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Records with Subject: Process Design
Showing records 555 to 579 of 2098. [First] Page: 1 20 21 22 23 24 25 26 27 28 Last
Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane
Edyta Słupek, Patrycja Makoś, Jacek Gębicki
March 27, 2023 (v1)
Keywords: Absorption, biogas, COSMO-RS, deep eutectic solvents, economic analysis, upgrading
This paper presents the theoretical screening of 23 low-cost deep eutectic solvents (DESs) as absorbents for effective removal of the main impurities from biogas streams using a conductor-like screening model for real solvents (COSMO-RS). Based on thermodynamic parameters, i.e., the activity coefficient, excess enthalpy, and Henry’s constant, two DESs composed of choline chloride: urea in a 1:2 molar ratio (ChCl:U 1:2), and choline chloride: oxalic acid in a 1:2 molar ratio (ChCl:OA 1:2) were selected as the most effective absorbents. The σ-profile and σ-potential were used in order to explain the mechanism of the absorptive removal of CO2, H2S, and siloxanes from a biogas stream. In addition, an economic analysis was prepared to demonstrate the competitiveness of new DESs in the sorbents market. The unit cost of 1 m3 of pure bio-methane was estimated to be in the range of 0.35−0.37 EUR, which is comparable to currently used technologies.
Energy Storage for 1500 V Photovoltaic Systems: A Comparative Reliability Analysis of DC- and AC-Coupling
Jinkui He, Yongheng Yang, Dmitri Vinnikov
March 27, 2023 (v1)
Keywords: 1500 V photovoltaic (PV), cost-oriented design, Energy Storage, reliability
There is an increasing demand in integrating energy storage with photovoltaic (PV) systems to provide more smoothed power and enhance the grid-friendliness of solar PV systems. To integrate battery energy storage systems (BESS) to an utility-scale 1500 V PV system, one of the key design considerations is the basic architecture selection between DC- and AC-coupling. Hence, it is necessary to assess the reliability of the power conversion units, which are not only the key system components, but also represent the most reliability-critical parts, in order to ensure an efficient and reliable 1500 V PV-battery system. Thus, this paper investigates the BESS solutions of DC- and AC-coupled configurations for 1500 V PV systems with a comparative reliability analysis. The reliability analysis is carried out through a case study on a 160 kW/1500 V PV-system integrated DC- or AC-coupled BESS for PV power smoothing and ramp-rate regulation. In the analysis, all of the DC-DC and DC-AC power interfa... [more]
Electromagnetic and Calorimetric Validation of a Direct Oil Cooled Tooth Coil Winding PM Machine for Traction Application
Alessandro Acquaviva, Stefan Skoog, Emma Grunditz, Torbjörn Thiringer
March 27, 2023 (v1)
Keywords: calorimetric measurement, efficiency validation, electromagnetic design, model verification, oil cooling, performance evaluation, permanent magnet machines
Tooth coil winding machines offer a low cost manufacturing process, high efficiency and high power density, making these attractive for traction applications. Using direct oil cooling in combination with tooth coil windings is an effective way of reaching higher power densities compared to an external cooling jacket. In this paper, the validation of the electromagnetic design for an automotive 600 V, 50 kW tooth coil winding traction machine is presented. The design process is a combination of an analytical sizing process and FEA optimization. It is shown that removing iron in the stator yoke for cooling channels does not affect electromagnetic performance significantly. In a previous publication, the machine is shown to be thermally capable of 25 A/mm 2 (105 Nm) continuously, and 35 A/mm 2 (140 Nm) during a 10 s peak with 6 l/min oil cooling. In this paper, inductance, torque and back EMF are measured and compared with FEA results showing very good agreement with the n... [more]
Utilization of Excess Production of Waste-Fired CHP Plants for District Cooling Supply, an Effective Solution for a Serious Challenge
Mika Fabricius, Daniel Øland Tarp, Thomas Wehl Rasmussen, Ahmad Arabkoohsar
March 27, 2023 (v1)
Keywords: district cooling, district heating, MSW management, Technoeconomic Analysis, waste incineration
District heating-connected waste incineration plants face a serious operating challenge during the warmer months of the year when the heating load is quite low. The challenge is the difficulty of managing the extra municipal solid waste to be disposed of, exposing great pressure and cost on the plant. Conventionally, the solution is either burning the surplus waste and providing the extra cooling required for the condenser with a summer chiller and paying the tax of the total heat generation of the plant, or paying other industries to burn the waste for their specific applications. Both of these solutions are, however, costly. In this study, to address this challenge the utilization of the extra available resources of waste incineration plants for district cooling supply is proposed. Then, the proposed solution is analyzed from the thermodynamic and economic points of view. The feasibility of the proposal is investigated for a real waste incineration plant in Denmark and its 50 neighbo... [more]
