Traditional research on apparent permeability in shale reservoirs has mainly focussed on effects such as poromechanics and porosity-assisted adsorption layers. However, for a more realistic representation of field conditions, a comprehensive multi-scale and multi-flowing mechanism model, considering the fracturing process, has not been thoroughly explored. To address this research gap, this study introduces an innovative workflow for dynamic permeability assessment. Initially, an accurate description of the pore size distribution (PSD) within three major mineral types in shale is developed using focussed ion beam-scanning electron microscopy (FIB-SEM) and nuclear magnetic resonance (NMR) data. Subsequently, an apparent permeability model is established by combining the PSD data, leading to the derivation of dynamic permeability. Finally, the PSD-related dynamic permeability model is refined by incorporating the effects of imbibition resulting from the fracturing process preceding shale... [more]

This work investigated hydrogen production from biomass feedstocks (i.e., glucose, starch, lignin and cellulose) using a 100 mL h-type proton exchange membrane electrolysis cell. Biomass electrolysis is a promising process for hydrogen production, although low in technology readiness level, but with a series of recognised advantages: (i) lower-temperature conditions (compared to thermochemical processes), (ii) minimal energy consumption and low-cost post-production, (iii) potential to synthesise high-volume H2 and (iv) smaller carbon footprint compared to thermochemical processes. A Lewis acid (FeCl3) was employed as a charge carrier and redox medium to aid in the depolymerisation/oxidation of biomass components. A comprehensive analysis was conducted, measuring the H2 and CO2 emission volume and performing electrochemical analysis (i.e., linear sweep voltammetry and chronoamperometry) to better understand the process. For the first time, the influence of temperature on current density... [more]

This paper proposes a high-efficiency and compact fuel cell−battery hybrid power system without DC/DC converters. Generally, fuel cells supply power to charge lithium batteries or loads using DC/DC converters. The disadvantages of a DC/DC converter are its complex design, poor efficiency, and large volume. Therefore, improvements in the volume, weight, and efficiency are the main objectives of the proposed topology, which is suitable for stable operation in power equipment. This paper proposes a novel topology without DC/DC converters for a fuel cell−battery hybrid forklift system and analyzes, discusses, and verifies it with experimental measurements. Additionally, the proposed topology uses an average charging method to charge the Li-ion battery. The dynamic response of fuel cells is slower than that of Li-ion batteries. By properly configuring the voltages of a fuel cell and a lithium battery, we propose a hybrid system that can maintain a stable output and high efficiency in differ... [more]

The research program “Engineered Artificial Minerals (EnAM)” addresses the challenge of recycling valuable elements from battery waste streams. These elements, such as lithium (Li), often migrate in the slag phase, in some cases as crystals. EnAM crystals represent concentrated reservoirs of these elements, which can only be effectively recycled if they are extracted from the slag matrix and then separated. Selective wet agglomeration is a separation process based on a three-phase system and is often used in coal and ore processing. The produced agglomerates in this process can be easily separated from the remaining suspension. The precise quantification of the wetting properties and adhesion strength between suspended particles and binding liquid droplets is a scientific challenge. An accurate technique suitable for adhesion force measurements in three-phase systems with micrometer-scale particles is Fluidic Force Microscopy (FluidFM®). An experimental setup with optical control is be... [more]

Considering energy conversion efficiency, pollution emissions, and economic benefits, combining biomass with fossil fuels in power generation facilities is a viable approach to address prevailing energy deficits and environmental challenges. This research aimed to investigate the thermodynamic and exergoeconomic performance of a novel power and cooling cogeneration system based on a natural gas−biomass dual fuel gas turbine (DFGT). In this system, a steam Rankine cycle (SRC), a single-effect absorption chiller (SEAC), and an organic Rankine cycle (ORC) are employed as bottoming cycles for the waste heat cascade utilization of the DFGT. The effects of main operating parameters on the performance criteria are examined, and multi-objective optimization is accomplished with a genetic algorithm using exergy efficiency and the sum unit cost of the product (SUCP) as the objective functions. The results demonstrate the higher energy utilization efficiency of the proposed system with the therma... [more]

