A process for obtaining ethyl levulinate through the direct esterification of levulinic acid and ethanol using AlCl3·6H2O as a catalyst was investigated. AlCl3·6H2O was very active in promoting the reaction and, the correspondent kinetic and thermodynamic data were determined. The reaction followed a homogeneous second-order reversible reaction model: in the temperature range of 318−348 K, Ea was 56.3 kJ·K−1·mol−1, whereas Keq was in the field 2.37−3.31. The activity of AlCl3·6H2O was comparable to that of conventional mineral acids. Besides, AlCl3·6H2O also induced a separation of phases in which ethyl levulinate resulted mainly (>98 wt%) dissolved into the organic upper layer, well separated by most of the co-formed water, which decanted in the bottom. The catalyst resulted wholly dissolved into the aqueous phase (>95 wt%), allowing at the end of a reaction cycle, complete recovery, and possible reuse for several runs. With the increase of the AlCl3·6H2O content (from 1 to 5 mol%), t... [more]

Accurate and timely macro forecasting requires new and powerful predictors. Carbon emissions data with high trading frequency and short releasing lag could play such a role under the framework of mixed data sampling regression techniques. This paper explores the China case in this regard. We find that our multiple autoregressive distributed lag model with mixed data sampling method setup outperforms either the auto-regressive or autoregressive distributed lag benchmark in both in-sample and out-of-sample nowcasting for not only the monthly changes of the purchasing managers’ index in China but also the Chinese quarterly GDP growth. Moreover, it is demonstrated that such capability operates better in nowcasting than h-step ahead forecasting, and remains prominent even after we account for commonly-used macroeconomic predictive factors. The underlying mechanism lies in the critical connection between the demand for carbon emission in excess of the expected quota and the production expans... [more]

Technological innovations in sociotechnical transitions are usually found in market or spatial niches. These novel niches may sometimes emerge and expand, and eventually may erode an established sociotechnical system regime. In this paper, we redefined niche emergence as potentially consequent from the convergence of different regimes. That is, it is proposed that innovative niches may be grounded in established regimes but subsequently expand or bridge to previously distinct and separate other sociotechnical system regimes. However, the extension of overlapping regimes creates new forms of “external” competition for industrial participants inside each regime. This paper therefore proposes that regime−regime confluence may be observed in (1) the boundaries between regimes potentially being broken via emergent new niches; (2) pre-existing local networks being fragmented and reformed into exclusive and/or wider networks; and (3) competitive challenges and pressures arising both from insi... [more]

Various kinds of pilot burners were experimentally investigated to examine the effects of their geometry and their location relative to the main burner of a real size combustor. In addition, a wide range of fuel equivalence ratios were investigated to analyze the feasibility of the novel pilot burner for the conventional burner application. From the results, it is shown that the novel pilot burner with multi air holes had a thin, straight, long and stable pilot flame, while the conventional pilot burner had a thick, lifted, short and unstable flame. It is also shown that the novel pilot burner with an upper air flow hole had a straight pilot flame which led to less thermal damage to the burner combustor. This study suggests that not only pilot burner flame shape but also the vertical location of the pilot burner from the main burner combustor has a significant effect on combustor durability.

In this paper, the fault current limiting (FCL) characteristics of a flux-coupled type superconducting fault current limiter (SFCL) with parallel connection between two windings in a DC system were analyzed. The flux-coupled type SFCL was composed of two coils connected in parallel and a superconducting element (SE), which was connected in series with the secondary coil. The flux-coupled type SFCL works in DC systems similar to those in AC systems. Before a fault occurs, the respective magnetic fluxes generated by the two coils connected in parallel offset each other, maintaining the voltage induced in the two coils at zero. In case of a fault, however, resistance is generated in the SE, preventing the magnetic fluxes generated by the two coils from offsetting each other. Thus, some voltage is induced in the two coils, and this starts to limit the fault current. DC short circuit tests were conducted, and the test results confirmed that the flux-coupled type SFCL with the two parallel c... [more]

The fluid catalytic cracking (FCC) process is an alternative olefin production technology, with lower CO2 emission and higher energy-saving. This process is used for olefin production by almost 60% of the global feedstocks. Different parameters including the operating conditions, feedstock properties, and type of catalyst can strongly affect the catalytic activity and product distribution. FCC catalysts contain zeolite as an active component, and a matrix, a binder, and a filler to provide the physical strength of the catalyst. Along with the catalyst properties, the FCC unit’s performance also depends on the operating conditions, including the feed composition, hydrocarbon partial pressure, temperature, residence time, and the catalyst-to-oil ratio (CTO). This paper provides a summary of the light olefins production via the FCC process and reviews the influences of the catalyst composition and operating conditions on the yield of light olefins.

