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Showing records 36800 to 36824 of 43292. [First] Page: 1 1469 1470 1471 1472 1473 1474 1475 1476 1477 Last
36800. LAPSE:2023.2331
Rapid Site Selection of Shale Gas Multi-Well Pad Drilling Based on Digital Elevation Model
February 21, 2023 (v1)
Subject: Energy Systems
Keywords: genetic clustering algorithm, multi-well pad drilling, platform location, shale gas
Drilling and completion platform construction is a fundamental part of oil and gas reservoir development, and the location of construction directly affects the whole process of shale gas drilling and development. Due to the complex surface conditions and fragile ecological environment in mountainous areas, having an appropriate platform location can significantly reduce shale gas development and environmental costs. The DEM (digital elevation model) includes geographic elevation, surface complexity, land use type, and other data, so it can be used for rapid site selection for shale gas multi-well pad drilling. In this study, first, research results related to drilling platform site selection were analyzed and summarized, and then a platform site selection method aiming to minimize the total well construction cost was developed. Second, the well construction costs were decomposed into the surface construction costs and the underground construction costs, and the site selection model wit... [more]
36801. LAPSE:2023.2330
Effect of Conical Spiral Flow Channel and Impeller Parameters on Flow Field and Hemolysis Performance of an Axial Magnetic Blood Pump
February 21, 2023 (v1)
Subject: Modelling and Simulations
Keywords: axial flow, blood pump, hemolysis performance, magnetic levitation, particle tracking method
For a blood pump, the blood flow channel and impeller parameters directly affect the performance of the pump and the resulting blood circulation. The flow channel in particular has a great impact on the hydraulic performance of the pump (e.g., flow and pressure), which directly determines the overall performance of the blood pump. Traditional bearing-supported blood pumps can cause mechanical damage to blood cells, leading to hemolysis and thrombosis. In this study, therefore, we designed a conical spiral axial blood pump with magnetic levitation. The blood pump was supported by electrodynamic bearings in the radial direction and electromagnetic bearings in the axial direction. The impeller and the front and rear hubs were integrated to minimize blood stagnation and reduce the formation of thrombosis. The hub had a conical spiral flow channel design, which not only reduced the size of the impeller but also increased blood flow and pressure while meeting the design requirements. Computa... [more]
36802. LAPSE:2023.2329
Managing Supply Chain Complexity and Sustainability: The Case of the Food Industry
February 21, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: complexity theory, cyber-physical systems, food industry, supply chain management, Sustainability
Consumer demand for organic products, rapidly growing urbanizations levels requires the food supply chain to reduce lead-time and maintain higher product quality. For the food supply chain to cope with the raising issues an e-commerce type of supply chain must be implemented. This approach creates challenges for supply chain, because the food industry must shift towards high variety and low quantity freight forwarding with multiple delivery points. The methodology of the paper consists of scientific literature analysis and macro indicator clustering. The author of the paper proposes a supply chain management framework, which is grounded through complexity theory. The framework mainly consists of 3 characteristics, which organizations should operationalize to maintain system resilience and which in the long-run would evolve to sustainable development−capabilities, collaboration, complexity management. The proposed framework defines how operational and tactical levels should be automated... [more]
36803. LAPSE:2023.2328
Study on the Heat Transfer Characteristics of an Ambient Air Vaporizer with Multi-Component Fluids
February 21, 2023 (v1)
Subject: Environment
Keywords: environmental parameters, heat transfer coefficient, multi-component, regasification, the ambient air vaporizer (AAV)
