Food waste is a matter of deep concern as it is creating multidimensional threats to the environment. Though these are potential sources of plant nutrients, a detailed investigation has not yet been conducted. Hence, a physico-chemical characterization of non-edible food waste such as brinjal waste, potato peels, banana peels, orange peels, eggshells, cow bones, chicken bones, fish bones, and their combined waste was accomplished using FTIR, TGA, XGT-5000, CHN corder, etc. The present study revealed that plant waste samples had lower ash contents (1.36−7.79%) but higher volatile matter (72.33−80.04%), and the reverse was true in animal waste. In addition, animal waste, except eggshells (22.48%), had lower fixed carbon (1.01−2.83%). On the other hand, fruit waste was documented with higher fixed carbon (11.33−14.27%). Results also indicated that animal waste and their combined samples, except eggshells, contained more nitrogen (3.82−5.06%). The concentration of P was statistically signi... [more]

Horizontal wells with extended lateral lengths and large-scale hydraulic fracturing are a key technology for shale gas development. Lateral length is the key factor in determining the production and economic benefits of horizontal wells. Therefore, based on geology−engineering−economy integration, a method for optimizing the lateral length of shale-gas horizontal wells is established. Through fracture-shape prediction, productivity simulation and input−output analysis, the net present-value model of the technical−economic evaluation of the economic lateral length is established. A comprehensive evaluation of lateral lengths in Changning Block is then conducted. The results show that, under the current geological, engineering, and economic conditions in Changning Block, a horizontal well with a lateral length between 175 m and 3508 m is economically viable, and the optimal economic lateral length is 2000 m. The porosity and thickness of the reservoir matrix, the production time, the dri... [more]

In this study, the effect of temperature on the velocity and trajectory of a hot sphere falling in a water block was experimentally investigated. The sphere, 12 mm in diameter, was thrown through the water inside an enclosure at the ambient temperature by an electromagnetic attachment mechanism, and the particle velocity was recorded by a high-speed camera at 2000 fps. Then, using an image-processing algorithm, the real-time particle location was extracted and its velocity was measured. The results of the cold sphere falling test were compared with those obtained from the numerical solving by the governing equations. An electric heater was used to heat the sphere up to 100, 200, and 300 °C in order to investigate the effect of temperature on the sphere. The sphere was thrown upon reaching the desired temperature. By increasing the temperature, the sphere’s velocity was increased up to around 40% of the velocity of the cold sphere. Further, the sphere was thrown from a point in the vici... [more]

Several chemicals, such as pesticides and heavy metals, are frequently encountered together in environment matrices, becoming a priority concerning the prevention of their emissions, as well as their removal from the environment. In this sense, this work aimed to evaluate the effectiveness of a permeable biosorbent bio-barrier reactor (PBR) on the removal of atrazine and heavy metals (copper and zinc) from aqueous solutions. The permeable bio-barrier was built with a bacterial biofilm of R. viscosum supported on 13X zeolite. One of the aims of this work is the investigation of the toxic effects of atrazine, copper and zinc on the bacterial growth, as well as the assessment of their ability to adapt to repeated exposure to contaminants and to degrade atrazine. The growth of R. viscosum was not affected by concentrations of atrazine bellow 7 mg/L. However, copper and zinc in binary solutions were able to inhibit the growth of bacteria for all the concentrations tested (5 to 40 mg/L). The... [more]

This paper presents the circuit and control method for piezo-ceramic drives. With the proposed method, a gap is imposed in the transformer core to increase the leakage inductance. This flattens the voltage gain curve of the piezo-ceramic driver over the resonant frequency range, so voltage gain changes are insensitive to frequency changes. In addition, resonant frequency tracking and power control methods are developed, while the circuit is capable of zero-voltage soft-switching such that the circuit operation efficiency can be improved. In order to solidify the practicality of the circuit design, mathematical analysis and experimental validations have been thoroughly performed. The test results help to confirm the effectiveness of the proposed method and demonstrate its practicality in industrial applications.

