Lighting provides an indispensable energy service, illumination. The field of societal exergy analysis considers light (and many other energy products) to be enablers of economic growth, and lighting contributes a non-negligible proportion of total useful exergy supplied to modern economies. In societal exergy analysis, the exergetic efficiency of electric lamps is central to determining the exergy contribution of lighting to an economy. Conventionally, societal exergy practitioners estimate the exergetic efficiency of lamps by an energy efficiency, causing confusion and, sometimes, overestimation of exergetic efficiency by a factor as large as 3. In response, we use recent results from the fields of radiation thermodynamics and photometry to develop an exact method for calculating the exergy of light and the exergetic efficiency of lamps. The exact method (a) is free of any assumptions for the value of the maximum luminous efficacy, (b) uses a non-unity spectral exergy-to-energy ratio... [more]

A photovoltaic-thermal (PVT) collector is a solar-based micro-cogeneration system which generates simultaneously heat and power for buildings. The novelty of this paper is to conduct energy and exergy analysis on PVT collector performance under two different European climate conditions. The performance of the PVT collector is compared to a photovoltaic (PV) panel. Finally, the PVT design is optimized in terms of thermal and electrical exergy efficiencies. The optimized PVT designs are compared to the PV panel performance as well. The main focus is to find out if the PVT is still competitive with the PV panel electrical output, after maximizing its thermal exergy efficiency. The PVT collector is modelled into Matlab/Simulink to evaluate its performance under varying weather conditions. The PV panel is modelled with the CARNOT toolbox library. The optimization is conducted using Matlab gamultiobj-function based on the non-dominated sorting genetic algorithm-II (NSGA-II). The results indi... [more]

This research presents the energy, exergy, economic, and environmental assessment, and multi-objective optimization of a flash-binary geothermal CCHP cycle. A sensitivity analysis of production well inlet temperature and cooling to power flow ratio on exergetic, economic, and environmental parameters was conducted. Furthermore, the effects of the inflation rate and plant working hours on economic parameters were investigated. Results showed that increasing the production well inlet temperature harms exergy efficiency and exergetic performance criteria and results in a gain in exergo-environmental impact index and heating capacity. In addition, the total plant cost increased by raising the production well temperature. Furthermore, increasing the cooling to power flow ratio caused a reduction in exergy efficiency, exergetic performance criteria, and produced net power and an enhancement in exergy destruction, cooling capacity, and total plant cost. The exergy efficiency and total cost ra... [more]

This paper contains the basic definition and application of the physical optimum as a method for process evaluation and optimization. By means of the exemplary balance of a wood pellet-fired boiler, the conventional efficiency is compared to the PhO. Furthermore, this study demonstrates the possibility of applying the thermodynamic state variable exergy as a physical reference property of a system within the PhO method. To explain the approach, the heat generation in the wood pellet-fired boiler is compared to the supply from a heat pump, which itself is connected to a power plant. Furthermore, the process-independent PhO is explained in order to illustrate the limitations of feasible optimization. Additionally, possible research topics such as the integration of dynamic behavior in the method are approached. As a conclusion, the differences between the methods outline the advantage of the PhO in the optimization process.

The production of light olefins by selective steam cracking is an energy-intensive process, and ethylene and propylene refrigeration cycles are key parts of it. The objective of this study was to identify opportunities for energy savings in an ethylene refrigeration cycle through an exergetic analysis. Two main causes of lower operational efficiency were identified: (1) Lower polytropic efficiency of the refrigerant compressor and (2) operating with the compressor mini-flow valve open to ensure reliability. The evaluation showed that the amount of irreversibilities generated by the cycle in operation is 22% higher than that predicted by the original design, which represents a 14% lower exergy efficiency. There is a potential savings of 0.20 MW in the cycle’s energy consumption with the implementation of the following improvements: recover refrigerant compressor efficiency by performing maintenance on the equipment and optimize the flow distribution between the recycle valve, the level... [more]

