LAPSE:2023.36156
Published Article

LAPSE:2023.36156
A Green Approach of Utilising Banana Peel (Musa paradisiaca) as Adsorbent Precursor for an Anionic Dye Removal: Kinetic, Isotherm and Thermodynamics Analysis
July 4, 2023
Abstract
Methods for removing pollutants include membrane isolation, ion exchange, precipitation, transformation, and biosorption. Adsorption is a cost-effective method of treating industrial wastewater and a common commercial method for concentrating valuable molecules or eliminating contaminants. Banana peel is one of the largest underutilized agricultural wastes in Malaysia. A novel method of using a low-cost biosorbent made from banana peel and Evans blue (EB) dye as a target is the target of this study. The optimal conditions for EB dye adsorption occurred at a dye concentration of 200 mg/L, adsorbent dosages between 10 and 20 g/L, temperature of 25 °C, incubation time of 180 min, and agitation speeds of 100 rpm. Statistical discriminatory analysis showed that the pseudo-second-order kinetic model and the Redlich−Petersen isotherm model were the best models. The maximum adsorption capacity based on Langmuir’s isotherm prediction was 58.51 mg g−1. A non−linear regression of the thermodynamic van’t Hoff plot based on a dimensionless equilibrium constant resulted in negative values for Gibb’s free energy and enthalpy, indicating that the adsorption process is spontaneous and exothermic.
Methods for removing pollutants include membrane isolation, ion exchange, precipitation, transformation, and biosorption. Adsorption is a cost-effective method of treating industrial wastewater and a common commercial method for concentrating valuable molecules or eliminating contaminants. Banana peel is one of the largest underutilized agricultural wastes in Malaysia. A novel method of using a low-cost biosorbent made from banana peel and Evans blue (EB) dye as a target is the target of this study. The optimal conditions for EB dye adsorption occurred at a dye concentration of 200 mg/L, adsorbent dosages between 10 and 20 g/L, temperature of 25 °C, incubation time of 180 min, and agitation speeds of 100 rpm. Statistical discriminatory analysis showed that the pseudo-second-order kinetic model and the Redlich−Petersen isotherm model were the best models. The maximum adsorption capacity based on Langmuir’s isotherm prediction was 58.51 mg g−1. A non−linear regression of the thermodynamic van’t Hoff plot based on a dimensionless equilibrium constant resulted in negative values for Gibb’s free energy and enthalpy, indicating that the adsorption process is spontaneous and exothermic.
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Keywords
biosorption, Evans blue dye, non-linear regression, thermodynamics
Subject
Suggested Citation
Basirun AA, Othman AR, Yasid NA, Shukor MYA, Khayat ME. A Green Approach of Utilising Banana Peel (Musa paradisiaca) as Adsorbent Precursor for an Anionic Dye Removal: Kinetic, Isotherm and Thermodynamics Analysis. (2023). LAPSE:2023.36156
Author Affiliations
Basirun AA: Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia—UPM, Serdang 43400, Selangor, Malaysia [ORCID]
Othman AR: Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia—UKM, Bangi 43600, Selangor, Malaysia [ORCID]
Yasid NA: Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia—UPM, Serdang 43400, Selangor, Malaysia [ORCID]
Shukor MYA: Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia—UPM, Serdang 43400, Selangor, Malaysia [ORCID]
Khayat ME: Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia—UPM, Serdang 43400, Selangor, Malaysia [ORCID]
Othman AR: Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia—UKM, Bangi 43600, Selangor, Malaysia [ORCID]
Yasid NA: Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia—UPM, Serdang 43400, Selangor, Malaysia [ORCID]
Shukor MYA: Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia—UPM, Serdang 43400, Selangor, Malaysia [ORCID]
Khayat ME: Department of Biochemistry, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia—UPM, Serdang 43400, Selangor, Malaysia [ORCID]
Journal Name
Processes
Volume
11
Issue
6
First Page
1611
Year
2023
Publication Date
2023-05-25
ISSN
2227-9717
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Original Submission
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PII: pr11061611, Publication Type: Journal Article
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LAPSE:2023.36156
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https://doi.org/10.3390/pr11061611
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[v1] (Original Submission)
Jul 4, 2023
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Jul 4, 2023
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Calvin Tsay
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