In this work, high-performance pore-filled anion-exchange membranes (PFAEMs) with double cross-linking structures have been successfully developed for application to promising electrochemical energy conversion systems, such as alkaline direct liquid fuel cells (ADLFCs) and vanadium redox flow batteries (VRFBs). Specifically, two kinds of porous polytetrafluoroethylene (PTFE) substrates, with different hydrophilicities, were utilized for the membrane fabrication. The PTFE-based PFAEMs revealed, both excellent electrochemical characteristics, and chemical stability in harsh environments. It was proven that the use of a hydrophilic porous substrate is more desirable for the efficient power generation of ADLFCs, mainly owing to the facilitated transport of hydroxyl ions through the membrane, showing an excellent maximum power density of around 400 mW cm−2 at 60 °C. In the case of VRFB, however, the battery cell employing the hydrophobic PTFE-based PFAEM exhibited the highest energy efficie... [more]

Increasing production rates of the biomethane lead to increased generation of waste biogases. These gases should be utilized on-site to avoid pollutant emissions to the atmosphere. This study presents a flexible swirl burner (~100 kW) with an adiabatic chamber capable of burning unstable composition waste biogases. The main combustion parameters and chemiluminescence emission spectrums were examined by burning waste biogases containing from 5 to 30 vol% of CH4 in CO2 under air, O2-enriched atmosphere, or with the addition of hydrogen. The tested burner ensured stable combustion of waste biogases with CH4 content not less than 20 vol%. The addition of up to 5 vol% of H2 expanded flammability limits, and stable combustion of the mixtures with CH4 content of 15 vol% was achieved. The burner flexibility to work under O2-enriched air conditions showed more promising results, and the flammability limit was expanded up to 5 vol% of CH4 in CO2. However, the combustion under O2-enriched conditi... [more]

The transient liquid crystal thermography can be a suitable tool to study heat-transfer performances on internal cooling schemes of gas turbine blades. One of the hot topics related to this methodology is about the level of reliability of the heat-transfer assessments in rotating tests where the fluid experiences time-dependent rotating effects. The present study contribution aims to experimentally validate by cross-comparison of the outcomes obtained by employing the transient technique with those from the steady-state liquid crystal thermography in which the rotational effects occur as time-stable by definition. Heat-transfer measurements have been conducted on a rib-roughened square cross-section channel, with an inlet Reynolds number equal to 20,000 and rotation number up to 0.2. Special attention has been paid to the definition of the more reliable calibration strategy for liquid crystals that are employed in the transient thermography and to the proper estimation of the heat loss... [more]

When using a certain type of Heating, Ventilation & Air Conditioning (HVAC) systems, it is primary to obtain their steady-state operating behaviors for achieving a better indoor thermal environment. This paper reports a development of a white-box-based dynamic model for a direct expansion (DX) air conditioning (A/C) system to predict its steady-state operating performance under variable speed operation. The established model consists of five sub-models, i.e., a compressor, an electronic expansion valve, an evaporator, a condenser and a conditioned space. Each sub-model was developed based on partial lumped parameter approach. Using the available data generated from an experimental DX A/C system, both transient and steady-state behaviors predictions agreed well with the experimental ones. With the help of the validated white-box model, the inherent steady-state operating performance expressed in terms of the relationship among total cooling capacity (TCC), equipment sensible heat ratio... [more]

The increasing penetration of Photovoltaic (PV) generation results in challenges regarding network operation, management and planning. Correspondingly, Distribution Network Operators (DNOs) are in the need of totally new understanding. The establishment of comprehensive standards for maximum PV integration into the network, without adversely impacting the normal operating conditions, is also needed. This review article provides an extensive review of the Hosting Capacity (HC) definitions based on different references and estimated HC with actual figures in different geographical areas and network conditions. Moreover, a comprehensive review of limiting factors and improvement methods for HC is presented along with voltage rise limits of different countries under PV integration. Peak load is the major reference used for HC definition and the prime limiting constraint for PV HC is the voltage violations. However, the varying definitions in different references lead to the conclusion that... [more]

In view of high ground stress, high geothermal temperature, and thermal hazard during deep mineral resource exploitation, the concept of phase-change heat storage backfill was put forward in this study. Further, the corresponding technical system was constructed and the main content involved in technical system, which is the optimized proportion of the backfill slurry added with phase-change materials (PCMs), was examined. Moreover, we elaborated upon the collaborative optimization of a backfill body’s mechanical and thermal properties and the mutual cooperation on backfill mining, geothermal energy exploitation, and simultaneous stope cooling. The heat transfer behavior of a backfill body plays a key role in technology system. We numerically simulated the heat transfer among a backfill body, surrounding rock, and airflow in the heat storage process, as well as the heat transfer between backfill body and cold fluid during the heat release process. The temperature distribution of a back... [more]

