Flue gas is composed of N2 and CO2, and is often used as an auxiliary agent for oil displacement, with good results and very promising development prospects for co-injection with steam to develop heavy oil. Although research on the oil displacement mechanism of flue gas has been carried out for many years, the flow characteristics of steam under the action of flue gas have rarely been discussed. In this paper, the flow resistance and heat transfer effect of flue gas/flue gas + steam were evaluated by using a one-dimensional sandpack, a flue gas-assisted steam flooding experiment was carried out using a specially customized microscopic visualization model, and the microscopic flow characteristics in the process of the co-injection of flue gas and steam were observed and analyzed. The results showed that flue gas could improve the heat transfer effect of steam whilst accelerating the flow of steam in porous media and reducing the flow resistance of steam. Compared with pure steam, when t... [more]

The comprehensive topological isomorphism of liquid−vapor, fusibility, and solubility diagrams in the proper sets of variables is proven with the aid of van der Waals equations of the shift in phase equilibrium. Analogues of Gibbs−Konovalov and Gibbs−Roozeboom laws are demonstrated in solubility diagrams of ternary and quaternary systems under crystallization of different types of solid solutions. For the demonstration, the quaternary reciprocal system K+,NH4+||Cl−,Br−−H2O and its ternary subsystems with modeling of the liquid phase within the framework of the classical Pitzer formalism are mainly used. An algorithm for calculating solubility equilibria in these systems is given.

Lyophilization is a widely used preservation method for thermosensitive products. It consists of three process steps: freezing, primary and secondary drying. One of the major drawbacks is the long processing time. The main optimization effort was put into the primary drying phase since it is usually the longest phase. However, the freezing step is of immense importance for process efficiency and product quality. The lack of control during freezing comprises a challenge for process design and tech transfer. In this study, four different freezing steps (shelf-ramped freezing with and without holding step, precooled shelves and an ice fog method for controlled nucleation) are used and their impact on primary drying experiments and simulations is shown. Only the ice fog method is able to control the nucleation temperature leading to low dry layer resistances with low deviations. During the primary drying simulations, the control of the nucleation temperature drastically increases the preci... [more]

Saffron spices are composed of dehydrated stigmas of Crocus sativus L. A large amount of bio-residues (stamens, tepals, and stigmas) is generated during the production of this spice (~92 g of bio-residues per 100 g of flowers). These bio-residues are usually discarded losing the chance to obtain interesting bioactive compounds from them. In this work, we use the saffron bio-residues as possible source of natural bioactive compounds. Different extraction conditions were applied obtaining hydrophilic and lipophilic components. The antioxidant activity of the bioactive compounds in the different conditions were analysed using the ABTS method developed by our team. Furthermore, the total content of phenolic compounds and flavonoids present in the bio-residues were estimated. We demonstrated that bio-residues contain a high amount of both phenolic and flavonoid compounds with a strong antioxidant potential effect. Moreover, we compared the antioxidant activities of saffron bio-residues (obt... [more]

Environmental protection laws require effective and green solutions to tackle water and air pollution issues. For this purpose, perovskite photocatalytic materials have proven to be a promising solution. In this study, CsSnBr3 perovskite, coupled with ZIF-67 and decorated with noble metal Au, was shown to effectively enhance the charge separation and increase the light-absorbing capacity, and thus make the photocatalytic reaction more efficient by surface plasmon resonance. Characterization results from XRD, FTIR, and UV-visible diffuse reflectance spectroscopy indicated that a mixture of cubic and tetragonal crystalline phases was found in the prepared catalyst material. XPS also revealed that in the presence of two oxidation states for tin (Sn), the Au 4f XPS peaks of Au NPs coincided with those retained in colloidal Au particles. Using malachite green as a model compound, organic pollutant photocatalytic degradation tests proved that CsSnBr3 generated good photocatalytic activity fo... [more]

