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Energy Storage Charging Pile Management Based on Internet of Things Technology for Electric Vehicles
Zhaiyan Li, Xuliang Wu, Shen Zhang, Long Min, Yan Feng, Zhouming Hang, Liqiu Shi.
June 9, 2023 (v1)
Keywords: charging piles, cloud service platform, EV, integration of charging and storage, Internet of Things.
The traditional charging pile management system usually only focuses on the basic charging function, which has problems such as single system function, poor user experience, and inconvenient management. In this paper, the battery energy storage technology is applied to the traditional EV (electric vehicle) charging piles to build a new EV charging pile with integrated charging, discharging, and storage; Multisim software is used to build an EV charging model in order to simulate the charge control guidance module. On this basis, combined with the research of new technologies such as the Internet of Things, cloud computing, embedded systems, mobile Internet, and big data, new design and construction methods of the energy storage charging pile management system for EV are explored. Moreover, K-Means clustering analysis method is used to analyze the charging habit. The functions such as energy storage, user management, equipment management, transaction management, and big data analysis ca... [more]
Task Containerization and Container Placement Optimization for MEC: A Joint Communication and Computing Perspective
Ao Liu, Shaoshi Yang, Jingsheng Tan, Zongze Liang, Jiasen Sun, Tao Wen, Hongyan Yan.
June 9, 2023 (v1)
Subject: Optimization
Keywords: cloud computing, computing force network, computing power network, container, edge computing, joint communication and computing, workflow.
Containers are used by an increasing number of Internet service providers to deploy their applications in multi-access edge computing (MEC) systems. Although container-based virtualization technologies significantly increase application availability, they may suffer expensive communication overhead and resource use imbalances. However, so far there has been a scarcity of studies to conquer these difficulties. In this paper, we design a workflow-based mathematical model for applications built upon interdependent multitasking composition, formulate a multi-objective combinatorial optimization problem composed of two subproblems—graph partitioning and multi-choice vector bin packing, and propose several joint task-containerization-and -container-placement methods to reduce communication overhead and balance multi-type computing resource utilization. The performance superiority of the proposed algorithms is demonstrated by comparison with the state-of-the-art task and container scheduling... [more]
An Authenticated Group Shared Key Mechanism Based on a Combiner for Hash Functions over the Industrial Internet of Things
Waleed Ali, Adel Ali Ahmed.
June 9, 2023 (v1)
Keywords: AGSK, ECDH, IIoT, random oracle model.
The Industrial Internet of Things (IIoT) provides internet connectivity for instruments, digital machines, and any other manufactured object to enable intelligent industrial operations to achieve high productivity. Securing communications between IIoT devices remains a critical and challenging issue due to the resource-constrained and processing capabilities of sensing devices. Moreover, the traditional group shared key might implement complex mathematical operations that are not suitable for the limited recourse capability of the IIoT device. Furthermore, the standard Diffie−Hellman (DH) and elliptic curve Diffie−Hellman (ECDH), which are the most suited for tiny devices, only work between a pair of IIoT devices, while they are not designed to work among a group of IIoT devices. This paper proposes an authenticated group shared key (AGSK) mechanism that allows a set of industrial objects to establish a common session key over the IIoT. The proposed AGSK utilizes the combiner for the h... [more]
In Vitro Effect of Molasses Concentration, pH, and Time on Chromium Removal by Trichoderma spp. from the Effluents of a Peruvian Tannery
Fabricio A. Tello-Galarreta, Juan H. Durand-Paz, Walter Rojas-Villacorta, Luis Cabanillas-Chirinos, Magaly De La Cruz-Noriega, Renny Nazario-Naveda, Santiago M. Benites, Segundo Rojas-Flores.
June 9, 2023 (v1)
Subject: Biosystems
Keywords: chromium removal, molasses, pH, tannery effluents, Trichoderma.
