Biosolids generated as byproducts of wastewater treatment processes are widely used as fertilizer supplements to improve soil condition and ultimately agricultural products yields and quality. However, biosolids may contain toxic compounds, i.e., per- and polyfluoroalkyl substances (PFAS), which can end up in soils, groundwater, and surface water, causing adverse environmental and health effects. The purpose of this study was to investigate the application of High-Temperature Pyrolysis (HTP) treatment for biosolids management, and its efficacy in eliminating PFAS from the solid fraction. Biosolid samples were pyrolyzed at two different temperatures, 500 and 700 °C, in a continuous bench-scale pyrolysis unit. The major finding is that the treatment process at higher pyrolysis temperatures can remarkably reduce or eliminate the level of PFAS (by ~97−100 wt%) in the resulting biochar samples.

This study investigated the effect of coal−Scenedesmus microalgae (with blending ratios of 100:0 (coal), 95:5 (Coalgae® 5%), 90:10 (Coalgae® 10%), 85:15 (Coalgae® 15%) and 80:20 (Coalgae® 20%)) on combustion temperature, mass loss, the formation of CO2, SO2 and NOx gases, and ash content under constant atmospheric air flow. Coalgae® refers to a material formed after blending coal and microalgae. The results showed that NOx came mainly from Coalgae® 10% and 15%, and this observation could be attributed to a variable air concentration level (O2 level) in the environment that could influence NOx during the combustion process, irrespective of the blending ratios. CO2 emission reductions (12%, 17%, 21% and 29%) and SO2 emission reductions (3%, 12%, 16% and 19%) increased with the increasing coal-microalgae blending ratio (Coalgae® 5−20%), respectively. Bubble-like morphology was observed in the ash particles of coal−microalgae blends through SEM, while the TEM confirmed the formation of car... [more]

Tannery sludge is disposed of in landfills as it is considered a special residue by the Italian legislation, creating pollution and waste. This paper aims at evaluating the performance of the anaerobic fermentation process to obtain short-chain fatty acids (SCFAs) from this waste. The assessment of the most appropriate conditions, in terms of pH, temperature, initial total solids (TSs) content, and application of oxidizing-thermal pretreatment has been developed. The batch test trials revealed that the combined microwave and hydrogen peroxide (MW-H2O2) pretreatment followed by thermophilic conditions gave the best results, in terms of the acidification yield (0.31 gCODSCFA/gVS0) and maximal SCFA concentration (above 26 g CODSCFA/L). In the tests conducted without pretreatment, the mesophilic temperature should be preferred since the acidification performances were comparable to or even better than their thermophilic counterparts. The SCFA composition analysis showed that in mesophilic... [more]

The contamination of surface and groundwater is of major concern around the globe due to the fast industrialization and urbanization. The groundwater and water quality of rivers, Ravi and Chenab in Faisalabad, Pakistan are contaminated due to the industrial wastewater. The aim of this study was the assessment of the physiochemical contaminants of Faisalabad’s industrial wastewater area and the adsorptive removal of ions present in high concentrations following the National Environmental Quality Standards (NEQS) for the municipal and industrial liquid effluents of Pakistan. One of the two samples was collected from a drain carrying wastewater from different industries and other from the outlet of a drain discharging wastewater into river Chenab. The analysis results obtained indicate that most of the contaminants were below the acceptable limit of industrial wastewater NEQS, Pakistan. However, contaminants like sulfate ions (714 mg/L), total dissolved solids (33,951−34,620 mg/L) and bar... [more]

CO2 biomethanisation is a rapidly emerging technology which can contribute to reducing greenhouse gas emissions through the more sustainable use of organic feedstocks. The major technical limitation for in situ systems is that the reaction causes CO2 depletion which drives up pH, potentially leading to instability and even digestion failure. The study aimed to test fundamentally derived predictive equations as tools to manage H2 addition to anaerobic digesters. The methodology used data from the literature and from experimental digesters operated with excess H2 to a point of failure and subsequent recovery. Two equations were tested: the first relating pH to CO2 partial pressure (pCO2), and the second extending this to include the influence of volatile fatty acids and ammonia. The first equation gave good agreement for data from studies covering a wide range of operating conditions and digester types. Where agreement was not good, this could usually be explained, and in some cases impr... [more]

