Cracks in concrete structures reduce bearing capacity, durability, and safety. This paper reveals the effect of superabsorbent polymers (SAP) on the self-healing property of pre-damaged concrete based on mechanical properties tests, mercury intrusion porosimetry, scanning electron microscopy, and energy dispersive spectrometer. The experimental results show that SAP reduces the mechanical properties of the SAP-modified concrete under the same W/C ratio, but a small amount of SAP can improve the later strength under the 0.35 W/C ratio. The addition of SAP increased the volume of small capillary pores (100 μm) and significantly reduced the former with an increase in age. The SEM-EDS analysis indicates that the water released by SAP promotes the formation of C-S-H gel. AFt in the cracks is the main reason for self-healing, and the addition of CO2 to produce calcium carbonate is another one. Furthermore, this study finds that SAP-modified concrete has the best self-healing effect and the d... [more]

Global greenhouse gas emissions must be reduced to achieve net-zero carbon emissions. One of the solutions for the reduction of greenhouse gas emissions is the adoption and transition from conventional vehicles to electrical vehicles (EVs). Previously, most research on EVs have been from a consumer adoption perspective, few of them are from industry transition and consumer adoption perspectives simultaneously. This also highlights the importance of SDG 12 (responsible for consumption and production). Additionally, the analyses were mostly obtained using one methodology and demonstrated only by weighting without relationships among factors. To consider the problem of adoption and transition, a systematic method should be developed. Therefore, this study intends to identify, prioritize, and display the relationship between EV adoption barriers from an automotive industry perspective using an analytic network process (ANP) and the decision-making trial and evaluation laboratory (DEMATEL)... [more]

The long dissolution time and large dispensed volumes of oil repellent polymers in offshore oil fields lead to a great increase in the volume and number of dissolution and maturation tanks in the polymer formulation system. However, there is limited space and load-bearing capacity at the offshore platform and only a small space is available for the dispensing system. To further optimize the polymer dispensing system and reduce its floor space, the super-gravity technology may be considered as a way to speed up the dissolution of the polymer. The mechanism of super-gravity rapid dissolution was investigated by establishing mathematical models and with indoor experiments. The effects of filler pore size and super-gravity factor on polymer dissolution time and solution viscosity were investigated using the super-gravity rapid dissolution device, then combined with established graded forced stretching devices for field magnification experiments. The results indicated that the super-gravity... [more]

Nitrogen, phosphorus, and metals’ pollutants discharged from industrial sources eventually accumulate in lake sediment, hence increasing the difficulty of sediment treatment and disposal. In this work, the water storage ceramsite is prepared from dredged lake sediment and cyano-bacterial powder. The effects of pyrolysis temperature and cyanobacterial sediment on the porosity of ceramsite were investigated. The results showed that the pyrolysis of organic matter and the de-composition of compounds or salts can produce gas, causing a rich pore structure inside the ceramsite. When the temperature increased to 1150 °C, vitrification would collapse the pore structure inside the material. At the cyanobacterial-to-sediment ratio of 3:7, the porosity and water absorption of the material could reach 81.82% and 92.45% when the pyrolysis temperature was 500 and 1050 °C, respectively. The internal macropore structure of ceramsite improved the water absorption performance, and the mesoporous struct... [more]

In this study, carbon aerogels (CAs) were synthesized by the sol-gel method, using environmentally friendly glucose as a precursor, and then they were further activated with potassium hydroxide (KOH) to obtain activated carbon aerogels (ACAs). After the activation, the electrochemical performance of the ACAs was significantly improved, and the specific capacitance increased from 19.70 F·g−1 to 111.89 F·g−1. Moreover, the ACAs showed a stronger hydrophilicity with the contact angle of 118.54° compared with CAs (69.31°). When used as an electrode for capacitive deionization (CDI), the ACAs had not only a better diffuse electric double layer behavior, but also a lower charge transfer resistance and intrinsic resistance. Thus, the ACA electrode had a faster CDI desalination rate and a higher desalination capacity. The unit adsorption capacity is three times larger than that of the CA electrode. In the desalination experiment of 100 mg·L−1 sodium chloride (NaCl) solution using a CDI device... [more]