The effluents generated by the tannery industry have a high content of chromium and other toxic elements, representing a potential threat to ecosystems. An eco-friendly alternative to treat these effluents is the use of microorganisms, such as fungi, with the capacity to biosorb heavy metals. The present work aims to determine the effect of the molasses concentration, pH variation, and time on the removal of total chromium using the filamentous fungus Trichoderma spp. An experimental design was adopted using pH (4 and 6), concentrations of molasses (0.5 and 1%), and time (8 and 12 days) as independent variables. The Trichoderma inoculum was constant in all the treatments. The different treatments were evaluated after 0, 8, and 12 days by taking 50 mL of sample from each bioreactor. The chromium concentration was subsequently determined in each sample. The results show that treatment 3 (1% molasses and pH 4) showed higher chromium removal after both 8 and 12 days. The concentrations of... [more]
Exploring Relationships among Crude Oil, Bitcoin, and Carbon Dioxide Emissions: Quantile Mediation Analysis
Tzu-Kuang Hsu, Wan-Chu Lien, Yao-Hsien Lee.
June 9, 2023 (v1)
Keywords: Brent crude (BRT), CO2 emissions, cryptocurrency, nonlinear inverted U-shaped curve, Renewable and Sustainable Energy.
Crude oil, Bitcoin, and carbon dioxide emissions are major issues that are significantly impacting the global economy and environment. These three issues are complexly interlinked, with profound economic and environmental implications. In this study, we explore the correlation among these three issues and attempt to understand the influence of crude oil and Bitcoin on carbon dioxide emissions. We created a novel approach, named quantile mediation analysis, which blends mediation regression with quantile regression, enabling us to explore the influence of Brent crude oil on carbon dioxide emissions by considering the mediating impact of Bitcoin. According to the findings from using our new approach, the impact of Brent crude oil on carbon dioxide emissions is partly mediated by Bitcoin, and the association between Brent crude oil and carbon dioxide emissions involves both direct and indirect effects. Since the carbon dioxide generated by the extraction of crude oil and Bitcoin has a gre... [more]
Rapeseed Meal Waste Biomass as a Single-Cell Protein Substrate for Nutritionally-Enhanced Feed Components
Dawid Dygas, Wiktoria Liszkowska, Aleksandra Steglińska, Michael Sulyok, Dorota Kręgiel, Joanna Berłowska.
June 9, 2023 (v1)
Subject: Biosystems
Keywords: crude fiber, rapeseed meal, single-cell protein, waste biomass valorization, yeast fermentation.
Rapeseed meal (RM) is produced in large quantities as a byproduct of oil extraction from rapeseeds. However, the efficient utilization of RM as animal feed is limited by its low metabolizable energy, poor palatability, and high levels of fiber and anti-nutritional components. Here, we investigate the potential of enriching RM with single-cell protein through fermentation with conventional and unconventional yeasts. The process of simultaneous saccharification and fermentation improved the parameters of the waste biomass, especially the protein content, while reducing the amount of crude fiber and enhancing the biotransformation of isoflavone compounds present in the waste. Fermentation yielded the highest protein gain for the Saccharomyces cerevisiae Ethanol Red strain (ΔN = 2.38%) at a biomass load of 12.5 g and for Scheffersomyces stipitis (ΔN = 2.34%) at an enzyme dose of 0.125 mL/10 g DM. The crude fiber content (CF) was reduced by 2.55−7.18%. The simultaneous saccharification and... [more]
Parameter Optimization and Control Strategy of Hybrid Electric Vehicle Transmission System based on Improved GA Algorithm
Daobao Luo, Wujun Ji, Xin Hu.
June 9, 2023 (v1)
Keywords: HEV, multi-objective optimization, PSO-GA, transmission parameters.
Most of the traditional hybrid electric vehicles (HEVs) choose to optimize the transmission ratio parameters, and the parameter changes of the whole vehicle and other components are only calculated as fixed values. It is difficult to give consideration to the optimization of the economy and power of hybrid vehicles. Therefore, the research proposes to build the transmission ratio, the required power of the vehicle’s working mode, and other models through the dynamic analysis. The parameters of the whole vehicle are optimized on the basis of parameter matching. At the same time, this paper chooses to adopt a hybrid optimization algorithm, combining particle swarm optimization (PSO) and genetic algorithm (GA). The weighted average method and constraint method are used to design the fitness function. The simulation experiment is carried out by Cruise software and MATLAB. Compare the iterative fitness of the PSO-GA algorithm with the traditional PSO and GA algorithm. It can be concluded th... [more]
Hybrid Plasma-Catalytic CO2 Dissociation over Basic Metal Oxides Combined with CeO2
Oleg Golubev, Anton Maximov.