The automotive air conditioning (AC) electromagnetic clutch plays a crucial role in accurately controlling power transmission between the engine and the compressor, ensuring the proper operation of the AC system. The aim of this paper is to provide high-quality experimental data for researchers who are interested in simulating the dynamic process of an AC electromagnetic clutch and also to assess the adaptiveness of empirical equations to describe the AC electromagnetic clutch performance that is limited in discussion in existing studies. In this study, an automotive AC electromagnetic clutch characteristic test system was employed along with an infrared (IR) camera to conduct comprehensive experimental analyses. The test system enabled the evaluation of various parameters, including the clutch torque output, compressor exhaust pressure, and temperature of the friction surface. The results revealed that the torque and exhaust pressure were closely associated with the on/off time and ro... [more]

Hydraulic vibrations in Francis turbines caused by cavitation profoundly impact the overall hydraulic performance and operational stability. Therefore, to investigate the influence of cavitation phenomena under high-load conditions, a three-dimensional unsteady numerical simulation is carried out for a Francis turbine with different head operating conditions, which is combined with the SST k-w turbulence model and two-phase flow cavitation model to capture the evolution of cavitation under high-load conditions. Additionally, utilizing entropy production theory, the hydraulic losses of the Francis turbine during cavitation development are assessed. Contrary to the pressure-drop method, the entropy production theory can quantitatively reflect the characteristics of the local hydraulic loss distribution, with a calculated error coefficient τ not exceeding 2%. The specific findings include: the primary sources of energy loss inside the turbine are the airfoil cavitation and cavitation vort... [more]

High-performance aeroengine design is an important component of modern industry, and advanced sealing technology is a key technology to meet the engine fuel consumption rate, thrust-to-weight ratio, pollutant emission, durability, and lifetime. Reducing the internal airflow leakage of the engine through a sealing technology can improve the performance and efficiency of the engine. In this paper, the typical sealing technology for an aeroengine is introduced in more detail, including the structural characteristics and use limitations of the labyrinth seal, brush seal, honeycomb seal, gas film face seal, and cylindrical gas film seal. It focuses on the development history, typical structure type, working principle, basic technology research method, steady-state performance, dynamic characteristics, multi-physical field coupling, structural deformation, experimental testing, processing technology. Finally, it summarizes the problems and future development trends of the current application... [more]

With the continuous breakthrough of natural language processing, the application of intelligent question-answering technology in electric power systems has attracted wide attention. However, at present, the traditional question-answering system has poor performance and is difficult to apply in engineering practice. This paper proposes an improved BERTserini algorithm for the intelligent answering of electric power regulations based on a BERT model. The proposed algorithm is implemented in two stages. The first stage is the text-segmentation stage, where a multi-document long text preprocessing technique is utilized that accommodates the rules and regulations text, and then Anserini is used to extract paragraphs with high relevance to the given question. The second stage is the answer-generation and source-retrieval stage, where a two-step fine-tuning based on the Chinese BERT model is applied to generate precise answers based on given questions, while the information regarding document... [more]

The study of crude oil oxidation characteristics is fundamental to the design of ignition in situ combustion. Experimentation is the most crucial method for studying the oxidation characteristics of crude oil. Aiming to address the challenges posed by high temperature, high pressure, and rapid temperature changes during the combustion of crude oil, a dynamic simulation system for high-temperature and high-pressure ignition is designed. In order to study the oxidation characteristics of the crude oil ignition process, we conducted experiments using a high-temperature and high-pressure dynamic ignition simulation device. The experiments focused on determining the ignition point of crude oil under different pressure conditions, oil−water ratios, heating rates, gas injection rates, and other relevant characteristics. The kinetic model for the oxidation process of crude oil ignition was established. The kinetic parameters were calculated for different ignition conditions and the apparent ac... [more]

