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Showing records 76 to 100 of 3237. [First] Page: 1 2 3 4 5 6 7 8 Last
Links between the Energy Intensity of Public Urban Transport, Regional Economic Growth and Urbanisation: The Case of Poland
Zuzanna Kłos-Adamkiewicz, Elżbieta Szaruga, Agnieszka Gozdek, Magdalena Kogut-Jaworska
May 23, 2023 (v1)
Subject: Environment
Keywords: energy intensity, environmental Kuznets curve, panel granger causality, panel VAR, polyconvergence, public urban transport
The article concerns the verification of links between the energy intensity of public urban transport, regional economic development and urbanisation in the light of sustainable development challenges and club convergence processes. Three research questions were formulated in the article: (1) Does the regional economic development of voivodeships affect the energy intensity of public urban transport? (2) Does urbanisation shape energy consumption patterns in public urban transport (and are there agglomeration effects)? (3) Does the level of urbanisation of voivodeships depend on their regional level? The study covered 16 subregions of Poland from 2010 to 2020. A spatial dynamic exploration of the relationships between energy intensity patterns of public urban transport and the phenomenon of urbanisation and regional economic development was carried out. Panel models of vector autoregression and panel causality testing were used. The influence of the economic development of regions and... [more]
Synergistic Evolution of Palaeoenvironment—Bionts and Hydrocarbon Generation of Permian Saline Lacustrine Source Rocks in Jimusar Sag, Junggar Basin
Zaibo Xie, Huifei Tao, Yongqiang Qu, Tao Wu, Dongzheng Ma, Tianhai Wang, Zhen Qin, Long Su, Zhongping Li
May 23, 2023 (v1)
Subject: Environment
Keywords: biomarker, hydrocarbon generation, Jimusar, Lucaogou Formation, synergistic evolution
This study focused on Middle Permian Lucaogou Formation saline lake source rocks, utilizing a combination of biomarkers and hydrocarbon generation thermal simulation to analyze their biological compositions, depositional environments, and hydrocarbon generation potential. The Pr/Ph ratio, Ph/nC18 ratio, and Pr/nC17 ratio indicate that the Lucaogou Formation was in a reducing environment during the deposition period, and the lower part of the Lucaogou Formation (P2l1) is more anoxic than the upper part of the Lucaogou Formation (P2l2). The maturity index 20S (%) and ββ (%) reflect that the maturity of organic matter in the P2l1 is slightly higher than that in the P2l2. The G/H index and the ETR index indicate that the stratification of the water column is better during the sedimentary period of Lucaogou Formation and the salinity of the P2l1 is higher than that of the P2l2. The biomarker parameters of nC21−/nC22+, CPI, S/H, and C22T/C21T reflect that the organic matter of the source roc... [more]
Calorific Value of Zea mays Biomass Derived from Soil Contaminated with Chromium (VI) Disrupting the Soil’s Biochemical Properties
Jadwiga Wyszkowska, Agata Borowik, Magdalena Zaborowska, Jan Kucharski
May 23, 2023 (v1)
Subject: Environment
Keywords: activity of soil enzymes, compost, energy from biomass Zea mays, humic acids, soil contamination with chromium
One of the major challenges faced by contemporary agriculture is how to achieve better yields of crops and, consequently, higher biomass, even in unfavorable environmental conditions. This challenge corresponds to the assumptions of sustainable development, wherein it is envisaged that plant biomass should be used on a large scale for heat generation or conversion of biofuels. Keeping pace with observed trends, the following study was conducted in order to determine the effect of Cr(VI) on the net calorific value of Zea mays, to assess the impact of this element on soil enzymatic activity, and to identify the effectiveness of compost and humic acids in alleviating possible negative effects of Cr(VI) toxicity. These aims were pursued by setting up a pot experiment, in which soil either uncontaminated or contaminated with increasing doses of Cr(VI) of 0, 15, 30, 45, and 60 mg Cr kg−1 d.m. was submitted to biostimulation with compost and the preparation HumiAgra, a source of humic acids,... [more]