Understanding Computational Methods for Solar Envelopes Based on Design Parameters, Tools, and Case Studies: A Review
Miktha Farid Alkadri, Francesco De Luca, Michela Turrin, Sevil Sariyildiz
March 27, 2023 (v1)
Keywords: computational design methods, passive design strategies, solar envelopes
The increasing population density in urban areas simultaneously impacts the trend of energy consumption in building sectors and the urban heat island (UHI) effects of urban infrastructure. Accordingly, passive design strategies to create sustainable buildings play a major role in addressing these issues, while solar envelopes prove to be a relevant concept that specifically considers the environmental performance aspects of a proposed building given their local contexts. As significant advances have been made over the past decades regarding the development and implementation of computational solar envelopes, this study presents a comprehensive review of solar envelopes while specifically taking into account design parameters, digital tools, and the implementation of case studies in various contextual settings. This extensive review is conducted in several stages. First, an investigation of the scope and procedural steps of the review is conducted to frame the boundary of the topic to b... [more]
The Influence of Luminaire Photometric Intensity Curve Measurements Quality on Road Lighting Design Parameters
Dariusz Czyżewski, Irena Fryc
March 27, 2023 (v1)
Keywords: Energy Efficiency, luminaire photometric intensity curve, luxmeter, street lighting
This article presents the research on a road lighting design. In this kind of design for a specific type of a roadway, the number and spacing of luminaires are calculated on the basis of luminaire photometric parameters such as intensity curve (LPIC) and luminous flux. The values of these parameters are measured using the luxmeter, i.e., a measuring instrument in which the spectral sensitivity should imitate spectral sensitivity of the human eye V(λ). However, the luxmeter’s spectral sensitivity S(λ) is not perfectly matched with the required one and varies for different instruments, resulting in measurement errors. To avoid this measurement error, the spectral mismatch correction factor (SMCF) should be applied to luxmeter’s readings. For a given luxmeter, the SMCF values depend on the measured light’s spectral composition SPD (described also by the lamp’s correlated color temperature CCT). Unfortunately, many laboratories do not apply SMCF to their luxmeter readings. Typical measurem... [more]
Analysis of Relaxation Time of Temperature in Thermal Response Test for Design of Borehole Size
Hobyung Chae, Katsunori Nagano, Yoshitaka Sakata, Takao Katsura, Ahmed A. Serageldin, Takeshi Kondo
March 27, 2023 (v1)
Keywords: groundwater velocity, moving line source theory, optical fiber distributed temperature sensor, relaxation time of temperature, thermal response test
A new practical method for thermal response test (TRT) is proposed herein to estimate the groundwater velocity and effective thermal conductivity of geological zones. The relaxation time of temperature (RTT) is applied to determine the depths of the zones. The RTT is the moment when the temperature in the borehole recovers to a certain level compared with that when the heating is stopped. The heat exchange rates of the zones are calculated from the vertical temperature profile measured by the optical-fiber distributed temperature sensors located in the supply and return sides of a U-tube. Finally, the temperature increments at the end time of the TRT are calculated according to the groundwater velocities and the effective thermal conductivity using the moving line source theory applied to the calculated heat exchange rates. These results are compared with the average temperature increment data measured from each zone, and the best-fitting value yields the groundwater velocities for eac... [more]
Total Cost of Ownership Model and Significant Cost Parameters for the Design of Electric Bus Systems
Anders Grauers, Sven Borén, Oscar Enerbäck
March 27, 2023 (v1)
Keywords: charging strategy, cost model, electric bus, public transport, Renewable and Sustainable Energy, TCO, total cost of ownership
