The effects of ash and slag from a biomass power plant on the compressive strength, setting time and fluidity of the pastes of Portland cement (P.O) and sulfoaluminate cement (SAC) were studied, and the hydration products and microstructure at the age of 7 days were analyzed via XRD, SEM and other test methods. The results show that the compressive strength of the composite cementitious material decreases, the setting time prolongs and the fluidity increases with the increase in the ash and slag content in the power plant. The microscopic analysis shows that the ash and slag of the biomass power plant can promote the hydration of Portland cement and sulfoaluminate cement paste, and increase the generation of hydration products. The results showed that replacing SAC clinker with 20−30% biomass power plant ash (BPPA) decreased the cement strength, and that an appropriate amount of BPPA (10−15%) could significantly improve the mechanical strength of SAC blended cement. The compressive str... [more]

The production of titanium dioxide via the sulfuric acid process generates large amounts of acidic wastewater. Investigating the possibility of reusing this wastewater after deep treatment can reduce pollutant discharge and conserve water resources. In a pilot study, a dual-membrane method of ultrafiltration (UF) and reverse osmosis (RO) was employed to perform deep treatments of sulfuric-acid−titanium-dioxide wastewater. The findings showed that the multimedia and precision filters reduced the turbidity of water from an external drainage to as low as 0.18 NTU, with a turbidity removal rate of approximately 50%, reaching a maximum of 68%. When the UF effluent had a membrane flux of 70−100 L/m2 h and a water production rate of 85−90%, the SDI15 was <5.0 and the turbidity was 95%, a CODCr removal rate of 85%, and a desalination rate of >98.5%. At a smooth operation system water recovery rate of 50%, the highest system recovery rate obtained was 64%. The water produced via RO adhered t... [more]

Natural gas hydrate (NGH) is a kind of clean energy with great potential because of its huge reserves. There are several effective methods for exploiting hydrate sediments such as depressurization, thermal excitation, inhibitor injection and displacement, etc. Among these methods, the combined depressurization and heat injection method is considered a very promising method, which solves the problem of insufficient heat supply during the depressurization process. In this paper, the mechanism of combined depressurization and heat injection exploitation of NGH is analyzed, and the multiphase flow models of the injection well and production well are established, respectively, for the parallel horizontal NGH well production system with this combined method. The multiphase flow laws of fluids in a wellbore were obtained, and the factors affecting the temperature and pressure distributions in the wellbore were analyzed. The results of this study show that gas and water are produced simultaneo... [more]

The landfill barriers effectively prevented the migration of high-concentration pollutants, such as NH4+ and Na+, from the landfills to the surrounding environment. However, due to the high hydraulic head inside the landfill compared to the surrounding environment, NH4+ and Na+ can migrate towards the outside of the landfill barrier with the infiltrating solution, potentially causing harm to the surrounding environment. To address this, saturated mixed soil column samples made of bentonite and Shanghai clay, with bentonite contents of 3% and 10%, were used in this study. Permeability coefficients of the column samples in solutions are obtained by using permeation tests, and using NaCl and NH4Cl solutions with concentrations of 37.4 mmol/L and 74.8 mmol/L, respectively. The concentration-depth result of the column samples after permeation tests was determined using Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES) and Ion Chromatography (ICS-1100). Numerical simulations... [more]

As societal interest in recycling of plastics increases, modeling thermochemical recycling of vinyl polymers, e.g., via pyrolysis or reactive extrusion, becomes increasingly important. A key aspect remains the reliability of the simulation results with fewer evaluation studies regarding convergence as in the polymerization or polymer reaction engineering field. Using the coupled matrix-based Monte Carlo (CMMC) framework, tracking the unzipping of individual chains according to a general intrinsic reaction scheme consisting of fission, β-scission, and termination, it is however illustrated that similar convergence demands as in polymerization benchmark studies can be employed, i.e., threshold values for the average relative error predictions on conversion and chain length averages can be maintained. For this illustration, three theoretical feedstocks are considered as generated from CMMC polymer synthesis simulations, allowing to study the effect of the initial chain length range and th... [more]