This paper assesses the application of the second-law of thermodynamics in a military Environmental Control Unit (ECU) to evaluate the exergy destruction (or irreversibility) in each component when operating at high ambient temperature. Experimental testings were conducted on three ECUs, 1.5 (5.3 kW), 3 (10.6 kW), and 5 (17.6 kW) tons of refrigeration (RT), to assess the potential contribution of each component to enhance the overall energy efficiency of the system, and to determine the feasibility of the thermodynamic model presented herein. The analysis provided for extreme high ambient conditions up to 51.7 °C (125 °F). The results yielded that the highest irreversibility was associated with compressors (32.4% to 42.5%). This is followed by the heat exchanges (19.6% to 32.9%) in the case of 1.5-RT and 3-RT units, whereas for the 5-RT unit, the highest irreversibility was associated with the evaporator followed by the one of the compressors. In the 3-RT ECU, the condenser’s second-la... [more]

In this study, the electrical, electrochemical and thermodynamic performance of a PV/T electrolyzer system was investigated, and the experimental results were verified with a numerical model. The annual amounts of electrical and thermal energy from the PV/T electrolyzer system were calculated as 556.8 kWh and 1912 kWh, respectively. In addition, the hydrogen production performance for the PV/T electrolyzer was compared with that of a PV electrolyzer system. The amount of hydrogen was calculated as 3.96 kg annually for the PV system, while this value was calculated as 4.49 kg for the PV/T system. Furthermore, the amount of hydrogen production was calculated as 4.59 kg for a 65 °C operation temperature. The electrical, thermal and total energy efficiencies of the PV/T system, which were obtained hourly on a daily basis, were calculated and varied between 12−13.8%, 36.1−45.2% and 49.1−58.4%, respectively. The hourly exergy analyses were also carried out on a daily basis and the results sh... [more]

Exergy is important and relevant in many areas of study such as Life Cycle Assessment (LCA), sustainability, energy systems, and the built environment. With the growing interest in the study of LCA due to the awareness of global environmental impacts, studies have been conducted on exergetic life cycle assessment for resource accounting. The aim of this paper is to review existing studies on exergetic life cycle assessment to investigate the state-of-the-art and identify the benefits and opportunity for improvement. The methodology used entailed an in-depth literature review, which involved an analysis of journal articles collected through a search of databases such as Web of Science Core Collection, Scopus, and Google Scholar. The selected articles were reviewed and analyzed, and the findings are presented in this paper. The following key conclusions were reached: (a) exergy-based methods provide an improved measure of sustainability, (b) there is an opportunity for a more comprehensi... [more]

In the last decade, particular attention has been paid to the organic Rankine cycle (ORC) power plant, a technology that implements a classical steam Rankine cycle using low-boiling fluid of organic origin. Depending on the specific application and the choice of the designer, the ORC can be optimized using one or several criteria. The selected objectives reflect various system performance aspects, such as: thermodynamic, economic, environmental or other. In this study, a novel criterion called exergy utilization index (XUI) is defined and used to maximize the utilization of an energy source in the ORC system. The maximization of the proposed indicator is equivalent to bring the heat carrier outlet temperature to the ambient temperature as close as possible. In the studied case, the XUI is applied along with the total heat transfer area of the system, and the multi-objective optimization is performed in order to determine the optimal operating conditions of the ORC. Moreover, to reveal... [more]

The energy transition from fossil-based energy sources to renewable energy sources of an industrialized country is a big challenge and needs major systemic changes to the energy supply. Such changes require a holistic view of the energy system, which includes both renewable potentials and consumption. Thereby exergy, which describes the quality of energy, must also be considered. In this work, the determination and analysis of such a holistic view of a country are presented, using Austria as an example. The methodology enables the calculation of the spatially resolved current exergy consumption, the spatially resolved current useful exergy demand and the spatially resolved technical potential of renewable energy sources (RES). Top-down and bottom-up approaches are combined in order to increase accuracy. We found that, currently, Austria cannot self-supply with exergy using only RES. Therefore, Austria should increase the efficiency of its energy system, since the overall exergy efficie... [more]

