Abstract
In the pursuit of understanding the oxidation mechanisms of hydrogenated biodiesel fuels and elucidating the combustion behavior of biomass fuels when blended with diesel, this study presents a comprehensive investigation into the reaction mechanism of hydrogenated biodiesel−ethanol−diesel mixtures. We develop a comprehensive reaction mechanism encompassing 187 components and 735 reactions for hydrogenated biodiesel−ethanol−diesel mixtures. Through kinetics analysis under varied conditions, including 1.0 MPa pressure, an equivalence ratio of 1.0, and temperatures of 900 K and 1400 K, we explore the impact of cross-reactions and changing fuel blend ratios on low- and high-temperature oxidation. Our findings indicate that oleic and stearic acid methyl esters serve as better substitutes for representing hydrogenated biodiesel kinetics than methyl decanoate. At lower temperatures, increased hydrogenated biodiesel and ethanol content leads to reduced OH generation, impacting reactivity. Conversely, higher temperatures result in enhanced OH production with increased hydrogenated biodiesel and ethanol concentrations, promoting reactivity. A cross-reaction analysis reveals CH2O as a prominent product, with the CH2O→HCO→CO pathway playing a pivotal role. In summary, our research unveils the intricate oxidation mechanisms of hydrogenated biodiesel−ethanol−diesel mixtures, providing insights into their combustion characteristics and offering implications for optimizing fuel blends for cleaner and more efficient energy solutions.