The conditions in the combustion zones, i.e., the raceways, are crucial for the operation of the blast furnace. In recent years, advancements in tuyere cameras and image processing and interpretation techniques have provided a better means by which to obtain information from this region of the furnace. In this study, a comprehensive approach is proposed to visually monitor the status of the pulverized coal cloud at the tuyeres based on a carefully designed processing strategy. Firstly, tuyere images are preprocessed to remove noise and enhance image quality, applying the adaptive Otsu algorithm to detect the edges of the coal cloud, enabling precise delineation of the pulverized coal region. Next, a Swin−Unet model, which combines the strengths of Swin Transformer and U-Net architecture, is employed for accurate segmentation of the coal cloud area. The extracted pulverized coal cloud features are analyzed using RGB super-pixel weighting, which takes into account the variations in color... [more]

To investigate the characteristics and generation potential of gas generated from over-mature shale, hydrous and anhydrous pyrolysis experiments were carried out on the Longmaxi Formation in the Anwen 1 well of the Sichuan Basin of China at temperatures of 400−598 °C and pressures of 50 Mpa, with (hydrous) and without (anhydrous) the addition of liquid water. The results show that in the presence of water, the total yield of carbon-containing gases (i.e., the sum of methane, ethane, and carbon dioxide) was increased by up to 1.8 times when compared to the total yield from the anhydrous pyrolysis experiments. The increased yield of carbon dioxide and methane accounted for 89% and 10.5% of the total increased yield of carbon-containing gases. This indicated that the participation of water could have promoted the release of carbon from over-mature shale, like we used in this study. The methane generated in the hydrous pyrolysis experiments was heavier, with a δ13C value of −21.27‱ (544 °C... [more]

The design for the remanufacturing process (DFRP) is a key part of remanufacturing, which directly affects the cost, performance, and carbon emission of used product remanufacturing. However, used parts have various failure forms and defects, which make it hard to rapidly generate the remanufacturing process scheme for simultaneously satisfying remanufacturing requirements regarding cost, performance, and carbon emissions. This causes remanufactured products to lose their energy-saving and emission-reduction benefits. To this end, this paper proposes an integrated design method for the used product remanufacturing process based on the multi-objective optimization model. Firstly, an integrated DFRP framework is constructed, including design information acquisition, the virtual model construction of DFRP solutions, and the multi-objective optimization of the remanufacturing process scheme. Then, the design matrix, sensitivity analysis, and least squares are applied to construct the mappi... [more]

It is generally accepted that organic−inorganic interactions involving H-rich fluids (i.e., H2O and H2) contribute significantly to hydrocarbon (HC) generation in sedimentary basins. However, the effects of two hydrogenation processes involving H2O and H2 on the generation and C/H isotope fractionation of HC gases from organic matter (OM) remain unclear. In this study, two groups of hydrothermal experiments involving low-mature kerogen without (Group 1) and with FeS (Group 2) at 330−420 °C and 50 MPa were conducted to simulate the hydrogenation of OM by H2O and H2, respectively. The experimental results show that the redox reactions between H2O and FeS lead to the generation of considerable amounts of H2 in the Group 2 experiments. HC gas yield in the Group 2 experiments reaches 1.8−3.6 times that in the Group 1 experiments at Easy%Ro of 1.05−2.50%. In addition, indirect hydrogenation via H2O-derived H2 generates HC gases with smaller 13C fractionation and more negative δ2H compared wi... [more]

Fossil fuel extraction and utilization are associated with several environmental issues. This study examined how altering the blending proportions of mixed diesel/biodiesel/n-butanol fuels impacts combustion. Additionally, it delved into the functioning of diesel engines when utilizing these blended fuels as well as conventional diesel. A three-dimensional fluid dynamics simulation was constructed and corroborated against test outcomes obtained at 25%, 50%, 75%, and 100% loads. The findings indicated that the n-butanol addition enhanced the indicated thermal efficiency. At a 100% load, D70B30 (70% diesel + 30% biodiesel), D70B25BU5 (70% diesel + 25% biodiesel + 5%N-butanol), D70B20BU10, and D70B10BU20 exhibited 4.76%, 5.75%, 6.79%, and 8.71% higher indicated thermal efficiency values than D100 (100% diesel), respectively. The introduction of butanol enhanced the combustion environment within the combustion chamber. Compared with pure diesel, all blended fuels reduced hydrocarbon and ca... [more]