China’s LNG import volume in 2021 reached 121.356 million tons, which makes China the largest importer in the world. The ambient air vaporizer (AAV) for LNG vaporization is an ideal selection for minimizing the average monetary value of terminals and maximizing operating efficiency. However, the heat and mass transfer performance of real multi-component LNG is not the same as that of the pure component in AAV; what is more, deep cryogenic and multi-component characteristics of LNG could lead to the deterioration of heat-transfer performance, which may cause catastrophic consequences. Thus, this difficulty should be concerning and solved in its operation. Based on the law of conservation of energy and mass, a heat and mass transfer model was established that can calculate the coupled heat transfer from the LNG to the air-side of the AAV along its own length. Empirical correlations are proposed to predict some basic properties of the frost layer at the outside of the tube, where the inte... [more]
36804. LAPSE:2023.2327
Electrospun SF/PLGA/ICG Composite Nanofibrous Membranes for Potential Wound Healing and Tumor Therapy
February 21, 2023 (v1)
Subject: Process Control
Keywords: controlled release, indocyanine green, nanofibrous membranes, near-infrared
Indocyanine green (ICG) is a near-infrared (NIR) organic reagent for clinical bioimaging and phototherapy. It is a suitable photosensitizer for photodynamic antimicrobial chemotherapy (PACT). In this study, various ICG-loaded nanofibrous membranes were prepared. The water vapor transmission rate (WVTR) of SF/PLGA/20ICG was 3040.49 ± 157.11 g·m−2 day−1, which allowed the maintenance of a humid environment above the wound. The growth inhibition rates for S. aureus and E. coli were 91.53% and 87.95%, respectively. The nanofibrous membranes exhibited excellent antimicrobial performance. Cellular experiments showed that the nanofibrous membranes have good cytocompatibility and antitumor efficacy. SF/PLGA/20ICG showed good potential for application in wound healing and cancer therapy.
36805. LAPSE:2023.2326
Leaching Kinetics of Aluminum from Alkali-Fused Spent Cathode Carbon Using Hydrochloric Acid and Sodium Fluoride
February 21, 2023 (v1)
Subject: Energy Systems
Keywords: acid leaching, Avrami equation, kinetics, spent cathode carbon of aluminum electrolysis
Abundant carbon resides in spent cathode carbon (SCC) of aluminum electrolysis and its high-purity carbon powder is conducive to high-value recycling. The alkali-fused SCC was separated and effectively purified using an HCl/NaF solution. Effects of particle size, leaching temperature, time, initial acid concentration, and sodium fluoride dosage, on the purity of carbon powder and aluminum removal rate, were investigated. Using aluminum as the research object, kinetics of aluminum acid leaching were examined by single-factor experiments. Results showed that under an initial 4 M HCl concentration, particle size D(50) = 67.49 μm, liquid-solid ratio of 15:1, 333 K, 120 min, 0.3 M NaF, carbon powder with ash level below 1% were obtained in subsequent purification of SCC. The leaching process was described by Avram equation, the model characteristic parameter was 0.75147 and the apparent activation energy was 22.056 kJ/mol, which indicated a mixed control mechanism between chemical reactivit... [more]
36806. LAPSE:2023.2325
A New Method for Measuring Water Holdup of Oil-Water Two-Phase Flow in Horizontal Wells
February 21, 2023 (v1)
Subject: Modelling and Simulations
Keywords: conductance sensor, horizontal well, oil-water two-phase flow, production profile logging, water holdup
The production profile logging technology of Oil-water two-phase flow is an important support technology for efficient development of horizontal oil wells. Moreover, the water holdup of Oil-water two-phase flow is one of the important dynamic measurement parameters for production profile logging technology. Flow patterns in horizontal oil wells are more complex than those in vertical oil wells, making water holdup measurements more difficult. In China, horizontal oil wells are characterized by low liquid production, high water cut and layered development; hence, the concentrating flow logging scheme is adopted to reduce the effects of flow patterns on measurement. In this paper, we proposed a new method of measuring water holdup of Oil-water two-phase flow for the production profile logging in horizontal oil wells. Firstly, the structure of water holdup sensors and the measuring principle of water holdup were introduced. Secondly, the dynamic test research was carried out on the horizo... [more]