June 9, 2023 (v1)
Subject: Materials
Keywords: basic oxides, CO2 utilization, dielectric barrier discharge, oxygen vacancies, plasma catalysis.
The problem of CO2 waste in the atmosphere is a major concern, and methods of CO2 utilization are being currently developed. In the present work, a plasma-catalytic process is applied for CO2 dissociation. A series of MgO and CeO2-containing catalysts were synthesized, and the samples were characterized by: a low-temperature N2 adsorption-desorption analysis, X-ray diffraction, X-ray photoelectron spectroscopy, temperature-programmed desorption of CO2, and X-ray fluorescence spectroscopy. It was stated that under dielectric barrier discharge conditions, the catalyst surface, composition, and phase content remain unchanged. The superior catalytic activity of the MgCe-Al sample is attributed to the combination of weak basic sites and oxygen vacancies on the catalyst surface.
Research on Two-Way Contra-Rotating Axial-Flow Pump−Turbine with Various Blade Angles in Pump Mode
Yiming Chen, Ce An, Rongyong Zhang, Qiang Fu, Rongsheng Zhu.
June 9, 2023 (v1)
Keywords: blade angle, streamline analysis, two-way pump–turbine, vortex characteristics.
In tidal two-way contra-rotating units, significant differences in performance often occur when arranging the front and rear impellers, which requires an optimized design of the impellers. To solve this problem, by reducing the blade inlet and outlet angles, the impact of different blade angles on the performance of two-way pump−turbines and the internal flow was explored, and the effects of the blade inlet angle of the impellers on the performance of the counter-rotating pump were obtained. Afterward, the streamline and vorticity of the two-stage impeller at different angles were analyzed. The results show that different blade angles will have a certain impact on the internal flow of the two-way pump−turbine. Different blade outlet angles have a significant impact. The variation in different inlet blade angles is not significant for the vorticity changes in the front impeller and rear impeller. In addition, changes in the outlet blade angle will have an impact on the location of LE im... [more]
Impact of Data Grouping on the Multivariate Analysis of Several Concrete Plants
Malika Perluzzi, William Wilson, Ryan Gosselin.
June 9, 2023 (v1)
Subject: Materials
Keywords: concrete plant, CPCA, data grouping, multivariate analysis, PCA.
Multivariate analysis can be used to study industrial process data exhibiting collinearity between variables. Such data can often be collected into conceptually meaningful groups or blocks. While data blocks may appear intuitive (e.g., raw material properties vs. process parameters), such blocking is sometimes much more subjective. The novelty of this work lies in the investigation of the impact of data blocking on the subsequent analysis. To our knowledge, no such investigation can be found in the literature. To fill this gap, we analyze the impact of grouping data from 10 Canadian concrete plants in which multiple blocking alternatives are considered. The analysis is performed via principal component analysis (PCA) to reduce the dimensionality of the matrix and also via consensus principal component analysis (CPCA). The data grouping options are as follows: (1) all data combined into a single block, (2) grouped according to the factory, (3) grouped according to parameter type, and (4... [more]
Expansive Soil Stabilization Using Alkali-Activated Fly Ash
Huan Wang, Tengjiao Liu, Chao Yan, Jianqi Wang.
June 9, 2023 (v1)
Subject: Materials
Keywords: alkali-activated binder, expansive soil, SEM, unconfined compressive strength.