Decoupling Analysis of Energy-Related Carbon Dioxide Emissions from Economic Growth in Poland
Zbigniew Gołaś
May 23, 2023 (v1)
Subject: Environment
Keywords: CO2 emissions, decoupling, economic growth, Energy, fossil fuels, LMDI, Poland
This paper addresses the conditions behind energy-related carbon dioxide (CO2) emissions in Poland following its accession to the European Union. The study analyzed some energy, fossil fuel, economic, and environmental indicators, such as energy use, CO2 emissions, driving factors, decoupling elasticity status, and decoupling effort status. It relied on the Kaya identity and Logarithmic Mean Divisia Index (LMDI) in determining the drivers of CO2 emissions. As shown by the results, between 2004 and 2020, energy consumption in Poland grew at an average annual rate of 0.8%, while fossil fuel carbon emissions declined at 0.7% per year. Energy intensity was found to be the key force behind the reduction in CO2 emissions, whereas rapid economic growth was the main driver of CO2 emissions. While other factors, i.e., carbon intensity, energy mix, and population, also contributed to reducing the emissions, they had a much smaller—if not marginal—effect. In turn, the decoupling elasticity analys... [more]
Tackling Climate Change through Multi-Stakeholder Partnerships: Promoting SDG 17 to Combat Climate Change
Elena Bulmer, Benito Yáñez-Araque
May 23, 2023 (v1)
Subject: Environment
Keywords: climate change, SDG 13, SDG 17, SDG 7, sustainable development, sustainable development goal 17
The seventeen Sustainable Development Goals (SDGs) aim to address environmental, social, global, and economic challenges. The SDGs were a continuation of the Millennium Development Goals and assumed a common vision for the year 2030. Efforts to achieve the SDGs must be carried out in an integrated manner, respecting the three pillars of sustainable development, which are economic, social, and environmental. This review analyses the viability of Sustainable Development Goal 17 (SDG 17), which aims to build global partnerships for development. It makes specific reference to multi-stakeholder collaboration between all sectors of society. While the first sixteen SDGs are dedicated to concrete actions, SDG 17 Partnerships for Development coordinates and facilitates the implementation of the other goals. SDG 17 promotes the “right way” of collaboration between different actors through the formation of multi-stakeholder partnerships, which are essential to foster sustainable development. Alth... [more]
Economic and Environmental Assessment of Hydrogen Production from Brazilian Energy Grid
José Carlos Curvelo Santana, Pedro Gerber Machado, Cláudio Augusto Oller do Nascimento, Celma de Oliveira Ribeiro
May 23, 2023 (v1)
Subject: Environment
Keywords: carbon credit, energy grid, environmental cost accounting, hydrogen production, levelized cost of hydrogen
The Brazilian energy grid is considered as one of the cleanest in the world, because it is composed of more than 80% of renewable energy sources. This work aimed to apply the levelized costs (LCOH) and environmental cost accounting techniques to demonstrate the feasibility of producing hydrogen (H2) by alkaline electrolysis powered by the Brazilian energy grid. A project of hydrogen production, with a lifetime of 20 years, had been evaluated by economical and sensitivity analysis. The production capacity (8.89 to 46.67 kg H2/h), production volume (25 to 100%), hydrogen sale price (1 to 5 USD/kg H2) and the MAR rate were varied. Results showed that at 2 USD/kg H2, all H2 production plant sizes are economically viable. On this condition, a payback of fewer than 4 years, an IRR greater than 31, a break-even point between 56 and 68% of the production volume and a ROI above 400% were found. The sensitivity analysis showed that the best economic condition was found at 35.56 kg H2/h of the pl... [more]
Climate Benefits Advocated by the Development of Sustainable Vehicles and Charging Infrastructures in the Transport Sector
José A. Ventura
May 23, 2023 (v1)
Subject: Environment
Sustainable transportation refers to low vehicular greenhouse gas (GHG) emissions, energy efficient vehicles, and affordable modes of transportation, including electric and alternative fuel (AF) vehicles [...]
