in the liquid fraction of municipal waste biogas plant digestate and solutions after coagulation/chemical precipitation with FeCl₃·6H₂O, PIX 112 and CaO were analyzed. The particle size distribution of the raw digestate was wide (0.4−300 µm; up to 900 µm without ultrasound). The median particle diameter was about 12 µm. The ζ potential ranged from −25 to −35 mV in the pH ra... [more]

Electrochemical energy storage and conversion systems such as electrochemical capacitors, batteries and fuel cells are considered as the most important technologies proposing environmentally friendly and sustainable solutions to address rapidly growing global energy demands and environmental concerns. Their commercial applications individually or in combination of two or more devices are based on their distinguishing properties e.g., energy/power densities, cyclability and efficiencies. In this review article, we have discussed some of the major electrochemical energy storage and conversion systems and encapsulated their technological advancement in recent years. Fundamental working principles and material compositions of various components such as electrodes and electrolytes have also been discussed. Furthermore, future challenges and perspectives for the applications of these technologies are discussed.

Currently, scientists are still looking for new polymeric materials characterized by improved mechanical, thermal as well as dielectric properties. Moreover, it should be stressed that new composites should be environmentally friendly. For this reason, the aim of this work is to establish the influence of natural fillers in the form of diatomaceous biosilica (B) and talc (T) on the properties of dielectric elastomer (DE)-based composites. The dielectric elastomer-based materials have been tested taking into account their morphology, thermal and mechanical properties. Moreover, the dielectric constant of the obtained materials was evaluated. Obtained results revealed that the presence of both diatomaceous biosilica and talc significantly increases dielectric properties while having no significant effect on the mechanical properties of the obtained composites. It should be stressed that the performed analyses constitute a valuable source of knowledge on the effective modification of the... [more]

The paper assesses the influence of the calcination temperature of synthetic gypsum binder on the binding properties of innovative gypsum pastes, as well as on masonry and plastering mortars. The calcination process of gypsum binder was carried out at four different temperatures ranging from 170 to 190 °C. The specimens for testing were prepared on the basis of the obtained raw material with a constant water to gypsum ratio of w/g = 0.75. It was noted that the calcination temperature influenced the setting time of the gypsum. Based on synthetic gypsum, mixtures of masonry and plastering mortars modified with tartaric acid and Plast Retard were designed. During the experiment, the particle diameter distribution of aqueous suspensions of building and synthetic gypsum particles (before and after calcination) was determined using the Fraunhofer laser method. The dimensions of the obtained artificial gypsum grains did not differ from the diameters of the gypsum grains in the reference sampl... [more]

Nanoparticles have been thoroughly investigated in the last few decades because they have many beneficial and functional qualities. Their capability to enhance and manipulate light absorption, thermal conductivity, and heat transfer efficiency has attracted significant research attention. This systematic and comprehensive work is a critical review of research on the photothermal energy conversion performance of various nanofluids as well as the recent advances in several engineering applications. Different nanofluids used in the photothermal energy conversion process were compared to identify the suitable applications of each nanofluid in thermal systems. An analysis of the previous investigations based on experimental and numerical studies has established that nanomaterials have the potential to increase the efficiency of solar thermal systems.

Cation-exchange capacity (CEC) measurements are widely used to quantify the smectite content in altered rocks. Within this study, we measure the CEC of drill cuttings in four wells from three different high-temperature geothermal areas in Iceland. The CEC measurements in all four wells show similar depth/temperature related pattern, and when comparing the CEC with electrical resistivity logs, we could show that the low resistivity zone coincides with CEC values >5 meq/100 g. The measurements show, in general, an exponential decrease of the CEC with increasing depth. At the facies boundary between the mixed-layer clay and epidote-chlorite zone, the CEC reaches a steady state at about 5 meq/100 g and below that it only decreases slightly within a linear trend with increasing depth. The facies boundary overlaps with the transition where the electrical resistivity logs show an increase in resistivity. It is shown that the measured CEC can be related to the clay mineral alteration within th... [more]