Expansive soil swells with water and shrinks with water loss, causing serious safety problems for construction projects. This study emphasizes alkali-activated binder (NaOH excited fly ash) stabilized expansive soil. We found that swelling decreased with an increase in the amount of NaOH in alkali-activated binder. It was found that the alkali-activated binder stabilized expansive soils (AABS) had higher shear strength than untreated expansive soils (US), manifested by increased cohesion and friction angle. In AABS, the highest cohesion and the highest shear strength were found when the NaOH mass was 6% of the fly ash mass. The strength of AABS was similar to that of US without curing. AABS had higher strength than US after 7 and 14 days of curing. The unconfined compressive strength increased with extension of curing time. Combined with XRD and SEM analysis, it was shown that the mechanism of AABS was the formation of C−S−H and (C,N)−A−S−H and the change in the internal structure of e... [more]
Techno-Economic Evaluation of the Thermochemical Energy Valorization of Construction Waste and Algae Biomass: A Case Study for a Biomass Treatment Plant in Northern Greece
Georgios Manthos, Dimitris Zagklis, Sameh S. Ali, Constantina Zafiri, Michael Kornaros.
June 9, 2023 (v1)
Keywords: biomass treatment, combustion, gasification, pyrolysis, techno−economic analysis, thermochemical treatment.
Biomass treatment for energy production is a promising way for achieving fossil fuel replacement and environmental relief. Thermochemical processes are a common way of processing biomass, but their potential economic benefits are not always clear to investors. In this work, three basic thermochemical processes (combustion, gasification, and pyrolysis) are examined in terms of their theoretical yields and their products, as well as their economic viability. The goal of this analysis was to look into the total amount of available biomass streams and compare business plans in terms of sustainability from a technical and economic perspective. The estimation of the fixed capital investment was based on ready−made solutions that are already available on the market. The analysis showed that the gasification unit has the optimum sustainability results since the total amount of gross income was EUR 0.13/kg of biomass while the treatment cost was estimated at EUR 0.09/kg of biomass. The internal... [more]
Modeling and Control of an Air Conditioner Powered by PV Energy and the Grid Using a DC Microgrid
Alberto Martinez-Barbosa, Gerardo Guerrero-Ramirez, Jorge Calleja-Gjumlich, Esteban Guerrero-Ramirez, Manuel Adam-Medina, Carlos Aguilar-Castillo, Jesus Aguayo-Alquicira.
June 9, 2023 (v1)
Keywords: air conditioner, power system modeling, renewable energy sources, renewable energy system modeling.
This paper presents the mathematical modeling and control design procedure of the compressor motor of an air conditioner using the energy from a photovoltaic system combined with the power grid in a DC microgrid. A comprehensive model considers the interconnection of the photovoltaic cells with their associated DC/DC converter, the DC bus, the three-phase squirrel-cage induction motor with its driver, the bidirectional DC/AC converter, the output filter, and the power grid. The state-of-the-art showed that a complete mathematical model of the proposed system is unavailable. Therefore, the mathematical model of the system is compared and validated in simulation with a block diagram in the Matlab/Simulink environment. In addition, several control approaches are used in the whole system to track the maximum power point of the photovoltaic cells, obtain a soft start on the machine, control the velocity using the variable frequency drive, regulate the DC bus voltage, and manage the power fl... [more]
Fostering a Sustainable Energy Future to Combat Climate Change: EESG Impacts of Green Economy Transitions
Dicao Tang, Yasir Ahmed Solangi.
June 9, 2023 (v1)
Subject: Energy Policy
Keywords: climate change, Delphi method, fuzzy AHP, green economy, Renewable and Sustainable Energy, sustainable development.
The transition to a green economy for any country is crucial for the sustainability development of the economy, environment, society, and governance (EESG). A green economy is a sustainable approach to combating climate change and promoting sustainable development through the adoption of sustainable energy. This research utilizes the Delphi and fuzzy analytical hierarchy process (AHP) methodologies to assess and rank the EESG criteria and policy options for transitions to a green economy. The factors and policy choices are identified using the Delphi approach for further analysis. These factors and policy alternatives for switching to a green economy for sustainable development are determined using the fuzzy AHP technique. According to the fuzzy AHP approach, environmental, social, and economic factors are best suited for green economy transitions. The findings also show that the most crucial policy options for the switch to a green economy are research and development, carbon pricing,... [more]
Bearing Inner Ring Raceway Low-Temperature Aerosol Cooling Lubrication Grinding
Zhou Chang, Lai Hu.