Without experiences of electric buses, public transport authorities and bus operators have faced questions about how to implement them in a cost-effective way. Simple cost modelling cannot show how costs for different types of electric buses differ between different routes and timetables. Tools (e.g., HASTUS, PtMS, and optibus) which can analyse such details are complicated, time consuming to use, and provide insufficient insights into the mechanisms that influence the cost. This paper therefore proposes a method for how to calculate total cost of ownership, for different types of electric buses, in a way which can predict how the cost varies based on route and timetable. The method excludes factors which cause minor cost variations in an almost random manor, in order to better show the fundamental mechanisms influencing different costs. The method will help in finding ways to reduce the cost and help to define a few cases which deserve a deep analysis with more complete tools. Testing... [more]
Design and Thermo-Economic Comparisons of an Absorption Air Conditioning System Based on Parabolic Trough and Evacuated Tube Solar Collectors
Adil Al-Falahi, Falah Alobaid, Bernd Epple
March 27, 2023 (v1)
Keywords: absorption cycles, air conditioning, evacuated tube collector, parabolic trough collector, solar collectors
Solar absorption cycles for air conditioning systems have recently attracted much attention. They have some important advantages that aid in reducing greenhouse gas emissions. In this work, design and thermo-economic analyses are presented in order to compare between two different collector types (parabolic trough and evacuated tube) by water−lithium bromide absorption systems, and to select the best operating conditions. Generally, the system consists of three major parts. The first part is the solar field for thermal power conversion. The second part is the intermediate cycle, which contains a flashing tank and pumping system. The third part is the water lithium bromide absorption chiller. A case study for a sports arena with 700−800 kW total cooling load is also presented. Results reveal that a parabolic trough collector combined with H2O−LiBr (PTC/H2O−LiBr) gives lower design aspects and minimum rates of hourly costs (USD 5.2/h), while ETC/H2O−LiBr configuration give USD 5.6/h. The... [more]
Development of Small-Sized Lead Inserted Laminated Rubber Bearing for Nuclear Component Seismic Isolation
Gyeong-Hoi Koo, Jin-Young Jung, Jin-Hyeong Lee, Tae-Myung Shin, Jin-Young Park
March 27, 2023 (v1)
Keywords: beyond design basis earthquake (BDBE), characteristic strength, effective stiffness, energy dissipation of cycle, equivalent viscous damping ratio, lead inserted laminated rubber bearing, nuclear component, seismic capacity, seismic isolation, shape factors
This paper presents a design specification of the small-sized lead inserted laminated rubber bearing (LRB) for application to nuclear component seismic isolation and describes the results of test verification on design performance parameters such as effective horizontal stiffness, equivalent viscous damping ratio, design seismic isolation frequency, and ultimate shear deformation. To do this, two types of LRB, having the same vertical design load of 10 kN but with different shape factors, are designed, fabricated, and tested by the quasi-static procedures. To determine the effective horizontal stiffness and the equivalent damping value from the test results, the new method is proposed and compared with the methods of the ASCE and ISO standards in case that the tangential stiffness curve is not linear in tests. From the comparison between tests and design specifications in the performance parameters, it was found that the design specifications developed in this paper are in a good agree... [more]
Reactor Design and Thermal Performance Analysis for Solar Thermal Energy Storage Application
Yabibal Getahun Dessie, Bachirou Guene Lougou, Hong Qi, Heping Tan, Juqi Zhang, Baohai Gao, Md Arafat Islam
March 27, 2023 (v1)
Keywords: reactor design, solar energy storage, sustainable, temperature distribution, thermal performance
Solar energy is a sustainable and low-cost renewable energy of enormous importance, especially at this time where non-renewable energy sources are unsustainable and costly. However, improving the thermal performance of a solar energy storage reactor poses some challenges. In this study, the location of fluid inlets and outlets in the given reactor design and its impact on the thermal performance were investigated. A P1 approximation radiation model coupled with shallow channel approximation of fluid flow was developed. By taking the frustum base as a reference, four fluid inlets along the edges of the frustum and two outlet locations at the base and side of the reactor were computed. Inlets located 4.81 cm from the base of the frustum and an outlet located at the side of the reactor were found to have a better thermal performance with a short conveyer energy flow system. It was also deduced that radiation applied at the edges of the frustum had better thermal performance than that appl... [more]
Effect of Soil Resistivity Measurement on the Safe Design of Grounding Systems
Vasilios P. Androvitsaneas, Katerina D. Damianaki, Christos A. Christodoulou, Ioannis F. Gonos
March 27, 2023 (v1)
Keywords: grounding system, soil models, soil resistivity, step voltage, touch voltage, uncertainty of measurement