Waste heat recovery is an actual goal. The best way to valorize waste heat is to use it directly with the appropriate level of temperature. If the temperature level is insufficient, many reverse machine configurations are available in order to obtain the appropriate conditions (the most known are heat pumps and heat transformers). Finally, the remaining unused heat could be converted to any noble form of energy (mechanical, electrical essentially). We propose here to examine, with a new point of view, the thermomechanical conversion limit of waste heat. This limit corresponds to adiabatic conversion for an endo-reversible Carnot engine, with a perfect thermal contact at the atmospheric sink (supposed infinite). The Carnot−Chambadal model version is applied to latent and sensible heat recovery cases. The results associated with these two cases differ fundamentally. Comments are provided on the two studied cases, and new criteria to characterize the corresponding waste heat recovery are... [more]

Reactivity controlled compression ignition (RCCI) strategy uses two different fuels with different reactivities which provides more control over the combustion process and has the potential to dramatically lower combustion temperature and NOX and PM emissions. The objective of the present study is to numerically investigate the impact of syngas composition on the combustion and emissions characteristics of an RCCI engine operating with syngas/diesel at constant energy per cycle. For this purpose, different syngas compositions produced through gasification process have been chosen for comparison with the simulated syngas (mixture of hydrogen and carbon monoxide). The results obtained indicate that using syngas results in more soot, CO and UHC emissions compared with simulated syngas. Even though more NOX reduction can be achieved while operating with syngas, the engine could suffer from poor combustion and misfire at low loads due to the presence of nitrogen in the mixture. In terms of... [more]

The paper presents the notion of high dimensionality—in the results—that could change the exergy and energy characteristics of the two-pass solar collector. To examine the energetic aspect of the collector, two different types of absorber plate surfaces were chosen: one that is smooth and one with triangular fins. Both designs have two-pass and wooden baffles underneath their absorber plates. The induced air blower was used for the forced convection of air. To examine the attribute of the data, the least angle regression (LARS) algorithm was used to find a new exergy model without overfitting the data. The second law efficiency dropped by 18.92% for the given models of the solar collector when the air flow rate surged further from 10.10 g·s−1 to 12.10 g·s−1, whereas the energy efficiency showed contradictory behaviour for the given range of air flow rate. It increased by 3% in the first half of the rise in the air flow rate, and on the other hand, a jump of 8% was recorded in the energ... [more]

The study targeted towards drying of cantaloupe slices with various thicknesses in a microwave dryer. The experiments were carried out at three microwave powers of 180, 360, and 540 W and three thicknesses of 2, 4, and 6 mm for cantaloupe drying, and the weight variations were determined. Artificial neural networks (ANN) and adaptive neuro-fuzzy inference systems (ANFIS) were exploited to investigate energy and exergy indices of cantaloupe drying using various afore-mentioned input parameters. The results indicated that a rise in microwave power and a decline in sample thickness can significantly decrease the specific energy consumption (SEC), energy loss, exergy loss, and improvement potential (probability level of 5%). The mean SEC, energy efficiency, energy loss, thermal efficiency, dryer efficiency, exergy efficiency, exergy loss, improvement potential, and sustainability index ranged in 10.48−25.92 MJ/kg water, 16.11−47.24%, 2.65−11.24 MJ/kg water, 7.02−36.46%, 12.36−42.70%, 11.25... [more]

To ensure dominance over a multi-domain battlespace, energy and power utilization must be accurately characterized for the dissimilar operational conditions. Using MATLAB/Simulink in combination with multiple neural networks, we created a methodology which was simulated the energy dynamics of a ground vehicle in parallel to running predictive neural network (NN) based predictive algorithms to address two separate research questions: (1) can energy and exergy flow characterization be developed at a future point in time, and (2) can we use the predictive algorithms to extend the energy and exergy flow characterization and derive operational intelligence, used to inform our control based algorithms or provide optimized recommendations to a battlefield commander in real-time. Using our predictive algorithms we confirmed that the future energy and exergy flow characterizations could be generated using the NNs, which was validated through simulation using two separately created datasets, one... [more]