36807. LAPSE:2023.2324
Transient Pressure and Temperature Analysis of a Deepwater Gas Well during a Blowout Test
February 21, 2023 (v1)
Subject: Modelling and Simulations
Keywords: coupled model of pressure and temperature field, deepwater gas well testing, multiphase flow, numerical simulation, transient flow
On one hand, a blowout test can clean the bottom of the well, and on the other, it can learn the productivity of the well, which is important work before putting the well into production and also the main basis for production allocation of the well. The accurate prediction of the blowout test process provides a theoretical basis for the design of a reasonable blowout test system and the determination of well cleaning time. During deepwater blowout tests, gas and liquid flows are unsteady in pipes, and flow parameters change over time. At present, accurately predicting changes in fluid temperature, pressure, liquid holdup, and other parameters in a wellbore during an actual blowout process using the commonly used steady-state prediction methods is difficult, and determining whether a test scheme is reasonable is impossible. Therefore, based on the conservation of mass, momentum, and energy during the blowout test process, in this study, formation, wellbore, and nozzle flows were coupled... [more]
36808. LAPSE:2023.2323
Thermal-Induced Autolysis Enzymes Inactivation, Protein Degradation and Physical Properties of Sea Cucumber, Cucumaria frondosa
February 21, 2023 (v1)
Subject: Biosystems
Keywords: autolysis enzyme, Cucumaria frondosa, inactivation, protein denaturation, texture, thermal processing
The main objective is to effectively denature the autolysis enzymes of C. frondosa on the premise of avoiding the quality deterioration caused by overheating. The effects of the different thermal treatments (blanching at 40−80 °C for 45 min, boiling and steaming at 100 °C for 15−120 min) on the cooking yield, moisture content, protein degradation, texture, and enzyme inactivation were studied, and the inner relationship was investigated by multivariate analysis. The autolysis enzymes of C. frondosa were thermally stable and cannot be denatured completely by blanching. Boiling and steaming could efficiently inactivate the enzymes but overheating for 60−120 min reduced the cooking yield and texture quality. Boiling at 100 °C for 45 min was suitable for pre-treatment, with cooking yield of 70.3% and protein content of 78.5%. Steaming at 100 °C for at least 30 min was preferable for long-term storage and instant food, in which the relative activity was only 3.2% with better palatability.
36809. LAPSE:2023.2322
A New Biosurfactant/Bioemulsifier from Gordonia alkanivorans Strain 1B: Production and Characterization
February 21, 2023 (v1)
Subject: Materials
Keywords: critical micelle concentration, emulsification index, G. alkanivorans strain 1B, new biosurfactant/bioemulsifier, surface tension
Biosurfactants and bioemulsifiers (BS/BE) are naturally synthesized molecules, which can be used as alternatives to traditional detergents. These molecules are commonly produced by microorganisms isolated from hydrocarbon-rich environments. Gordonia alkanivorans strain 1B was originally found in such an environment, however little was known about its abilities as a BS/BE producer. The goal of this work was to access the potential of strain 1B as a BS/BE producer and perform the initial characterization of the produced compounds. It was demonstrated that strain 1B was able to synthesize lipoglycoprotein compounds with BS/BE properties, both extracellularly and adhered to the cells, without the need for a hydrophobic inducer, producing emulsion in several different hydrophobic phases. Using a crude BS/BE powder, the critical micelle concentration was determined (CMC = 16.94 mg/L), and its capacity to reduce the surface tension to a minimum of 35.63 mN/m was demonstrated, surpassing many... [more]
36810. LAPSE:2023.2321
Open Tubular Column Immobilized with Covalent Organic Frameworks for Rapid Separation of Small Molecular Compounds by Capillary Electrochromatography
February 21, 2023 (v1)
Subject: Materials
Keywords: benzoic acids, capillary electrochromatography, covalent organic frameworks, open-tubular column, parabens, sulfonamides