A prerequisite for the proper and safe designing of a grounding system is the full knowledge of the ground structure in the terrain of installation. Through soil resistivity measurements, engineers are able to illustrate the ground profile, which constitutes the most significant parameter for the design of a grounding system and for determining the maximum permissible limits of step and touch voltages. This paper highlights the high importance and necessity for engineers to choose the proper measurement axes of soil resistivity in the terrain of interest and to choose suitable measurement depths, as well the combination of axes for the final determination of the ground profile. The variance of soil resistivity values, as a function of axis distance and the impact of axis placement on determining the uncertainty of measurements, is also analyzed in detail in this study. Furthermore, this work studies the value variance of step and touch voltages as a function of measurement axes, consid... [more]
Revisiting Electricity Network Tariffs in a Context of Decarbonization, Digitalization, and Decentralization
Nicolás Morell Dameto, José Pablo Chaves-Ávila, Tomás Gómez San Román
March 27, 2023 (v1)
Keywords: customer response, distributed energy resources, electricity network tariffs, tariff principles
The electricity system is evolving due to three driven forces: decarbonization, digitalization, and decentralization (3 Ds). Should these three forces occur, electricity network tariffs must be revisited. In most countries, actual network charges incentivize inefficient network usage when volumetric or low granular (temporal and locational) charges are applied. This paper analyses the effect of 3 Ds on tariff design principles and proposes an efficient methodology for network tariff design that promotes efficient usage of the network as well as an equitable share of the costs for network users. The proposed network tariff consists of two components: a peak-coincident and a fixed charge. The peak-coincident forward-looking charge considers the cost of future network reinforcements required, calculated element-by-element, and assigned to customers during the peak utilization hours of each network element. Fixed charges allocate the residual part of the total network costs following equit... [more]
Factors Influencing the Prediction of Pile Driveability Using CPT-Based Approaches
Luke J. Prendergast, Putri Gandina, Kenneth Gavin
March 27, 2023 (v1)
Keywords: CPT, driveability, pile design, pile installation, piles
This paper investigates the applicability of Cone Penetration Test (CPT)-based axial capacity approaches, used for estimating pile static capacity, to the prediction of pile driveability. An investigation of the influence of various operational parameters in a driveability study is conducted. A variety of axial capacity approaches (IC-05, UWA-05 and Fugro-05) are assessed in unmodified and modified form to appraise their ability to be used in estimating the driveability of open-ended steel piles used to support, for example, offshore jackets or bridge piers. Modifications to the CPT-based design approaches include alterations to the proposed base resistance to account for the resistance mobilized under discrete hammer impacts and the presence of residual stresses, as well as accounting for the effects of static capacity increases over time, namely ageing. Furthermore, a study on the influence of various operational parameters within a wave equation solver is conducted to ascertain the... [more]
Techno-Economic Assessment of the Use of Syngas Generated from Biomass to Feed an Internal Combustion Engine
J. R. Copa, C. E. Tuna, J. L. Silveira, R. A. M. Boloy, P. Brito, V. Silva, J. Cardoso, D. Eusébio
March 27, 2023 (v1)
Keywords: biomass gasification, Energy Efficiency, internal combustion engines-generator, Monte Carlo method, small-scale systems, Technoeconomic Analysis
The focus of this study is to provide a comparative techno-economic analysis concerning the deployment of small-scale gasification systems in dealing with various fuels from two countries, Portugal and Brazil, for electricity generation in a 15 kWe downdraft gasifier. To quantify this, a mathematical model was implemented and validated against experimental runs gathered from the downdraft reactor. Further, a spreadsheet economic model was developed combining the net present value (NPV), internal rate of return (IRR) and the payback period (PBP) over the project’s lifetime set to 25 years. Cost factors included expenses related to electricity generation, initial investment, operation and maintenance and fuel costs. Revenues were estimated from the electricity sales to the grid. A Monte Carlo sensitivity analysis was used to measure the performance of the economic model and determine the investment risk. The analysis showed an electricity production between 11.6 to 15 kW, with a general... [more]
Non-Uniform Three-Dimensional Pulsating Heat Pipe for Anti-Gravity High-Flux Applications