A simple vapor-compression refrigeration system becomes ineffective and inefficient as it consumes a huge energy supply when operating between large temperature differences. Moreover, the recent Kigali amendment has raised a concern about phasing out some hydrofluorocarbon refrigerants due to their impact on the environment. In this paper, a numerical investigation is carried out to compare the performance of a cascade refrigeration system with two environmentally friendly refrigerant combinations, namely, R170−R404A and R41−R404A. Refrigerant R170, from the hydrocarbon category, and refrigerant R41, from the hydrofluorocarbon category, are separately chosen for the low-temperature circuit due to their similar thermophysical properties. On the other hand, refrigerant R404A is selected for the high-temperature circuit. An attempt is made to replace refrigerant R41 with refrigerant R170 as a possible alternative. The condenser temperature is kept constant at 40 °C, and the evaporator tem... [more]

The scaling of oil pipelines over time leads to issues including diminished flow rates, wasted energy, and decreased efficiency. To take appropriate action promptly and avoid the aforementioned issues, it is crucial to determine the precise value of the scale within the pipe. Non-invasive gamma attenuation systems are one of the most accurate detection methods. To accomplish this goal, the Monte Carlo N Particle (MCNP) algorithm was used to simulate a scale thickness measurement system, which included two sodium iodide detectors, a dual-energy gamma source (241 Am and 133 Ba radioisotopes), and a test pipe. Water, gas, and oil were all used to mimic a three-phase flow in the test pipe, with the volume percentages ranging from 10% to 80%. Moreover, a scale ranging in thickness from 0 to 3 cm was inserted into the pipe, gamma rays were shone on the pipe, and on the opposite side of the pipe, photon intensity was measured by detectors. There were 252 simulations run. Fifteen time and freq... [more]

Research into bone tissue engineering is increasing with advances in biomaterials. Natural products of plant origin have exciting therapeutic effects through multiple targets. The purpose of this article is to review the outstanding performance of herbal-derived natural products in bone tissue engineering. We have categorized herbal-derived natural products that exert different effects in bone tissue engineering into osteogenic, vascular, chondrogenic, anti-inflammatory and antibacterial. Natural products of plant origin are readily available and can be combined with biomaterials as bioactive molecules to complement each other and provide additional opportunities for bone tissue engineering. Finally, we discuss the challenges and opportunities for the development of plant composite biomaterials for bone tissue engineering and highlight emerging strategies in this field.

The mixing transport courses of three-phase particle flows exist in some industrial applications, such as metallurgy material extraction, lithium electric slurry dispersion, and material mixing in the high-end chemical industry. Its mixing transport mechanism is a fluid−structure coupling dynamic issues with intensive shear and nonlinear characteristics, making the real-time prediction of the flow field face challenges. To address the above problem, a bidirectional fluid−structure coupling three-phase particle flow dynamic model is built based on the coupled computational fluid dynamics and discrete element model (CFD-DEM) to explore the mixing transport mechanism. An interphase coupling solution method is utilized to solve the interaction effects of the fluid and particle. Research results illustrate that the proposed method modeling can well reveal the mixing transport mechanism of the three-phase particle flows. Due to the additive effects of stirring speed, stirring blade size, and... [more]

High current rate charging causes inevitable severe heat generation, thermal inconsistency, and even thermal runaway of lithium-ion batteries. Concerning this, a liquid cooling plate comprising a multi-stage Tesla valve (MSTV) configuration with high recognition in microfluidic applications was proposed to provide a safer temperature range for a prismatic-type lithium-ion battery. Meanwhile, a surrogate model with the objectives of the cooling performance and energy cost was constructed, and the impact of some influential design parameters was explored through the robustness analysis of the model. On this basis, the multi-objective optimization design of the neighborhood cultivation genetic algorithm (NCGA) was carried out. The obtained results demonstrated that if the MSTV channel was four channels, the valve-to-valve distance was 14.79 mm, and the thickness was 0.94 mm, the cold plate had the most effective cooling performance and a lower pumping power consumption. Finally, the optim... [more]