Burning hydrogen-rich syngas fuels derived from various sources in combustion equipment is an effective pathway to enhance energy security and of significant practical implications. Emissions from the combustion of hydrogen-rich fuels have been a main concern in both academia and industry. In this study, the NO and CO emission characteristics of both laminar and turbulent counterflow premixed hydrogen-rich syngas/air flames were experimentally and numerically studied. The results showed that for both laminar and turbulent counterflow premixed flames, the peak NO mole fraction increased as the equivalence ratio increased from 0.6 to 1.0 and decreased as the strain rate increased. Compared with the laminar flames at the same bulk flow velocity, turbulent flames demonstrated a lower peak NO mole fraction but broader NO formation region. Using the analogy theorem, a one-dimensional turbulent counterflow flame model was established, and the numerical results indicated that the small-scale t... [more]

The integration of theoretical insights and current findings in the articles included in this Special Issue holds the potential to bridge the gap between academic research and real-world challenges in enhancing physical−chemical processes [...]

This work highlights the frustration that a researcher may face when trying to convince people in industries to use a new technology that has been developed in a small-scale laboratory. A moderate-reaction-severity process for hydrotreating of heavy crude oil (HIDRO-IMP technology) in fixed-bed reactors is used as an example. Although the development of such a technology has been scaled-up from bench and pilot-plant scales to a semi-commercial level with positive technical and economical results, the people in petroleum refinery who make decisions on the suitability of technologies for commercial implementation always ask for previous applications of the process developed. The different stages of development of the HIDRO-IMP technology are commented on, and some results that corroborate its feasibility for commercial application are discussed.

In the pursuit of understanding the oxidation mechanisms of hydrogenated biodiesel fuels and elucidating the combustion behavior of biomass fuels when blended with diesel, this study presents a comprehensive investigation into the reaction mechanism of hydrogenated biodiesel−ethanol−diesel mixtures. We develop a comprehensive reaction mechanism encompassing 187 components and 735 reactions for hydrogenated biodiesel−ethanol−diesel mixtures. Through kinetics analysis under varied conditions, including 1.0 MPa pressure, an equivalence ratio of 1.0, and temperatures of 900 K and 1400 K, we explore the impact of cross-reactions and changing fuel blend ratios on low- and high-temperature oxidation. Our findings indicate that oleic and stearic acid methyl esters serve as better substitutes for representing hydrogenated biodiesel kinetics than methyl decanoate. At lower temperatures, increased hydrogenated biodiesel and ethanol content leads to reduced OH generation, impacting reactivity. Con... [more]

Casing deformation is evident during the development of shale oil and gas wells in the Sichuan and Junggar Basins in China. Their casing deformation characteristics, distribution law of deformation points, and main controlling factors were analyzed. According to the analysis results, shear is the main cause of casing deformation of shale oil and gas wells in the Sichuan and Junggar Basins in China and has the characteristics of “a dense heel end and a sparse toe end”. Faults account for 75% of casing deformation points, and fault slip caused by multi-stage fracturing is the primary factor responsible. The calculation model for fault slip that takes into account fracturing fluid invasion was established, and the dynamic variation law of fault slip was clarified: the fracturing fluid intruded into the fault, the relative dislocation of the damaged fault was caused by gravity, and the fault slippage was caused by the increase in fault activation length. This resulted in a linear increase... [more]