June 9, 2023 (v1)
Keywords: aerosol cooling lubrication, low temperature, raceway grinding, residual stress.
A low-temperature aerosol cooling and lubrication grinding test bench was built to evaluate the cooling and lubrication performance of the low-temperature aerosol. The mechanism of grinding residual stresses in the inner ring raceway under the coupling effect of grinding force and grinding heat was studied, and the effects of the grinding process parameters and cooling and lubrication conditions on the distribution state of the grinding residual stresses in the surface layer of the inner ring raceway were revealed. The results showed that reducing the initial temperature of the grinding fluid could reduce the residual tensile stresses on the raceway surface. The results also showed that the low-temperature aerosol cooling lubrication method is conducive to the generation of the axial residual compressive stress of −500 MPa and tangential residual compressive stress of −300 MPa in the inner ring raceway surface layer of the bearing. Compared with the convective heat transfer coefficient... [more]
Thermal Methane Cracking on Molten Metal: Kinetics Modeling for Pilot Reactor Design
Emma Palo, Vittoria Cosentino, Gaetano Iaquaniello, Vincenzo Piemonte, Emmanuel Busillo.
June 9, 2023 (v1)
Keywords: CO2 free process, Hydrogen, methane cracking, Modelling, molten metal process.
Up to 80% of hydrogen production is currently carried out through CO2 emission-intensive natural gas reforming and coal gasification. Water-splitting electrolysis using renewable energy (green H2) is the only process that does not emit greenhouses gases, but it is a quite energy-demanding process. To significantly contribute to the clean energy transition, it is critical that low-carbon hydrogen production routes that can replace current production methods and can expand production capacity to meet new demands are developed. A new path, alternative to steam reforming coupled with CCS (blue H2) that is based on methane cracking, in which H2 production is associated with solid carbon instead of CO2 (turquoise H2), has received increasing attention recent years. The reaction takes place inside the liquid bath, a molten metal reactor. The aim of this article is to model the main kinetic mechanisms involved in the methane cracking reaction with molten metals. The model developed was validat... [more]
Low-Carbon Optimal Scheduling Model for Peak Shaving Resources in Multi-Energy Power Systems Considering Large-Scale Access for Electric Vehicles
Kang Dai, Kun Zhang, Jicheng Li, Liang Liu, Zhe Chen, Peng Sun.
June 9, 2023 (v1)
Keywords: carbon reduction, electric vehicle, multi-energy storage, peak regulating resources.
Aiming at the synergy between a system’s carbon emission reduction demand and the economy of peak shaving operation in the process of optimizing the flexible resource peaking unit portfolio of a multi-energy power system containing large-scale electric vehicles, this paper proposes a low-carbon optimal scheduling model for peak shaving resources in multi-energy power systems considering large-scale access for electric vehicles. Firstly, the charging and discharging characteristics of electric vehicles were studied, and a comprehensive cost model for electric vehicles, heat storage, and hydrogen storage was established. At the same time, the carbon emission characteristics of multi-energy power systems and their emission cost models under specific carbon trading mechanisms were established. Secondly, the change characteristics of the system’s carbon emissions were studied, and a carbon emission cost model of multi-energy power was established considering the carbon emission reduction de... [more]
Interval Forecasting Method of Aggregate Output for Multiple Wind Farms Using LSTM Networks and Time-Varying Regular Vine Copulas
Yanwen Wang, Yanying Sun, Yalong Li, Chen Feng, Peng Chen.
June 9, 2023 (v1)
Keywords: interval forecast, LSTM network, multiple wind farms, regular vine copulas, time-varying copula.