Electrolysis of seawater is a promising technique to desalinate seawater and produce high-purity hydrogen production for freshwater and renewable energy, respectively. For the application of seawater electrolysis technique on a large scale, simplicity of manufacture method, repeatability of catalyst products, and stable product quality is generally required in the industry. In this work, a facile, one-step, and metal salt-free fabrication method was developed for the seawater-oxygen-evolution-active catalysts composed of CoCrFeNiMo layered double hydroxide array self-supported on CoCrFeNiMo high entropy alloy substrate. The obtained catalysts show improved performance for oxygen evolution reaction in alkaline artificial seawater solution. The best-performing sample delivered the current densities of 10, 50, and 100 mA cm−2 at low overpotentials of 260.1, 294.3, and 308.4 mV, respectively. In addition, high stability is also achieved since no degradation was observed over the chronoampe... [more]

Every year, diverse types of safety accidents cause major damage to human life and property. In particular, failure to suppress safety accidents caused by fires during the early stages can lead to large-scale accidents, which in turn can cause more serious damage than other types of accident. Therefore, this paper presents an analysis of the prevailing research trends and future directions for research on preventing safety accidents due to fire. Since fire outbreaks can occur in many types of places, the study was conducted by selecting the places and causes involved in frequent fires, using fire data from Korea. As half of these fires were found to occur in buildings, this paper presents an analysis of the causes of building fires, and then focuses on three themes: fire prevention based on fire and gas detection; fire prevention in electrical appliances; and fire prevention for next-generation electricity. In the gas detection of the first theme, the gas referred to does not denote a... [more]

The influence mechanism of the blade tip clearance (TC) of an inducer on the performance of a centrifugal pump at high speed was researched under different flow rate conditions in this work. An experiment on the pump’s external performance was carried out, and numerical calculation was also performed under four different TCs. The full characteristic performance curves, static pressure and pressure pulsation distributions of the pump were obtained. Through the research and analysis, it was found that the influence of the TC on the efficiency and the head of the centrifugal pump are related to the flow rate. Under the influence of a large flow rate, the increase in the TC is helpful to improve the efficiency and the head of the pump. The increase in the TC helps to weaken the gap jet effect on the inducer. The inlet jet of the inducer, caused by TC leakage, will form a low-pressure vortex zone at the inlet of the inducer. The splitter-bladed inducer’s pressure pulsation is affected by th... [more]

In recent years, global climate change, environmental pollution, and energy shortage have become increasingly serious [...]

γ-valerolactone can be a game-changer in the chemical industry because it could substitute fossil feedstocks in different fields. Its production is from the hydrogenation of levulinic acid or alkyl levulinates and can present some risk of thermal runaway. To the best of our knowledge, no studies evaluate the thermal stability of this production in a continuous reactor. We simulated the thermal behavior of the hydrogenation of butyl levulinate over Ru/C in a continuous stirred-tank reactor and performed a sensitivity analysis. The kinetic and thermodynamic constants from Wang et al.’s articles were used. We found that the risk of thermal stability is low for this chemical system.

Natural products are increasingly becoming part of our daily lives through their use in industry, food, as therapeutic agents, etc. To evaluate their possible applications, it is essential to characterize them chemically to explore their potential. Different techniques may be used to characterize natural products, including microextraction techniques. These techniques have been gaining popularity due to the advantages associated with their low use of organic solvents and the small amount of sample used relative to more classical sample preparation techniques. Their application in the extraction of compounds from natural products is still scarce. This manuscript intends to review the most used solid-based miniaturized sample preparation techniques applied to determining compounds in natural products. The main applications of these methodologies will be discussed, with a particular focus on natural product analysis, as well as their advantages and disadvantages over traditionally used sa... [more]

Surface location error (SLE) caused by forced vibration is a key factor to determine the quality of the finished part. When machining thin-walled structures with sculptured surfaces, the complicated milling process is significantly influenced by the vibration due to the flexibility of the part. The dynamics of the part are dominant and vary with the material removal during machining. This paper presents a prediction method of SLE considering the varying dynamics of thin-walled parts in five-axis flank milling. The in-process part is decomposed into unmachined and machined portions, which are both modelled based on the thin-plate theory. The dynamics models of the two portions are coupled using the substructure method. Coordinate transformation based on the screw theory and the general cutting dynamics model for five-axis flank milling is employed to transform the cutting force vectors and frequency response function (FRF) to the same coordinate system for the prediction of SLE. The pro... [more]

In this paper, a new prediction model for accurately recognizing and appropriately evaluating the trends of domestic chemical products and for improving the forecasting accuracy of the chemical products’ prices is proposed. The proposed model uses the minimum forecasting error as the evaluation objective to forecast the settlement price. Active contracts for polyethylene and polypropylene futures on the Dalian Commodity Futures Exchange for the next five days were used, the data were divided into a training set and test set through normalization, and the time window, batch processing size, number of hidden layers, and rejection rate of a long short-term memory (LSTM) network were optimized by an improved genetic algorithm (IGA). In the experiments, with respect to the shortcomings of the genetic algorithm, the crossover location determination and some gene exchange methods in the crossover strategy were improved, and the predicted results of the IGA−LSTM model were compared with those... [more]