As one of the most ideal alternative fuels for internal combustion engines, methanol can achieve near-zero carbon emissions. The main problem of methanol application in compression combustion engines is the phase lag caused by its poor combustion characteristics, but under low load conditions, the fuel activity can be improved by adding the cetane number improver EHN (Isooctyl nitrate), and the dependence on intake heating can be reduced to a certain extent. Based on a three-dimensional CFD simulation, the effects of methanol injection parameters and the addition of EHN on the combustion characteristics of a four-stroke exhaust turbocharged diesel engine were studied in this paper. With or without EHN, the increase in injection pressure and the advance in injection timing lead to an increase in the peak temperature, pressure, and heat release rate, as well as a shortening of the combustion duration. Adding EHN witnesses reduced requirements for methanol ignition, including a decreased... [more]

Understanding the influence of environmental boundary parameters on the through-flow characteristics of two-stage supercharged centrifugal compressors is the key to maximizing the power recovery potential of diesel engines at high altitudes. In this paper, the influence of the compressor through-flow characteristics on the full-load thermal cycle performance of a diesel engine under variable altitude is studied by means of tests and simulation. The results show that with the increase in altitude, the range of stable work flow decreases, and the pressure ratio of the plugging point changes greatly with altitude. The efficiency of the compressor with the same mass flow point decreases, and the highest efficiency point moves in the direction of the small flow range. With the goal of maximizing the torque of the diesel engine under full load and low speed, the key geometric parameters of the variable-altitude through-flow characteristics of the two-stage supercharged compressor were optimi... [more]

Extensive research has been conducted on the performance of pump turbines, particularly focused on understanding the generation mechanism of S-shaped characteristics. However, there has been a lack of research on unsteady flow characteristics in hump characteristics with small guide vane openings. This study focuses on the hump characteristics of a pump turbine in pump mode. The unsteady numerical simulation method is used along with experimental testing to examine the internal flow characteristics and induced pressure fluctuations under pump operating conditions. The results indicate that flow separation occurs in the impeller when the flow rate decreases to the valley operating condition, and recirculation flow occurs near the impeller inlet at the partial flow rate. Moreover, the unstable flow on the positive slope exhibits a low-frequency characteristic of 0.15fn. The pressure fluctuation from the hub to shroud areas of the guide vane region diminishes sequentially. Notably, distin... [more]

H2 production via membrane-assisted steam methane reforming (MA-SMR) can ensure higher energy efficiency and lower emissions compared to conventional reforming processes (SMR). Ceramic-supported Pd−Ag membranes have been extensively investigated for membrane-assisted steam methane reforming applications, with outstanding performance. However, costs, sealings for integration in the reactor structure, and resistance to solicitations remain challenging issues. In this work, the surface quality of a low-cost, porous Hastelloy-X filter is improved by asymmetric filling with α-Al2O3 of decreasing size and deposition of γ-Al2O3 as an interdiffusion barrier. On the modified support, a thin Pd−Ag layer was deposited via electroless plating (ELP), resulting in a membrane with H2/N2 selectivity >10,000. The permeation characteristics of the membrane were studied, followed by testing for membrane-assisted methane steam reforming. The results showed the ability of the membrane reactor to overcome t... [more]

The rising global demand for animal-based food has an increasingly detrimental ecological impact, exacerbated by significant food waste (approximately one-third of all food). This research aimed to analyze the possibility of changing the usually balanced feed with sustainable alternatives that remain as a by-product of the production of farms, grain processing, and breweries, thus promoting the sustainability of agriculture. The mealworm larvae were reared on different substrates: (1) agar-agar gels, wheat bran, and brewer’s yeast, (2) carrots, wheat bran, and brewer’s yeast, (3) sprouted potatoes, wheat bran, and brewer’s yeast, and (4) carrots, brewers’ spent grain and brewer’s yeast. For analysis, the frozen larvae were lyophilized and tested for chemical safety in three accredited laboratories. The results have shown that all tested samples had lower levels of pesticides than the detection limit. In scientific literature, we didn’t find studies on polycyclic aromatic hydrocarbons (... [more]