Is the Polish Solar-to-Hydrogen Pathway Green? A Carbon Footprint of AEM Electrolysis Hydrogen Based on an LCA
Artur Pawłowski, Agnieszka Żelazna, Jarosław Żak
May 23, 2023 (v1)
Subject: Environment
Keywords: anion exchange membrane (AEM), carbon footprint, green hydrogen, life cycle assessment (LCA), photovoltaic power plant, solar-to-hydrogen
Efforts to direct the economies of many countries towards low-carbon economies are being made in order to reduce their impact on global climate change. Within this process, replacing fossil fuels with hydrogen will play an important role in the sectors where electrification is difficult or technically and economically ineffective. Hydrogen may also play a critical role in renewable energy storage processes. Thus, the global hydrogen demand is expected to rise more than five times by 2050, while in the European Union, a seven-fold rise in this field is expected. Apart from many technical and legislative barriers, the environmental impact of hydrogen production is a key issue, especially in the case of new and developing technologies. Focusing on the various pathways of hydrogen production, the essential problem is to evaluate the related emissions through GHG accounting, considering the life cycle of a plant in order to compare the technologies effectively. Anion exchange membrane (AEM)... [more]
Life Cycle Assessment and Cost−Benefit Analysis as Combined Economic−Environmental Assessment Tools: Application to an Anaerobic Digestion Plant
Morena Bruno, Michela Marchi, Nicolò Ermini, Valentina Niccolucci, Federico Maria Pulselli
May 23, 2023 (v1)
Subject: Environment
Keywords: anaerobic digestion, biogas, carbon footprint, cost benefit analysis, economic–environmental assessment, environmental externality
In the present study, using Life Cycle Assessment (LCA) and Cost−Benefit Analysis (CBA), we assess the economic−environmental performance of an anaerobic digestion (AD) plant, fed by cultured crops (i.e., maize and wheat), in Italy. The biogas generated by the AD plant is used for the production of electricity, imputed into the Italian energy grid. The LCA evaluated potential greenhouse gas (GHG) emissions, measured via Carbon Footprint (CF), while the CBA analysed the financial and economic profiles via the Net Present Value (NPV) and Internal Rate of Return (IRR) indicators. The strength of combining these methodologies is the joint examination of the financial and social−environmental performance of the plant. The results of the CBA are complemented with the GHG emissions avoided by producing electricity from biogas. The CF of 0.28 kg CO2eq·kWh−1 of electricity produced is mainly due to the nitrogen fertilizers involved in the production of the additional feedstock matrix (i.e., mai... [more]
Cavitation Hydrodynamic Performance of 3-D Printed Highly Skewed Stainless Steel Tidal Turbine Rotors
Stylianos Argyrios Pitsikoulis, Sravya Tekumalla, Anurag Sharma, Wai Leong Eugene Wong, Serkan Turkmen, Pengfei Liu
May 23, 2023 (v1)
Subject: Environment
Keywords: blade skewness, cavitation, cavitation tunnel, environmental impact, power generation, structural integrity, tidal turbines
Hydraulic turbines contribute to 60% of renewable energy in the world; however, they also entail some adverse effects on the aquatic ecology system. One such effect is their excessive noise and vibration. To minimize this effect, one of the most effective and feasible solutions is to modify the design of the turbine rotor blade by introducing a skew. In this study, two 0.3-meter tidal turbines with 0-degree (no-skewness) and positive 90-degree skewness made of stainless steel 316L were designed and printed using a 3-D printing powder bed fusion technique. These rotors were then tested at the Emerson Cavitation Tunnel (ECT) at Newcastle University, UK, and the variation in the skewness of the blades of the turbines as a function of the power coefficient on a given tip speed ratio (TSR) value was ascertained. Results showed that the highly skewed rotor had significantly lower drag and torque fluctuations, with a slight decrease in efficiency compared to the non-skewed one, which warrants... [more]
The Coupling Relationship between Building Morphology and Outdoor Wind Environment in the High-Rise Dormitory Area in China
Liping Fan, Siwen Ren, Yuan Ma, Qibo Liu
May 23, 2023 (v1)
Subject: Environment
Keywords: building morphology, high-rise dormitory area, numerical simulation, orthogonal experimental design, outdoor wind environment