The cryogenic industry has been experiencing continuous progress in recent years, primarily due to the global development of oil and gas activities. Natural gas liquefaction is a cryogenic process, with the refrigeration system being crucial to the overall process. The objective of the study presented herein is to carry out an exergoeconomic assessment for a dual nitrogen expander process used to liquefy natural gas, employing the SPecific Exergy COsting (SPECO) methodology. The air coolers and throttling valve are dissipative components, which present fictitious unit cost rates that are reallocated to the final product (Liquefied Natural Gas). The liquefaction process has an exergy efficiency of 41.89%, and the specific cost of liquefied natural gas is 292.30 US$/GJ. It was verified that this cost increased along with electricity. The highest exergy destruction rates were obtained for Expander 1 and Air cooler 2. The highest average cost per exergy unit of fuel was obtained for the ve... [more]

Geothermal energy is a sustainable renewable source of energy. The installed capacity of geothermal energy in Kenya is 847.4 MWe of the total 2.7 GWe. This paper presents the effect of six different working fluids to optimize the geothermal of 21.5 MWe of reinjected brine at a single-flash power plant in Kenya. Engineering Equation Solver (EES) code was used to design and optimize simple organic Rankine (ORC) and regenerative cycles. The objective was to combine pinch point analysis and exergy analysis for the optimum utilization of geothermal energy by varying the turbine inlet pressure, pinch point, and reinjection temperature. The turbine inlet pressures, and pinch points were varied to obtain optimum pressures for higher net power output and exergy efficiencies. As the pressure increased, the efficiencies and net power generated increase to optimal at turbine inlet pressures between 2000 and 3000 kPa. By maintaining a condenser temperature at 46.7 °C, the turbine outlet pressures w... [more]

The performance of turbochargers is heavily influenced by heat transfer. Conventional investigations are commonly performed under adiabatic assumptions and are based on the first law of thermodynamics, which is insufficient for perceiving the aerothermodynamic performance of turbochargers. This study aims to experimentally investigate the non-adiabatic performance of an automotive turbocharger turbine through energy and exergy analysis, considering heat transfer impacts. It is achieved based on experimental measurements and by implementing a novel innovative power-based approach to extract the amount of heat transfer. The turbocharger is measured on a hot gas test bench in both diabatic and adiabatic conditions. Consequently, by carrying out energy and exergy balances, the amount of lost available work due to heat transfer and internal irreversibilities within the turbine is quantified. The study allows researchers to achieve a deep understanding of the impacts of heat transfer on the... [more]

This paper aims at assessing the impact of retrofitting an existing, 730 MWe, coal-fired power plant into a biomass-fired combined heat and power (CHP) plant on its energetic and exergetic performances. A comprehensive thermodynamic model of the power plant was developed and validated against field data, resulting in less than 1% deviation between the model and the measurements for the main process parameters. The validated model was then used to predict the behaviour of the biomass CHP after retrofitting. The modelled CHP unit is coupled to a steam-explosion biomass upgrading plant, a biorefinery process, and a high-temperature heat network. 13 scenarios were studied. At constant boiler load, delivering heat to the considered heat clients can increase the total energy efficiency of the plant from 44% (electricity only) to 64%, while the total exergy efficiency decreases from 39% to 35%. A total energy efficiency of 67% could be reached by lowering the network temperature from 120∘C to... [more]

The environmental performance of a combined cooling, heating, and power system is analyzed in this study at a component-level using a SPECO-based exergoenvironmental analysis. The engine consumes natural gas and produces 168.6 kW net power. The waste heat is recovered by a LiBr-H2O absorption chiller and a heat exchanger, which are used for cooling and heating purposes. The energy system is assisted by a solar field. An environmental Life Cycle Assessment quantifies the environmental impacts of the system, and these data are combined with exergy evaluations. The highest total environmental impact rate, 23,740.16 mPt/h, is related to the internal combustion engine, of which pollutant formation is the primary source of environmental impact. Compared with a non-renewable energy system, the solar-assisted trigeneration system decreased the environmental impact per exergy unit of chilled water by 10.99%. Exergoenvironmental performance can be further improved by enhancing the exergy efficie... [more]