Chih-Yung Tseng, Kai-Shing Yang, Chi-Chuan Wang
March 27, 2023 (v1)
Keywords: anti-gravity, compact arrangement, pulsating heat pipe, thermal resistance ratio
This study proposes a novel high-flux pulsating heat pipe that can lift the major constraint of the conventional pulsating heat pipe (PHP) which is unable to function properly upon anti-gravity operations. The proposed PHP introduces additional unbalance force via uneven tube diameter/geometry in the adiabatic sections to tailor the problem in anti-gravity operation. The design contains a three-dimensional configuration circuitry with compact arrangement tubes on the evaporator and condenser. Through this design, the non-uniform three-dimensional pulsating heat pipe (3D-PHP) manipulates the uneven inner diameters of the adiabatic sections to form uneven vapor/liquid distributions in the adiabatic sections to yield a unitary flow pattern that is able to withstand a much higher input power. The present PHP uses methanol as working fluid, with 38% volumetric filling ratio, and has a high-flux of 22.9 W/cm2 and a low the thermal resistance ratio (Ranti-gravity/Rgravity-assisted) of 1.05 wh... [more]
Techno-Economic Analysis of Biofuel, Solar and Wind Multi-Source Small-Scale CHP Systems
Angelo Algieri, Pietropaolo Morrone, Sergio Bova
March 27, 2023 (v1)
Keywords: biodiesel, CHP, multi-source, multi-variable optimization, ORC, photovoltaic, wind turbine
The aim of the paper is the techno-economic analysis of innovative integrated combined heat and power (CHP) systems for the exploitation of different renewable sources in the residential sector. To this purpose, a biofuel-driven organic Rankine cycle (ORC) is combined with a wind turbine, a photovoltaic system and an auxiliary boiler. The subsystems work in parallel to satisfy the electric and heat demand of final users: a block of 40 dwellings in a smart community. A 12.6 kWel ORC is selected according to a thermal-driven strategy, while wind and solar subsystems are introduced to increase the global system efficiency and the electric self-consumption. The ORC can be switched-off or operated at partial load when solar and/or wind sources are significant. A multi-variable optimization has been carried out to find the proper size of the wind turbine and photovoltaic subsystems and to define the suitable operating strategy. To this purpose, several production wind turbines (1.0−60.0 kWel... [more]
Case Studies of Rock Bolt Support Loads and Rock Mass Monitoring for the Room and Pillar Method in the Legnica-Głogów Copper District in Poland
Krzysztof Skrzypkowski
March 27, 2023 (v1)
Keywords: mechanical and vibrating wire sensors, monitoring, rock bolt support, room and pillar method
The article presents the impact of geological and mining factors on the stability of room excavations in the Legnica-Głogów Copper District (LGOM) in Poland. In underground mining, the primary task of bolting of mining excavations is to ensure their stability as an essential condition of work safety. Appreciating the role and importance of the rock bolting in Polish ore mining; rock bolt load sensors were designed, manufactured and tested under laboratory conditions. The purpose of the research was to characterize the sensors and determine the elastic range of the bearing plate, which are an integral part of the sensor. The sensors have been verified in industrial conditions. The tests were carried out in the underground copper ore mine in Poland. Three rooms in the exploitation field were selected for testing, where exploitation was carried out at a depth of 809−820 m below the ground surface with the application of room and pillar with roof deflection and maintaining the central part... [more]
Survey and Classification of Business Models for the Energy Transformation
Johannes Giehl, Hayri Göcke, Benjamin Grosse, Johannes Kochems, Joachim Müller-Kirchenbauer
March 27, 2023 (v1)
Keywords: business model classification, business model framework for the energy transformation, business model ontology, business models, Energiewende, energy transformation, value creation networks
The energy transformation is changing the structure of the energy sector in Europe and Germany. In this paper the current structure of the energy sector is analysed both empirically as well as theoretically. Therefore, the authors have developed the business model framework for the energy transformation (BMFE). The framework is a synthesis of classical business model designs. An exhaustive survey of existing business models based on primary data collection and a literature review leads to 638 business models. Finally, 69 prototypical business models of the energy sector are the result of the classification of these business models. The information of the business models within the BMFE is applied to show the growing importance of value creation networks in energy industry. The work represents the current status of the business models in the energy sector.