Renewable energy integration is a crucial approach for achieving a low-carbon energy supply in industrial utility systems. However, the uncertainty of user demand often leads to a mismatch between the system’s real operating conditions and the optimal operating points, resulting in energy wastage and high emissions. This study presents a multi-source heat and power system that integrates biomass gasification, solar collecting, solid oxide fuel cell (SOFC), gas turbine, and steam power systems. A scheduling strategy that varies the heat-to-power ratio is proposed to accommodate changes in user requirements. A simulation model of this multi-source system is established and validated. The influence of three key parameters on system performance under different configurations is explored. Energy and economic evaluations are conducted for three different configurations, and the system’s energy production and adjustable range are determined. The analysis reveals that, under the optimal config... [more]

With the increasing popularity and development of electric vehicles, the demand for electric vehicle charging is also constantly increasing. To meet the diverse charging needs of electric vehicle users and improve the efficiency of charging infrastructure, this study proposes an optimization strategy for electric vehicle charging and discharging. This method considers both the user’s travel mode and the operational efficiency of the charging pile. Firstly, a probability model based on travel spatiotemporal variables and Monte Carlo algorithm were used to simulate the travel trajectory of electric vehicles, providing a data foundation for optimizing the charging and discharging schemes of electric vehicles. Then, with the dual objective of minimizing the operating costs of charging piles and user charging costs, a linear programming model was constructed to optimize the charging and discharging strategies of electric vehicles. Finally, the model was validated using an apartment building... [more]

The microwave drying of sewage sludge is characterized by its speed and safety. A novel method for identifying free and bound water is proposed in this study. Experiments were performed to investigate the process performance and energy consumption in a microwave drying unit. The results indicate that the microwave drying process can be described in three stages, i.e., the preheating stage, constant-rate stage, and decreasing-rate stage. The preheating and constant-rate stages mainly remove free water, while the decreasing-rate stage mainly removes bound water. The Linear model effectively describes the kinetic processes in the constant-rate stage, and the modified Page I model is suitable for describing the decreasing-rate stage. The energy conversion process in microwave drying is explored, revealing that heat efficiency and energy consumption are consistent with microwave power changes. The heat efficiency in the constant-rate drying stage ranges from 60.33% to 71.01%, lower than tha... [more]

Nowadays, the environmental challenges associated with plastics are becoming increasingly prominent, making the exploitation of alternatives to landfill disposal a pressing concern. Particularly, polyvinyl chloride (PVC), characterized by its high chlorine content, poses a major environmental risk during degradation. Furthermore, PVC recycling and recovery present considerable challenges. This study aims to optimize the PVC pyrolysis valorization process to produce effective adsorbents for removing contaminants from gaseous effluents, especially CO2. For this purpose, PVC waste was pyrolyzed under varied conditions, and the resulting solid fraction was subjected to a series of chemical and physical activations by means of hydroxides (NaOH and KOH) and nitrogen. Characterization of the PVC-based activated carbons was carried out using surface morphology (SEM), N2 adsorption/desorption, elemental analysis, and FTIR, and their capacity to capture CO2 was assessed. Finally, neuro-fuzzy mod... [more]

In response to the challenges of global warming and the development of A low-carbon economy, the integrated electricity and natural gas energy system (IEGES) is known as an important structure for future energy supply; thus, its planning and design must take low-carbon and environmental protection factors into account. Regarding carbon emissions as an optimization criterion, this paper built life-cycle carbon emission models of IEGES components. Then, taking the capacities of the energy resources, storage and conversion units of IEGES as the optimization variables, a multi-objective optimization configuration model was established considering the annual investment operation cost and the life-cycle carbon emissions. The multi-objective model was transformed into a single-objective one by an ε-constraint approach and the polynomial fitting method was employed to obtain the value of ε for obtaining uniformly distributed Pareto sets. Based on the fuzzy entropy weight method and the fuzzy a... [more]