Composting is a sustainable alternative for green waste (GW) valorization contributing to the circular bioeconomy. However, the processing time must be reduced and the end-product quality must be improved. This study determined the effect of the incorporation of processed food waste (PFW), unprocessed food (UPFW), sawdust (SW), phosphate rock (PR) and a specific bacterial inoculum on GW-composting process parameters and product quality. Three treatments were evaluated in 120 kg piles: (i) TA: (GW + UPFW + PFW + inoculum), (ii) TB (GW + UPFW + PFW), and (iii) TC (GW). An inoculum of Bacillus sp. and Paenibacillus sp. was incorporated in the cooling phase for TA. On the other hand, the effect of the inoculum at the laboratory scale (20 kg reactors) was compared with that found at the pilot scale (120 kg piles). The incorporation of FW, SW, PR and the inoculum increased the amount of lignocellulose biodegradation (TA: 29.1%; TB: 22.7%; TC: 18.2%), which allowed for a reduction of up to 14... [more]

Minced beef is a popular meat product due to its low price and superior nutritional value. The contamination of minced beef is a significant risk for the worldwide meat market. Both natural and synthetic preservatives are used to expand the shelf life and improve the quality properties of meat. The harmful effects of synthetic preservatives make natural preservatives more appealing. Therefore, this research was performed to study the impact of different concentrations of Cassia glauca leaf extract (CGE) on increasing the shelf life of minced beef. Seventy-two minced beef samples were divided into control, 0.25, 0.5, and 1% w/w CGE treated groups. The control and treated samples were kept at 3 ± 1 °C in the refrigerator for 15 days. Minced beef samples’ sensory, chemical, and microbiological properties were assessed every three days. The gained results showed that the CGE addition effectively decreased the microbial count and maintained the minced beef’s sensory and chemical quality. Ad... [more]

What is presented in this research is an intelligent system for detecting the volume percentage of three-phase fluids passing through oil pipes. The structure of the detection system consists of an X-ray tube, a Pyrex galss pipe, and two sodium iodide detectors. A three-phase fluid of water, gas, and oil has been simulated inside the pipe in two flow regimes, annular and stratified. Different volume percentages from 10 to 80% are considered for each phase. After producing and emitting X-rays from the source and passing through the pipe containing a three-phase fluid, the intensity of photons is recorded by two detectors. The simulation is introduced by a Monte Carlo N-Particle (MCNP) code. After the implementation of all flow regimes in different volume percentages, the signals recorded by the detectors were recorded and labeled. Three frequency characteristics and five wavelet transform characteristics were extracted from the received signals of each detector, which were collected in... [more]

In water-in-oil-in-water (W1/O/W2) double emulsions several irreversible instability phenomena lead to changes. Besides diffusive processes, coalescence of droplets is the main cause of structural changes. In double emulsions, inner droplets can coalesce with each other (W1−W1 coalescence), inner droplets can be released via coalescence (W1−W2 coalescence) and oil droplets can coalesce with each other (O−O coalescence). Which of the coalescence pathways contributes most to the failure of the double emulsion structure cannot be determined by common measurement techniques. With monodisperse double emulsions produced with microfluidic techniques, each coalescence path can be observed and quantified simultaneously. By comparing the occurrence of all possible coalescence events, different hydrophilic surfactants in combination with PGPR are evaluated and discussed with regard to their applicability in double emulsion formulations. When variating the hydrophilic surfactant, the stability aga... [more]

Hydraulic fracturing is a technique that can provide space for oil and gas flow by pumping fracturing fluid into a reservoir to fracture rock and filling proppant to create fractures or fracture nets [...]

In 2019, a new lethal and mutant virus (COVID-19) spread around the world, causing the deaths of millions of people. COVID-19 demonstrates that scientists are involved in significant research efforts to face bacteria with less effort than that dedicated to viruses. Since then, engineers and bio-materials scientists have been trying to develop antiviral research and find a suitable effective medication. Strategies and opportunities for interference diagnostics, treatment strategies, and predicting future factors became mandatory. From a statistical point of view, estimating and modelling these factors play an important role in preventing future viral epidemics. In this article, modelling the recovery rate of COVID-19 is investigated through a new distribution which is called the unit exponential Pareto distribution. The new continuous distribution with three parameters displays a prominent level of flexibility to model decreasing, symmetric, and asymmetric data with a monotone failure r... [more]