Enhanced oil recovery (EOR) from heavy oil reservoirs is challenging. High oil viscosity, high mobility ratio, inadequate sweep, and reservoir heterogeneity adds more challenges and severe difficulties during any EOR method. Foam injection showed potential as an EOR method for challenging and heterogeneous reservoirs containing light oil. However, the foams and especially polymer enhanced foams (PEF) for heavy oil recovery have been less studied. This study aims to evaluate the performance of CO2 foam and CO2 PEF for heavy oil recovery and CO2 storage by analyzing flow through porous media pressure profile, oil recovery, and CO2 gas production. Foam bulk stability tests showed higher stability of PEF compared to that of surfactant-based foam both in the absence and presence of heavy crude oil. The addition of polymer to surfactant-based foam significantly improved its dynamic stability during foam flow experiments. CO2 PEF propagated faster with higher apparent viscosity and resulted i... [more]

Hydrothermal carbonization (HTC) reactor systems used to convert wet organic wastes into value-added hydrochar are generally classified in the literature as liquid water-based (HTC) or vapor-based (VTC). However, the distinction between the two is often ambiguous. In this paper, we present a methodological approach to analyze process conditions for hydrothermal systems. First, we theoretically developed models for predicting reactor pressure, volume fraction of liquid water and water distribution between phases as a function of temperature. The reactor pressure model predicted the measured pressure reasonably well. We also demonstrated the importance of predicting the condition at which the reactor system enters the subcooled compression liquid region to avoid the danger of explosion. To help understand water−feedstock interactions, we defined a new solid content parameter %S(T) based on the liquid water in physical contact with feedstock, which changes with temperature due to changes... [more]

P2-type sodium layered transition metal oxides have been intensively investigated as promising cathode materials for sodium-ion batteries (SIBs) by virtue of their high specific capacity and high operating voltage. However, they suffer from problems of voltage decay, capacity fading, and structural deterioration, which hinder their practical application. Therefore, a mechanistic understanding of the cationic/anionic redox activity and capacity fading is indispensable for the further improvement of electrochemical performance. Here, a prototype cathode material of P2-type Na0.6Mg0.3Mn0.7O2 is comprehensively investigated, which presents both cationic and anionic redox behaviors during the cycling process. By a combination of soft X-ray absorption spectroscopy and electroanalytical methods, we unambiguously reveal that only oxygen redox reaction is involved in the initial charge process, then both oxygen and manganese participate in the charge compensation in the following discharge proc... [more]

Nanoparticles (NPs) have been proposed for enhanced oil recovery (EOR). The research has demonstrated marvelous effort to realize the mechanisms of nanoparticles EOR. Nevertheless, gaps still exist in terms of understanding the nanoparticles-driven interactions occurring at fluids and fluid−rock interfaces. Surface-active polymers or other surface additive materials (e.g., surfactants) have shown to be effective in aiding the dispersion stability of NPs, stabilizing emulsions, and reducing the trapping or retention of NPs in porous media. These pre-requisites, together with the interfacial chemistry between the NPs and the reservoir and its constituents, can result in an improved sweep efficiency. This paper investigates four types of polymer-coated silica NPs for the recovery of oil from water-wet Berea sandstones. A series of flooding experiments was carried out with NPs dispersed at 0.1 wt.% in seawater in secondary and tertiary oil recovery modes at ambient conditions. The dynamic... [more]

The potential utilization of boiler slag generated in large amounts from pulverized-coal-combustion (PCC) power plants has recently drawn much attention due to the serious problems caused to ecosystems. In order to make maximal use of the boiler slag and reduce the environmental risk it poses, this study focused on manufacturing acoustic materials using boiler slag from Chinese PCC power plants. Three promising acoustic materials were successfully manufactured from up to 80% boiler slag with different grain sizes, with the addition of 20% Portland cement. The density and compressive strength of the products were inversely proportional and the sound absorption coefficient was positively proportional to the grain size of the boiler slag. The best sound absorption coefficient was obtained in products made from the coarsest fraction of the boiler slag (MS-C). Nonetheless, all the boiler-slag-based acoustic products still demonstrated compressive strength and densities comparable to those o... [more]

The important topic of modelling tanks filled with phase change materials (PCMs) is discussed in this article. Due to the increasing use of heating and cooling installations, tanks containing two types of PCMs are the subject of many experimental analyses. However, there are still deficiencies in their models, which are presented in this paper. The theory model was created in order to design two tanks, each with a volume of 2 m3. They were filled with water and containers with two PCMs. The modelled tanks were meant to replace the existing water tanks that were previously used in the solar heating and cooling installation in a research building located in the southern part of Spain. After the tanks were assembled, the model was validated during the summer period when the designed storage tanks supported the operation of the solar system operating in the cooling mode. The created model consists of a 1D description of the heat transfer in the storage tank, and also a 1D description of th... [more]