This paper proposes a milli-reactor design method incorporating reactor runaway criteria. Based on Computational Fluid Dynamic (CFD) simulation, neural networks are applied to obtain the optimal reactor structure according to the target reaction requirements. Varma’s theory, the critical Nusselt number for stable operation of the flow reactor, is derived. Inserts of the multi-blade structure are designed and investigated to enhance mixing and heat transfer performance. The flow field and heat transfer capacities are obtained by CFD calculations in the range of Re 50−1800. The internal components increase the heat transfer performance up to 21 times, and the pressure drop up to 16 times. The inclined angle of the blade is recommended to be 45°, which can effectively improve heat transfer without generating excessive pressure drop. By partial least squares regression (PLS) analysis, Re and the number of blades are the most critical factors affecting heat transfer, and the five blades and... [more]

Chickpeas and other high protein plants are becoming increasingly popular. Traditionally, attrition or hammer mills are used for milling chickpeas. However, the use of roller mills on chickpeas has not been extensively researched. This study compared pilot-scale milling trials involving whole Kabuli compared to split and de-hulled Desi chickpeas. A flow sheet was designed and optimized for meal production with minimal co-product flour produced. Milling yields, particle size, and proximate analysis data were recorded. The optimum flow sheet consisted of 4 break passages, 2 smooth roll passages, and 4 purifiers. Results showed whole Kabuli chickpeas had a higher meal yield, at 63.8%, than split Desi seeds, at 54.1%; with both percentages proportional to the weight of milled seed. The remaining 36.2% or 45.9% consisted of co-product flour, feed streams and process losses. Both meals had an average particle size between 600 and 850 microns and both flours had a bimodal particle size distri... [more]

From the perspective of pollution, economics, and product quality, it is very important to find an efficient way to minimize the sulfur content of petroleum products such as gasoline and diesel. In this work, an effective, inexpensive, and simple oxidative desulfurization system based on hydrogen peroxide activation by three dicarboxylic acids which have different carbon numbers (i.e., malonic acid, succinic acid, and glutaric acid) was utilized for the desulfurization of a real diesel sample with high organic sulfur-containing compounds. The desulfurization process was based on the oxidation of sulfur compounds in diesel fuel to the corresponding sulfones followed by acetonitrile extraction of the sulfones. To select the optimal experimental conditions, the effects of several parameters, including temperature, catalyst H2O2 dosages, and treatment time, were investigated. The results showed that the developed system was effective in desulfurizing real diesel fuel with high sulfur conte... [more]

As an agroindustrial waste product, potato peels contain valuable phenolic compounds that can be extracted before they are sent to the landfill. Based on previous work, this study focused on determining the efficacies of phenolic compound extraction from potato peels using conventional shaking extraction (CSE) and both direct ultrasound-assisted extraction (DUAE), and indirect ultrasound-assisted extraction (IUAE). The yield curve associated with each extraction method was measured and characterized. The maximum yield of phenolic compounds and its dependence on processing parameters were evaluated. The applicability of the Peleg model for describing the yield curve was evaluated. Based on the Peleg model, a recovery ratio was defined to calculate its corresponding extraction rate. This extraction rate, combined with the yield, can be used for describing the efficacy of an extraction method. Our results indicate that the ultrasound-assisted extraction methods were capable of extracting... [more]

Pavement structure bearing capacity is an important evaluation parameter in pavement design, construction, maintenance management, and reconstruction, and is generally expressed by the pavement deflection value. Some of the current road bearing capacity detection equipment have high detection accuracy, but the detection speed is slow, they cannot achieve real-time continuous detection; and some detection speeds are fast, but the measurement accuracy is easily affected by the pavement roughness and vehicle vibration. Moreover, the detection result is the pavement displacement, which cannot directly reflect the comprehensive modulus of the pavement structure. In this paper, firstly, a two-stage jump mechanical model of “machine-pavement” system is established in order to develop a device that can simulate the real driving load and continuously test the bearing capacity of pavement structure, and the main factors affecting the acceleration response of vibrating drums were determined throu... [more]

