High-efficiency production of xylene/trimethylbenzene from benzene/toluene with methanol is a potential way to promote the implementation on the coupled cycle development strategy of petrochemical and coal chemical industry and optimize the resource structure. At the same time, relying on the innovation of catalytic new materials, physical chemistry, intelligent capture technology, process engineering, and other principles and methods, p-xylene (PX) and trimethylbenzene (TMB) with higher added value were prepared by C6-8~arene methylation, which could elevate the level of methylation field and improve the competitiveness of the industry. This paper focuses on the one-step methylation reaction of benzene with methanol or toluene with methanol to obtain high-purity p-xylene (BM-PX/TM-PX), and the one-step methylation reaction of xylene with methanol to obtain mesitylene (XM-TMB). The methylation reaction mechanism and the preparation strategy of a high-performance catalyst were reviewed.... [more]

Soil cyclic degradation is a serious issue that should be considered in engineering design and maintenance. The hysteretic response causes strength degradation and excessive settlement of soil structure in engineered and natural geosystems. Hysteresis is essentially the coupling deformation of elastic and plastic components during reloading and unloading processes. Conventional hysteretic models for sand in the elastoplastic framework rely highly on yield surface or potential surface evolution and fall short on complexity and inaccuracy. This study proposes a decoupling method to describe the hysteretic response of sand. In contrast to the conventional elastoplastic approach, this decoupling method can directly decouple the elastic and plastic components by determining the boundary between the elastic strain extension domain and the plastic strain extension domain for each stress cycle. In this way, the elastic and plastic stress−strain branches during cyclic loading can be separately... [more]

Based on both theoretical and practical experiences, the measures aimed at controlling emergency shutdowns of stopes have been highlighted. These stopes are connected with the emergency rigid settlements of powered complexes. In terms of the Western Donbas mines, there are certain risks of a shutdown of stopping operations within the zone of primary roof caving. Thus, the causes of emergency rigid settlements of the support may include the following: layers of the main roof rocks are hanging and not timely delaminated; sudden changes in lithology; hydraulic overloading of the main roof; structural flaws of support under certain conditions of its use, etc. In this paper, the theoretical method of scientific cognition was applied, which, with its help, makes it possible to switch from single low-efficiency measures to a set of actions aimed at preventing any uncontrolled situation. Obtaining certain generalized knowledge means obtaining a much deeper representation of reality, penetratin... [more]

The Grootspruit valley bottom wetland in South Africa, due to the impact of acid mine drainage (AMD) from an abandoned coal mine, was severely degraded before ecologically engineered interventions, as a passive treatment process, in 2014. The surface water flow of the wetland was redirected using concrete structures to enlarge the surface area of the wetland by 9.4 ha and to optimize passive treatment. Although the ecologically engineered interventions showed an improvement in water quality after the rewetting of the enlarged wetland areas, the 2016 drought had a devastating effect on the wetland’s water quality. Limited natural removal of metals and sulfate concentrations by the wetland occurred during the 2016 drought, when compared with the 2015 pre-drought conditions. This period showed higher concentrations of metals, sulfate (SO42−), and electrical conductivity (EC) associated with the acidic surface water. Of particular interest was an observation of a substantial shift in pollu... [more]

Over the years, due to the surge in energy demand, the use of alternative fuels has emerged as an interesting area of research. In the current work, a comparative study was conducted by employing gasoline, 6% ethanol−gasoline (E6), and 12% ethanol−gasoline (E12) in a spark-ignition engine. Performance, emissions, and lube oil damage tests were conducted at a constant load by varying engine speed. E12 showed improved performance, i.e., 7.82% higher torque and 14.69% improved brake thermal efficiency (BTE) in comparison with neat gasoline. In addition, CO, CO2, HC, and NOx emissions were found to be minimal for E12. Furthermore, lubricating oil properties (kinematic viscosity, flash point, and total base number (TBN)) and wear debris (iron, aluminum, and copper) showed a visibly improved performance with gasoline compared to E6 and E12. The highest decline in kinematic viscosity of 27.87%, compared to fresh oil, was recorded for E12. Thus, the lube oil properties have to be modified acco... [more]