The primary energy consumption and greenhouse gas emissions from nickel smelting products have been assessed through case studies using a process model based on mass and energy balance. The required primary energy for producing nickel metal, nickel oxide, ferronickel, and nickel pig iron is 174 GJ/t alloy (174 GJ/t contained Ni), 369 GJ/t alloy (485 GJ/t contained Ni), 110 GJ/t alloy (309 GJ/t contained Ni), and 60 GJ/t alloy (598 GJ/t contained Ni), respectively. Furthermore, the associated GHG emissions are 14 tCO2-eq/t alloy (14 tCO2-eq/t contained Ni), 30 t CO2-eq/t alloy (40 t CO2-eq/t contained Ni), 6 t CO2-eq/t alloy (18 t CO2-eq/t contained Ni), and 7 t CO2-eq/t alloy (69 t CO2-eq/t contained Ni). A possible carbon emission reduction can be observed by comparing ore type, ore grade, and electricity source, as well as allocation strategy. The suggested process model overcomes the limitation of a conventional life cycle assessment study which considers the process as a ‘black box... [more]

Granite is one of those materials that due to its thermal parameters is used as a filling for storage beds, including high-temperature ones. The article analyzes local material that was extracted in Strzegom, Poland. The purpose of the paper is the assessment of storage material with regard to its cooperation with a heat source that is available for a short time, e.g., a solar installation. Three different shapes of granite material were tested: rock, cube and sphere. Each shape has its advantages and disadvantages, which are associated with economic and strength aspects. The article presents experimental tests of the material, which were conducted in order to determine the efficiency of the charging process. The results show that rock-shaped granite filling elements are characterized with the best parameters during the charging process, and that they obtained the highest first- and second-law efficiency in the entire tested range of inlet air temperature and flow rate. The efficiency... [more]

This paper deals with the reliability of the Pulsed Electro-Acoustic (PEA) technique in the case of a specimen containing an air layer. The first approach to this study has been proposed by the authors in previously published works. In these papers, the mathematical description, the PEA cell simulation model, and some experimental tests have been reported. In this work, a more accurate description of the acoustic wave behavior within the PEA cell and specimen with and without an air layer is given. Moreover, the comparison between simulation and experimental tests for both cases (specimen with and without air layer) allowed the validation of the previously developed PEA cell simulation model. The latter was previously validated only for a single layer specimen, here the good performances of the model have also been confirmed in the case of a multilayer specimen, also with an air layer. Experimental and simulation results show that the air layer acts as a barrier for the acoustic signal... [more]

Thermal energy storage (TES), which features an innovative technology, can enhance energy efficiency in the building sector and reduce CO2 emissions. Due to their high heat storage capacity, phase change materials (PCMs) have impressed many researchers. This paper investigates the energy performance of an individual house integrating a solar Trombe wall containing PCM with respect to heating demand and thermal comfort applications. The thermal energy performance of the design house was simulated using Dymola/Modelica, the thermal building simulation tool, whereby the optimization of objective functions as regards heating demand and thermal comfort was executed using GenOpt, the generic optimization software. Optimization of the solar Trombe wall focuses on the feasibility to find the optimal PCM parameters when running GenOpt, which consist of latent heat, melting temperature, PCM thickness and thermal conductivity, in order to minimize both the annual energy consumption for heating an... [more]

Pretreatment to improve the enzymatic digestibility of highly crystallized lignocellulosic biomass is essential in biorefinery processes. This study investigates the combination of lignocellulose pretreatment with continuous alkaline single-screw extrusion and ultrasonication for biosugar production. Miscanthus sacchariflorus was used because it is a promising bioenergy crop. The results show that ultrasonication with continuous alkaline pretreatment increased the enzymatic digestibility of carbohydrates and reduced the use of chemicals during pretreatment. An hour of ultrasonication following 0.2 M NaOH (2.25 mol-NaOH/kg-biomass) continuous alkaline pretreatment resulted in a 6.7% increase in total biosugar production (83.1% of theoretical yield), a decrease of up to 26.1% in chemical usage, and a 17.0% increase in lignin removal compared with the case without ultrasonication. The developed method can be considered an effective and eco-friendly approach to the production of bio-based... [more]