The effect of phospholipid nanoparticles with different contents of phosphatidylcholine (PhNP80 and PhNP100) on dsDNA was studied by means of the electrochemical method. Changes in the electrochemical behavior of heterocyclic bases guanine, adenine and thymine in the range of potentials of 0.2−1.2 V in the presence of PhNPs were used for the assessment of the binding mechanism of the ligand−DNA interaction. Comparative analysis of the effect of PhNPs with different contents of phosphatidylcholine showed a more pronounced effect on the dsDNA of the PhNP100 nanosystem. From the obtained experimental data on the decrease in the amplitude of the nucleobases’ electrochemical oxidation currents, the electrochemical coefficient of the toxic effect was calculated as the ratio of the electrooxidation currents of dsDNA and dsDNA in the presence of phospholipid nanoparticles. PhNP80/100 (up to 11.4 mg/mL) does not influence dsDNA, PhNP80/100 (14.3−28.5 mg/mL) has a moderate toxic effect on dsDNA,... [more]

Barium sulfide is an important intermediate in the manufacture of ceramics, glass, plastics, and pharmaceutical products. This substance is traditionally obtained by carbothermal reduction of barite (barium sulfate) in the presence of a carbon-containing reducing agent, mainly coal. Herein, it is demonstrated that compaction of the charge before the carbothermal reduction significantly enhances the conversion of barium sulfate to sulfide due to an increase in the contact time of carbon monoxide with barite in a compact sample in comparison with a powder sample. In the presence of NaOH as a catalyst, the degree of conversion of barium sulfate in a compact sample was 0.95−0.97 upon roasting at 1150 °C for 65 min, while in a powder sample this value did not exceed 0.6. Furthermore, charge compaction reduced the conversion activation energy (136 vs. 264 kJ mol−1), which could be a tool for reducing the energy intensity of obtaining barium sulfide from its sulfate.

Accurate production efficiency evaluation can assist enterprises in adjusting production strategies, improving production efficiency, and, thereby, weakening environmental impacts. However, the current studies on production efficiency evaluation do not accurately consider interactions inside the production system in parallel production processes. Based on the concept of the manufacturing service, this paper describes the production process of a complex product system (CoPS) with a manufacturing service chain. An efficiency calculation model based on the triangular intuitionistic fuzzy number−solid waste recycling−super-efficiency data envelopment analysis (TIFN-SWR-SDEA) is proposed under the consideration of the internal parallel structure of the production system on the example of solid waste recycling. Additionally, the technique for order preference by similarity to ideal solution (TOPSIS) method and the entropy weight method were combined to determine the proportion of solid waste... [more]

Traditional economic dispatch methods, which are used to minimize fuel costs, have become inadequate because they do not consider the environmental impact of emissions in the optimization process. By taking into account the horizon year load and carbon taxes, this paper examines the operation and dispatch of power units in a power system. The objective function, including the cost of fuels and the cost of carbon taxes, is solved by the modified particle swarm optimization with time-varying acceleration coefficient (MPSO-TVAC) method under operational constraints. Based on different load scenarios, the influences of various carbon taxes for the dispatch of units are simulated and analyzed. The efficiency and ability of the proposed MPSO-TVAC method are demonstrated using a real 345KV system. Simulation results indicate that the average annual CO2 emissions are 0.36 kg/kwh, 0.41 kg/kwh, and 0.44 kg/kwh in 2012, 2017 and 2022, respectively. As the capacity of gas-fired plants was increase... [more]