A new dynamic air classifier was designed to address the problems of uneven material dispersion and high dust concentration in industrial applications of turbo air classifiers. This paper presents a study on the use of guide cones in the new dynamic air classifier. The ANSYS-Fluent 19.2 software was implemented to simulate the airflow in the dynamic air classifier, and the impact of the guide cone size on the flow field and classification performance of the dynamic air classifier was investigated. The simulation results indicated that with the increase in the guide cone height, the flow field distribution becomes reasonable and the velocity distributions become uniform. When the guide cone height is greater than twice the distance between the guide cone and the bottom of the rotor cage, there is no discernible change in the flow field distribution and classification efficiency. When the guide cone diameter is approximately 0.9 times the diameter of the rotor cage, the airflow pathline... [more]

This study presents the development of a method for the washcoating of Ni/boehmite gels, prepared by the sol−gel process, onto the surface of a commercial ceramic monolith. Indeed, a cordierite monolith in a honeycomb shape was used as the substrate for the Ni/Al2O3 deposition. An experimental assembly was made in order to apply the coating on the cordierite surface. Different suspensions were used with various viscosities, and multiple coating parameters were tested as the withdrawal speed, or the number of impregnations. It was observed that the simple deposition of the Ni/boehmite gel led to the formation of coating. Different morphologies were observed, and defects were highlighted as cracks, coating-free areas or aggregates. Among the various parameters studied, the pH of the sol appeared to play a role even more important than the viscosity. Indeed, the sol acidified with nitric acid showed a coating which was almost free of cracks or of large aggregates. Moreover, the use of a s... [more]

Biotechnologies based on microbial species capable of destroying harmful pollutants are a successful way to solve some of the most important problems associated with a clean environment. The subject of investigation is the Antarctic fungal strain Aspergillus glaucus AL1. The culturing of the examined strain was performed with 70 mg of wet mycelium being inoculated in a Czapek Dox liquid medium containing naphthalene, anthracene, or phenanthrene (0.3 g/L) as the sole carbon source. Progressively decreasing naphthalene and anthracene concentrations were monitored in the culture medium until the 15th day of the cultivation of A. glaucus AL1. The degradation was determined through gas chromatography−mass spectrometry. Both decreased by 66% and 44%, respectively, for this period. The GC-MS analyses were applied to identify salicylic acid, catechol, and ketoadipic acid as intermediates in the naphthalene degradation. The intermediates identified in anthracene catabolism are 2-hydroxy-1-napht... [more]

An integrated divertor simulation code, SONIC, has been developed in order to predict a self-consistent transport solution of the plasma, neutral and impurities in the scrape-off layer (SOL) and divertor. SONIC code has contributed to determining the divertor design and power handling scenarios for the Japanese (JA) fusion demonstration (DEMO) reactor. Radiative cooling scenario of Ar impurity seeding and the divertor performance have been demonstrated to evaluate the power exhaust scenarios with Psep = 230−290 MW. The simulation identified the decay length of the total parallel heat flux profile as being broader than the electron one, because of the ion convective transport from the outer divertor to the upstream SOL, produced by the plasma flow reversal. The flow reversal also reduced the impurity retention in the outer divertor, which may produce the partial detachment. Divertor operation margin of key power exhaust parameters to satisfy the peak qtarget ≤ 10 MWm−2 was determined in... [more]

Despite the research that has been conducted on biogas production from different waste materials through the anaerobic digestion process, there are still limited studies on their application for thermal systems. This paper presents an energetic and exergetic analysis of a multigeneration system comprising a micro-gas turbine, an organic Rankine cycle (ORC), an absorption chiller, and a water heater. It uses energy from biogas combustion produced through anaerobic co-digestion of food and animal waste. The reported biogas yield from 3 different studies was used in designing the fuel input for the system. The results showed that substrate combination of poultry manure and food waste (Biogas-A) needs 35.07 tons of volatile solids (tons-VS/day) of waste compared to 33.11 tons-VS/day for Biogas-B (Cattle manure and food waste), and 81.87 tons-VS/day for Biogas-C (swine manure and corn straw). For an increase in the methane content from 40% to 60%, the substrate amounts were reduced by 42.3%... [more]

