Ammonia accumulation in biogas plants reactors is becoming more frequently encountered, resulting in reduced methane (CH4) production. Ammonia toxicity occurs when N-rich substrates represent a significant part of the biogas plant’s feedstock. The aim of this study was to develop an estimation method for the effect of ammonia toxicity on the CH4 production of biogas plants. Two periods where a biogas plant operated at 3200 mg·L−1 (1st period) and 4400 mg·L−1 (2nd period) of ammonium nitrogen (NH4+−N) were examined. Biomethane potentials (BMPs) of the individual substrates collected during these periods and of the mixture of substrates with the weight ratio used by the biogas plant under different ammonia levels (2000−5200 mg·L−1 NH4+−N) were determined. CH4 production calculated from the substrates’ BMPs and the quantities used of each substrate by the biogas plant was compared with actual CH4 production on-site. Biogas plant’s CH4 production was 9.9% lower in the 1st and 20.3% in the... [more]

The sonolysis of certain substrates in water has proved its effectiveness for the enhancement of the sonochemical production of hydrogen. In this study, the sonolysis of methane has been investigated for the first time in a single acoustic bubble (microreactor) over a frequency from 140 to 515 kHz. The obtained findings have been compared to those available in the literature. Independently of the methane dose (inside the bubble), the yield of H2 was improved especially with the decrease in wave frequency (from 515 to 140 kHz). For the driving frequencies 140, 213, 355, and 515 kHz, the production of hydrogen was maximized at 20, 15, 10, and 10% CH4, respectively. For 213 kHz, and the presence of 10% methane, the yield of hydrogen goes up by 111 fold compared to the case where the gas atmosphere is saturated only by argon. On the other hand, the highest methane conversions (~100% for 2, 5 and 7% CH4) were retrieved at 140 and 213 kHz. In terms of hydrogen formation and methane decay, th... [more]

Arguably, one of the most important issues the world is facing currently is climate change. At the current rate of fossil fuel consumption, the world is heading towards extreme levels of global temperature rise if immediate actions are not taken. Transforming the current energy system from one largely based on fossil fuels to a carbon-neutral one requires unprecedented speed. Based on the current state of development, direct electrification of the future energy system alone is technically challenging and not enough, especially in hard-to-abate sectors like heavy industry, road trucking, international shipping, and aviation. This leaves a considerable demand for alternative carbon-neutral fuels such as green ammonia and hydrogen and renewable methanol. From this perspective, we discuss the overarching roles of each fuel in reaching net zero emission within the next three decades. The challenges and future directions associated with the fuels conclude the current perspective paper.

The prediction of tidal waves is essential for improving not only our understanding of the hydrological cycle at the boundary between the land and ocean but also energy production in coastal areas. As tidal waves are affected by various factors, such as astronomical, meteorological, and hydrological effects, the prediction of tidal waves in estuaries remains uncertain. In this study, we present a novel method that can be used to improve short-term tidal wave prediction using a fixed-lag smoother based on sequential data assimilation (DA). The proposed method was implemented for tidal wave predictions of the estuary of the Nakdong River. As a result, the prediction accuracy was improved by 63.9% through DA and calibration using regression. Although the accuracy of the DA diminished with the increasing forecast lead times, the 1 h lead forecast based on DA still showed a 44.4% improvement compared to the open loop without DA. Moreover, the optimal conditions for the fixed-lag smoother we... [more]

Composite pressure vessels (CPVs) have become the main equipment for hydrogen storage; however, the effect of defect in the laminates of CPVs is difficult to detect. In this paper, composite specimens containing wrinkle defects were investigated, and a heterogeneity model of a wrinkle defect is proposed. A three-dimensional finite element code was developed to predict the behavior of carbon fiber-reinforced composite laminates with wrinkle defects. The effect of the geometric asymmetry of clamping was distinguished from the whole response. It was found that wrinkle defects are sensitive to tension but completely insensitive to torsion and that the distortion of out-of-plane displacement is strongly dependent upon wrinkle defects. An optical−mechanical method based on fringe projection was presented to measure the response of wrinkle defects, which shows an outstanding performance on wrinkle location and deformation visualization.

Hydrogen is expected to become a key component in the decarbonized energy systems of the future [...]