Experimental work on grounding systems has shown that the characteristics of grounding systems under high impulse conditions are different than those obtained at steady-state conditions. Investigations on the grounding systems under high impulse conditions make it evident that ionization process could occur in soil, due to field enhancement in air voids in the soil. This process can lead to an ionization zone that reduces the impulse resistance of grounding systems (due to an enlargement of a virtually increased cross-sectional area) from its steady state. There have been many studies pointing towards the effect of various soils and the ground electrode’s arrangement on the reduction of impulse resistance from its steady state, and its decrease with increasing currents. It was, however, noted that very few studies on the effect of the configurations of horizontal ground electrodes have been performed by field measurements before. This work presents the experimental and simulated work o... [more]

Within the frame of upgrading and modernisation of the Water Supply System (WSS), our work is focussing on the safety systems/devices implemented or that should be implemented in the WSS. The implementation of safety systems is supposed to reduce hazard occurrence and hazardous consequences in case of a WSS unsafe disruption. To assess this reduction, we preconise the use of the safety integrity levels standards. The implementation of the safety systems/devices is undertaken on the ground of the multi-barriers safeguard approach. The “Water Contamination Hazard” is considered in the paper. A case study is presented, assessed and conclusions are drawn. The methodology presented in the paper and the results of the case study assessment will contribute to the decision-making regarding the upgrading of the safety and the performance of the WSS.

In this study, Kraft lignin was depolymerised by hydrothermal liquefaction in near-critical water (290−335 °C, 250 bar) using Na2CO3 as an alkaline catalyst. Isopropanol was used as a co-solvent with the objective of investigating its capping effect and capability of reducing char formation. The resulting product, which was a mixture of an aqueous liquid, containing water-soluble organic compounds, and char, had a lower sulphur content than the Kraft lignin. Two-dimensional nuclear magnetic resonance studies of the organic precipitates of the aqueous phase and the char indicated that the major lignin bonds were broken. The high molar masses of the char and the water-soluble organics, nevertheless, indicate extensive repolymerisation of the organic constituents once they have been depolymerised from the lignin. With increasing temperature, the yield of char increased, although its molar mass decreased. The addition of isopropanol increased the yield of the water-soluble organic products... [more]

The transient analysis model of grounding systems is an important tool to analyze the lightning characteristics of grounding devices. When lightning enters the soil through the grounding device, there is a centralized discharge channel. The spatial structure of the discharge channel in the soil has a great effect on the accuracy of the transient analysis model of the soil impulse discharge. In this paper, based on the gray information analysis method, the volume of successive impulse discharge channels in the ground under various currents and soil conditions is calculated, and the changing law with time interval is analyzed. According to the experimental results, an analysis method of the model considering the discharge channel structure is proposed, and an example is analyzed. The results show that the time interval has an effect on the volume of the discharge channel. In a certain range, the volume of the channel increases with the time interval of successive impulse discharges. Taki... [more]

The gas flow regime and pressure drop in a gas−solid packed bed with irregularly shaped sinter particles were experimentally investigated. Using a self-made experimental facility for data measurement, the gas flow pressure drop in a sinter bed layer was determined for various experimental conditions. According to the changes in the modified coefficients, α and β, for different flow regimes, the flow transitions from one regime to another in packed beds with different particle diameters were described. Furthermore, the pressure drop correlations for different flow regimes were determined, and the reliabilities of the obtained correlations were contrastively analyzed. The results show that, when the particle diameter is constant, the modified pressure drop per unit height, ΔP/Hu, increases linearly with the increasing gas superficial velocity. When the gas superficial velocity is larger than 1.15 m/s under atmospheric conditions, the gas flow regime in the sinter bed layer is the turbule... [more]

The Paris Agreement was signed by 195 nations in December 2015 to strengthen the global response to the threat of climate change following the 1992 United Nations Framework Convention on Climate Change (UNFCC) and the 1997 Kyoto Protocol [...]

Power lines are often placed in ground or sea water, which are weakly conductive media. In the paper, a new analytical formula, taking into account the proximity effect in a twin line placed in a weakly conductive medium, is derived, and the effect of the conductive medium is considered. In the first step, one of the wires is replaced by a current filament, and the solution is sought for magnetic vector potential around the filament. In the next step, an analytical formula for eddy currents induced in a long straight conductor of circular cross-section placed near to the current filament in the extensive conductive medium is found by using the method of separation of variables. The correctness of the formula is checked by comparison with the results obtained via other methods like finite and boundary element methods. Then, the effect of various parameters on the eddy current distribution is tested. Next, the proximity effect in a twin symmetrical line is considered, and the effect of t... [more]