Non-furnace boilers can improve the efficiency of industrial once-through boilers. However, temperature non-uniformity occurs in the economizer connected vertically to the boiler. Heat transfer performance is degraded by temperature non-uniformity. To solve this problem, a corbel was installed on the side wall of the economizer, and a baffle was installed on the transition duct. Consequently, although the thermal efficiency of the boiler was improved, significant temperature non-uniformity was still observed in the area upstream of the economizer. To address this issue, this study designed a turning guide vane (TGV) at the economizer inlet using computational fluid dynamics (CFD). First, CFD was performed for a case without a guide vane and a case with an existing baffle installed. By analyzing the streamlines obtained using CFD, two TGV designs were proposed. In the first design, guide vanes were installed along the desired streamline, and the concept of the existing TGV was followed.... [more]

Novel phthalimide derivatives, namely N-(1,3-dioxoisoindolin-2-yl)-2-(2-methyl-4-oxoquinazolin-3(4H)-yl)acetamide (1a) and N-(1,3-dioxoisoindolin-2-yl)thiophene-2-carboxamide (1b), and hexahydrophthalimide derivative N-(1,3-dioxohexahydro-1H-isoindol-2(3H)-yl)-2-(2-methyl-4-oxoquinazolin-3(4H)-yl)acetamide (2), have been synthesized. The phthalimide derivatives were synthesized from phthalic anhydride and 2-(2-methyl-4-oxoquinazolin-3(4H)-yl)acetohydrazide or thiophene-2-carbohydrazide, and the hexahydrophthalimide derivative has been synthesized from hexahydrophthalic anhydride and 2-(2-methyl-4-oxoquinazolin-3(4H)-yl)acetohydrazide. The chemical structures of the compounds are elucidated by Nuclear Magnetic Resonance (NMR) and Infrared (IR) spectra. The new in vitro antioxidant activities of the obtained substances were evaluated using the DPPH method. All tested compounds showed antioxidative activity, the most active compound being 1b. Bioinformatics tools were used for the predict... [more]

In this study, the combustion characteristics of pine needles, pine needle humus, and the co-combustion of these two types of biomass with coal were compared. In addition, the optimization of the combustion performance of coal/humus was assisted through the following studies: (i) the combustion performance of coal/pine needle humus was studied under four different oxygen concentrations (N2, 10%O2/90%N2, 20%O2/80%N2, and 40%O2/60%N2); (ii) the synergistic effect between the humus and coal during combustion was also investigated by adjusting the blending ratio and oxygen content; (iii) the mechanisms of the optimized combustion processes were expounded by kinetics and thermodynamics discussion. The results demonstrated that the combustion characteristics of the coal/humus blends were found to be higher than those of the coal/pine needle blends. The coupling interactions of the oxygen content and blending ratio contributed to the significant synergistic effect between the two fuels, and t... [more]

Gas/liquid contactors are widely used in chemical and biotechnological applications. The selection and design of bubble-column-type gas/liquid contactors requires knowledge about the gas distributor design to provide appropriate gas flow patterns. This study presents the continuous chemisorption of CO2 in 0.1 molar sodium hydroxide solution in a counter currently operated gas/liquid Taylor-Couette disc contactor (TCDC). This vertical-column-type contactor is a multi-stage agitated gas/liquid contactor. The performance of a lab-size TCDC contactor in gas/liquid mass transfer operations was investigated. The apparatus design was adjusted for gas/liquid operations by installing perforated rotor discs to provide a rotational-speed-dependent dispersed gas phase holdup in the column. The parameters of dispersed gas phase holdup, volumetric mass transfer coefficient and residence time distribution were measured. In the first step, hydraulic characterization was performed. Then, the efficiency... [more]

This work considers the stabilization of a high-order system with time delay; an observer−predictor scheme is designed to estimate an internal signal of the system that is not available for measurement: this internal signal is the output before being delayed. By using the estimated signal, it is possible to design a controller for the delay-free system. The key point to carrying out this estimation strategy is to obtain conditions assuring that the estimated signal converges to the internal variable of the system. A necessary and sufficient condition to achieve an appropriate convergence in the proposed observer−predictor scheme is given. In addition, an analysis of the disturbance rejection and robustness with respect to the delay term is provided. The correct functioning of this scheme is verified through an example.