Interval forecasting has become a research hotspot in recent years because it provides richer uncertainty information on wind power output than spot forecasting. However, compared with studies on single wind farms, fewer studies exist for multiple wind farms. To determine the aggregate output of multiple wind farms, this paper proposes an interval forecasting method based on long short-term memory (LSTM) networks and copula theory. The method uses LSTM networks for spot forecasting firstly and then uses the forecasting error data generated by LSTM networks to model the conditional joint probability distribution of the forecasting errors for multiple wind farms through the time-varying regular vine copula (TVRVC) model, so as to obtain the probability interval of aggregate output for multiple wind farms under different confidence levels. The proposed method is applied to three adjacent wind farms in Northwest China and the results show that the forecasting intervals generated by the pro... [more]
Study on the Optimal Double-Layer Electrode for a Non-Aqueous Vanadium-Iron Redox Flow Battery Using a Machine Learning Model Coupled with Genetic Algorithm
Qiang Ma, Wenxuan Fu, Jinhua Xu, Zhiqiang Wang, Qian Xu.
June 9, 2023 (v1)
Keywords: 3D finite-element numerical simulation, artificial neural network, DES electrolyte, Genetic Algorithm, gradient porous electrode, Machine Learning, operational performance, redox flow battery, vanadium-iron.
To boost the operational performance of a non-aqueous DES electrolyte-based vanadium-iron redox flow battery (RFB), our previous work proposed a double-layer porous electrode spliced by carbon paper and graphite felt. However, this electrode’s architecture still needs to be further optimized under different operational conditions. Hence, this paper proposes a multi-layer artificial neural network (ANN) model to predict the relationship between vanadium-iron RFB’s performance and double-layer electrode structural characteristics. A training dataset of ANN is generated by three-dimensional finite-element numerical simulations of the galvanostatic discharging process. In addition, a genetic algorithm (GA) is coupled to an ANN regression training process for optimizing the model parameters to elevate the accuracy of ANN prediction. The novelty of this work lies in this modified optimal method of a double-layer electrode for non-aqueous RFB driven by a machine learning (ML) model coupled wi... [more]
Underutilized Fig (Ficus carica L.) Cultivars from Puglia Region, Southeastern Italy, for an Innovative Product: Dried Fig Disks
Giuseppe Ferrara, Andrea Magarelli, Andrea Mazzeo, Antonio Coletta, Pasquale Crupi, Francesco Loperfido, Giuseppe Maggi, Pasquale Venerito.
June 9, 2023 (v1)
Keywords: disks, dried figs, fig processing, health benefits, sensory analysis.
Fig fruits have recently received more attention by consumers for their quality as either fresh or dried fruits and, consequently, growers are becoming more interested in the cultivation of this species. Figs are mainly consumed as processed fruits (dried, marmalade, jam, etc.), but limited attention has been paid to new possible processing applications of several local cultivars grown in Mediterranean countries. This study aimed to investigate both the morpho-pomological characteristics and consumer sensory ratings (two groups: students and technicians) for four fig cultivars processed as a new type of product, ‘dried fig disks’. The results showed that three out of the four cultivars (Processotto Nero, Natalese Nera, and Verde di Natale) had good pomological characteristics such as fruit weight and skin color, as well as easy peeling, yield, ripening time, and TSS. The same cultivars received positive hedonic scores for appearance (>5 on a 10-point hedonic scale), flavor (4−6 on a 10... [more]
Fabrication of Strong Self-Reinforced Polyethylene Terephthalate Composites through the In Situ Nanofibrillation Technology
Eric S. Kim, Patrick C. Lee.
June 9, 2023 (v1)
Subject: Materials
Keywords: fibrillation, foam, polyethylene terephthalate, self-reinforced composite, spun bond, thermal conductivity.
Fabrication of self-reinforced polyethylene terephthalate (PET) has been achieved through the in situ generation of PET fibrils via a spun bond process. The reinforcement fibrils created from the PET with higher Tm are made from a unique in situ processing method. As a result, the fibrils are well dispersed and distributed in the lower Tm PET matrix. The high degree of molecular similarity affords perfect interfaces between the matrix and dispersed phase, leading to excellent stress transfer from the matrix to the dispersed fibrils. While the extremely large interfaces from the nanofibrillation process can maximize the advantage of the excellent molecular similarity of the self-reinforced polymeric composites, few studies have been conducted to research nanofibrillar self-reinforced polymeric composite systems. Hence, as a proof of concept, this work provides new insight into an approach for developing a self-reinforced polymeric system with a nanofibrillation process. This process inc... [more]
A New Method for Calculating Reservoir Core-Bound Water Saturation Using the Cast Thin Section
Yunjiang Cui, Jun Ming, Xinlei Shi, Wangwang Yang, Zhansong Zhang, Chong Zhang.