This article identifies and characterizes the network of dominant businesses which owned wind farms in Galicia (Spain) from 1995 to 2017. This research contributes to reduce the research gap about identifying the investment groups involved and to appreciate the real size of the wind sector. The novelty of the research lies in identifying the network of real owners of wind farms through the application of Domhoff’s power structure analysis, normally used in the analysis of the power structure of corporations and political institutions. With this method, it is possible to observe how the individual wind farm companies are assessed as well as the matrix company, and/or the principal shareholders to which the farm belongs are identified. The article shows that the installed wind power in Galicia is owned by large energy firms with the participation of international investment funds as well, even though the smaller number of local companies in the sector were given favored status under the... [more]

International and UK fuel cycle scenario analyses performed to date have focused on nuclear plants producing electricity without considering in detail the other potential drivers for nuclear power, such as industrial process heat. Part of the reason behind the restricted applications of nuclear power is because the assumptions behind the future scenario are not fully captured, for example how big are demands from different sectors? Here we present a means to fully capture the potential opportunities for nuclear power using Sankey diagrams and then, using this information, consider for the first time in the UK the fuel cycle implications of decarbonising industrial heat demand in the year 2050 with nuclear power using the ORION fuel cycle code to study attributes related to spent fuel, uranium demand and decay heat from the spent fuel. We show that even in high industrial energy demand scenarios, the sensitivity of spent fuel masses and decay heat to the types of reactor deployed is rel... [more]

Endowing wind farms (WFs) with fault ride through (FRT) capability is crucial to their continuous availability under various operating conditions. This paper proposes a dynamic adaptive multi-cell fault current limiter (MCFCL) topology to enhance the FRT capability of grid connected WFs. The proposed MCFCL consists of one transient cell (TC) and multi resistive cells (RCs) directly connected to the grid’s high voltage without using any series injection transformers nor any series connection of semiconductor switches. The transient cell of the MCFCL includes two transient limiting reactors (TLRs) to mitigate the transient fault current and limit the rate of change of the currents of the semiconductor switches during fault occurrence. The number of RCs in the MCFCL is determined based on voltage sag level. These latter are inserted in the fault path to provide an adaptive voltage sag compensation mechanism according to the voltage sag level. Assessment of the MCFCL under various sag cond... [more]

A review on the rotating stall in the vaneless diffuser of centrifugal compressors is presented showing that different stall modes characterized by different numbers of cells can be detected within the diffuser even if the operating condition remains unchanged. The interaction between the inlet perturbation and the stall cells near the diffuser outlet is supposed to be the trigger of the stall mode transformation. In order to determine if the inlet perturbation will interact with the downstream stall cells, a characteristic time analysis is proposed to estimate the characteristic time of the perturbation in radial and tangential directions. An additional theoretical model which focused on the development of the vaneless diffuser rotating stall is presented to determine the propagation velocity of the cells. The comparison between the characteristic time in two directions shows that one stall mode is able to evolve into another stall mode if a critical condition is met, and the stall mo... [more]

The management of electricity consumption by household consumers requires multiple ways of consumer monitoring. One of these is the signature i(v) determined by monitoring the consumer voltage-current trajectory. The paper proposes a novel method for obtaining signatures of 2-multiple consumers, i.e., a pair of consumers connected in parallel. Signatures are obtained from samples of the voltage at the consumers’ terminals and of the total current absorbed by the consumers, measured at a frequency of only 20 Hz. Within the method, signatures are calculated using genetic algorithms (GA) and nonlinear regression, according to a procedure developed by the authors in a previous paper. The management of the data selected for the signature assignment represents the novelty. The method proposed in this paper is applied in two case studies, one concerning household consumers within the same power level, the other for household consumers of different power levels. The results confirm the possibi... [more]

The paper presents the results of the pelletization (agglomeration) tests of post-harvest tobacco waste as a feedstock for fuel pellet production. The experiment was conducted on a prototype pelleting−briquetting device with a flat matrix. The influence of the tobacco waste moisture content (17, 21 and 25wt.%) and the rotational speed of the agglomerating rolls (120, 170 and 220 rpm) on the power demand and on the pellet’s kinetic durability and density were determined. It was found that the moisture content has a significant impact on the pellet’s density but slightly affects its kinetic durability. The obtained pellets were characterized by a high density above 1000 kg·m−3 and kinetic durability above 97%. In order to examine the exhaust composition, the obtained pellets were combusted in a 25 kW fixed great boiler. High amounts of CO, SOx, NO and HCl were obtained, which suggests that the selection of a different technology for tobacco waste pellet combustion should be made.

