Biomass as a clean and renewable source of energy has immense potential to aid in solving the energy crisis in the world. In order to accurately predict the fluidization behavior of biomass particles using the Eulerian−Eulerian approach and the kinetic theory for granular flows (KTGF), employing appropriate models that adapt to irregularly shaped particles and can precisely predict the interaction between particles is crucial. In this study, the effects of varying radial distribution functions (RDF), frictional viscosity models (FVM), angles of internal friction (ϕ), and stress blending functions (SBF) on the performance of two-fluid models (TFM) were investigated. Simulation predictions were compared and validated with the previous experiments in the literature on Geldart B biomass particles of walnut shells. When applying sphericity to account for size irregularities of biomass particles, the results of this study demonstrated that predictions of both the Ma−Ahmadi and the Carnahan−S... [more]

The recovery of vegetal waste for energy purposes is one of the ways to increase the amount of energy obtained from renewable sources. The Top-Lit Updraft (TLUD) gasification and combustion process is recognized as the least polluting of all other combustion processes, resulting in a sterile charcoal called biochar, which can be used as an amendment in agricultural soils. The purpose of this research was to determine the influence of excess air in the combustion area compared to the (theoretical) calculated requirement for a TLUD energy module. Most scientific publications on this topic recommend primary/secondary air flow rate ratios of 1/3 or 1/4. In this study, the two recommended ratios were tested, and it was found that better energy results correspond to the ratio of 1/3. For this 1/3 ratio, the investigations continued in order to optimize the combustion process. The results achieved demonstrate that the excess combustion air flow of 30% improves the performance of the energy mo... [more]

Grass and other herbaceous biomass are abundant, but often under- or not utilized as a renewable resource. Here, the production of biochar from extensive late-harvest grass via multiple thermochemical conversion technologies was investigated at lab and farm scale for use in soil applications. While biochar is a product with highly diverse potential applications, it has a multitude of benefits for agricultural usage as a soil amendment, if the quality adheres to certain limit values of potentially toxic constituents. The results show that the biochar can adhere to all limit values of the European Biochar Certificate (EBC) for utilization in agriculture. Generally, the contents of heavy metals were well below the proposed EBC limits and very low PAH concentrations in the biochar were achieved. The high ash content in the grass of 7.71 wt resulted in high nutrient concentrations in the biochar, of benefit in soil applications, but the ash also contains chlorine, nitrogen and sulphur, whic... [more]

This article is a brief and critical review of the state of the art in algae production in the food and energy industries. Review and experimental articles from the last five years were selected to recapitulate the reasons for interest in algae cultivation, for which we highlight the most valuable phytochemicals passing through their niches in the food market, their bioenergetic potential and the possible uses of algal waste biomass. In addition, we punctuate the advent of algae biorefineries. The objectives of this study were to list the main points related to interest in cultivation, drawing a parallel between the establishment of algae in the food market and its potential to establish itself in the energy market. It was concluded that the use of algae biorefineries has been used as a solution for the food, chemical and energy markets, despite the need for the development of broader research on industrial scale.

Biofuels have become a source of renewable energy to offset the use of fossil fuels and meet the demand for electricity, heat, and cooling in the industrial sector. This study aims to (a) develop a simulation of a trigeneration system based on a gas turbine cycle and an absorption chiller unit, using biomass and syngas from spent coffee grounds (SCGs) to replace the conventional system currently supplying the energy requirements of an instant coffee plant located in Guayaquil, Ecuador, and (b) carry out an exergoeconomic analysis of the simulated system to compare the effects of different fuels. The results showed an increase in the exergetic efficiency from 51.9% to 84.5% when using a trigeneration system based on biomass instead of the conventional non-integrated system. Furthermore, the biomass-based system was found to have the lowest operating costs ($154.7/h) and the lowest heating, cooling, and power costs ($10.3/GJ, $20.2/GJ, and $23.4/GJ, respectively). Therefore, the results... [more]