In this study, a superabsorbent polymer dryer (Polydryer) used to obtain dried medicinal plant materials (Simplicia) was incorporated with a heater to enhance the drying rate. In general, the Polydryer was constructed using a cabinet containing polymer hydrogel (polygel), a gas-fueled heater, and a drying cabinet. A polygel synthesized from acrylic acid and cassava starch was utilized to reduce the moisture content in the drying air prior to entering the heater. The drying performance of the Polydryer with and without heater operation was investigated. The results showed that the drying in the Polydryer with heater operation required 18−26 h to attain a final moisture content of 8.8−10%, significantly faster than the Polydryer without heater employment (95−119 h). In addition, the drying of medicinal plants in the modified Polydryer followed the Page thin-drying model. The Simplicia products also showed a slightly lighter color, with no significant structural differences than those obt... [more]

Differential Evolution (DE) has been extensively adopted for multi-objective optimization due to its efficient and straightforward framework. In DE, the mutation operator influences the evolution of the population. In this paper, an adaptive Grid-based Multi-Objective Differential Evolution is proposed to address multi-objective optimization (ad-GrMODE). In ad-GrMODE, an adaptive grid environment is employed to perform a mutation strategy in conjunction with performance indicators. The grid reflects the convergence and diversity performance together but is associated with the user-specified parameter “div”. To solve this problem, we adaptively tune the parameter “div”. Among the DE mutation strategies, “DE/current-to-best/1” is applied extensively in single-objective optimization. This paper extends the application of “DE/current-to-best/1” to multi-objective optimization. In addition, a two-stage environmental selection is adopted in ad-GrMODE, where in the first stage, one-to-one sel... [more]

In emergency rescue operations, it is very important for emergency management to arrange emergency materials scientifically and reasonably according to emergency needs. However, the decision criteria for emergency material distribution are often diverse, coupled with the lack of information acquisition due to the suddenness and development complexity of disasters, which makes the scientific decisions about emergency material distribution face great challenges. This paper proposes a multi-criteria decision optimization model of emergency material distribution under uncertainty that combines the 4E criteria of performance evaluation (economic criterion, efficiency criterion, effectiveness criterion and equity criterion). Then, the solution method of the multiple decision criteria model is designed. Finally, a case study of emergency medical material distribution during COVID-19 in China was conducted for model verification. The results show that different decision criteria have an import... [more]

Increases in energy demand and waste are a major cause of natural resource depletion and environmental pollution, and technology capable of processing waste to convert it into energy is required to mitigate this issue. Hydrothermal carbonization (HTC) is an example of this technology that can convert waste into energy, and various studies have been conducted using it for fuel conversion. This study focused on the production of a solid fuel equivalent to coal for power generation through HTC processes using waste wood. Unlike previous work, which consists only of laboratory-scale HTC experiments, we confirmed scalability through pilot-scale HTC experiments. Overall, it was possible to convert waste wood into HTC solid fuel with a calorific value of over 27,000 kJ/kg through the pilot plant HTC process. Additionally, heavy metal and hazardous substance analyses proved that it can be used as a biosolid fuel.

Guide vanes (GVs) are installed between the runner and the stay vanes for flow guidance and discharge regulation in reversible pump-turbines. The unstable torsional self-excited vibration of the guide vane (GV) may occur when running at small guide vane opening angles during the transient operations involving pump flow. In addition, the double-stage radial vanes may induce complex flow in the vanes and influence the stability of torsional self-excited vibration of the guide vane. In this study, numerical simulations were conducted at small guide vane opening angles in pump mode for two different guide vanes based on the three-dimensional computational fluid dynamics (CFD) method. The flow regime with a deflection was formed on the trailing edge with a circle in the vaneless region that rotated reversely against the runner rotation when operating at smaller guide vane opening angles for both of the two guide vanes. Based on this, the coupling simulations based on the CFD method with a s... [more]

Accurate evaluation of shale oil reservoir fracability helps avoid blind fracturing and ensures efficient fracturing. However, the current evaluation of the fracability index rarely considers the impact of hydration caused by drilling fluid invasion during drilling. The results of a rock triaxial mechanical test conducted to evaluate the mechanical properties of shale oil reservoirs are reported in this paper. Based on the results, we developed a comprehensive evaluation method of shale oil reservoir fracability that considers hydration; the effects of the brittleness index, horizontal difference stress, and fracture toughness; and the law of water phase intrusion into shale oil reservoirs. The research results show that the average compressive strength decreased by 37.99%, the average elastic modulus decreased by 53.36%, and the average Poisson’s ratio increased by 68.75% after being soaked for 48.00 h at 80 °C and 30.00 MPa. The water saturation rate at the borehole wall was the high... [more]