Exergy is a thermodynamic property that represents the quantification of the maximum useful work that can be extracted from a system interacting with the environment. Regarding solar radiation, radiative exergy has been a matter of study over the last 60 years where the main models applied describe the radiation as undiluted and diluted. The exergy of solar radiation is useful in the preliminary assessment of the performance of solar technologies, since the efficiency of the system depends directly on this value. The present paper describes a review of the main models reported in the literature considering these two approaches, analysing the main differences between the models and the main assumptions applied. A comparative analysis is carried out for the models of diluted and undiluted radiation, where the behaviour of every expression is discussed in detail. For the undiluted expressions, the behaviour of every model within a temperature range is analysed. For black-body radiation at... [more]

This study applies the Physical Optimum (PhO) as a reference value to rate the efficiency of two technical options for the oxygen supply of a hospital. The systematic comparison of the alternative processes using the PhO as a benchmark for the minimum input (exergy in this case) required to run a process with a certain benefit allows to determine the potential for optimization of each technology. Differences are analyzed by visualizing the losses of each individual production step in a process as well as by the resulting overall energy demand, including the primary energy. Possible alternatives are purchasing liquid oxygen from a cryogenic process or the production by means of Pressure Swing Adsorption (PSA) on site. The cryogenic production shows a lower exergy demand even though it also has a higher potential for optimization. Yet, the total losses, significantly impacted by the unavoidable transportation, sum up, resulting in the conclusion that the PSA is the preferable option over... [more]

This paper presents a conceptual development of sustainability evaluation, through an exergy-based indicator, by using the new concept of the Thermoeconomic Environment (TEE). The exergy-based accounting methods here considered as a background are Extended Exergy Accounting (EEA), which can be used to quantify the exergy cost of externalities like labor, monetary inputs, and pollutants, and Cumulative Exergy Consumption (CExC), which can be used to quantify the consumption of primary resources embodied in a final product or service. The new concept of bioresource stock replacement cost is presented, highlighting how the framework of the TEE offers an option for evaluating the exergy cost of products of biological systems. This sustainability indicator is defined based on the exergy cost of all resources directly and indirectly consumed by the system, the equivalent exergy cost of all externalities implied in the production process and the exergy cost of the final product.

Space cooling demand is increasing globally due to climate change. Cooling has also been linked to all 17 sustainable development goals of the United Nations. Adequate cooling improves productivity and thermal comfort and can also prevent health risks. Meanwhile, policy initiatives such as the European Union’s Green Deal require participants to cut greenhouse gas emissions and reduce energy use. Therefore, novel cooling systems that are capable of efficiently producing high levels of thermal comfort are needed. Radiant cooling systems provide a design capable of fulfilling these goals, but their application in hot and humid climates is limited due to the risk of condensation. In this study, we compare the performances of radiant cooling systems with and without dehumidification. The studied systems are supplied by geothermal energy. The study is conducted using building energy models of a small office building belonging to a three-building school complex located in Sant Cugat near Barc... [more]

The residential heating sector accounts for a large share of the worldwide annual primary energy consumption. In order to reduce CO2-emissions, it is therefore particularly important to analyse this sector for potential efficiency improvements. In Europe, natural gas boilers are the most widely used heating technology since they are cost-effective and can be installed in any type of building. The energy efficiency of these boilers is already high. However, in their internal process, heat is generated at a high temperature level which is only used for space heating and therefore a high amount of exergy remains unused. This research aims to develop the potential of using the exergy to further improve the efficiency of the systems. A novel combination of methods is applied to analyse the thermodynamic behaviour of gas-fired boilers in detail and over the cycle of a year. The analysis is performed in two steps: In the first step a system is examined in stationary operating points. This is... [more]