Sewage sludge may pose a fire risk. The safe storage of biomass waste is a challenge due to self-heating processes. This study aims to assess the propensity to spontaneously combust of sewage sludge in order to determine safe storage and transport conditions. The evaluation of spontaneous ignition hazard was assessed according to EN 15188, by the determination of the self-ignition temperature. Certain parameters assumed to affect the inclination of sewage sludge to self-ignite, including the moisture content, bulk density, elemental composition, and particle size, were discussed. The results showed the risk of self-ignition during the storage and transport of sludge dust and pellets. The usage of the smallest basket volume resulted in the highest self-ignition temperatures, which were 186 °C and 160 °C for sludge pellets and dust, respectively. The comparison of the two forms of thermally dry sludge showed, that despite sludge pellets being easier to store and handle issues, the more f... [more]

Despite market-oriented reforms, China’s energy sector is subject to energy price distortions, which are believed to be a crucial determinants of energy efficiency in China. This paper investigates the impact of energy price distortions on energy efficiency in China from the perspective of spatial correlation. Using the nonradial directional distance function approach, we first estimate the provincial-level energy efficiency in China. Paying attention to spatial correlation among the provinces of China, in stage two, we identify the determinants of energy efficiency. Our empirical results suggest that price distortions have a significant impact on energy efficiency in China. This impact holds when the cross-region effect is considered, i.e., besides its own energy price distortion, a region’s energy efficiency is also correlated to the adjacent provinces’ energy price distortions. Furthermore, we found that the levels of energy efficiencies in adjacent provinces are highly correlated.... [more]

Tidal power generation technology has advanced quickly in recent years. In this study, the Hilbert-Huang transform (HHT) was used to examine the electrical energy distribution law of tidal power generation according to the time periods of days, months, and years based on observed data for tidal power generation. Our analysis summarized the tidal power generation law as follows: in the span of one day, the motor ran for 14 h before shutting off for 10 h. The frequency was 28 Hz, and the maximum voltage was 259 V. The tidal power generation swung twice a month, reaching its peak in the middle of the month and its trough at the beginning. The tidal power output fluctuated twice a year, reaching its peak in August, September, and October and its trough in February, March, and April. In the investigation of tidal power generation patterns, the HHT transformation’s precision and potency were confirmed.

A centered water nozzle steam−water injector is driven by cold water to pump steam at a low pressure and to produce a high outlet water pressure. It can be used as a safety pump in a light water reactor to inject cooling water into the reactor core with no power supply in case of an accident. In this study, a modified calculation method for a centered water nozzle steam−water injector is proposed and verified by experimental data in the literature. The calculation method consists of a water nozzle model, a steam nozzle model, a mixing section model, and a shock wave model. Comparisons between the calculated results and the experimental results under different inlet steam pressures, inlet water pressures, and back pressures are conducted, and the calculated results show good agreement with the experimental results. The calculated results with different back pressures show that no shock wave occurs in the mixing section when the back pressure is small, but with the back pressure increasi... [more]

The detonation initiation characteristics of a single tube liquid-fueled pulse detonation combustor (PDC) is investigated at different inlet air temperatures in this paper. The inner diameter of the PDC is 62 mm. Gasoline and air are used as fuel and oxidant, respectively. The inlet air temperature is 288−523 K and the operating frequency of the PDC is 10~30 Hz. The experimental results show that the deflagration to detonation transition (DDT) distance, detonation initiation time, DDT time and jet ignition time decrease with the increasing operating frequency at the same inlet temperature. When the inlet temperature is 288 K, the DDT distance is shortened from 860.5 mm to 787.7 mm as the operating frequency increases from 10 Hz to 30 Hz. The detonation initiation time, the jet ignition time and the DDT time are reduced from 10.01 ms, 7.66 ms and 2.35 ms to 6.55 ms, 4.99 ms and 1.56 ms, respectively. When the inlet air temperature increases, the atomization and evaporation of the gasoli... [more]