The metallurgical industry is seeking raw material substitutes more and more intensively in order to replace materials traditionally used in pig iron production. Research has been conducted on the use of char obtained from waste car tires via a pyrolysis process in an iron ore sintering process. The char obtained from car tires could be a potential substitute for some of the coke breeze used in the iron ore sintering process. However, the Zn and S content of the char is a major technological issue. This paper presents the results of research conducted to assess the possibility of substituting coke breeze with a commercial char from waste tires. The experiments were carried out in a laboratory stand capable of sintering 200 kg of sintering blend. The results obtained show that it is possible to replace 10 %m/m of coke breeze with waste tire char without any technological danger for sintering lines. The application of waste tire char in metallurgical processes is an example of actions th... [more]

Bearings and other revolute pairs in gear drives will form clearances due to wear after working for a long time, which will aggravate the vibration and noise of the gear. Therefore, taking the gear drives with revolute pair clearance as the research object, the calculation formulas of the backlash and contact ratio is derived, and the time-varying mesh stiffness model considering the clearance is presented in this work. Then, a nonlinear dynamic model for the gear drives with revolute pair clearance is proposed by combining the backlash, contact ratio and the time-varying mesh stiffness. The effects of the clearance on the meshing stiffness, load sharing factor and nonlinear behavior are investigated. Results indicate that the revolute pair clearance weakens the meshing stiffness and increases working hours in single teeth contact area, thereby increasing the risk of premature failure of the gear drive. In addition, the revolute pair clearance has negligible effect on the nonlinear beh... [more]

Waste-printed circuit boards (WPCBs) account for approximately 3−6 wt% of total electronic waste. Due to their content of thermosetting materials and added brominated fire retardants, their recycling and disposal is difficult and not eco-friendly. Pyrolysis as a thermal degradation process may assist in the solution of this problem. In addition, using biomass as an additive can upgrade the bio-oil and fix bromines in the char. In this study, cotton stalk (CS) is chosen as an additive and kinetic of the pyrolysis of three samples namely: PCB, CS, and CS:PCB (50:50) were investigated by the thermogravimetric analyzer (TGA) at heating rates of 5, 10, and 15 K/min. Three non-isothermal methods: FWO, KAS, and Starink were found in good agreement with the TGA data; however, the FWO method was more efficient in the description of the degradation mechanism of solid-state reactions. For CS and CS:PCB (50:50), α was increased from 0.2 to 0.9 with the FWO method, and calculated Eα values were fou... [more]

Due to issues such as heat accumulation, the site area, and project investment, the reasonable determination of the hole spacing for heat exchangers has become one of the key design points of the ground-coupled heat pump system. Based on the definition of heat penetration in heat transfer and the research method of the inverse problem, a direct algorithm of the heat penetration distance in the aquifer was proposed using the analytical solution to the mathematical model for one-dimensional heat convection−conduction problems. Taking a vertical ground-coupled heat pump project in Hefei, Anhui Province, China, as an example, a three-dimensional hydro-thermal coupling numerical simulation model was established, and the influence radius during the refrigeration and heating periods under the action of a single borehole heat exchanger was determined. Comparing the heat penetration distance with the influence radius, the results show that the relative errors of the results obtained by the two... [more]

Direct electrochemical oxidation, as an economical and efficient method, has recently received increasing attention for ammonia-nitrogen wastewater treatment. Developing a low-cost, efficient catalytic electrode is the key to solve the problem of sluggish ammonia oxidation reaction (AOR) kinetics. In this study, a three-dimensional (3D) Ni foam electrode coated with NiCuOOH petal-like cluster structures was prepared using a simple sonochemical method combined with a surface electrochemical reconstruction strategy. This structure has a large surface area and abundant NiCuOOH active sites, giving a good premise for extraordinary electrocatalytic activity of AOR. The results show that the maximum current density for AOR reaches 97.8 mA cm−2 at 0.60 V vs. saturated calomel electrode (SCE). Additionally, 96.53% of NH4+-N removal efficiency and 63.12% of TN removal efficiency were acquired in the electrolysis system based on the NiCuOOH-NF electrode, as well as a good stability for at least... [more]

This paper studies the potential of carbon-abatement cost-sharing contracts in optimizing the joint economic−environmental benefit of a green supply chain. One-way and two-way cost-sharing contracts were investigated, respectively, in scenarios in which a capital-constrained manufacturer has a dominant downstream retailer or a dominant upstream supplier. The manufacturer obtains financing from a competitively priced bank to fulfill its production, carbon-abatement investment, and even insufficient emission permit purchase given the fact that the cap-and-trade regulation exists. Results show that in both one-way and two-way cost-sharing cases, cost sharing of carbon abatement has no effect on the manufacturer’s output or its counterparty’s wholesale price decisions; however, it improves the carbon abatement level of the supply chain. As a result, such cost-sharing of carbon abatement is proven to hamper the profit of the overall supply chain, but it improves the joint “economic-environm... [more]