Aiming at the shortcomings of the beetle swarm algorithm, namely its low accuracy, easy fall into local optima, and slow convergence speed, a rebellious growth personality−beetle swarm optimization (RGP−BSO) model based on rebellious growth personality is proposed. Firstly, the growth and rebellious characters were added to the beetle swarm optimization algorithm to dynamically adjust the beetle’s judgment of the optimal position. Secondly, the adaptive iterative selection strategy is introduced to balance the beetles’ global search and local search capabilities, preventing the algorithm from falling into a locally optimal solution. Finally, two dynamic factors are introduced to promote the maturity of the character and further improve the algorithm’s optimization ability and convergence accuracy. The twelve standard test function simulation experiments show that RGP−BSO has a faster convergence speed and higher accuracy than other optimization algorithms. In the practical problem of P... [more]

This paper presents a literature review of reinforcement learning (RL) and its applications to process control and optimization. These applications were evaluated from a new perspective on simulation-based offline training and process demonstrations, policy deployment with transfer learning (TL) and the challenges of integrating it by proposing a feasible approach to online process control. The study elucidates how learning from demonstrations can be accomplished through imitation learning (IL) and reinforcement learning, and presents a hyperparameter-optimization framework to obtain a feasible algorithm and deep neural network (DNN). The study details a batch process control experiment using the deep-deterministic-policy-gradient (DDPG) algorithm modified with adversarial imitation learning.

The new process developed here consisting of sulfurization roasting transformation and water immersion can effectively realize the separation of rare earth elements (REEs) and impurities from spent Nd-Fe-B magnets. For the industrial application of the new process, it is critical to determine how to economically and efficiently prepare rare earth oxide (RExOy) products with higher purity from the obtained water leaching solution. Therefore, according to rare earth sulfate (RE2(SO4)3) solution characteristics, the oxalic acid precipitation−calcination method, sodium carbonate precipitation−calcination method, and double sulfates precipitation−alkali conversion−calcination method were optimized and compared. The results show that the recovery efficiency of REE recovery via the oxalic acid precipitation−calcination method is 99.44%, and the purity of RExOy is 99.83% under optimal technological conditions. However, the cost of oxalic acid precipitation is higher. The process consisting of... [more]

This study presents an approach for targeted comminution of component mixtures within a wet-operated stirred media mill. In the first step, a general understanding of the interactions between individual components on the grinding result with mixtures could be gained with basic experiments and following our former research work. In particular, a protective effect of the coarser particles on the fines could be elucidated. These findings were used to develop a process for the production of a battery slurry containing fine ground silicon particles as well as dispersed carbon black and graphite particles. By a tailored sample preparation applying a combination of particle dissolution and separation, the particle size distributions of carbon black and graphite particles were analyzed separately within the produced battery slurries. Based on the selective particle size analysis, the slurry preparation could be transferred from a complex multistage batch process using a dissolver to a stirred... [more]

Thermally enhanced oil recovery methods, such as in situ combustion and steam injection, are generating considerable interest in terms of improving oil reserve exploitation and satisfying oil demand and economic growth. However, the early breakthrough of the in situ combustion front and the significant amount of heat loss associated with steam injection for deeper reservoir applications are the main challenges that require urgent solutions. Further data collection related to the effects of a reservoir’s physical and chemical properties, temperature, and pressure on in situ combustion front propagation and steam injection heat transfer inefficiency would be needed to achieve better reservoir oil recovery. Most studies have focused on the application of catalytic systems and the investigation of minerals’ effects on combustion front stabilization; however, the effect of clay interlayers’ minerals on the performance of in situ combustion is still poorly understood. This paper takes a new... [more]