Preparation of a novel TpBD (synthesized from phloroglucinol and benzidine) covalent organic framework (COF) immobilized open-tubular (OT) capillary is described by in situ growth strategy. The stationary phase in the column was characterized by Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD), thermogravimetric analysis (TGA), nitrogen adsorption−desorption isotherms, scanning electron microscope (SEM), transmission electron microscopy (TEM) and energy-dispersive X-ray spectrum (EDS). Several families of compounds with different properties (alkylbenzenes, parabens, sulfonamides and benzoic acids) were selected to evaluate the performance of the TpBD COF immobilized capillary. The results showed that the stationary phase was uniform with about 6.0 μm thickness under the optimal preparation conditions, and the relative standard deviations (RSDs) were no more than 3.13% of alkylbenzenes on the TpBD COF immobilized capillary for 11 consecutive runs, which exhibited its e... [more]
36811. LAPSE:2023.2320
Numerical and Experiment Investigation on Novel Guide Vane Structures of Turbo Air Classifier
February 21, 2023 (v1)
Subject: Modelling and Simulations
Keywords: guide vane, numerical simulation, particle classification efficiency, tromp curves, turbo air classifier
In this paper, three types of air guide vanes are designed: direct-type, L-type, and logarithmic spiral type, respectively. ANSYS-FLUENT 20.0 is used to numerically simulate the internal flow field of turbo air classifier by novel different structures. The numerical results show that the guide vane structures have a good effect on the flow field stability of the annular function zone in the classifying chamber. The distribution of tangential velocity and radial velocity verified the logarithmic spiral guide vane, and makes the airflow flow along the rotor cage circumferentially uniformly. In addition, the turbulent dissipation rate and energy loss decreases in the rotor cage region, which also shows that the guide vane is beneficial to improve classification performance. The tromp curve of the numerical simulation shows that the logarithmic spiral guide vane reduced the cutting size by 6.3% and 23.7% at two different process parameters, and is obviously better than other guide vane str... [more]
36812. LAPSE:2023.2319
A Review of Digital Transformation on Supply Chain Process Management Using Text Mining
February 21, 2023 (v1)
Subject: Planning & Scheduling
Keywords: analytics, Big Data, digital transformation, Industry 4.0, supply chain management, text mining
Industry 4.0 technologies are causing a paradigm shift in supply chain process management. The digital transformation of the supply chains provides enormous benefits to organizations by empowering collaboration among multiple internal and external organizations and systems. This study presents a narrative review explaining the existing knowledge on digital transformation in supply chain process management using text mining. It summarizes the existing literature to explain the current state of the art in supply chain digitalization. This comprehensive review identifies the most important topics and technologies and determines the future trends in this emerging field. We investigate the articles published in Web of Science and Scopus databases and use text mining techniques (clustering and topic modeling) on the article contents. Using VOS viewer, a bibliometric analysis of 395 articles with 12,700 references is analyzed. The contents of the articles are explored using text mining approa... [more]
36813. LAPSE:2023.2318
Bio-Refinery of Oilseeds: Oil Extraction, Secondary Metabolites Separation towards Protein Meal Valorisation—A Review
February 21, 2023 (v1)
Subject: Biosystems
Keywords: alternative solvents, anti-nutritional factors, oil extraction, oilseed, protein meal, secondary metabolites
Edible oil extraction is a large and well-developed sector based on solvent assisted extraction using volatile organic compounds such as hexane. The extraction of oil from oilseeds generates large volumes of oilseed by-products rich in proteins, fibres, minerals and secondary metabolites that can be valued. This work reviews the current status and the bio-macro-composition of oilseeds, namely soybean, rapeseed, sunflower and flaxseed, and the refining process, comprising the extraction of oil, the valorisation and separation of valuable secondary metabolites such as phenolic compounds, and the removal of anti-nutritional factors such as glucosinolates, while retaining the protein in the oilseed meal. It also provides an overview of alternative solvents and some of the unconventional processes used as a replacement to the conventional extraction of edible oil, as well as the solvents used for the extraction of secondary metabolites and anti-nutritional factors. These biologically active... [more]