A good outdoor wind environment can guarantee the safety and comfort of student activities. It is also conducive to building energy-saving and low-carbon goals. In this study, the high-rise dormitory area of a university was selected as a research object in the cold region. The study used a combination of numerical simulation and orthogonal tests to analyze the weighting of the influencing factors of the wind environment and to recommend the optimal design scheme. The results indicated that the building layout, building length, width, and height all had different degrees of influence on the outdoor wind environment of the dormitory area. For the slab-type high-rise dormitory, the influence weight of the layout was the strongest, followed by the building height, the width, and, finally, the length. The optimal scheme is a staggered layout with a building length of 50 m, width of 18 m, and height of 85.2 m. The wind environment in this situation performed well in winter and summer. For t... [more]
Mitigation of CO2 Emissions from Commercial Ships: Evaluation of the Technology Readiness Level of Carbon Capture Systems
Valentina Bortuzzo, Serena Bertagna, Vittorio Bucci
May 23, 2023 (v1)
Subject: Environment
Keywords: carbon capture systems, CO2 emissions, commercial ships, environment protection, Technology Readiness Level
The challenge of achieving net-zero carbon emissions in the shipping sector is a pressing issue that is yet to be fully overcome. While new fuels and technologies hold promise for the future, they are not currently viable solutions on a large scale in the short-term. One strategy that is being considered as a way to reduce CO2 and CO emissions in the immediate future is carbon capture technology. Additionally, the possibility of a carbon tax being implemented in the future further strengthens the case for the adoption of this technology, which is already quite mature and in use in industries, although it has yet to be developed in the maritime sector. In this paper, the authors start from the definition of carbon capture technology to provide a technical overview of the solutions that are currently available to the maritime sector. Given the absolute innovation of such systems for application on board ships, the authors studied their installation and developed appropriate schemes to il... [more]
High-Energy Transformations of Fossil Fuels in the Cement Industry
Mirosław Szwed, Witold Żukowski, Krzysztof Misztal, Rafał Kozłowski
May 23, 2023 (v1)
Subject: Environment
Keywords: air pollution, greenhouse gases, scanning microscopy, toxicity
The energy stored in fossil fuels is released through combustion and is a fundamental process in the production of cement. The negative aspect of this combustion is the emission of greenhouse gases and dust. This paper presents the results of a study conducted within a cement plant in Ożarów (south-eastern Poland). The chemical properties (selected elements) in the needles of Scots pine (Pinus sylvestris L.) were determined. The needle surface was scanned using a scanning electron microscope (SEM) and was characterised in terms of chemical composition through energy dispersive spectroscopy (EDS). The concentrations of selected analytes in the biennial needles formed the following descending sequence: Fe > Al > Mn > Zn > Cu > Pb > Cr > Ni. SEM/EDS microphotographs showed the presence of particles of varying shape, size and chemical composition indicative of anthropogenic origin.
Establishment of Austria’s First Regional Green Hydrogen Economy: WIVA P&G HyWest
Nikolaus Fleischhacker, Niusha Shakibi Nia, Markus Coll, Ewald Perwög, Helmut Schreiner, Andreas Burger, Emmanuel Stamatakis, Ernst Fleischhacker
May 23, 2023 (v1)
Subject: Environment
Keywords: circular economy, energy autonomy, green hydrogen economy, green industry, green mobility, Renewable and Sustainable Energy
The regional parliament of Tyrol in Austria adopted the climate, energy, and resources strategy “Tyrol 2050 energy autonomous” in 2014 with the aim to become climate neutral and energy autonomous. “Use of own resources before others do, or have to do” is the main principle within this long-term strategic approach, in which the “power on demand” process is a main building block and the “power-to-hydrogen” process covers the intrinsic lack of a long-term, large-scale storage of electricity. Within this long-term strategy, the national research and development (R&D) flagship project WIVA P&G HyWest (ongoing since 2018) aims at the establishment of the first sustainable, business-case-driven, regional, green hydrogen economy in central Europe. This project is mainly based on the logistic principle and is a result of synergies between three ongoing complementary implementation projects. Among these three projects, to date, the industrial research within “MPREIS Hydrogen” resulted in the fir... [more]
Environmental Assessment of Hellisheidi Geothermal Power Plant based on Exergy Allocation Factors for Heat and Electricity Production
Maryori Díaz-Ramírez, Snorri Jokull, Claudio Zuffi, María Dolores Mainar-Toledo, Giampaolo Manfrida