Experimental Assessment on Air Clearance of Multiple Valve Unit Considering Switching Impulse and DC Superimposed Switching Impulse
Jae-Hong Koo, Jae-Kyu Seong, Ryul Hwang, Bang-Wook Lee
March 27, 2023 (v1)
Keywords: air clearance, critical flashover voltage, DC, DC pre-stress, dielectric characteristics, HVDC, multiple valve unit, superimposed, switching impulse
Multiple valve unit (MVU), which converts AC to DC and DC to AC, is one of the key elements of high voltage DC (HVDC) transmission. Therefore, the insulation design of MVU against overvoltage should be considered for the stable and reliable operation of HVDC transmission system. Especially, the air clearance of MVU should be calculated based the switching impulse, since it is fatal to MVU in terms of electrical insulation. However, the previous studies were limited to wave front, and the air clearance of the switching impulse is specified only for an ultra-high voltage (UHV) above 750 kV. As a result, it is difficult to calculate the air clearance of MVU which must endure for a switching impulse under 750 kV. In addition, when the switching impulse introduced while the MVU is in normal operation, it is superimposed to DC and creates the most severe situation, but the studies on such subjects are also insufficient. Therefore, as a fundamental step to calculate the air clearance of MVU,... [more]
Design and Construction of a New Metering Hot Box for the In Situ Hygrothermal Measurement in Dynamic Conditions of Historic Masonries
Mirco Andreotti, Marta Calzolari, Pietromaria Davoli, Luisa Dias Pereira, Elena Lucchi, Roberto Malaguti
March 27, 2023 (v1)
Keywords: dynamic conditions, HeLLo, historic masonries, hygrothermal measurement, in situ, metering hot box
The main purpose of the HeLLo project is to contribute to data available on the literature on the real hygrothermal behavior of historic walls and the suitability of insulation technologies. Furthermore, it also aims at minimizing the energy simulation errors at the design phase and at improving their conservation features. In this framework, one of the preliminary activities of the study is the creation of a real in situ hot box to measure and analyze different insulation technologies applied to a real historic wall, to quantify the hygrothermal performance of a masonry building. Inside this box, ‘traditional’ experiments can be carried out: recording heat flux, surface temperature, and air temperatures, as well as relative humidity values through the use of a new sensing system (composed of thermocouples and temperature/relative humidity combined sensors). Within this paper, the process of development, construction, and validation of this new metering box is exhibited. The new hot bo... [more]
Integral PWR-Type Small Modular Reactor Developmental Status, Design Characteristics and Passive Features: A Review
Chireuding Zeliang, Yi Mi, Akira Tokuhiro, Lixuan Lu, Aleksey Rezvoi
March 27, 2023 (v1)
Keywords: integrated pressurized water reactors, passive safety systems, small modular reactors
In recent years, the trend in small modular reactor (SMR) technology development has been towards the water-cooled integral pressurized water reactor (iPWR) type. The innovative and unique characteristics of iPWR-type SMRs provide an enhanced safety margin, and thus offer the potential to expand the use of safe, clean, and reliable nuclear energy to a broad range of energy applications. Currently in the world, there are about eleven (11) iPWR-type SMRs concepts and designs that are in various phases of development: under construction, licensed or in the licensing review process, the development phase, and conceptual design phase. Lack of national and/or internatonal comparative framework for safety in SMR design, as well as the proprietary nature of designs introduces non-uniformity and uncertainties in regulatory review. That said, the major primary reactor coolant system components, such as the steam generator (SG), pressurizer (PRZ), and control rod drive mechanism (CRDM) are integr... [more]