Recently, many efforts have been made to reuse spent batteries in response to the growing demand for sustainable materials production. In parallel, supercapacitors have attracted significant attention for their use in addressing some of the limitations of conventional capacitors and batteries. In this context, this paper describes the preparation, characterization, and supercapacitive performance evaluation of carbon-graphite (CG) electrodes obtained from spent zinc−carbon batteries and modified with polypyrrole (PPY) and polyaniline (PANI). The parameters of PPY and PANI electropolymerization were optimized. CG/PPY, CG/PANI, and CG/PPY/PANI electrodes were obtained to compare their electrochemical responses. Cyclic voltammetry (CV), galvanostatic charge−discharge curves (GCDC), and electrochemical impedance spectroscopy (EIS) were used to evaluate the pseudocapacitive properties of the CG/PPY/PANI-modified electrode. The CG/PPY/PANI electrode showed a specific capacitance of 3416 mF c... [more]

This study presents an aerostructural optimization process for wind turbine blades aimed at enhancing the turbine’s performance. The optimization framework integrates DAFoam as the computational fluid dynamics (CFD) solver, TACS as the finite element method (FEM) solver, Mphys for fluid−structure coupling, and SNOPT as the optimizer within the OpenMDAO framework. The objective is to simultaneously increase the torque generated by the wind turbine while decreasing the mass of the blade, thereby improving its efficiency. The design variables in this optimization process are the blade shape and panel thickness. The aerodynamic objective function is torque, a key performance indicator for wind turbine efficiency. The structural objective function is the blade mass, as reducing mass is essential to minimize material and manufacturing costs. The optimization process utilizes the integrated capabilities of DAFoam, TACS, Mphys, and SNOPT to iteratively evaluate and modify the blade shape and p... [more]

Coal is complex as it includes organic matter (macerals) and inorganic matter (minerals) [...]

To accurately evaluate the size and distribution characteristics of the emission particles exhausted from in-use motor vehicle engines, we independently developed a condensation particle counter (CPC) known as BHCPC. It was calibrated by conducting the calibration procedures stated in the International Standard ISO 27981. After calibration, we conducted on-site measurements and offline sampling analysis of soot particles exhausted from different engines at a motor vehicle inspection center. The calibration results show that the detection efficiency is 90% when the particle diameter is 20.6 nm and the startup response time of the instrument is 3.53 s. The experiment results show that the self-developed BHCPC demonstrates good consistency in measuring particle-number concentration (PNC) in motor vehicle exhaust, with significant count fluctuations only occurring when PNC is higher than 25,000 P/cc. Under idle conditions, motor vehicles compliant with China VI emission regulations exhibit... [more]

Aiming at the problem that the energy consumption of the boiler system varies greatly under the flexible peaking requirements of coal-fired units, an energy consumption prediction model for the boiler system is established based on a Least-Squares Support Vector Machine (LSSVM). First, the Mean Impact Value (MIV) algorithm is used to simplify the input characteristics of the model and determine the key operating parameters that affect energy consumption. Secondly, the Snow Ablation Optimizer (SAO) with tent map, adaptive t-distribution, and the opposites learning mechanism is introduced to determine the parameters in the prediction model. On this basis, based on the operation data of an ultra-supercritical coal-fired unit in Xinjiang, China, the boiler energy consumption dataset under variable load is established based on the theory of fuel specific consumption. The proposed prediction model is used to predict and analyze the boiler energy consumption, and a comparison is made with oth... [more]