A change in human development patterns is needed, including mankind’s environmental, economic, and social behavior. Engineering methods and practices have a substantial impact on the way to sustainable development. An overview of the guiding principles of sustainability, sustainable design, green engineering, and sustainable engineering is presented first. Sustainable engineering principles need to be updated to include the present state of the art in human knowledge. Therefore, the updated principles of sustainable development are presented, including traditional and more recent items: a holistic approach, sustainability hierarchies, sustainable consumption, resource scarcity, equalities within and between generations, all stakeholders’ engagement, and internalizing externalities. Environmental, social, and economic impacts that respect humans’ true needs and well-being are of importance to the future. The updated 12 principles include the tridimensional system’s approach, precautiona... [more]

Sucrose contributes to the key physical and sensory characteristics of cookies. Due to the negative health effects associated with excess sucrose consumption, the replacement of sucrose in baking applications is of interest. In this study, nine variations of rolled cookies were prepared (n = 3) using a sucrose control (C), Splenda for baking (SB), Equal for baking (EB), Truvia (TR), Sweet’N Low (SNL), and 1:1 (wt%) mixtures of sweeteners and sucrose (S). The cookies were characterized by a width-to-thickness (W/T) ratio, moisture loss, color, hardness, and fracturability. The W/T ratios of TR (5.7) and TR + sucrose (6.6) were similar, the closest to C (7.7), and bigger than (p < 0.05) all other treatments. Color was not affected (p > 0.05) by the sugar type or concentration. C showed the greatest hardness (5268 N), and SNL had the greatest fracturability (8667 N). Overall, regarding physiochemical characteristics, TR + sucrose (1:1 replacement) and SB (100% replacement) were the closes... [more]

Surrounding rock deformation control of gob-side coal-rock roadway in inclined coal seams (GCRICS) is a major problem in gob-side entry technology application practice. This paper describes a case study of the surrounding rock deformation characteristics and control technology of a typical GCRICS in Guizhou, China. As according to data obtained during a field investigation, the reasons for the deformation and failure of 151509 tailentry and the shortcomings of the original support scheme were analyzed. In combination with existing theory and field experience, the “anchor cable + U-shaped steel + shotcreting + grouting” (CUSG) support method was proposed. The plastic zone distribution, displacement, and stress evolution law of the roadway-surrounding rock under the four support modes were analyzed and compared by numerical simulation. The results show that the supporting effects of several support methods varied from good to poor; CUSG was the best, followed by anchor cable support, U-s... [more]

Focused on the troubles and defects introduced by the traditional single form of electric vehicle transmission, this paper proposes an electro-hydraulic power coupled electric vehicle based on the working principle of an electro-hydraulic power integrated drive system for light-duty cargo vehicles. The integration of the planetary row into the drive system allows the interconversion of mechanical, electrical, and hydraulic energy. By describing the system structure and composition, several working conditions during automobile driving are proposed, and the working principle of every circumstance is introduced. Simultaneously, the article determines the preliminary optimal ratio with the battery’s state of charge (SOC) as the constraint. Then, the orthogonal test matrix of electro-hydraulic ratios and speed thresholds for each operating condition is established according to Taguchi’s method. The impact of each optimized parameter on the motor torque and hydraulic torque as well as the SO... [more]

The development and adoption of digital twins (DT) for Quality-by-Design (QbD)-based processes with flexible operating points within a proven acceptable range (PAR) and automation through Advanced Process Control (APC) with Process Analytical Technology (PAT) instead of conventional process execution based on offline analytics and inflexible process set points is one of the great challenges in modern biotechnology. Virus-like particles (VLPs) are part of a line of innovative drug substances (DS). VLPs, especially those based on human immunodeficiency virus (HIV), HIV-1 Gag VLPs, have very high potential as a versatile vaccination platform, allowing for pseudotyping with heterologous envelope proteins, e.g., the S protein of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). As enveloped VLPs, optimal process control with minimal hold times is essential. This study demonstrates, for the first time, the use of a digital twin for the overall production process of HIV-1 Gag VLPs... [more]

