LAPSE:2023.1121
Published Article

LAPSE:2023.1121
Thermal Stability for the Continuous Production of γ-Valerolactone from the Hydrogenation of N-Butyl Levulinate in a CSTR
February 21, 2023
Abstract
γ-valerolactone can be a game-changer in the chemical industry because it could substitute fossil feedstocks in different fields. Its production is from the hydrogenation of levulinic acid or alkyl levulinates and can present some risk of thermal runaway. To the best of our knowledge, no studies evaluate the thermal stability of this production in a continuous reactor. We simulated the thermal behavior of the hydrogenation of butyl levulinate over Ru/C in a continuous stirred-tank reactor and performed a sensitivity analysis. The kinetic and thermodynamic constants from Wang et al.’s articles were used. We found that the risk of thermal stability is low for this chemical system.
γ-valerolactone can be a game-changer in the chemical industry because it could substitute fossil feedstocks in different fields. Its production is from the hydrogenation of levulinic acid or alkyl levulinates and can present some risk of thermal runaway. To the best of our knowledge, no studies evaluate the thermal stability of this production in a continuous reactor. We simulated the thermal behavior of the hydrogenation of butyl levulinate over Ru/C in a continuous stirred-tank reactor and performed a sensitivity analysis. The kinetic and thermodynamic constants from Wang et al.’s articles were used. We found that the risk of thermal stability is low for this chemical system.
Record ID
Keywords
GVL, hydrogenation, Simulation, thermal stability
Subject
Suggested Citation
Vásquez Salcedo WN, Renou B, Leveneur S. Thermal Stability for the Continuous Production of γ-Valerolactone from the Hydrogenation of N-Butyl Levulinate in a CSTR. (2023). LAPSE:2023.1121
Author Affiliations
Vásquez Salcedo WN: INSA Rouen Normandie, University Rouen Normandie, Normandie Université, LSPC, UR 4704, F-76000 Rouen, France; INSA Rouen-Normandie, UNIROUEN, CNRS, CORIA, Normandie University, F-76000 Rouen, France [ORCID]
Renou B: INSA Rouen-Normandie, UNIROUEN, CNRS, CORIA, Normandie University, F-76000 Rouen, France
Leveneur S: INSA Rouen Normandie, University Rouen Normandie, Normandie Université, LSPC, UR 4704, F-76000 Rouen, France [ORCID]
Renou B: INSA Rouen-Normandie, UNIROUEN, CNRS, CORIA, Normandie University, F-76000 Rouen, France
Leveneur S: INSA Rouen Normandie, University Rouen Normandie, Normandie Université, LSPC, UR 4704, F-76000 Rouen, France [ORCID]
Journal Name
Processes
Volume
11
Issue
1
First Page
237
Year
2023
Publication Date
2023-01-11
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr11010237, Publication Type: Journal Article
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LAPSE:2023.1121
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https://doi.org/10.3390/pr11010237
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Feb 21, 2023
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