Biofuels used as biocomponents for transport fuels should meet quality requirements. Their properties have a significant impact on the proper functioning of the engine supply system and the wear of its components. Changes in the performance of biofuel functionality may already occur during storage. Therefore, the present study aimed to evaluate changes in selected rheological and tribological parameters of higher fatty acid esters depending on the time and method of their storage by considering different types of substrates used for their production. The presence of possible microbiological contamination, which may affect the examined parameters of biofuels, was also analyzed. The dynamic viscosity of the biofuels tested changed depending on the substrate used. The biofuel produced from waste oil had the highest viscosity. Tribological studies show that both the linear wear of samples and the friction moment were higher after the storage period. The acid number of the esters did not ex... [more]

The demand for alternative sources of clean, sustainable, and renewable energy has been a focus of research around the world for the past few decades. Microbial/enzymatic biofuel cells are one of the popular technologies for generating electricity from organic substrates. Currently, one of the promising fuel options is based on glucose due to its multiple advantages: high energy intensity, environmental friendliness, low cost, etc. The effectiveness of biofuel cells is largely determined by the activity of biocatalytic systems applied to accelerate electrode reactions. For this work with aerobic granular sludge as a basis, a nitrogen-fixing community of microorganisms has been selected. The microorganisms were immobilized on a carbon material (graphite foam, carbon nanotubes). The bioanode was developed from a selected biological material. A membraneless biofuel cell glucose/oxygen, with abiotic metal catalysts and biocatalysts based on a microorganism community and enzymes, has been d... [more]

Ethanol is a widely produced fuel, as well as a fuel additive. Its price is closely related to the price of gasoline, its major substitute. This paper focuses on the impacts of the related variables on regional ethanol prices. Additionally, the length of the price dataset made it possible to isolate the impacts of COVID-19 on the ethanol prices. Using multiple regression and Confirmatory Factor Analyses, we found no significant correlation between the European and US ethanol prices because the major influencing factors were regionally different. In the case of the European ethanol markets, the positive factors were wheat, maize, and potassium chloride prices, while the European sugar and diammonium phosphate prices were negative. In the US markets, gasoline, sugar, and most of the artificial fertilizer prices were positive, while wheat prices were negative. Based on factor analysis, artificial fertilizers and maize factors proved to be important to the European markets, while US ethano... [more]

A simple ultrasonic radiation method was employed for the preparation of zinc and cadmium sulfide solid solution (ZnxCd1−xS; x = 0−0.25 wt.%) with the aim to investigate its efficiency for H2 production via a visible light-driven water-splitting reaction. The catalyst characterization by X-ray diffraction confirmed the formation of solid solution (ZnxCd1−xS) between CdS and ZnS phases. All catalysts exhibited hierarchical morphology (from SEM and TEM) formed by aggregated nanoparticles of ZnxCd1−xS solid solution with crystals showing mainly (111) planes of cubic CdS phase. The crystal size linearly decreased with an increase in Zn incorporation in the crystal lattice (from 4.37 nm to 3.72 nm). The ZnxCd1−xS photocatalysts showed a gradual increase in the H2 evolution, with an increase in the Zn concentration up to 0.2 wt.% making the most effective Zn0.2Cd0.8S catalyst toward H2 production. From the catalyst activity−structure correlation, it has been concluded that the twin-like CdS... [more]

Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are two innovative classes of porous coordination polymers. MOFs are three-dimensional materials made up of secondary building blocks comprised of metal ions/clusters and organic ligands whereas COFs are 2D or 3D highly porous organic solids made up by light elements (i.e., H, B, C, N, O). Both MOFs and COFs, being highly conjugated scaffolds, are very promising as photoactive materials for applications in photocatalysis and artificial photosynthesis because of their tunable electronic properties, high surface area, remarkable light and thermal stability, easy and relative low-cost synthesis, and structural versatility. These properties make them perfectly suitable for photovoltaic application: throughout this review, we summarize recent advances in the employment of both MOFs and COFs in emerging photovoltaics, namely dye-sensitized solar cells (DSSCs) organic photovoltaic (OPV) and perovskite solar cells (PSCs). M... [more]