Urbanization and climate change are requiring cities to find novel pathways to a sustainable future, and therefore the urban context may accelerate the conversion to a circular economy. In this sense, climate change is a considerable threat to the environment, affecting both human and natural systems, and in this context individuals have a very important role. Therefore, the paper aims to investigate, on the one hand, what determines people to undertake specific actions in fighting climate change and, on the other hand, what determines some people to engage in adopting multiple actions exhibiting extra mitigation behaviour compared to others, paving the way to an urban circular economy. In order to do that, multilevel logistic regression analysis using hierarchical data (individuals grouped in counties), reflecting group variability and group-level characteristics effects on outcomes at individual level has been applied. Special attention was given to modernisation thesis validation, s... [more]

Bioethanol production from lignocellulosic biomass is still struggling with many obstacles. One of them is lignocellulosic inhibitors. The aim of this review is to discuss the most known inhibitors. Additionally, the review addresses different detoxification methods to degrade or to remove inhibitors from lignocellulosic hydrolysates. Inhibitors are formed during the pretreatment of biomass. They derive from the structural polymers-cellulose, hemicellulose and lignin. The formation of inhibitors depends on the pretreatment conditions. Inhibitors can have a negative influence on both the enzymatic hydrolysis and fermentation of lignocellulosic hydrolysates. The inhibition mechanisms can be, for example, deactivation of enzymes or impairment of vital cell structures. The toxicity of each inhibitor depends on its chemical and physical properties. To decrease the negative effects of inhibitors, different detoxification methods have been researched. Those methods focus on the chemical modif... [more]

Drilling technology and specially drilling equipment has dramatically changed in the last 10 years through intensive and innovative technologies, both in terms of hardware and software. While engineers are focusing on safer, faster, and more reliable than ever technologies, big data and automation are currently considered the way forward to achieve these goals. Especially when automation concepts are proposed, the prior testing and qualification under a laboratory-controlled environment are mandatory. Drilling simulators have been hugely successful in training industry personnel and academic professionals. A big reason for its success lies in the seamless integration of hardware and software to include an interactive user interface. Physical experimental simulators have the advantage of exposing the user with visual and auditive aids to better understand the real process. This paper provides an insight into the construction and results obtained using a dedicated laboratory setup, which... [more]

We present a novel methodology for the control of power unit commitment in complex ship energy systems. The usage of this method is demonstrated with a case study, where measured data was used from a cruise ship operating in the Caribbean and the Mediterranean. The ship’s energy system is conceptualized to feature a fuel cell and a battery along standard diesel generating sets for the purpose of reducing local emissions near coasts. The developed method is formulated as a model predictive control (MPC) problem, where a novel 2-stage predictive model is used to predict power demand, and a mixed-integer linear programming (MILP) model is used to solve unit commitment according to the prediction. The performance of the methodology is compared to fully optimal control, which was simulated by optimizing unit commitment for entire measured power demand profiles of trips. As a result, it can be stated that the developed methodology achieves close to optimal unit commitment control for the con... [more]

Power supply security tops the agenda of policies, and it is related to restructuring with the intention of improving efficiency. To investigate relationships between restructuring and reliability in the electricity industry of 15 OECD countries from 1987 to 2013, reliability is measured by the index of the sub-sectors (resources, generation, transmission and distribution, and electricity import), and the effects of the forms of liberalized restructuring—entry, privatization, and vertical divestiture—on sub-sectors are evaluated with the random-effect model. Results indicate that restructuring has a partially negative relationship with reliability, but the effect differs by the type of liberalization and supply sub-sectors.

Accounting for more than half of buildings in South Korea, the energy consumed by residential buildings has become a main concern and the cooing demand has rapidly increased. To reduce energy consumption, several passive and active design strategies have generally been applied. However, there has been an increasing demand for high window-to-wall ratios in residential buildings, it is imperative to block sunlight into a building effectively. Focusing on the reduction of cooling energy consumption in a residential building, the present study assessed the daylight and energy performance of shading devices. Among various types of shading devices, the Venetian blind, horizontal louver, light shelf, and egg-crate were selected. The illuminance levels in three different areas in a building were measured. In addition, the annual cooling energy consumption by these shading devices was investigated. As a result, both daylight and energy performance varied with different design options of these s... [more]