Betulinic acid, BA, is a lupane derivative that has caught the interest of researchers due to the wide variety of pharmacological properties it exhibits towards tumor cells. Because of their prospective increased anti−proliferative efficacy and improved pharmacological profile, BA derivatives continue to be described in the scientific literature. The current work was conducted in order to determine the antiproliferative activity, under an in vitro environment of the newly developed 1,2,4−triazole derivatives of BA. The compounds and their reaction intermediates were tested on three cancer cell lines, namely RPMI−7951 human malignant melanoma, HT−29 colorectal adenocarcinoma, A549 lung carcinoma, and healthy cell line (HaCaT human keratinocytes). BA−triazole derivatives 4a and 4b revealed lower IC50 values in almost all cases when compared to their precursors, exhibiting the highest cytotoxicity against the RPMI−7951 cell line (IC50: 18.8 μM for 4a and 20.7 μM for 4b). Further biologica... [more]

Even in modern times, the popularity level of medicinal plants and herbal medicines in therapy is still high. The World Health Organization estimates that 80% of the population in developing countries uses these types of remedies. Even though herbal medicine products are usually perceived as low risk, their potential health risks should be carefully assessed. Several factors can cause the toxicity of herbal medicine products: plant components or metabolites with a toxic potential, adulteration, environmental pollutants (heavy metals, pesticides), or contamination of microorganisms (toxigenic fungi). Their correct evaluation is essential for the patient’s safety. The toxicity assessment of herbal medicine combines in vitro and in vivo methods, but in the past decades, several new techniques emerged besides conventional methods. The use of omics has become a valuable research tool for prediction and toxicity evaluation, while DNA sequencing can be used successfully to detect contaminants... [more]

The genotoxicity, mutagenesis, and carcinogenic effects of polycyclic aromatic hydrocarbon (PAH) derivatives may exceed the parent PAHs. However, their influence on the soil environment has not been explored to a large extent. Oxygenated polycyclic aromatic hydrocarbons (OPAHs) and nitrated polycyclic aromatic hydrocarbons (NPAHs) are typical polar substituted compounds. We offer a review of the literature on the sources, quantification, incidence, toxicity, and transport of these compounds in soil. Although their environmental concentrations are lower than those of their parent compounds, they exert higher toxicity. Both types of substances are basically related to carcinogenesis. OPAHs are not enzymatically activated and can generate reactive oxygen species in biological cells, while NPAHs have been shown to be mutagenic, genotoxic, and cytotoxic. These compounds are largely derived from the transformation of PAHs, but they behave differently in soil because of their higher molecular... [more]

Serious air pollution has occurred in China since 2012. With the increasing investment in technological innovation in China, the role of green technological innovation in reducing air pollution has attracted more and more attention. By constructing the spatial Durbin model and threshold regression model and using the statistical data of China’s provinces, this study explores the spatial effects and threshold characteristics of China’s green technology innovation on the environmental pollution of China’s air pollution-intensive industrial agglomeration. The research objective is to find out the spatial effects and threshold characteristics of green technology innovation on the environmental pollution of China’s air pollution-intensive industrial agglomeration. The results show that thermal power, etc., air pollution-intensive industrial are important sources of sulfur dioxide emissions; however, their degree of concentration is gradually increasing, resulting in rising sulfur dioxide em... [more]