The demand for ever-lighter structures raises the interest in bonding as a joining method, especially for materials that are difficult to join with traditional welding and bolting techniques. Structural adhesives, however, are susceptible to defects, but can be toughened in several ways: by changing their chemical composition or by adding fillers, even of nanometric size. Nanomaterials have a high surface area and limited structural defects, which can enhance the mechanical properties of adhesives depending on their nature, quantity, size, and interfacial adhesion. This work analyzes the Mode I fracture toughness of joints bonded with METLBOND® 1515-4M epoxy film and XantuLayr electrospun XD 10 polyamide nanofibers. Two joint configurations were studied, which differed according to the position of the nanomat within the adhesive layer: one had the nanofibers at the substrate/adhesive interfaces, and the other had the nanofibers in the center of the adhesive layer. Double cantilever bea... [more]

In the current investigation, elements extracted from Saccharum officinarum were identified as exporters of Fenton catalysts. Saccharum officinarum was soaked in an alkali prior to acidic treatment and then subjected to pyrolysis for elemental recovery. X-ray diffraction (XRD) and scanning electron microscopy (SEM) augmented with energy-dispersive X-ray spectroscopy (EDX) were used to identify the prepared catalyst. The material was combined with hydrogen peroxide, which led to Fenton’s reaction. Then, the modified Fenton system was applied to eliminate the textile dye, named Bismarck Brown Azo dye, contaminating the aqueous effluent. Response surface methodological model (RSM) analysis was used to identify the most effective operational parameters, and the model set the optimized values as 39 and 401 mg/L for Saccharum officinarum and H2O2 doses, respectively, at pH 2.9. The maximum Bismarck Brown Azo dye removal achieved was 85%. Increasing the temperature to 60 °C improved the dye o... [more]

As an exogenous substance, bulking agent plays a considerable role in dewatered sludge (DS) biodrying by affecting the organics degradation and water migration. Meanwhile, biodried product needs to be further dried because its final moisture content (MC) is usually too high for direct incineration. In this study, the influence of adding different bulking agents on organics decomposition and extracellular polymeric substances (EPS) release during DS biodrying, and thermal drying characteristics of the biodrying mixtures was investigated. Results showed that spent coffee ground (SCG), corncob (CC) and wheat husk (WH) improved water removal ratios of DS biodrying. SCG contributed various types of organic matter to the biodrying matrix, thus attaining the longest high-temperature period (4.5 days). Meanwhile, SCG contributed lipids, which have high calorific value, to the biodrying pile, leading to the highest biodrying index (3.70) among all treatments. SCG, CC and WH also accelerated EPS... [more]

Japanese knotweed is an invasive alien plant species with characteristic rapid expansion in Europe and North America and resistance to extermination. It displaces autochthonous biodiversity and causes major damage to infrastructure, thus causing global ecological and economic damage. The Japanese knotweed plant is usually eradicated using various chemical, biological, or mechanical techniques, which at a large scale include heavy equipment, usually followed by incineration. Therefore, excavation is preferred to eradication techniques, and as a biomass waste recovery method due to the extraction of high-value biocompounds. This is supported by the fact that the Japanese knotweed possesses various bioactive compounds with beneficial effects on human health. Its rhizome bark extract produces strong and stable antioxidant activity over time, as well as apoptotic, antibacterial, and other beneficial activities. In this work, an environmental impact assessment, including greenhouse gas footp... [more]

Wellbore leakage mostly occurs in structurally developed fractured formations. Analyzing the real-time leakage rate during the drilling process plays an important role in identifying the leakage mechanism and its rules on-site. Based on the principles of fluid mechanics and using Herschel-Bulkley (H-B) drilling fluid, by reasonably simplifying the drilling fluid performance parameters, fracture roughness characteristic parameters, pressure difference between the wellbore and formation, and the radial extension length of drilling fluid, the radial leakage model is improved to improve the calculation accuracy. Using the Euler format in numerical analysis to solve the model and with the help of numerical analysis software, the radial leakage law of this flow pattern in the fractures is obtained. The results show that the deformation coefficient of the fracture index, fracture aperture, pressure difference, leakage rate, and cumulative leakage rate are positively correlated. The larger the... [more]