The objective of the study is to evaluate a new proposal for a coating based on corn starch (CS) enriched with basil essential oil (BEO) to overcome the rapid deterioration of quail eggs under nonrefrigerated conditions. One hundred and seventy-one quail eggs were divided into treatments of uncoated eggs (control), eggs coated with CS, and eggs coated with CS/BEO, and analyzed over four weeks at room temperature. The CS/BEO coating reduced the growth of total aerobic mesophilic bacteria, Enterobacteriaceae, molds, and yeasts on the surface of eggshells to <2 log10 CFU/mL compared to the control treatment at week four storage. The average Haugh unit (HU) of the four weeks of storage of the CS/BEO treatment was notably higher compared to the control. There was no significant difference between the sensory parameter scores of coated eggs and control treatment. Based on the findings, the CS/BEO coating can be used to mitigate the contamination of quail eggs and preserve their internal q... [more]

Methods for removing pollutants include membrane isolation, ion exchange, precipitation, transformation, and biosorption. Adsorption is a cost-effective method of treating industrial wastewater and a common commercial method for concentrating valuable molecules or eliminating contaminants. Banana peel is one of the largest underutilized agricultural wastes in Malaysia. A novel method of using a low-cost biosorbent made from banana peel and Evans blue (EB) dye as a target is the target of this study. The optimal conditions for EB dye adsorption occurred at a dye concentration of 200 mg/L, adsorbent dosages between 10 and 20 g/L, temperature of 25 °C, incubation time of 180 min, and agitation speeds of 100 rpm. Statistical discriminatory analysis showed that the pseudo-second-order kinetic model and the Redlich−Petersen isotherm model were the best models. The maximum adsorption capacity based on Langmuir’s isotherm prediction was 58.51 mg g−1. A non−linear regression of the thermodynami... [more]

The unreasonable development and pollution of groundwater have caused damage to the groundwater system and environmental problems. To prevent this, the concept of “groundwater vulnerability” was proposed, and various evaluation methods were developed for groundwater protection. However, with changing climatic conditions and human activities, groundwater vulnerability is now emphasizing physical processes. This study aims to review and analyze the principles and applications of process-based groundwater vulnerability methods to achieve the source protection of groundwater resources. It introduces the assessment method and elaborates on pollutant migration processes and numerical simulation technology. Relevant articles from the past 30 years are reviewed to show the evolution of process-based groundwater vulnerability assessment. The study also discusses current research trends and proposes future development paths. It concludes that process-based groundwater vulnerability assessment wi... [more]

The development of the palm oil industry has induced the generation of palm oil mill effluent (POME) together with its waste activated sludge (WAS) in recent years. This study aims to discover new opportunities in treating POME WAS that has high organic content with low degradability but having potential in converting waste into energy. The optimized electrochemical oxidation (EO) of pre-treated WAS was applied prior to anaerobic digestion (AD) to improve the POME WAS digestibility (by assessing its solids minimization and biogas production) under mesophilic conditions at 30 ± 0.5 °C and solids retention time of 15 days. The enhancement in sludge minimization was verified, with 1.6-fold over the control at steady-state. Promising results were obtained with a total chemical oxygen demand (COD) removal of 68.8% with 11.47 mL CH4/g CODadded in pre-treat digester, compared with 37.1% and 3.9 mL CH4/g CODadded in control digester. It is also worth noting that the specific energy (SE) obtain... [more]

In the chemical process, abnormal situations are precursor events of incidents and accidents. Abnormal situation management (ASM) can effectively identify abnormalities and prevent them from evolving into incidents or accidents, ensuring the safe and smooth operation of chemical plants. In recent years, ASM has attracted extensive attention from the process industry and from academia, and a lot of research work has been conducted. However, the intelligence level of ASM in actual chemical plants is still relatively low, and industrial applications still face many difficulties and challenges. This review first summarizes the concepts and involved in the contents of ASM. Then, the latest research progress in various aspects of ASM is systematically reviewed. Finally, the challenges and future research directions of ASM are analyzed based on the perspective of industrial application. This review aims to provide the most cutting-edge reference for follow-up research on ASM, and to promote t... [more]