Pump-turbines experience complex flow phenomena and fluid−structure interactions during transient operations, which can significantly impact their stability and performance. This paper presents a comprehensive field test study of the pump mode startup process for a 150 MW prototype pump-turbine. By analyzing pressure fluctuations, structural vibrations, and their short-time Fourier transform (STFT) results, multiple stages were identified, each exhibiting distinct characteristics. These characteristics were influenced by factors such as runner rotation, free surface sloshing in the draft tube, and rotor−stator interactions. The natural frequencies of the metallic components varied during the speed-up and water-filling stages, potentially due to gyroscopic effects or stress-stiffening phenomena. The opening of the guide vanes and dewatering valve inside the guide vanes significantly altered the amplitude of the rotor−stator interaction frequency, transitioning the vibration behavior fro... [more]

The research on the deep coalbed methane (CBM) in the Ordos Basin is mostly concentrated on the eastern margin of the basin. The geological resources of the Benxi Formation in the Yulin area, located in the central-eastern part, cover 15,000 × 108 m3, indicating enormous resource potential. However, the characteristics of the reservoir distribution and the favorable areas are not yet clear. This research comprehensively performed data logging, coal rock experiments, and core observations to identify the geological characteristics of the #8 coal seam, using a multi-level fuzzy mathematics method to evaluate the favorable area. The results indicate the following: (1) The thickness of the #8 coal in the Yulin Block ranges from 2.20 m to 11.37 m, with depths of between 2285.72 m and 3282.98 m, and it is mainly underlain by mudstone; the gas content ranges from 9.74 m3/t to 23.38 m3/t, showing a northwest−low and southeast−high trend. The overall area contains low-permeability reservoirs, w... [more]

Carbonic anhydrase (CA)-based biological CO2 capture is emerging as a prominent carbon capture and storage (CCS) technology. We developed a tagged CA−Ferritin chimera, resulting in a high-purity, high-activity, micrometer-sized CA aggregate, SazF, with a yield of 576.6 mg/L (protein/medium). SazF has an optimum temperature of 50 °C and demonstrates thermal stability between 40 and 60 °C. It operates efficiently in Tris−HCl buffer (pH = 8−9), making it compatible with ship exhaust conditions. For enhanced stability and reusability, SazF was encapsulated in SiO2 and integrated into an epoxy resin to produce a corrosion-active coating. This coating, applied to foam metal fillers, showed less than 3% protein leakage after ten days and retained over 70% activity after a month at 60 °C. This simple preparation method and the cost-effective production of these biomaterials that can continuously and efficiently absorb CO2 in high-temperature environments are suitable for most CO2 capture devic... [more]

This paper introduces a novel and cost-effective method for detecting adulterated diesel, specifically targeting contamination with kerosene, by leveraging machine learning and the refractive index values of mixed diesel samples. It proposes a laser-based sensor, employing COMSOL simulations for synthetic data generation to facilitate machine learning training. This innovative approach not only streamlines the detection process by eliminating the need for expensive equipment and specialized personnel but also enables on-site testing without extensive sample preparation. The sensor’s design, utilizing light refraction and reflection principles, allows for the accurate measurement of diesel adulteration levels. Validation results showcase the machine learning models’ high precision in predicting adulteration percentages, as evidenced by an R-squared value of 0.999 and a mean absolute error of 0.074. This research signifies a leap in sensor technology, offering a practical solution for ra... [more]

Anaerobic co-digestion (AnCoD) presents several advantages over conventional mono-digestion. Various factors can impact the efficiency of the co-digestion process, including the mixing ratio of the feedstocks. This study primarily investigates the effects of different mixing ratios on methane production during the co-digestion of source-separated municipal organic waste (SSO) with thickened waste activated sludge (TWAS). While the C/N or COD/N ratio has generally been used for optimizing the mixing ratios of co-digested feedstocks, a new approach is introduced in this study to evaluate the effects of the lipid, protein, and carbohydrate (L:P:C) ratios on the efficiency of AnCoD with respect to methane production, kinetics, and synergism at mixing ratios of TWAS:SSO of 10:90, 30:70, 50:50, 70:30, and 10:90. AnCoD improved methane production and kinetics relative to TWAS at all mixing ratios, the highest of which was at the 10:90 ratio, corresponding to a methane yield, maximum methane p... [more]