36814. LAPSE:2023.2317
Quantitative Design Method for Grouting in Sand Layers: Practice in Qingdao Metro Line 2
February 21, 2023 (v1)
Subject: Process Design
Keywords: diffusion, fracture-compaction mode, grouting design, permeation mode, reinforcement effect, sand
Grouting is an effective method to reduce permeability and improve the mechanical performance of sand layers, preventing a disastrous inrush of sand and water. A scientific grouting design scheme is the premise for satisfying grouting reinforcement requirements. Due to a lack of theoretical basis for current grouting designs, grouting projects are conducted empirically and blindly. This paper presents a quantitative design method for grouting in sand layers. Based on this method, a quantitative design is realized for judgment of the grouting mode, determination of grouting range and calculation of grouting reinforcement effect. Moreover, for the fracture−compaction grouting mode, a theoretical model is proposed to calculate the grouting process, considering the coupling effect of grout flow and sand layer deformation. Meanwhile, a calculation method for reinforcement is put forward, which can connect macroscopic performance of the grouted body and individual performance of grout veins,... [more]
36815. LAPSE:2023.2316
Challenges in Using Handheld XRFs for In Situ Estimation of Lead Contamination in Buildings
February 21, 2023 (v1)
Subject: System Identification
Keywords: buildings, calibration, contamination, identification, in situ measurements, lead, paints, quantification, XRF
Lead in buildings can be found in certain materials such as paints or can be a result of contamination during the use stage. In situ methods for lead identification can be vital for the proper treatment of hazardous CDW (from repair works or selective demolition). A conventional handheld XRF (HHXRF) spectrometer can be used for this purpose, and this study analysed its reliability. A laboratory experiment was conducted to test different calibrations, and to establish a procedure for the conversion of the HHXRF lead concentrations into lead loadings. Model latex paint with a constant lead content was used on two types of surfaces (plasterboard and concrete). A field study was performed to identify and quantify the lead in paint on masonry walls in a public building. ICP-MS analysis was performed in order to verify the lead content. The coefficients of proportionality in the proposed model depend on various parameters: the contamination type, the layer thickness, the substrate, and the b... [more]
36816. LAPSE:2023.2315
An Empirical Investigation to Understand the Issues of Distributed Software Testing amid COVID-19 Pandemic
February 21, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: best practices, remote work, software quality assurance, software testing, test automation
Generally, software developers make errors during the distributed software development process; therefore, software testing delay is a significant concern. Some of the software mistakes are minor, but others may be costly or harmful. Since things can still go wrong—individuals encounter mistakes from time to time—there is a need to double-check any software we develop in a distributed environment. The current global pandemic, COVID-19, has exacerbated and generated new challenges for IT organizations. Many issues exist for distributed software testing that prevent the achievement of successful and timely risk reduction when several of the mechanisms on which testing is based are disrupted. The environment surrounding COVID-19 is quickly evolving on a daily basis. Moreover, the pandemic has exposed or helped to develop flaws in production systems, which obstruct software test completion. Although some of these issues were urgent and needed to be evaluated early during the distributed so... [more]
36817. LAPSE:2023.2314
Optimization of Phycobiliprotein Solubilization from a Thermotolerant Oscillatoria sp.