May 23, 2023 (v1)
Subject: Environment
Keywords: district heating system, electricity, environmental indicators, Exergy, geothermal energy, life-cycle assessment
The Hellisheidi geothermal power plant, located in Iceland, is a combined heat and power double-flash geothermal plant with an installed capacity of 303.3 MW of electricity and 133 MW of hot water. This study aimed to elucidate the environmental impacts of the electricity and heat production from this double-flash geothermal power plant. In this vein, firstly, the most updated inventory of the plant was generated, and secondly, a life-cycle assessment approach based on the exergy allocation factor was carried out instead of applying the traditionally used allocations in terms of mass and energy. The functional unit was defined as the production of 1 kWh of electricity and 1 kWh of hot water for district heating. The life-cycle stages included the (i) construction, (ii) operation (including abatement operations and maintenance), and (iii) well closure of the geothermal plant. All of the life-cycle stages from construction to dismantling were considered. Finally, the results on the parti... [more]
Greenhouse Gas Balance in the City of Reggio Calabria and Assessment of the Effects of Measures of Emission Reduction and Absorption
Concettina Marino, Antonino Nucara, Maria Francesca Panzera, Matilde Pietrafesa
May 23, 2023 (v1)
Subject: Environment
Keywords: emission absorption, emission mitigation measures, greenhouse gas emission balance, IPCC methodology
Climate change and its ascertained attribution to anthropic activity need to be tackled with extreme urgency and must not be postponed. The need to reduce greenhouse gas emissions require a change in the energy paradigm, mainly affecting the construction and mobility sectors. Countries need to move towards climate neutrality with a widespread adoption of innovative models, systems, and technologies, reducing dependence on non-renewable sources and increasing energy efficiency. Measures to be adopted to achieve the prefixed decarbonization targets should involve, in addition to central governments, local communities. In this paper, in order to contribute to the definition of mitigation measures by the local administration, the balance of emissions and removal of greenhouse gases, assessed following the IPCC guidelines, for an Italian city (Reggio Calabria) on the date of 1 January 2020 is presented. Several hypotheses concerning reduction measures to be applied to the building and trans... [more]
Considerations for Achieving Equivalence between Hub- and Roller-Type Dynamometers for Vehicle Exhaust Emissions
Christian Engström, Per Öberg, Georgios Fontaras, Barouch Giechaskiel
May 2, 2023 (v1)
Subject: Environment
Keywords: chassis dynamometer, coast down, hub dynamometer, rotational mass, tire slip, wheel radius
Emissions from vehicles can be measured on the road or in laboratories using dynamometers that simulate the forces that a vehicle is subject to while driving on the road. In the light-duty vehicle regulations, only roller-type dynamometers are allowed. For hub-type dynamometers, due to the direct connection of the dynamometers to the wheel hubs, additional parameters that are used are rotational mass, dynamic wheel radius, and the tire force−slip relationship. Following up on an experimental study which showed that equivalent emission results can be achieved between roller- and hub-type dynamometers, this work presents and evaluates methods to determine parameters used by a hub-type dynamometer for mimicking roller-type dynamometer behavior. It also discusses methods to determine the parameters to simulate specific road conditions or when using only a hub-type dynamometer. The results show that using a constant dynamic radius for each wheel and a linear tire force−slip relationship is... [more]
The Analysis of Selected Factors Improving the Cargo Susceptibility to Modal Shift
Mateusz Zając
April 28, 2023 (v1)
Subject: Environment
Keywords: case study, CO2 reduction, intermodal transport, modal shift, rail transport utilization
The issue of shifting loads from road to rail is always vivid when it comes to reducing CO2 emissions from transport. Practically not every load transported by road vehicles over a long distance can be transferred to rail. Additionally, the potential of the railway lines is limited, which means that the network is not able to accept huge amounts of loads from road transport. In the article, attention was paid to the typology of cargo susceptible to changing the means of transport. The article discusses the factors influencing the real possibility of CO2 reduction by changing the mode of transport. The analysis and calculation example of the selected region in Poland is presented.