At present, there have been a number of hydrogen storage tank explosions in hydrogen filling stations, causing casualties and property losses, and having a bad social impact. This has made people realize that the risk assessment and preventive maintenance of hydrogen storage tanks are crucial. Therefore, this paper innovatively proposes a comprehensive risk assessment model based on connection coefficient algorithms and quintuple subtractive set pair potential. First of all, the constructed index system contains five aspects of corrosion factors, material factors, environmental factors, institutional factors and human factors. Secondly, a combined weighting analysis method based on FAHP and CRITIC is proposed to determine the weight of each indicator. The basic indicators influencing hydrogen storage tanks are analyzed via the quintuple subtraction set pair potential and full partial connection coefficient. Finally, the risk level and development trend of hydrogen storage tanks in hydr... [more]

Bioglycerol is a major by-product of the biodiesel manufacturing process. Various chemical derivatives from bioglycerol would enhance its economic value. An antifreeze of glycerine acetate was chemically converted from an esterification reaction of bioglycerol with acetic acid. The photocatalyst TiO2/SO42− irradiated with ultraviolet light assisted the chemical conversion reaction. The molar ratio of acetic acid/bioglycerol was varied to obtain the optimum composition of the derived antifreeze product. Different cosolvents were considered to enhance the homogeneous extent between the antifreeze of glycerine acetate and biodiesel, and thus, the anti-freezing effect. The cosolvent/glycerine acetate, at various volumetric ratios from 0 to 0.25 vol.%, was blended into a commercial biodiesel. After 5 vol.% antifreeze of the glycerine acetate/cosolvent mixture of the biodiesel was added to the commercial biodiesel, the fuel properties of the biodiesel were analyzed. The effects of the cosolv... [more]

The impact of particle addition jets on the flow field in natural gas pipelines was investigated, and the structural information of the flow field at different flow velocities in a symmetric jet flow was analyzed via numerical simulation. The results of coherent structures in the high-pressure natural gas pipeline reveal vortex structures of varying sizes both upstream and downstream of the jet flow. To determine the spatial distribution of the main vortex structures in the flow field, proper orthogonal decomposition (POD) mode analysis was performed on the unsteady numerical results. Moreover, the detailed spatial characteristics of the coherent vortex structures represented by each mode were obtained. The results indicate that the large-scale vortex structures within the pipeline are balanced and stable, with their energy increasing as the jet flow velocity increases. Additionally, higher-order modes exhibit significant shedding of small-scale vortex structures downstream of the jet... [more]

The moving bed heat exchanger (MBHE) has been widely applied in the recovery of waste heat of industrial particles. Currently, investigations focus on uniform-size particles in the MBHE, but few studies are conducted on multi-size particles produced by industrial granulation. Therefore, based on the discrete element method (DEM), the heat transmission model of multi-size particles is established, and flow and heat transmission processes of typically normal distribution particles in the MBHE are studied. In conclusion, there are significant differences in particles tangential velocity and contact number in local regions of a heat exchanger pipe, resulting in different local heat transmission coefficients. In addition, the increases in outlet particle velocity and inlet particle temperature significantly enhance the heat transmission. When the outlet particle velocity grows from 1 mm/s to 5 mm/s, the overall heat transmission coefficient increases by 36.4%, and as the inlet particle temp... [more]

Optimization algorithms play a crucial role in a wide range of fields, from designing complex systems to solving mathematical and engineering problems. However, these algorithms frequently face major challenges, such as convergence to local optima, which limits their ability to find global, optimal solutions. To overcome these challenges, it has become imperative to explore more efficient approaches by incorporating chaotic maps within these original algorithms. Incorporating chaotic variables into the search process offers notable advantages, including the ability to avoid local minima, diversify the search, and accelerate convergence toward optimal solutions. In this study, we propose an improved Archimedean optimization algorithm called Chaotic_AO (CAO), based on the use of ten distinct chaotic maps to replace pseudorandom sequences in the three essential components of the classical Archimedean optimization algorithm: initialization, density and volume update, and position update. T... [more]