The continued use of energy sources based on fossil fuels has various repercussions for the environment. These repercussions are being minimized through the use of renewable energy supplies and new techniques to decarbonize the global energy matrix. For many years, hydrogen has been one of the most used gases in all kinds of industry, and now it is possible to produce it efficiently, on a large scale, and in a non-polluting way. This gas is mainly used in the chemical industry and in the oil refining industry, but the constant growth of its applications has generated the interest of all the countries of the world. Its use in transportation, petrochemical industries, heating equipment, etc., will result in a decrease in the production of greenhouse gases, which are harmful to the environment. This means hydrogen is widely used and needed by countries, creating great opportunities for hydrogen export business. This paper details concepts about the production of green hydrogen, its associ... [more]

The interaction mechanism between oil shale and catalyst is very important for the design and synthesis of related catalysis. In this work, dimethyl sulfoxide (DMSO) serves as a model molecule for organic sulfur compounds in oil shale to explore the catalytic effect and mechanism of the pure and transition metal Cu−doped SBA−15 molecular sieves regarding the decomposition of organic sulfur compounds in oil shale using the density functional theory (DFT) method. It is found that DMSO adsorption on both surfaces is primarily attributed to hydrogen bonding or the interaction between the S and O moieties within the molecule and the surface Cu atoms. The adsorption energies on both surfaces are indistinguishable; however, the Cu−doped SBA−15 shows enhanced catalytic activity in dissociation reactions. The Gibbs free energy changes for both possible reaction pathways of DMSO breaking C−S bonds on the pure SBA−15 surface are positive, and the activation energy barriers are as high as ~75 kcal... [more]

In this study, the chemical composition and the antioxidant and antidiabetic properties of S. elaeagnifolium flower (SEFl), fruit (SEFr), and leaf (SEFe) extracts were investigated in vitro and in silico. HPLC-DAD analysis was used to determine the chemical components. Colorimetric techniques were used to identify polyphenols and flavonoids. The antioxidant capacity was determined using DPPH and TAC assays. The antidiabetic activity was examined using the enzymes α-amylase and α-glucosidase. Molecular docking methods were used to assess the anti-dipeptidyl peptidase IV (DPP-IV) activity. According to HPLC findings, extracts of S. elaeagnifolium flowers, leaves, and fruits are rich in salicylic acid, sinapic acid, chlorogenic acid, naringin, quercetin, quercetin-3-O-beta-glucoside, kaempferol, and chalcone. The IC50 for flower, leaf, and fruit extracts were 132 ± 5.59 μg/mL, 43.19 ± 1.46 μg/mL, and 132 ± 5.59 μg/mL, respectively. The total antioxidant capacity of SEFr, SEFe, and SEFl we... [more]

3D scanning, 3D printing, and CAD design software are considered important tools in Industry 4.0 product development processes. Each one of them has seen widespread use in a variety of scientific and commercial fields. This work aims to depict the added value of their combined use in a proposed workflow where a customized product needs to be developed. More specifically, the geometry of an existing physical item’s geometry needs to be defined in order to fabricate and seamlessly integrate an additional component. In this instance, a 3D scanning technique was used to digitize an e-bike’s frame geometry. This was essential for creating a peripheral component (in this case, a rear rack) that would be integrated into the frame of the bicycle. In lieu of just developing a tail rack from scratch, a CAD generative design process was chosen in order to produce a design that favored both light weight and optimal mechanical behaviors. FDM 3D printing was utilized to build the final design using... [more]