February 21, 2023 (v1)
Subject: Biosystems
Keywords: allophycocyanin, biomass/solvent ratio, cell lysis, drying, phycocyanin, phycoerythrin, surface response methodology
The present study evaluated the effect of multiple variables (drying time, drying temperature, biomass/solvent ratio, glass beads/biomass ratio, extraction time, and extraction speed) in the solubilization of three different phycobiliproteins (C-PC, APC, and PE) from a thermotolerant Oscillatoria sp. The strain was grown in BG11 media (28 °C, light: dark cycle of 12:12 h at 100 µmol·m−2·s−1, 20 days) and the experiments were conducted according to a two-level randomized factorial design with six center points (38 runs). Results show that biomass/solvent ratio, glass beads/biomass ratio, and extraction time, are the most significant variables in the extraction of all three proteins, whereas the glass beads/biomass ratio and extraction time significantly affect their purity. The optimized conditions allow a statistical increase in the concentration of C-PC, APC, and PE extracted from the biomass; however, the purity was lower in comparison with the expected value. The latter occurs due t... [more]
36818. LAPSE:2023.2313
Contamination of Heavy Metals in Sediments from an Estuarine Bay, South China: Comparison with Previous Data and Ecological Risk Assessment
February 21, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: ecological risk, heavy metal, sediment, Shantou Bay
Heavy metal contamination is an elevating threat to the aquatic environment of estuarine bays. In the present study, surface sediments from Shantou Bay in South China were collected and detected for the concentrations of heavy metals including copper (Cu), zinc (Zn), chromium (Cr), nickel (Ni), cadmium (Cd), and lead (Pb) using ICP-MS. Spatial distribution, temporal trend, and potential ecological risks for the metal pollution were discussed. The results showed that levels of metals generally decreased by the order of Zn > Pb > Cr > Cu > Ni > Cd. Spatial variation of metal contents was observed with an order of Rongjiang River > Niutian Bay > Shanthou Harbor for Zn and Cd. Sediments of the Niutian Bay were observed with higher levels of Cu, Cr, Ni, and Pb. Compared with reported data from the same region at different sampling periods, a low−high−low trend was observed for the concentrations of the six elements, suggesting a great improvement of sediment quality in Shantou Bay. The aver... [more]
36819. LAPSE:2023.2312
A Lean Manufacturing Progress Model and Implementation for SMEs in the Metal Products Industry
February 21, 2023 (v1)
Subject: Materials
Keywords: lean manufacturing, process improvement, SMEs, VSM (value stream map)
The manufacturing industry faces the challenge of small and diversified customer orders. To meet this challenge, strong internal production capabilities are required. A lean manufacturing process that uses fewer resources and offers greater process improvement will help SMEs to continue to contribute to the global economy. Though SMEs provide most employment opportunities, previous studies have focused on large companies in auto-manufacturing-related industries. With the commitment and support of the management, and the application of a value stream map (VSM) and related improvement tools, we produced a practical process improvement model for a lean manufacturing system in an SME. With the commitment and support of the management and the joint efforts of the project improvement staff, the 10 improvement projects over a six-month period all achieved their goals: reduction in lead time from 26 days to 19.5 days, improvement of welding per people per hour (PPH) efficiency by 28.3%, improv... [more]
36820. LAPSE:2023.2311
Preparation and Characterization of Porous Carbon Composites from Oil-Containing Sludge by a Pyrolysis-Activation Process
February 21, 2023 (v1)
Subject: Materials
Keywords: acid-washing, Fe/C composite, oil-containing sludge, pore analysis, thermal activation
Large amounts of oil-containing sludge (OS) are produced in the energy, industry and services sectors. It is mainly composed of residual oil and particulate matter, thus posing an environmental threat and leading to resource depletion if it is improperly handled. In this work, the OS feedstock was thermally treated to produce porously magnetic carbon composites (CC) using a pyrolysis-activation process. Using the data on the thermogravimetric analysis (TGA) of the OS feedstock, the thermal activation experiments were performed at 850 °C as a function of residence time (30, 60 and 90 min). The results of pore analysis for the resulting CC products showed that the Brunauer−Emmett−Teller (BET) surface area greatly decreased from 21.59 to 0.56 m2/g with increasing residence time from 30 to 90 min. This decline could be associated with continuous gasification by CO2, thus causing the removal of limited carbon on the surface of CC for a longer reaction time. Furthermore, the physical propert... [more]
36821. LAPSE:2023.2310
Research on the Construction and Application Mode of Digital Plans for Sudden Water Pollution Events
February 21, 2023 (v1)
Subject: Process Control