Various techniques are implemented to reduce odor emission due to their potential multi-source nature. One modern approach is the use of thermochemically processed biomass to eliminate odors. Compared with raw biomass, processed biomass is characterized by greater porosity and an expanded specific surface. In these laboratory experiments, adsorption tests for a mixture of indole, 2,3-dimethylpyrazine, and 2,3,5-trimethylpyrazine are carried out using torreficates produced from biomass from the agri-food industry (walnut shells, orange peels, peach stones, and apple wood chips). This research is focused on the determination of the correlation between the physical-hydraulic properties of the torreficates and their ability to reduce the odors simulated by the selected compounds. The results indicate that 2,3-dimethylpyrazine and 2,3,5-trimethylpyrazine are not detected in any of the investigated low-temperature biochars. However, indole is detected in most materials, and its most signific... [more]

The production of biochar from biomass and industrial wastes provides both environmental and economic sustainability. An effective way to ensure the sustainability of biochar is to produce high value-added activated carbon. The desirable characteristic of activated carbon is its high surface area for efficient adsorption of contaminants. Feedstocks can include a number of locally available materials with little or negative value, such as orchard slash and crop residue. In this context, it is necessary to determine and know the conversion effects of the feedstocks to be used in the production of activated carbon. In the study conducted for this purpose; several samples (piñon wood, pecan wood, hardwood, dried grass, Wyoming coal dust, Illinois coal dust, Missouri coal dust, and tire residue) of biomass and industrial waste products were investigated for their conversion into activated carbon. Small samples (approximately 0.02 g) of the feedstocks were pyrolyzed under inert or mildly oxi... [more]

The availability of freshwater and energy is a serious issue in remote and islanded areas, especially at a small scale, where there may not be the possibility to access the grid and/or water distribution systems. In this context, polygeneration systems operating on the basis of local, renewable energy sources can be an answer to the users’ demand for electricity, heating, cooling, and domestic hot water. The scope of the proposed paper was to investigate, numerically, the energy and economic feasibility of a novel hybrid polygeneration system powered by biomass, solar, and wind energy for a micro-district of households. The proposed system consists of a biomass-fueled steam cycle, wind turbine, photovoltaic field coupled with thermal and electrical energy storage, adsorption chiller, and a reverse osmosis water desalination unit. The system is also assisted by an LPG generator set running as backup. The system provides space heating and cooling, electrical energy, and fresh and domesti... [more]

Currently, one of the main directions of agricultural development in Poland is the pursuit of sustainable development, rational management of material resources, and striving for energy self-sufficiency, while maintaining low greenhouse gas emissions. It is an alternative to constantly supported coal solutions. Sustainable development in the sense of processes taking place in enterprises affects many key areas of their activity. One of them is the measurement of efficiency, another is the compatibility with nature and the environment, and the perception of humans and their role. Measures of enterprises’ effectiveness should be considered in relation to the objectives of the enterprise. Biorefineries play a special role in shaping the new energy reality, being a system that connects various devices and biomass conversion processes to produce energy, fuel, and other valuable products. The essence of the functioning of biorefineries is as value chains; that is, a series of interrelated ac... [more]

Glycerol, a highly functionalised polyol, can be used as a platform molecule to produce a variety of high-value chemicals. As glycerol production is projected to increase over the coming years, it’s critically important that technology and infrastructure are developed to make use of the inevitable surplus. The catalytic production of ‘green’ mono alcohols from glycerol, in the absence of H2, is an emerging area of research that, in recent years, has generated significant industrial interest. Herein, we provide an update on recent advances in this field and discuss challenges which need to be overcome if this approach is to be considered viable industrially. The economic significance of using crude glycerol as a feedstock for glycerol valorisation strategies is also addressed and suggestions for improving the impact of research conducted in this field are proposed.