Operations and Maintenance (O&M) can make up a significant proportion of lifetime costs associated with any wind farm, with up to 30% reported for some offshore developments. It is increasingly important for wind farm owners and operators to optimise their assets in order to reduce the levelised cost of energy (LCoE). Reducing downtime through condition-based maintenance is a promising strategy of realising these goals. This is made possible through increased monitoring and gathering of operational data. SCADA data are useful in terms of wind turbine condition monitoring. This paper aims to perform a comprehensive comparison between two types of normal behaviour modelling: full signal reconstruction (FSRC) and autoregressive models with exogenous inputs (ARX). At the same time, the effects of the training time period on model performance are explored by considering models trained with both 12 and 6 months of data. Finally, the effects of time resolution are analysed for each algorithm... [more]

The main aim of this paper is to analyze the influence of laser shaping of the photovoltaic cell based on its efficiency. The authors described both process of the monocrystalline photovoltaic cell manufacturing, its efficiency, and the possibilities of usage in architecture and the process of creating the photovoltaic cells of unconventional shapes by using laser technology. A method for cutting photovoltaic cells using a fiber laser was presented as well as the parameters of the laser cutting process. The described method allows cutting the massively produced silicon cells according to the predetermined trajectory. Using the proposed process parameters, satisfactory cutting edge quality, and negligible impact of the laser beam on changes in the structure of the photovoltaic cell active layers were achieved. In each cycle of structure cutting, only a small part of the material is removed (from 1 to 2 μm), and depending on the thickness, the process is repeated from 50 to 300 times. It... [more]

PV temperature significantly affects the module’s power output and final system yield, and its accurate prediction can serve the forecasting of PV power output, smart grid operations, online PV diagnostics and dynamic predictive management of Building Integrated Photovoltaic (BIPV) systems. This paper presents a dynamic PV temperature prediction model based on transient Energy Balance Equations, incorporating theoretical expressions for all heat transfer processes, natural convection, forced convection, conduction and radiation exchanges between both module sides and the environment. The algorithmic approach predicts PV temperature at the centre of the cell, the back and the front glass cover with fast convergence and serves the PV power output prediction. The simulation model is robust, predicting PV temperature with high accuracy at any environmental conditions, PV inclination, orientation, wind speed and direction, and mounting configurations, free-standing and BIPV. These, alongsid... [more]

The common use of electric lighting in interiors has led to the need to search for user- and environmentally-friendly solutions. In this research, the impact of the luminaires and room parameters on the selected parameters of general lighting in interiors was assessed. To achieve the objective of this work, a computer simulation and statistical analysis of results were conducted. The illuminance uniformity on work plane, ceiling and wall relative illuminances, utilance, and normalized power density of lighting installations for 432 situations were analyzed in detail. The scenarios were varied in terms of room size, reflectance, lighting class, luminaire downward luminous intensity distribution, and layout. The lighting class was a factor having the highest impact on ceiling and wall illumination, utilance, and power. It was also shown that the impact of lighting class on ceiling illumination, utilance and power, was different in interiors of various sizes. The impact of reflectances an... [more]

As the market share of electric vehicles increases, the intermittent load on the electricity grid due to charging will increase. This can be counteracted by Vehicle-to-Grid (V2G) which utilises dormant electric vehicles to feed power into the grid, generating income for the vehicle owner while relieving load across the grid. However, increased battery use through V2G can negatively affect battery health. In this work, a computational model of an electric vehicle with battery degradation is used to investigate the relationship of these effects. The analysis was conducted at the top level of detail, only considering the battery pack of the vehicle. The findings of this investigation show that the cost relating to battery degradation is smaller than the potential profit available from Vehicle-to-Grid over a three-year period. However, the benefit does not seem to be enough to justify the upfront investment requirement, and further financial incentives, such as net billing, may be required... [more]

The new generation of internal combustion engines is facing various research challenges which often include modern fuels and different operating modes. A robust modeling framework is essential for predicting the dynamic behavior of such complex phenomena. In this article, the implementation, verification, and validation of a Eulerian multi-fluid model for spray applications within the OpenFOAM toolbox are presented. Due to its open-source nature and broad-spectrum of available libraries and solvers, OpenFOAM is an ideal platform for academic research. The proposed work utilizes advanced interfacial momentum transfer models to capture the behavior of deforming droplets at a high phase fraction. Furthermore, the WAVE breakup model is employed for the transfer of mass from larger to smaller droplet classes. The work gives detailed instructions regarding the numerical implementation, with a dedicated section dealing with the implementation of the breakup model within the Eulerian multi-flu... [more]

The aim of this work was to propose a small-scale Concentrated Solar Power plant using conventional technologies, in order to improve their flexibility and performances, and reinforce their competitiveness compared to traditional systems. Additionally, this study analyzed the possibility of providing continuity of energy production through an optimized hybrid system, which considered thermal energy storage from a gaseous Heat Transfer Fluid, air. It also considered the possibility of recovering part of the energy of the thermodynamic cycle through an Organic Rankine Cycle system with appropriate dimensions. The final outcomes were a 170 kW CSP plant with about 805 MWh of annual electricity production with a global solar capacity of 32.5%, about 900 kWh of thermal storage daily capacity, and an ORC recovery section of 54.2 kW with a specific production of 260 MWh/y.