Shale reservoirs typically exhibit high density, necessitating the use of horizontal wells and hydraulic fracturing techniques for efficient extraction. Proppants are commonly employed in hydraulic fracturing to prevent crack closure. However, limited research has been conducted on the impact of shale mineral composition and proppant filling patterns on shale stress sensitivity. In this study, shale cylindrical core samples from two different lithologies in Jimusaer, Xinjiang in China were selected. The mineral composition and microscopic structures were tested, and a self-designed stress sensitivity testing system was employed to conduct stress sensitivity tests on natural cores and fractured cores with different proppant filling patterns. The experimental results indicate that the stress sensitivity of natural shale porous cores is weaker, with a stress sensitivity coefficient below 0.03, significantly lower than that of fractured cores. The shale mineral composition has a significan... [more]

This article describes the results of a comprehensive comparative study of the production of fatty acid ethyl esters (FAEEs) for use as biodiesel in perfect mixing reactors (PMRs) and plug flow reactors (PFRs). The products obtained on a laboratory scale at all stages of the separation and purification of the FAEE phase were analyzed using the FTIR, XRF and GC-MS methods. We compared distillation methods for the separation of stoichiometrically excessive ethanol from the reaction mixture. Neutralization methods with H2SO4 solution and carbonation with CO2 were applied for FAEE phase purification from the catalyst. Emulsions formed during the water flushing stage were analyzed via the optical microscopy method. The optimal conditions of stirring speed and temperature were selected to maintain a high level of FAEE−water phase contact area with minimum phase separation time. The efficiency of the carbonation method for catalyst neutralization in the FAEE phase has been proven, allowing us... [more]

In this paper, coal measure kaolin after flotation decarburization was made into an adsorbent by ball milling and acid modification to absorb methylene blue in water, achieving the treatment of waste with waste. The objective of this paper is to expand the application of coal measure kaolin, reduce its stock, and lower the raw material cost of adsorbents while treating wastewater containing methylene blue. The optimum milling time, acid boiling conditions, and adsorption conditions were investigated. Furthermore, the adsorption mechanism was investigated by kinetic calculation. The results show that the optimum milling time is 7 h. Relatively good acid modification conditions include a boiling temperature of 100 °C, a stirring time of 135 min, a stirring speed of 1000 r·min−1, and a concentration of hydrochloric acid of 8 mol·L−1. When 0.05 g of flotation kaolin adsorbent was used to adsorb the solution with pH 12 and a methylene blue concentration of 100 mg·L−1, the optimal adsorption... [more]

Blending with light oil is a commonly used and reliable method of crude oil transportation, and the blending ratio is a crucial operating parameter in determining the safe and efficient operation of the pipeline. In this paper, in-house flow and deposition experiments are used to evaluate the flow and deposition characteristics of crude oils with varying blending ratios. The results show that (1) blending with light oil basically does not affect the shape of the DSC curve of crude oil; (2) blending with light oil will not eliminate the thermal treatment effect, and the mixed oil flowability still remains highly dependent on the thermal treatment temperature; (3) blending with light oil can greatly decrease the abnormal point and oil viscosity, in which the low-temperature viscosity decreases more significantly; and (4) a wax deposition model of mixed oil is obtained through the fitting of Huang’s model, where the blending ratio is a crucial factor in the determination of the model para... [more]

Desalination plants, which provide drinking water for residents, rely on electricity generated by fossil fuels. However, the excessive use of fossil fuels leads to their rapid depletion and has detrimental effects on the environment. Thus, the use of renewable energy resources in water desalination has gained popularity. The current research investigates the integration of renewable energy systems with seawater and brackish water desalination technologies. In this regard, three primary renewable energy sources—wind, solar, and geothermal—are selected. Accordingly, a thorough investigation of the related research published and the trend of evolutions between 2013 and 2023 is carried out for Reverse Osmosis (RO), Multistage flash (MSF), and Multi-effect distillation (MED)-based water desalination facilities coupled with renewable energy sources. In our investigation, we particularly focus on performance indicators, energy efficiency, economic factors, and environmental effects. Also, the... [more]