For liquid hydrogen transportation, thermal insulation materials that are lightweight, compact and exhibit high-performance have been pursued for several decades, and variable density multi-layer insulation (VD-MLI) has been regarded as a promising choice. The thermal insulation performance of the insulation materials is important, but is not at the top of the list; many constraints, such as the space and weight of the insulation structures, are imposed on the design of a VD-MLI. Consequently, this makes the optimization of VD-MLIs more complicated. The present authors conducted a multi-objective optimization of a VD-MLI stacked with specific insulation units. The number of repetitions of the basic insulation unit was regarded as the dimensionless design parameter of the VD-MLI. Based on the experimentally validated layer-by-layer (LBL) model for MLI design, the multi-objective optimization of VD-MLI for liquid hydrogen storage was conducted by the combination of proper orthogonal deco... [more]

Solar is a significant renewable energy source. Solar energy can provide for the world’s energy needs while minimizing global warming from traditional sources. Forecasting the output of renewable energy has a considerable impact on decisions about the operation and management of power systems. It is crucial to accurately forecast the output of renewable energy sources in order to assure grid dependability and sustainability and to reduce the risk and expense of energy markets and systems. Recent advancements in long short-term memory (LSTM) have attracted researchers to the model, and its promising potential is reflected in the method’s richness and the growing number of papers about it. To facilitate further research and development in this area, this paper investigates LSTM models for forecasting solar energy by using time-series data. The paper is divided into two parts: (1) independent LSTM models and (2) hybrid models that incorporate LSTM as another type of technique. The Root me... [more]

Cobalt oxide has good catalytic activity for peroxydisulfate (PDS) activation but poor stability and is vulnerable to inactivation because of agglomeration. In this work, the chlortetracycline (CTC) degradation by peroxydisulfate (PDS) catalysis using the reduced graphene oxide support cobalt oxide (Co3O4/rGO) composite catalyst was investigated. It was found that 86.3% of CTC was degraded within 120 min in the Co3O4/rGO-800/PDS system. The influences of catalyst dosage, PDS concentration, solution pH, and reaction temperature were systematically explored. The excellent removal performance of CTC could be attributed to the synergistic effect between adsorption and catalytic degradation. ≡Co2+ and surface functional groups played as active sites to catalyze PDS, and the circulation of ≡Co2+/≡Co3+ was achieved. Moreover, Co3O4/rGO-800 showed satisfactory reusability after three cycles. This research can provide useful information for the development of efficient PDS catalysts and facilit... [more]

Several metaheuristic algorithms have been implemented to solve global optimization issues. Nevertheless, these approaches require more enhancement to strike a suitable harmony between exploration and exploitation. Consequently, this paper proposes improving the arithmetic optimization algorithm (AOA) to solve engineering optimization issues based on the cuckoo search algorithm called AOACS. The developed approach uses cuckoo search algorithm operators to improve the ability of the exploitation operations of AOA. AOACS enhances the convergence ratio of the presented technique to find the optimum solution. The performance of the AOACS is examined using 23 benchmark functions and CEC-2019 functions to show the ability of the proposed work to solve different numerical optimization problems. The proposed AOACS is evaluated using four engineering design problems: the welded beam, the three-bar truss, the stepped cantilever beam, and the speed reducer design. Finally, the results of the prop... [more]

Mango seed kernel (MSK) extract contains phytochemicals, bioactives, and fatty acids that are of interest to food and nutritional scientists. The subcritical water extraction process (SCWE) can be effective in extracting valuable bioactives from MSK. In this study, SCWE was investigated and optimized for the extraction of bioactives from MSK using Box−Behnken experimental design. The extract yield was examined as a function of various process variables, namely, solvent-to-feed (L/S) ratio, extraction temperature (T), and extraction time (t). Analysis of variance (ANOVA) for experimental results showed that extraction temperature was the most significant variable that impacted the extract yield. A maximum yield of 52.3% was obtained at optimized extraction conditions of L/S ratio = 20.7, T = 116.5 °C, and t = 45 min. Antioxidant assessment of the SCWE extract obtained at the optimized conditions showed higher total phenolic content (19.2 mg GAE/g), and DPPH and ABTS radical scavenging a... [more]

The environment consists of living and inanimate elements that mutually interact and affect each other’s health and lifespan [...]