Nanoscale tungsten bronze can convert near-infrared light into thermal energy. For a chemical synthesis, intermediate products and processes are potentially positive or negative to an end product. In this study, (NH4)2SO4 was added into the hydrothermal system of WO3, CsCl, CH3CH2CHO, and NH3·H2O to increase the Cs/W ratio in solution. An intermediate, Cs1.1W1.65O5.5, was isolated. Subsequently, it was confirmed via a kinetics experiment conducted for different times. The results of the NH3·H2O and NH4COOCH3 system indicate there are two influence factors that influence the formation of Cs1.1W1.65O5.5: the leaching out of W and imine reactions. A low leaching out rate induces a high Cs/W ratio and low-concentration W in solution, leading to the formation of Cs1.1W1.65O5.5. The imine reaction decreasing CH3CH2CHO restrains the reduction in Cs1.1W1.65O5.5. The increase in CH3CH2COO− with the reduction reaction results in both the micron-size sticks and nano-size equiaxial particles in po... [more]

The present investigation concerns the potentiality of Rhodopseudomonas sp. cells to produce clean energy such as molecular hydrogen (H2). The abovementioned goal could be reached by improving the capability of purple non-sulfur bacteria to produce H2 via a photofermentative process through the enzyme nitrogenase. Rhodopseudomonas sp. cells were immobilized in calcium alginate gel beads and cultured in a cylindrical photobioreactor at a working volume of 0.22 L. The semi-continuous process, which lasted for 11 days, was interspersed with the washing of the beads with the aim of increasing the H2 production rate. The maximum H2 production rate reached 5.25 ± 0.93 mL/h with a total output of 505 mL. The productivity was 40.9 μL (of H2)/mg (of cells)/h or 10.2 mL (of H2)/L (of culture)/h with a light conversion efficiency of 1.20%.

This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90% Fe2O3, 10% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions’ kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured ki... [more]

The organic flash cycle (OFC) is a novel power cycle with small exergy loss in the endothermic process. However, the low-pressure throttle valve in the cycle has a large throttling loss. Aiming to reduce the cycle exergy loss and improve the system performance, this study constructs a new configuration named the organic flash Rankine cycle (OFRC). Using the R600/R245fa mixture as the circulating working fluid and 200 °C geothermal water as the heat source, the effects of the change in working fluid composition on the thermal properties of the OFRC were studied based on the first and second laws of thermodynamics. Then, the economic performance of the proposed OFRC was investigated and then compared with that of the conventional OFC. The results show that the OFRC system has a significant improvement in thermal performance and economy compared with the OFC system. When the mole composition of the R600/R245fa mixture is 0.5/0.5, the net output work, thermal efficiency, and exergy efficie... [more]

Introducing a cathode modification layer is an effective method to obtaining highly efficient organic solar cells (OSCs) and improving their stability. Herein, we innovatively introduced a double cathode modification layer (SnO2/ZnO) into a non-fullerene OSCs based on PM7:IT-4F and explored the mechanisms. The effects of SnO2/ZnO film on charge carriers transfer in OSCs are studied via a variety of electrical testing methods including Photo-CELIV measurements. As a result, a cathode buffer layer with low recombination rate and high carrier mobility could be introduced, which is beneficial to electron transport and collection. The champion device based on the double cathode modification layer acquires an efficiency of 12.91%, obviously higher than that of the single cathode modification layer (SnO2 or ZnO) device. Moreover, The SnO2/ZnO double layer is demonstrated to be of great help in the improvement of device stability, and our work could provide a new inspiration for the preparatio... [more]

Converting CO2 into fuels via solar-driven thermochemical cycles of metal oxides is promising to address global climate change and energy crisis challenges simultaneously. However, it suffers from low energy conversion efficiency (ηen) due to high sensible heat losses when swinging between reduction and oxidation cycles, and a single product of fuels can hardly meet multiple kinds of energy demands. Here, we propose an alternative way to upsurge energy conversion efficiency by integrating solar thermochemical CO2 splitting with a supercritical CO2 thermodynamic cycle. When gas phase heat recovery (εgg) is equal to 0.9, the highest energy conversion efficiency of 20.4% is obtained at the optimal cycle high pressure of 260 bar. In stark contrast, the highest energy conversion efficiency is only 9.8% for conventional solar thermochemical CO2 splitting without including a supercritical CO2 cycle. The superior performance is attributed to efficient harvesting of waste heat and synergy of CO... [more]

Energy efficiency is becoming one of the key research topics in the energy field and has, therefore, attracted extensive attention in recent research [...]