Due to global warming, technologies reducing CO2 emissions in the metallurgical industry are being sought. One possibility is to use bio-coke as a substitute for classic coke made of 100% fossil coal. Bio-coke can be produced on the basis of coal with the addition of substances of biomass origin. Blends for the production of bio-coke should have appropriate coke-making properties to ensure the appropriate quality of bio-coke. The article presents the results of the research on the influence of the addition (up to 20%) of bio-components of different origins to the coke blend on its coke-making properties, i.e., Gieseler Fluidity, Arnu—Audibert Dilatation and Roga Index. The bio-components used in the research were raw and thermally processed waste biomass of different origins (forestry: beech and alder woodchips; sawmill: pine sawdust; and the food industry: hazelnut shells and olive kernels) and commercial charcoal. Studies have shown that both the amount of additive and the type of ad... [more]

Due to global warming, technologies reducing CO2 emissions in the metallurgical industry are being sought. One possibility is to use bio-coke as a substitute for classic coke made of 100% fossil coal. Bio-coke can be produced on the basis of coal with the addition of substances of biomass origin. Blends for the production of bio-coke should have appropriate coke-making properties to ensure the appropriate quality of bio-coke. The article presents the results of the research on the influence of the addition (up to 20%) of bio-components of different origins to the coke blend on its coke-making properties, i.e., Gieseler Fluidity, Arnu—Audibert Dilatation and Roga Index. The bio-components used in the research were raw and thermally processed waste biomass of different origins (forestry: beech and alder woodchips; sawmill: pine sawdust; and the food industry: hazelnut shells and olive kernels) and commercial charcoal. Studies have shown that both the amount of additive and the type of ad... [more]

Increasing the share of renewable energy in the final energy consumption is a way to ensure independence from external supplies of fossil fuels, which is a fundamental political and economic challenge for many countries nowadays. One such country is Ukraine, which depended on Russian gas supplies and energy (electricity) from nuclear power plants. Russian gas is not delivered anymore to Ukraine, and Russians have recently taken over some of the nuclear power plants. The changes in the political situation force Ukraine to search for alternative energy sources. In countries with high agricultural production potential, one of the basic options seems to be popularization of modern methods of obtaining energy from biomass (bioenergy), which so far has played a minor role in the country’s energy mix (less than 2% in the case of Ukraine). The analysis carried out on the case of the Kyiv Region indicates that the annual economic potential of biomass in the region is equivalent to 1743 thousand... [more]

The study presents the results of research on using fixed-bed, activated carbon (AC) adsorbers in the cleaning of heavily tar-laden producer gas from the gasification of biomass. The efficiency of removal of organic compounds as well as the remaining adsorption capacity of the bed were determined using a spectrum of commonly applied diagnostic methods, including qualitative and quantitative analyses of the adsorbed compounds and changes in the pore volume of the bed material (IN, MN). The authors compare these lab quantifications with a simple technique which is based on the analysis of the changes in the position of temperature front in the bed. The main benefit of the latter is the possibility of performing the diagnostics of the bed “online” and using low-cost temperature measurements. The test was performed using a commercially available AC Desotec AIRPEL 10-3 and real producer gas obtained through the gasification of alder chips. For tar, VOC and C2−C5 compounds, the removal effic... [more]

Background: Bioenergy attracts much attention due to the global demand for renewable and sustainable energy resources. Waste biomass feedstocks—date pits, coffee waste, and cow dung—require efficient and environmentally friendly waste-management technologies such as pyrolysis. Fast pyrolysis occurs at fast heating rates (10−100 °C/s), generates high bio-oil yields, and is the most widely used process for biofuel generation. The aim of the study is to compare the effect of pyrolysis between single, binary, and ternary feeds on thermal degradation behavior and bio-oil composition. Methods: Thermogravimetric analysis (TGA) was conducted at 30 °C/min from room temperature to 850 °C to understand the thermal degradation behavior of the biomasses. A Pyroprobe® reactor—a micro-scale pyrolyzer—was used to conduct the fast pyrolysis at 500 °C with a heating rate of 10 °C/s, and the volatile contents were quantified using a gas chromatograph−mass spectrometer (GC/MS). Results: The (TGA) showed t... [more]