In this study, methyl orange, methylene blue, and amido black 10B were removed as target dyes using purified, synthetic, and purchased zinc ferrite as adsorbents and photocatalysts. The highest removal rates of amido black 10B by these adsorbents ranged from 81.62% to 88.33%. The removal rate of methyl orange was approximately 1%, and the removal rate of methylene blue was approximately 2%. Hence, an investigation was conducted to elucidate the factors that influence the removal efficacy of purified zinc ferrite on amido black 10B. Titanium dioxide prepared at different calcination temperatures was unsuccessful in removing amido black 10B, but the physical mixing of titanium dioxide prepared at suitable calcination temperatures with purified zinc ferrite had a positive effect on amido black 10B removal. Since zinc ferrite could not be used as an adsorbent to remove methyl orange and methylene blue, the photocatalytic degradation properties of zinc ferrite and its influencing factors we... [more]

Range anxiety seriously restricts the development of electric vehicles (EVs). To address the above issue, a hybrid battery swapping system (HBSS) is developed in this paper. In the system, EVs can swap their battery at battery swapping stations or by the roadside via battery swapping vans. The proposed scheduling strategy aims to achieve the best service quality for the HBSS by controlling the mobile swapping service fee. In the model, the uncertainty of EV selection is managed by leveraging the Sigmoid function. Based on proving the uniqueness of the solution, the particle swarm optimization algorithm is used to solve the problem. Simulations validate the effectiveness of the proposed strategy in alleviating range anxiety. Moreover, the impacts of maximum service capacity and the operating rule have been analyzed.

Accurate parameter estimation of photovoltaic (PV) cells is crucial for establishing a reliable cell model. Based on this, a series of studies on PV cells can be conducted more effectively to improve power output; an accurate model is also crucial for the operation and control of PV systems. However, due to the high nonlinearity of the cell and insufficient measured current and voltage data, traditional PV parameter identification methods are difficult to solve this problem. This article proposes a parameter identification method for PV cell models based on the radial basis function (RBF). Firstly, RBF is used to de-noise and predict the data to solve the current problems in the parameter identification field of noise data and insufficient data. Then, eight prominent meta-heuristic algorithms (MhAs) are used to identify the single-diode model (SDM), double-diode model (DDM), and three-diode model (TDM) parameters of PV cells. By comparing the identification accuracy of the three models... [more]

The objective of the study is to investigate the thermal, electrical, and exergetic performance of a hybrid photovoltaic−thermal (PVT) system under the influence of copper oxide (CuO) nanofluid and phase change material (Vaseline (petroleum jelly)) as a heat storage medium. A mathematical model was developed with the help of various energy-balance equations over the layers of the hybrid system. The performance evaluation of the PVT system was performed using pure water, CuO-water nanofluid (0.2 and 0.4% weight fractions), and CuO-water nanofluid 0.4% weight fraction with Vaseline as a phase change material. The results of the overall analysis show that the performance of the PVT system is better using CuO-water nanofluid (0.4% wt. fraction) with PCM as compared to the water-cooled PVT system and CuO-water nanofluid. The results obtained from the study show indicate that the cell temperature of PVT was reduced by 4.45% using nanofluid cooling with PCM compared to a water-cooled PVT syst... [more]

The rapid increase in demand for renewable energy has led to a need for more efficient and effective ways to produce biogas from palm oil mill effluent (POME), which is rich in biological and chemical oxygen demand (BOD and COD). Despite its potential as a source of biogas, POME is not always effectively utilized in biogas production due to a lack of optimization of the treatment process. This study aims to address this issue by identifying the critical parameters affecting biogas production from POME and optimizing the process for maximum biogas yield and COD removal. This study employed comparative analysis and response surface methodology to optimize the performance of palm oil mill effluent (POME)-based biogas plants in Malaysia. Historical data from three commercial POME-based biogas plants in Malaysia were analyzed to identify the most critical parameters for biogas yield and COD removal. Response surface methodology, using Box−Behnken design and Design-Expert software, was then... [more]