Research on Carbon Emission Efficiency Measurement and Regional Difference Evaluation of China’s Regional Transportation Industry
Guoyin Xu, Tong Zhao, Rong Wang
April 28, 2023 (v1)
Subject: Environment
Keywords: carbon emission efficiency of transportation industry, regional differences, transportation industry
From a global perspective, carbon emissions are a global problem that needs to be solved urgently. At present, 61% of countries have committed to achieving net zero emissions. Compared with industry and construction, the transportation sector has become the focus and challenge for countries to achieve carbon neutrality due to the characteristics of strong mobility, scattered emission sources, and complex social behaviors. Therefore, the issue of carbon emissions in the transportation industry has become the focus of academic attention. This paper first calculates the carbon emission efficiency (CEE) of the regional transportation industry through the super-efficiency SBM model and then evaluates its regional differentiation characteristics through the Theil index, which has important practical significance for reducing regional carbon emissions. The results show that the national transportation CEE average value is 0.612, a relatively low level. The spatial distribution of China’s tran... [more]
Direct and Indirect Carbon Emission from Household Consumption Based on LMDI and SDA Model: A Decomposition and Comparison Analysis
Jingjing Chen, Yangyang Lin, Xiaojun Wang, Bingjing Mao, Lihong Peng
April 28, 2023 (v1)
Subject: Environment
Keywords: household carbon emissions, logarithmic mean divisia index, structural decomposition analysis, urban–rural disparity
Household consumption has become an important field of carbon dioxide emissions. Urban−rural disparity in the household carbon emissions (HCEs) of residents and their influencing factors are relevant to HCE reduction. Taking Fujian as the study area, the LMDI and SDA models were used to analyze the effects of influencing factors for the direct household carbon emissions (DHCEs) and indirect carbon emissions (IHCEs) of urban and rural residents from 2006 to 2018. The HCEs continue to rise, approximately 65% from the IHCEs in 2017, and urban areas occupied 67% in 2018. The gap between urban and rural per capita HCEs is narrowing. In 2017, approximately 75% of urban per capita HCEs came from the IHCEs, while the per capita DHCEs’ occupation exceeded the IHCEs in rural areas. Per capita consumption expenditure has the largest positive effect on the DHCEs and IHCEs in urban and rural areas. With the urbanization process, the inhibition effect of rural DHCEs is larger than the positive effec... [more]
Storage and Disposal Options for Nuclear Waste
Katarzyna Kiegiel
April 28, 2023 (v1)
Subject: Environment
Nuclear technology has multiple applications that are fundamental to our daily life [...]
Evaluation of the Effect of Chassis Dynamometer Load Setting on CO2 Emissions and Energy Demand of a Full Hybrid Vehicle
Artur Jaworski, Maksymilian Mądziel, Krzysztof Lew, Tiziana Campisi, Paweł Woś, Hubert Kuszewski, Paweł Wojewoda, Adam Ustrzycki, Krzysztof Balawender, Mirosław Jakubowski
April 28, 2023 (v1)
Subject: Environment
Keywords: chassis dynamometer, CO2 emission, energy demand, hybrid vehicle, resistance forces
Among the solutions that make it possible to reduce CO2 emissions in the transport sector, particularly in urban traffic conditions, are hybrid vehicles. The share of driving performed in electric mode for hybrid vehicles is highly dependent on motion resistance. There are different methods for determining the motion resistance function during chassis dynamometer testing, leading to different test results. Therefore, the main objective of this study was to determine the effect of the chassis dynamometer load function on the energy demand and CO2 emissions of a full-hybrid passenger car. Emissions tests according to the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer for three different methods of determining the car’s resistance to motion. The study showed that adopting the motion resistance function according to different methods, results in differences in CO2 emissions up to about 35% for the entire cycle. Therefore, the authors suggest that in the case of... [more]