June 9, 2023 (v1)
Keywords: cast thin sections, hydropower station, irreducible water saturation, low resistivity reservoir, unconsolidated sandstone.
The rock coring of the reservoir in the Bohai A field is difficult. The cores of the target section in the study area are loose, making it difficult to accurately measure the core-bound water saturation. The purpose of this research was to develop and validate a method for calculating a reservoir core-bound water saturation ratio using the cast thin section. First, pepper noise denoising and image enhancement were performed on the thin section by median filtering and gamma variation. Based on this, the enhanced sheet images were thresholded for segmentation by the two-dimensional OTSU algorithm, which automatically picked up the thin section pore-specific parameters. Then, the thin section image was equivalent to a capillary cross-section, while the thin film water fused to the pore surface was observed as bound water. For hydrophilic rocks with a strong homogeneity, the area of thin film water in the pore space of the sheet was divided by the total area of the pore space, which produc... [more]
Product Yields Dependency on the Carbide Phase Presence in Cobalt and Iron SBA-15 Catalysts Structure in the Fischer−Tropsch Synthesis
Nikita Sharkov, Zahra Gholami, Ivana Hradecká, Zdeněk Tišler, Josef Šimek.
June 9, 2023 (v1)
Keywords: carbide catalyst, CoCx/SBA-15, FeCx/SBA-15, Fischer–Tropsch synthesis.
The use of carbide catalysts in Fischer−Tropsch synthesis (FTS) is an active area of research, as carbide phases have been shown to improve the stability and performance of catalysts in this reaction. This study compared the catalytic activity and product selectivity of cobalt and iron catalysts supported on SBA-15, with and without a carbide phase and reduction treatment before the reaction. Results showed that the presence of the carbide phase had a noticeable influence on the catalytic behavior of the catalysts, and the reduction of the catalyst with hydrogen also affected the product selectivity. The presence of the carbide phase in non-reduced cobalt catalysts resulted in increased selectivity to liquid phase products, as evidenced by a CO conversion of 37% with 68% selectivity to the products in the liquid phase. The catalytic activity of the iron carbide catalyst for CO dissociation was found to be 38% after reducing the catalyst with hydrogen, leading to the formation of more a... [more]
Biowax Production from the Hydrotreatment of Refined Palm Oil (RPO)
Giovanny Olarte, Laura Garzón, José Sarmiento, Luis Javier López-Giraldo, July C. Vivas-Báez.
June 9, 2023 (v1)
Keywords: biowax, hydrotreatment, refined palm oil.
In this study, conditions were determined to obtain a solid wax with a waxy ester content of more than 25% from the hydrotreating of palm oil. The experiments were conducted in a pilot-scale fixed-bed reactor. The influence of temperature, liquid hourly space velocity (LHSV), and pressure on the conversion of triglycerides were evaluated using a nickel molybdenum catalyst (NiMo/Al2O3). The variables were evaluated between 240 and 260 °C, 1 and 2 h−1 and 41 and 55 bar, respectively. Based on these results, the best conditions were T:240−260 °C; P: 90 bar; LHSV: 1.5 h−1; hydrogen/oil ratio 472 LN/L with a conversion around 60 wt%; and a selectivity towards waxy esters of 40 wt%. These conditions were then validated with a second catalyst (NiMoB/Al2O3), yielding a triglyceride conversion of about 60 wt% and a waxy ester concentration of around 30 wt%.
Special Issue on “Bioethanol Production Processes”
Antonio D. Moreno, Paloma Manzanares.
June 9, 2023 (v1)
Subject: Uncategorized
The transportation sector is facing a profound challenge to utilize a greater proportion of sustainable substitutes in relation to oil-derived products [...]
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