Sonic log compressional and shear-wave velocities combined with logged bulk density can be used to calculate dynamic elastic moduli in organic shale reservoirs. We use linear multivariate regression to investigate modulus prediction when shear-wave velocities are not available in seven unconventional shale reservoirs. Using only P-wave modulus derived from logged compressional-wave velocity and density as a predictor of dynamic shear modulus in a single bivariate regression equation for all seven shale reservoirs results in prediction standard error of less than 1 GPa. By incorporating compositional variables in addition to P-wave modulus in the regression, the prediction standard error is reduced to less than 0.8 GPa with a single equation for all formations. Relationships between formation bulk and shear moduli are less well defined. Regressing against formation composition only, we find the two most important variables in predicting average formation moduli to be fractional volume o... [more]

Most research about Light and elevated Temperature Induced Degradation (LeTID) is focused on multicrystalline silicon (mc-Si). In this work, the degradation kinetics of Czochralski-grown monocrystalline silicon (Cz-Si) induced by light at an elevated temperature were studied in detail. The lifetime evolutions over time during (1) light soaking (LS), (2) dark annealing−light soaking (DA−LS), and (3) DA−LS cycling experiments were analyzed. Ratios of the capture coefficients for the electrons and holes (k-values) were used to characterize the possible defects responsible for degradation. We found that the behavior of degradation and recovery under light soaking with or without a dark annealing treatment was mostly like boron−oxygen (BO)-related degradation but gave k-values from 19 to 25. In the DA−LS cycling experiment, the max degradation amplitudes hardly changed from the second cycle, and the k-values decreased with an increase in the cycling number. We then analyzed the possible rea... [more]

It is commonly believed that matrix and natural fractures randomly distribute in carbonate gas reservoirs. In order to increase the effective connected area to the storage space as much as possible, highly deviated wells are widely used for development. Although there have been some studies on the composite model for highly deviated wells, they have not considered the effects of stress sensitivity and threshold pressure gradient in a dual-porosity gas reservoir. In this paper, a semi-analytical composite model for low permeability carbonate gas reservoir was established to study the effect of non-Darcy flow. By employing source function, Fourier transform and the perturbation method, the pressure performance and typical well test curves were obtained. Eight flow regimes were identified, and their characteristics were discussed. As a result, it can be concluded that the effects of stress sensitivity and threshold pressure gradient would make pseudo-pressure and derivative curves rise, w... [more]

A new methodology of determination of the theoretical and actual working volume of a hydraulic motor based on the characteristics of the delivered flow rate into hydraulic motor vs. the rotational speed at a constant pressure drop in the working chambers is described in this paper. A new method of describing the delivered flow rate into a motor per one shaft revolution as a nonlinear function of the pressure drop in the motor working chamber is proposed. The influence of the flowmeter location in the measurement system on the result of the theoretical and actual working volume calculation is described. It is shown that, in order to assess the energy losses (volumetric and mechanical) in the motor, the actual working volume must be a polynomial function (third degree) of its pressure drop in the working chambers. The result of the experimental tests of the satellite hydraulic motor confirmed the validity of the proposed method. The result of the calculation of the theoretical working vo... [more]

In this paper, according to the analysis of optimum circuits, we present an efficient ventilation network solution based on minimum independent closed loops. Our main contribution is optimizing the circuit dividing strategy to improve the iteration convergence and the efficiency of a single iteration. In contrast to a traditional circuit, a minimum closed loop may contain one or more co-tree branches but fewer high-resistance branches and fan branches. It is helpful in solving the problem of divergence or slow convergence for complex ventilation networks. Moreover, we analyze the dividing rules of closed loops and improve the dividing algorithm of minimum independent closed loops. Compared with the traditional Hardy Cross iteration method, the improved solution method has better iteration convergence and computation efficiency. The experimental results of real-world mine ventilation networks show that the improved solution method converges rapidly within a small number of iterations. W... [more]

In this study, four ammonium hydroxide ionic liquids (AHILs) with varying alkyl chains were evaluated for their kinetic hydrate inhibition (KHI) impact on pure carbon dioxide (CO2) and methane (CH4) gas hydrate systems. The constant cooling technique was used to determine the induction time, the initial rate of hydrate formation, and the amount of gas uptake for CH4-AHILs and CO2-AHILs systems at 8.0 and 3.50 MPa, respectively, at 1 wt.% aqueous AHILs solutions. In addition, the effect of hydrate formation sub-cooling temperature on the performance of the AHILs was conducted at experimental temperatures 274.0 and 277.0 K. The tested AHILs kinetically inhibited both CH4 and CO2 hydrates at the studied sub-cooling temperatures by delaying the hydrate induction time and reducing the initial rate of hydrate formation and gas uptake. The hydrate inhibition performance of AHILs increases with increasing alkyl chain length, due to the better surface adsorption on the hydrate crystal surface w... [more]