The development and utilization of biomass can not only address the demand for low-carbon energy and reduce environmental pollution, but can also facilitate the achievement of carbon neutrality. However, there are many factors justifying the case for low utilization of agricultural residues. These factors could be well controlled by producing top-quality pellets. Production of pellets is generally accompanied by the problems of high energy consumption and serious mold wearing. To eliminate these deficiencies, pretreatment has attracted scholars’ attention. In this review, the effects of four pretreatments on the properties of pellets were assessed. Thermal pretreatment can improve the hydrophobicity of pellets, and optimize their properties, while degradation of diverse extractives is noteworthy. Hydrothermal pretreatment improves the physical properties of pellets, through the increase of polar functional groups on the surface of the biomass. Ultrasonic vibration-assisted (UV-A) pelle... [more]

In recent years, global warming and climate change associated with emissions of CO2 from fossil fuel-fired power systems are a big worry for authorities in many countries worldwide. The utilization of biomass as an alternative, carbon-neutral fuel can reduce emissions of CO2 and other greenhouse gases. Furthermore, the coupling of oxy-combustion of biomass with CO2 capture is an option for carbon-negative power generation technology. In this study, emissions of NOx, SO2, and CO from the air- and oxy-combustion of three energy crops (Miscanthus giganteus, Sida hermaphrodita, and Salix viminalis) are presented and compared with emissions from other biomass fuels and reference coal. Combustion tests in air and O2/CO2 mixtures were conducted in a 12-kW bench-scale CFB combustor at 850 °C. Measurements of flue gas compositions were taken using an FTIR spectrometer. In all tested atmospheres, emissions of SO2, N2O, and CO for biomass were lower than those for the reference coal. The oxidatio... [more]

The gasification rate of fuel, biomass gasification in particular, is an important parameter which is worth considering in the process of creating a gasifier with a continuous operation process. The gasification of biomass is a complex thermochemical process. The theoretical and practical studies of the gasification rate of biomass are complicated because of a high thermochemical rate of reactions in the functioning zones of a gasifier. The complexity of the study prevents the achievement of the required accuracy of the analytical model of the gasification rate of biomass. The known theoretical models of the gasification rate only partially describe the dynamics of the gasification rate of biomass. Moreover, most scientific studies are focused on establishing the effects of gasifier parameters and the gasification process on the quality indicators of the received gas but not on the gasification rate of fuel. To build an accurate model of the gasification rate the authors propose a seri... [more]

A theoretical evaluation of the biochar production process using a biomass gasifier has been carried out herein. Being distinguished from the previous research trend examining the use of a biomass gasifier, which has been focused on energy efficiency, the present study tries to figure out the effect of biochar production rate on the overall process performance because biochar itself has now been given a spotlight as the main product. Biochar can be utilized for agricultural and industrial purposes, along with the benefit of climate change mitigation. A thermodynamic model based on chemical equilibrium analysis is utilized to demonstrate the effect of biochar production rate on the producer gas characteristics such as gas composition, LHV (lower heating value) and cold gas efficiency. Three gasifier models using chemical equilibrium model are reconstructed to simulate biochar-producing gasifiers, and seven kinds of biomass are considered as feed material. Depending on the assumptions ap... [more]

The large-scale integration of variable renewable energy sources into the energy system presents techno−economic challenges. Long−term energy system optimization models fail to adequately capture these challenges because of the low temporal resolution of these tools. This limitation has often been addressed either by direct improvements within the long−term models or by coupling them to higher resolution power system models. In this study, a combined approach is proposed to capitalize on the advantages and overcome the disadvantages of both methods. First, the temporal resolution of an energy model was enhanced by approximating the joint probability of the electricity load and the supply of intermittent sources. Second, the projected electricity mix was simulated by a power model at an hourly resolution. This framework was used to analyze mid−century deep decarbonization trajectories for Colombia, subject to future uncertainties of hydroclimatic variability and the development of the b... [more]