An Insight into the Separation of 1,2-Propanediol, Ethylene Glycol, Acetol and Glycerol from an Aqueous Solution by Adsorption on Activated Carbon
Jorge Fortea, Lucía García, Joaquín Ruiz, Miriam Oliva, Jesús Arauzo
March 27, 2023 (v1)
Keywords: 1,2-propanediol, acetol, activated carbon, Adsorption, ethylene glycol, glycerol
Glycerol conversion processes such as aqueous phase reforming and hydrogenolysis generate value-added compounds highly diluted in water. Because distillation is a high energy demand separation step, adsorption could be an attractive alternative to recover these chemicals. Adsorption isotherms of 1,2-propanediol, acetol, ethylene glycol and glycerol onto activated carbon were determined by batch adsorption experiments. These isotherms were fitted slightly better to the Freundlich equation than to the Langmuir equation. Acetol is the compound with the highest adsorption at concentrations smaller than 1 M. Properties of the adsorbate such as the −OH group number, chain length, molecular size and dipole moment, besides characteristics of the adsorbent such as the surface area, oxygen and ash content, are considered to explain the observed results. Moreover, adsorption experiments were performed with mixtures of compounds and it was determined that the molar amount adsorbed is less than pre... [more]
Thermal and Kinetic Behaviors during Co-Pyrolysis of Microcrystalline Cellulose and Styrene−Butadiene−Styrene Triblock Copolymer
Shijie Yu, Xiaoxiao Yang, Hui Zhou, Zhongchao Tan, Kunlin Cong, Yanguo Zhang, Qinghai Li
March 27, 2023 (v1)
Keywords: activation energy, co-pyrolysis, interaction, municipal solid waste, thermogravimetric
The interaction between various municipal solid waste components is very important for the actual solid waste treatment process. Microcrystalline cellulose (MC) and styrene−butadiene−styrene triblock copolymer (SBS) are important components of municipal solid waste. In this paper, co-pyrolysis characteristics and kinetics of MC and SBS with different heating rates were investigated using a thermogravimetric analyzer. The overlap ratio was defined to evaluate the interaction between MC and SBS. The results showed that the decomposition temperature of MC was lower than that of SBS during pyrolysis. The interaction between MC and SBS, an inhibitory effect, was most significant when the MC mass fraction was 70% with an overlap ratio of 0.9764. SBS had almost no effect on the pyrolysis temperature of MC, while MC delayed the pyrolysis of SBS. Adding MC in SBS can significantly reduce the energy required for the reaction.
Optimal Design of Welded Plate Heat Exchanger for Ammonia Synthesis Column: An Experimental Study with Mathematical Optimisation
Leonid Tovazhnyanskyy, Jiří Jaromir Klemeš, Petro Kapustenko, Olga Arsenyeva, Olexandr Perevertaylenko, Pavlo Arsenyev
March 27, 2023 (v1)
Keywords: ammonia synthesis, Energy Efficiency, heat transfer, multi-pass arrangement, optimal design, plate heat exchanger
The production of ammonia, consuming up to 5% of natural gas global production, accounts for about 2% of world energy. Worldwide, the Haber−Bosch process is the mainly used method of ammonia catalytic synthesis, involving temperatures up to 600 °C and pressures up to 32 MPa. In this paper, the results of the development and study of the special welded construction of plate heat exchanger (WPHE) for a column of ammonia synthesis are presented. The heat transfer and hydraulic performance of developed WPHE are investigated on a one-pass model in laboratory conditions. An equation for the relation between heat transfer effectiveness and the number of heat transfer units is proposed. A mathematical model of multi-pass WPHE is developed using these results. The validity of this model is confirmed by results of industrial tests performed with the prototype WPHE installed in operating column of ammonia synthesis at temperatures about 500 °C and pressure about 32 MPa. The tests confirmed the re... [more]
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