Fe impurity is abundant in rare earth leaching solutions. The optimal hydrate structure of Fe(OH)2+ was calculated based on the quantum chemical in the water environment to investigate the microscopic occurrence of Fe impurity on kaolinite surfaces. The adsorption structure and bonding mechanism (including outer and inner layer) of hydrate Fe(OH)2+ on the kaolinite (001) surface were investigated. According to the results, the stable hydrate form of Fe(OH)2+ is [Fe(OH)(H2O)5]2+. Hydrated Fe(OH)2+ has a tendency to adhere to the Si-O surface in the form of outer layer adsorption. Adsorbate tends to adsorb to the Ou (deprotonated upright hydroxyl) site, where it generates a monodentate adsorption compound, and to the Ol and Ou (deprotonated lying and upright hydroxyl) sites, where it generates a bidentate adsorption compound if inner layer adsorption occurs. The Mulliken population and density of state analysis demonstrate that the ionic properties of Fe-Os in the inner layer adsorption... [more]

The unsustainable take-make-dispose linear economy prevalent in healthcare contributes 4.4% to global Greenhouse Gas emissions. A popular but not yet widely-embraced solution is to remanufacture common single-use medical devices like electrophysiology catheters, significantly extending their lifetimes by enabling a circular life cycle. To support the adoption of catheter remanufacturing, we propose a comprehensive emission framework and carry out a holistic evaluation of virgin manufactured and remanufactured carbon emissions with Life Cycle Analysis (LCA). We followed ISO modelling standards and NHS reporting guidelines to ensure industry relevance. We conclude that remanufacturing may lead to a reduction of up to 60% per turn (−1.92 kg CO2eq, burden-free) and 57% per life (−1.87 kg CO2eq, burdened). Our extensive sensitivity analysis and industry-informed buy-back scheme simulation revealed long-term emission reductions of up to 48% per remanufactured catheter life (−1.73 kg CO2eq).... [more]

In the last decades, the EPS (expanded polystyrene) and the XPS (extruded polystyrene) have become the most frequently used thermal insulation. Furthermore, the XPS has step resistant thermal insulation with higher strength. Nowadays in our current economic situation, the circular economy plays a significant role. That means we need to intend making a product that becomes waste as late as possible. Instead of a product, the goal is to return it to the economy as a basic material for a new product. Instead of generating waste, a new chance must be given by reusing it. Based on that consideration, our research work was in producing reinforced EPS material, which has the physical and thermal properties at least, as the XPS is much more expensive to produce. For reinforcement, materials have been chosen, in terms of its current life cycle, considered as product or waste. The first choice were plastic straws and cutleries that will be redrawn from the market. The next additives were renewab... [more]

The objective of this work was to present an overview of abrasive technologies with solid carbon dioxide as a blasting medium. These methods can be successfully used for the removal of a wide range of types of industrial pollution. The article covers literature reports in the field of the examined cleaning mechanisms and manufacturing process of dry ice, focusing on the structure and size of the product. Having the correct understanding of these processes is crucial for further technological development. Then various configurations of the dry-ice-blasting and snow-blasting systems are presented, including a range of typical parameters met in the literature and in industrial applications. Because the nozzle can be treated as a key part of the system, typical examples of nozzles are described. Special attention is paid to the usability of each type. This study also covers the actual scope of applications for the described systems, especially in industry and science.

When finishing the Topical Issue “New Research on Detection and Removal of Emerging Pollutants”, some reflections came to my mind, which I include in the piece below [...]

Large-scale deployment of CO2 capture, transport, and storage (CCTS) requires the rolling-out of extensive value chains. In this study, we present the development, design, techno-economic, environmental, and regulatory analysis of four pioneering chains that capture and condition CO2 from existing European industrial plants and their multi-modal transport to selected ports in Northern Europe. The pioneering chains can avoid between 65% and 87% of the industrial emissions, including scope 3, with a cost of CO2 avoided ranging between 100 and 300 euro/tCO2. The economic and environmental performance of the CCTS chains are substantially affected by the geographic location of the industrial emitters and the CO2 volumes to be transported. The analysis relies on the assumption that the four industrial plants would be early movers. While, in the future, technology maturation and infrastructure development are expected to reduce costs and emissions associated with the CCTS chain, this study q... [more]