The co-torrefaction of several biomasses may be a viable solution in the study area, as it produces biofuels and addresses waste-treatment concerns. This review evaluates biomass through ultimate, proximate, and FTIR analyses, and the mechanism of the co-torrefaction process is observed for product quality with a synergistic effect. Furthermore, the parameters of co-torrefaction, including temperature, reaction time, mass yield, energy yield, and the composition of the H/C and O/C ratio of the co-torrefied materials, are similar to those for coal composition. Different reactor types, such as fixed-bed, fluidized-bed, microwave, and batch reactors, are used for co-torrefaction, in which biomass blends with optimized blend ratios. The co-torrefaction process increases the bio-solid yield and heating value, the capacity to adsorb carbon dioxide, and the renewable fuel used for gasification. One of the objectives of this study is to adopt a process that must be viable, green, and sustainab... [more]

In this study, a new method for biomass thermal treatment was introduced. The volatile organic compounds (VOCs) of Ficus hispida biomass were obtained via hydrodistillation. The qualitative analysis of VOCs performed by GC−MS and GC−FID techniques identified pentadecanal (14.65%), 2-(E)-hexenal (11.15%), and 2-butyl-5-methyl-2-hexenoic acid ethyl ester (8.53%) as the major compounds. The chemical components varied significantly from the previous study. The results of the DPPH, ABTS, and FRAP methods gave IC50 and antioxidant capacity values of 3.08 ± 0.024 mg/mL, 0.44 ± 0.009 mg/mL, and 135.64 ± 25.49 mM/g, respectively. From the results, the VOCs distilled from F. hispida leaves have an antioxidant property that can be utilized as a natural botanical supplement as an antioxidant and preservative. In addition, the present research offers additional scientific support and a chemical basis for future natural drug discovery.

In this study, an algae biomass gasification process using a dual fluidized bed with combined power and methanol cogeneration was developed. The gasification process was modeled using Aspen Plus and validated using experimental data of two microalgae species (Nannochloropsis oculata and Dunaliella salina) commonly found on the western coast of Saudi Arabia. The impacts of different operating conditions, including the gasifier temperature, steam-to-biomass ratio, and algae-char split ratio, on the compositions of four main gases (CO, CO2, CH4, and H2) were investigated. The results of the parametric studies indicated that the gasification temperature has a significant effect on the composition of the synthesis gas, where 700−850 °C was the ideal operating range for gasification. Altering the ratio of biomass to steam showed a slightly smaller effect on the synthesis gas composition. The char split ratio should be kept below 75% to ensure an adequate heat supply to the process. The propo... [more]

This paper shows a practice to raise the reliability of an electric power system by the installation of distributed generation, taking gasified biomass as fuel. To calculate the reliability index, a probabilistic load flow was used. This index is determined as the fault probability of the system. The resolution of this probabilistic load flow combines the method of cumulants and Gram−Charlier expansion. To achieve the reliability index, simulating a number of contingencies is required; the greater the number of simulated contingencies, the higher the accuracy of the index obtained. This probabilistic technique uses the random variables as starting information, so the two generators and loads are simulated as random variables. The generators of this distributed generation are biomass-fueled gas engines, commonly found in Spain. The simulations carried out on the IEEE 14-bus Test System, including three biomass generators, show that the inclusion of this type of generation improves the o... [more]

The energy sector is nowadays facing new challenges, mainly in the form of a massive shifting towards renewable energy sources as an alternative to fossil fuels and a diffusion of the distributed generation paradigm, which involves the application of small-scale energy generation systems. In this scenario, systems adopting one or more renewable energy sources and capable of producing several forms of energy along with some useful substances, such as fresh water and hydrogen, are a particularly interesting solution. A hybrid polygeneration system based on renewable energy sources can overcome operation problems regarding energy systems where only one energy source is used (solar, wind, biomass) and allows one to use an all-in-one integrated systems in order to match the different loads of a utility. From the point of view of scientific literature, medium- and large-scale systems are the most investigated; nevertheless, more and more attention has also started to be given to small-scale... [more]