Cement production is the third largest source of nitrogen oxides (NOx), an air pollutant that poses a serious threat to the natural environment and human health. Reducing NOx emissions from cement production has become an urgent issue. This paper aims to explore and investigate more efficient denitrification processes to be applied in NOx reduction from precalciner. In this study, firstly, the flow field, temperature field, and component fraction in the precalciner are studied and analyzed using numerical simulation methods. Based on this, the influence of the reductant injection height and amount on the SNCR was studied by simulating the selective non-catalytic reduction (SNCR) process in the precalciner. The effect of natural gas on the NOx emissions from the precalciner was also investigated. The simulation results showed that, with the increase in height, the NOx concentration in the precalciner decreased, then increased, then decreased, and then increased again. The final NOx conc... [more]

Efficient and environmentally friendly ore collecting operation requires that the ore collecting head can provide just enough suction to start the ore particles in different working conditions. In this work, computational fluid dynamics and discrete element method (CFD-DEM) is used to simulate the hydraulic suction process of ore particles. After analyzing the pressure and velocity characteristics of the flow field, the effects of different suction velocities on the lateral displacement offset, drag coefficient Cd and Reynolds number Rep of particles are studied. It is determined that the lifting force is caused by the different flow velocities of the upper and lower flow fields; particle start-up time and the lateral offset are inversely proportional to suction speed. When h/d ≥ 2.25, the vertical force on particles is no longer affected by h/d. When S/d = 2.5, FZ decreases to 0 N; when h/d increases from 1.5 to 1.75, FZ decreases by nearly half. Three empirical equations for FZ repre... [more]

This paper is concerned with the observer-based H∞ proportional-integral-derivative (PID) control issue for discrete-time systems using event-triggered mechanism subject to periodic random denial of service (DoS) jamming attacks and infinitely distributed delays. In order to characterize the occurrence of periodic random DoS jamming attacks in the network channel between controller and actuator, the Kronecker delta function is used to represent the periodic switching between the sleeping period and attack period, and a Bernoulli-distributed random variable is utilized to reflect the probabilistic occurrence of DoS attacks. Infinitely distributed delay is involved to reflect actual state lag. The relative event-triggering mechanism is employed to reduce unnecessary information transmission and save communication energy in the network channel between sensor and observer. An observer-based PID controller is constructed for the regulation of the system to achieve an appropriate working eff... [more]

Thermal desorption technologies have been extensively applied for the disposal of oil-based drill cuttings. Fluent-software-based phase changes in multiphase flow models within thermal desorption chamber temperature field simulations were examined to study the effects of oil-based drill cuttings fluid content and feed rates, nitrogen content, thermal desorption chamber length and diameter, and extraction tube position on the thermal desorption chamber and temperature field. Our results demonstrate that these factors had a considerable influence on the temperature field of the chamber, with the liquid content of the oil-based drill cuttings having the greatest influence. The heat transfer process was enhanced by appropriately increasing the diameter and length of the chamber and reasonably setting the extraction tube. When the chamber length was insufficient, there was a risk that the outlet temperature would be extremely low and the oil content of the residue would exceed the standard.... [more]

This paper presents results obtained for the thermal and hydrothermal ageing of seven commercial precious metals-based catalysts for the combustion of methane. Experiments are performed in a large excess of oxygen representing lean conditions. Temperatures used are those typically found in lean burn compression ignition engines. The precious metals used were platinum, palladium and rhodium, present either singly or in combination. The most active catalyst contains a platinum and palladium mixture, with palladium being dominant. This catalyst was also the least affected by both thermal and hydrothermal ageing. The second most active catalyst contained only palladium, but this catalyst also demonstrated more susceptibility to ageing. The least active catalyst contained only platinum, although this catalyst was also the least affected by hydrothermal ageing. The addition of rhodium to either palladium or platinum−palladium catalysts caused a more rapid loss in activity at higher temperatu... [more]