This study focuses on aspects specific to adaptive mobile robotic systems. These include providing flexibility, high performance, the use of widely available element bases and others. The science intensity and technical level of the development of mobile robots are constantly growing. The element base of robots is constantly updated. In the presented article, the direction of research is related to the problems specific to mining robots. The use of research robots makes it possible to ensure safety of work in hard-to-reach places, monitor the status of active and idle mines, and find new minerals in idle mines, the processing of which was previously impossible. The article discusses the issues of ensuring the versatility of the design, the need to miniaturize robots, reducing the cost of the robot while maintaining high performance, achieving the required level of protection from environmental influences in mines, and compatibility with control systems. Various ways of navigating robot... [more]

An air curtain machine is used in the entrances and exits of public places where air conditioners are used. The high-speed centrifugal or axial fan blows out the air, creating an airflow barrier to prevent air convection inside and outside, reducing air conditioning losses, and maintaining the indoor air quality by preventing dust, insects, and harmful gases from entering the room. Observation of the airflow behavior was conducted using CFD simulation, to explore whether it has a blocking effect, and the air curtain principle was applied to the air purification equipment. It is mainly composed of several rows of arrayed hole air outlets to form a multi-composite air wall. The airflow on the two sides, or below, can be blocked by the composite air wall and integrated into the main airflow, so that the air walls will not affect each other, and form a barrier effect to prevent infection. This research includes the measurement of impedance characteristics for three layers of filters made o... [more]

In the era of Industry 4.0, numerous AI technologies have been widely applied. However, implementation of the AI technology requires observation, analysis, and pre-processing of the obtained data, which takes up 60−90% of total time after data collection. Next, sensors and features are selected. Finally, the AI algorithms are used for clustering or classification. Despite the completion of data pre-processing, the subsequent feature selection and hyperparameter tuning in the AI model affect the sensitivity, accuracy, and robustness of the system. In this study, two novel approaches of sensor and feature selecting system, and hyperparameter tuning mechanisms are proposed. In the sensor and feature selecting system, the Shapley Additive ExPlanations model is used to calculate the contribution of individual features or sensors and to make the black-box AI model transparent, whereas, in the hyperparameter tuning mechanism, Hyperopt is used for tuning to improve model performance. Implement... [more]

For β-cell replacement therapies, one challenge is the manufacturing of enough β-cells (Edmonton protocol for islet transplantation requires 0.5−1 × 106 islet equivalents). To maintain their functionality, β-cells should be manufactured as 3D constructs, known as spheroids. In this study, we investigated whether β-cell spheroid manufacturing can be addressed by a stirred-tank bioreactor (STR) process. STRs are fully controlled bioreactor systems, which allow the establishment of robust, larger-scale manufacturing processes. Using the INS-1 β-cell line as a model for process development, we investigated the dynamic agglomeration of β-cells to determine minimal seeding densities, spheroid strength, and the influence of turbulent shear stress. We established a correlation to exploit shear forces within the turbulent flow regime, in order to generate spheroids of a defined size, and to predict the spheroid size in an STR by using the determined spheroid strength. Finally, we transferred th... [more]

Technologies that predict the sources of substances diffused in the atmosphere, ocean, and chemical plants are being researched in various fields. The flows transporting such substances are typically in turbulent states, and several problems including the nonlinearity of turbulence must be overcome to enable accurate estimations of diffusion-source location from limited observation data. We studied the feasibility of machine learning, specifically convolutional neural networks (CNNs), to the problem of estimating the diffusion distance from a point source, based on two-dimensional, instantaneous information of diffused-substance distributions downstream of the source. The input image data for the learner are the concentration (or luminance of fluorescent dye) distributions affected by turbulent motions of the transport medium. In order to verify our approach, we employed experimental data of a fully developed turbulent channel flow with a dye nozzle, wherein we attempted to estimate th... [more]