One of the main challenges for a further integration of renewable energy sources in the electricity grid is the development of large-scale energy storage systems to overcome their intermittency. This paper presents the concept named CHEST (Compressed Heat Energy STorage), in which the excess electricity is employed to increase the temperature of a heat source by means of a high-temperature heat pump. This heat is stored in a combination of latent and sensible heat storage systems. Later, the stored heat is used to drive an organic Rankine cycle, and hereby to produce electricity when needed. A novel application of this storage system is presented by exploring its potential integration in the Spanish technical constraints electricity market. A detailed dynamic model of the proposed CHEST system was developed and applied to a case study of a 26-MW wind power plant in Spain. Different capacities of the storage system were assessed for the case under study. The results show that roundtrip... [more]

With a Euler−Euler (E2P) approach, a mathematical model for predicting the pointwise hydrodynamic behavior of a spouted bed was implemented though computational fluid dynamics (CFD) techniques. The model considered a bed elasticity approach in order to reduce the number of required sub-models to provide closure for the solids stress strain-tensor. However, no modulus of elasticity sub-model for a bed elasticity approach has been developed for spouted beds, and thus, large deviations in the predictions are obtained with common sub-models reported in literature. To overcome such a limitation, a new modulus of elasticity based on a sensitivity analysis was developed and implemented on the E2P model. The model predictions were locally validated against experimental measurements obtained in previous studies. The experimental studies were conducted using our in-house developed advanced γ-ray computed tomography (CT) technique, which allows to obtain the cross-sectional time-averaged solids h... [more]

The objective of this research was to explore correlates and predictors that play a role in the process of adopting and withdrawing from using a smart metering information platform (SMP). The SMP supports energy monitoring behaviors of the electricity consumers. The literature review shows, however, that not every customer is ready to the same extent to adopt novel solutions. Adoption requires going through stages of readiness to monitor energy consumption in a household. In a longitudinal field experiment on Polish residential consumers, we aimed to see whether messages congruent with the stage of readiness in which participants declared to be at a given moment will be more effective in prompting participants to progress to the next stage than a general message or a passive control condition. We also tested the effect of attitude and knowledge about energy monitoring on phase changes. Our study reveals that what affects the phase change is the participation in the study. The longer th... [more]

The article offers a systematic approach to the method of developing mathematical models of a chemical-technological system (CTS) in conditions of deficit and fuzziness of initial information using available data of various types. Based on the results of research and processing of the collected quantitative and qualitative information, mathematical models of the reactor are constructed. Formalized and obtained mathematical statements of the control problem for choosing effective modes of operation of technological systems are based on mathematical modeling. Based on the obtained expert information, linguistic variables were described and a database of rules describing the operation of the input parameters of the reactor unit of the catalytic cracking unit was obtained.

The energy contained in wastewaters has been identified as a promising sustainable energy resource that could be harvested by using microbial fuel cells (MFC). When dealing with real wastewaters, the MFCs should be able to manage high flow rates and flow rates fluctuations. In this work, the short-term effects of the influent flow rate variations on the performance of a microbial fuel cell has been studied. With this aim, the influent flow rate was stepwise increased from 0.72 to 7.2 L/d and then stepwise decreased. The obtained results indicate that, on the one hand, an increase in the influent flow rate leads to higher chemical oxygen demand removal rates up to 396 g/(L/d) and higher electric power generation almost 18 mW/m2, but to lower coulombic efficiencies. On the other hand, the reduction of the flow rate increases the coulombic efficiencies, as well as the percentage of chemical oxygen demand removed, but decreases electric power generation. In the short-term, the exposition t... [more]

The central heating technology with thermal storage technology is an important means to realize thermoelectric decoupling, meet heating demand, reduce primary energy consumption, and protect the ecological environment. For this paper, the numerical simulation method was used to study the temperature variation of large-capacity hot water storage tank (HWST) in an actual combined heat and power system. The influence of various factors, including the length diameter ratio, water supply temperature, and water supply flow, as well as the orifice diameter and number of the water distributor, on the flow uniformity and performance of the HWST was investigated. The results show that the heat storage efficiency and flow uniformity of the HWST can be improved by properly increasing the water supply flow, the orifice diameter, and number of the water distributor. Increasing the length diameter ratio can improve the flow uniformity, but it will reduce the heat storage efficiency of the HWST. Incre... [more]