The Influencing Effects of Industrial Eco-Efficiency on Carbon Emissions in the Yangtze River Delta
Zaijun Li, Xiang Zheng, Dongqi Sun
April 28, 2023 (v1)
Subject: Environment
Keywords: carbon emissions, industrial eco-efficiency, spatial econometric model, spatio-temporal correlation, Yangtze River Delta
A low-carbon economy is the most important requirement to realize high-quality integrated development of the Yangtze River Delta. Utilizing the following models: a super-efficiency slacks-based measure model, a spatio-temporal correlation model, a bivariate LISA model, a spatial econometric model, and a geographically weighted random forest model, this study measured urban industrial eco-efficiency (IEE) and then analyzed its influencing effects on carbon emission in the Yangtze River Delta from 2000 to 2017. The influencing factors included spatio-temporal correlation intensity, spatio-temporal association type, direct and indirect impacts, and local importance impacts. Findings showed that: (1) The temporal correlation intensity between IEE and scale efficiency (SE) and carbon emissions exhibited an inverted V-shaped variation trend, while the temporal correlation intensity between pure technical efficiency (PTE) and carbon emissions exhibited a W-shaped fluctuation trend. The negati... [more]
The Process and Kinetics of Pesticide Desorption from Clay as a Function of Cleaning Polluted Waters
Esad Behrami, Vahid Avdiu
April 28, 2023 (v1)
Subject: Environment
Keywords: atrazine, benalaxyl, clay, desorption, dimethoate, methomyl
This study presents an investigation into the desorption process of pesticides, namely benalaxyl, atrazine, dimethoate, and methomyl, from aqueous solutions in natural Brari clay (Tirana) located at 41°21′14.49″ N and 19° 50′17.74″ E and Dardha clay (Korça) located at 40°31′16.59″ N and 20°49′33.69″ E. The desorption process was fast, where in the first 2 hours of contact, 99.1% of atrazine was desorbed from Brari clay, and 90.1% of atrazine was desorbed from Dardha clay. In addition, in the first 2 hours of contact, 80.3% of benalaxyl was desorbed from pear clay and 79.2% of benalaxyl from Brari clay; 96.2% of methomyl and 81.2% of dimethoate were desorbed. According to the acquired curves, the desorption process began with the dominance of methomyl from Brari clay, followed by dimethoate from Brari clay, dimethoate from Dardha clay, atrazine from Brari clay, benalaxyl from Brari clay, benalaxyl from Dardha clay, and lastly atrazine from Dardha clay. Hence, compared to Dardha clay, le... [more]
Enhanced Activation of Peroxymonosulfate via Sulfate Radicals and Singlet Oxygen by SrCoMn1−xO3 Perovskites for the Degradation of Rhodamine B
Penghui Shao, Xiping Yin, Chenyu Yu, Shuai Han, Baohuai Zhao, Kezhi Li, Xiang Li, Zhenyu Yang, Zhiwei Yuan, Qinzhi Shi, Jing Ren, Haiqiang Hu, Kai Cui, Tengfei Li, Jun Jiang
April 28, 2023 (v1)
Subject: Environment
Keywords: degradation of RhB, oxygen vacancy, perovskite, PMS, wastewater treatment
Perovskite is of burgeoning interest in catalysis, principally due to such material having high thermal stability, modifiable variability, ferromagnetism, and excellent catalytic performance in peroxomonosulfate (PMS) activation. In this study, the SrCoMn1−xO3 perovskites with different Mn doping were synthesized by a facile sol-gel method for peroxymonosulfate (PMS) activation to degrade Rhodamine B. The obtained SrCo0.5Mn0.5O3 perovskite exhibited the best catalytic efficiency, as Rhodamine B (40 mg/L) was removed completely within 30 min. In the system of SrCo0.5Mn0.5O3−PMS, several reactive species were produced, among which sulfate radicals and the singlet oxygen mainly contributed to Rhodamine B degradation. The relatively high catalytic performance could be attributed to the coupled redox cycle between Mn and Co, and the abundant oxygen vacancies. Moreover, the SrCo0.5Mn0.5O3 catalyst showed excellent stability and reusability, maintaining a high catalytic activity after several... [more]
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