Keywords: decision support system, digital emergency plan, emergency plan management, emergency response, knowledge visualization, sudden water pollution events
Water pollution is an important aspect of a national water treatment. Sudden water safety incidents are random and destructive, often bringing about huge losses of life and property. Due to the uncertainty of sudden water pollution, it is difficult to respond in a timely and rapid manner. Emergency personnel must deal with emergencies quickly and effectively to reduce the harm caused by these emergencies. The randomness and uncertainty of sudden water pollution events make emergency work more complicated; it is difficult for current emergency plans to play guiding roles in complex responses. The decision-making and use of traditional water safety procedures largely depend on the experiences of command personnel, as well as on the emergency plan, which often has poor applicability. This can result in ineffective implementation of emergency actions and use of resources stemming from the high subjectivity and low efficiency of emergency plans. In this paper, we summarize previous research... [more]
36822. LAPSE:2023.2309
A GAPN Approach for the Flexible Job-Shop Scheduling Problem with Indirect Energy and Time-of-Use Electricity Pricing
February 21, 2023 (v1)
Subject: Planning & Scheduling
Keywords: flexible job-shop scheduling, Genetic Algorithm, indirect energy, petri nets, time-of-use pricing
The flexible job-shop scheduling problem with indirect energy and time-of-use (ToU) electricity pricing (FJSP-IT) is investigated. Considering the production cost, which includes the indirect energy cost, direct energy cost and time cost, the cost evaluation model under ToU pricing is built. To minimize the total production cost of the FJSP-IT, an approach based on a genetic algorithm and Petri nets (GAPN) is presented. Under this approach, indirect energy and direct energy are modeled with Petri net (PN) nodes, the operation time is evaluated through PN simulation, and resource allocation is fine-tuned through genetic operations. A group of heuristic operation time policies, especially the exhausting subsection policy and two mixed policies, are presented to adapt to the FJSP-IT with vague cost components. Experiments were performed on a data set generated from the banburying shop of a rubber tire plant, and the results show that the proposed GAPN approach has good convergence. Using... [more]
36823. LAPSE:2023.2308
Design of Linear PID Controller for Pure Integrating Systems with Time Delay Using Direct Synthesis Method
February 21, 2023 (v1)
Subject: Process Design
Keywords: disturbance rejection, PID controller, pure integrating system, regulatory performance, set-point filter, time delay
The pure integrating process model with dead-time is inherently an unstable open-loop system. This paper presents a 2-DOF (2-degree of freedom) PID controller, based on the direct synthesis (DS) method, to improve the set-point tracking and load disturbance rejection performance for the pure integrating processes with time delays (PIPTD) models. The 2-DOF PID controller consists of a linear PID controller for rejecting the load disturbance in regulatory response and a set-point filter for relieving the overshoot in servo response. The DS method is based on comparing the desired closed-loop characteristic equation with the closed-loop characteristic equation, consisting of plant and PID controller. The adjustment parameter is only one desired time constant, with the roots of the desired characteristic equation placed at the same location, and the desired time constant was expressed as a function of the maximum magnitude of the sensitivity function (MS), for providing convenience in the... [more]
36824. LAPSE:2023.2307
Deep Eutectic Solvent-Based Coating Sorbent for Preconcentration of Formaldehyde by Thin-Film Solid-Phase Microextraction Technique
February 21, 2023 (v1)
Subject: Environment
Keywords: benzyldimethylhexadecylammonium chloride, deep eutectic solvent, formaldehyde, lauric acid, thin-film solid-phase microextraction
A thin-film solid-phase microextraction method with a sorbent composed of a deep eutectic solvent was developed for the preconcentration of formaldehyde from river and lake water samples. Four new deep eutectic solvents (DESs) were synthesized, each in molar ratios 1:1, 1:2, and 1:3. Among prepared compounds, the greatest efficiency in the proposed method of preconcentration of formaldehyde derivatized with Nash reagent was demonstrated by DES-3 consisting of benzyldimethylhexadecylammonium chloride and lauric acid, in a molar ratio of 1:3. For the proposed method, the parameters affecting the extraction efficiency of formaldehyde were optimized (including the choice of DES-based sorbent and desorption solvent as well as the sample volume and pH, the salting-out effect, the extraction time, and the desorption time). Under optimal conditions, the proposed method achieved good precision between 3.3% (for single sorbent) and 4.8% (for sorbent-to-sorbent) as well as good recovery ranging f... [more]
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