The seismic sensors used for automatic seismic trip systems (ASTS) of nuclear power plants (NPPs) are mainly arranged on the raft foundation of reactor buildings; however, the arrangement principle of seismic sensors is not clear. In order to analyze the seismic response sensitivity of the raft foundation of reactor building in NPPs, this paper carried out the seismic response sensitivity research at seven positions on the raft foundation of a reactor building under three site conditions, with two sets of time histories as input. The results show that (1) the peak acceleration of the outer ring point of the raft foundation was the largest, and the peak acceleration of the center point was the smallest; (2) the peak value of the floor response spectrum at the outer ring point of the raft foundation was the largest, and the peak value at the center point was the smallest. In an earthquake, the outer ring point of the raft foundation of the reactor building was the most sensitive. It was... [more]

The aim of this analysis is to identify the possibility of treating eco-innovation in micro and small enterprises as a factor influencing the energy efficiency of the economy. In order to obtain an answer to such a research question, quantitative research was carried out among Polish enterprises from the SME sector (N = 400). Accordingly, the CATI technique was applied. The selection of enterprises was random and took place in the non-returnable drawing process. The criterion for selecting the sample was the size of enterprises, but in order to ensure the possibility of drawing conclusions based on a sufficiently large research sample, its structure (300 micro and 100 small enterprises) assumed the study of small enterprises in a proportion greater than their actual share in the population of enterprises. As a result of this research, the existence of a relationship between the improvement of the company’s competitive position and its activity in the field of eco-innovation implementat... [more]

Currently, woodchips and logging residues form the greatest share of biomass fuels used to generate heat in combined heat and power plants. They are supplied from various regions of the EU. The calorific values of the wood species used as biomass may vary significantly depending on the moisture and composition of the fuel, harvest seasonality, location, and other factors. This article presents the main resources of forest biomass and its characteristic features, as well as the calorific value of woodchips depending on the moisture content. Our research is based on the source data of forest resources from the State Forests National Forest Holding (PGLLP) in Poland. The research conducted by the main forestry enterprise in Poland covered a period of four years. The data on the harvesting of woodchips and logging residues converted into the calorific values of biomass were based on our research and a review of reference publications. Standard methods were used in the research, which inclu... [more]

This article was aimed to answer the question of whether local energy communities have a sufficient energy surplus for storage purposes, including hydrogen production. The article presents an innovative approach to current research and a discussion of the concepts of the collective prosumer and virtual prosumer that have been implemented in the legal order and further amended in the law. From this perspective, it was of utmost importance to analyze the model of functioning of an energy cluster consisting of energy consumers, energy producers, and hydrogen storage, whose goal is to maximize the obtained benefits, assuming the coopetitive nature of the relationship. The announced and clear perspective of the planned benefits will provide the cluster members a measurable basis for participation in such an energy community. However, the catalogue of benefits will be conditioned by the fulfillment of several requirements related to both the scale of covering energy demand from own sources a... [more]

Future grid refers to the next generation of the electrical grid, which will enable smart integration of conventional, renewable, and distributed power generation, energy storage, transmission and distribution, and demand management [...]

The properties of GaAsSbN and GaAsSb layers grown by liquid-phase epitaxy on n-GaAs substrates were investigated in a comparative plan with a view of their possible application in multi-junction solar cells. To avoid non-uniformity effects in the composition of these compounds with two or three different group-V volatile elements, the crystallization was carried out from finite melt with a thickness of 0.5 mm at low (<560 °C) temperatures. X-ray microanalysis and X-ray diffraction were used to determine the composition, lattice mismatch, and crystalline quality of the epitaxial layers. The morphology and surface roughness were examined by atomic force microscopy. Surface photovoltage (SPV) spectroscopy at room temperature was applied to study the optical absorption properties and the photocarrier transport in the samples. The long-wavelength photosensitivity of the GaAsSbN and GaAsSb layers, determined from their SPV spectra, is extended down to 1.2 eV. Although GaAsSb has a slightl... [more]

The resilience of energy systems is gaining more importance under the threat of pandemics, extreme weather, natural disasters, military conflicts, trade wars, energy supply shortages, rising energy demand, etc. [...]