In the context of climate change and the reduction in CO2 emissions from fossil fuel combustion, the integration of CO2 capture technologies in steam power plants is a key solution. The aim of this study was to analyze the use of ammonia, at different mass concentrations, in capturing post-combustion CO2 in a coal-fired power station and comparing it with the reference 30% MEA case. In this regard, a multi-criteria model was developed to establish the optimal solvent used, considering the least impact on technical performance, economic, and environmental indicators. As a result, the lowest CO2 capture cost was obtained for the CO2 capture process based on 7% NH3, with 59.07 €/tCO2. Integration of the CO2 capture process is more economically viable when the CO2 emissions tax is higher than 70 €/tCO2 for 7% NH3 and 15% NH3, 80 €/tCO2 for 5% NH3 and 30% MEA, and 90 €/tCO2 for 2% NH3. Regarding the overall efficiency, the energy penalty associated with the CO2 capture process integration v... [more]

Researchers have scrutinized data hiding schemes in recent years. Data hiding in standard images works well, but does not provide satisfactory results in distortion-sensitive medical, military, or forensic images. This is because placing data in an image can cause permanent distortion after data mining. Therefore, a reversible data hiding (RDH) technique is required. One of the well-known designs of RDH is the difference expansion (DE) method. In the DE-based RDH method, finding spaces that create less distortion in the marked image is a significant challenge, and has a high insertion capacity. Therefore, the smaller the difference between the selected pixels and the more correlation between two consecutive pixels, the less distortion can be achieved in the image after embedding the secret data. This paper proposes a multilayer RDH method using the multilevel thresholding technique to reduce the difference value in pixels and increase the visual quality and the embedding capacity. Opti... [more]

The high intensity of solar radiation and long sunshine time in the Turpan area lead to the necessity of sunshade construction. Sunshade components can effectively block direct solar radiation and the secondary heating of buildings. Through the analysis of the importance and sensitivity of sunshade components, it was found that the importance of sunshade components accounts for the largest proportion of multi-parameters, and the sensitivity of sunshade components accounts for about 60% of the total. At the same time, the change in sunshade length has an important influence on the proportion of air conditioning energy consumption and space comfort when the sunshade length reached the 0.6 m−0.8 m range. The energy consumption curve of air conditioning no longer decreased and tended to be horizontal, which showed that a sunshade could effectively reduce the energy consumption of air conditioning, while the PMV comfort curve gradually increased and tended to be horizontal, indicating that... [more]

(1) Background: This study aimed to investigate the feasibility of using Maackia amurensis branch extract as a cosmetic ingredient with skin-whitening and antiwrinkle effects. (2) Methods: The skin-whitening effect of M. amurensis branch extract was confirmed by investigating α-melanocyte-stimulating hormone (α-MSH)-induced melanin synthesis and melanogenic protein expression in B16F1 cells. The antiwrinkle effect of M. amurensis branch extract was verified by assessing matrix metalloproteinase (MMP)-1 expression and soluble collagen content in CCD-986sk cells. The major compounds in M. amurensis branch extract were identified through isolation and characterization and confirmed by high-performance liquid chromatography analysis. (3) Results: M. amurensis branch extract significantly inhibited α-MSH-induced melanin synthesis by 49%, 42%, and 18% at 50, 37.5, and 25 μg/mL concentrations, respectively, compared with the negative control (NC). M. amurensis branch extract also significantl... [more]

Efficient and reasonable utilization of waste biomass resources can not only avoid serious waste of material resources, but also solve the problem of environmental pollution. Therefore, the development of efficient and environmentally friendly waste biomass carbonization technology has important practical significance. Here, the activated carbon from orange peel (OAC) is prepared by potassium hydroxide (KOH) activation combined with high-temperature carbonization. The adsorption effects of OAC on three different pollutant aqueous solutions, methylene blue (MB), tetracycline (TC), and fluorescein sodium (NaFL), are examined. The OAC absorbent has excellent adsorption capacity for MB, TC, and NaFL pollutants of 10 mg L−1, with adsorption rates of 99.17%, 73.5%, and 94.24%, respectively. This study provides a new idea for turning waste biomass into treasure and eliminating the hidden danger of environmental pollution.