An experimental study was performed to investigate the characteristics of two different combustion instability modes in a swirl-stabilized combustor. The first is the eigenfrequency corresponding to the half-wave of the combustion chamber section, and the second is the quarter-wave eigenmode of the inlet mixing section. The purpose of this study is to understand the effects of the swirl number on each combustion instability mode and analyze their generalized characteristics. Premixed gases composed of hydrocarbon fuels (C2H4 and CH4) and air were burned by independently varying the experimental conditions. Three dynamic pressure transducers and a photomultiplier tube were installed to detect pressure oscillations and heat release fluctuations in the inlet and combustion chamber sections, respectively. A high-speed camera was used to capture the instantaneous flame structures. In the swirl-stabilized combustor, the bands of the dominant frequencies were strongly dependent on the swirl n... [more]

We prove that the steady states of a class of multidimensional reaction−diffusion systems are asymptotically stable at the intersection of unweighted space and exponentially weighted Sobolev spaces, paying particular attention to a special case, namely, systems of equations that arise in combustion theory. The steady-state solutions considered here are the end states of the planar fronts associated with these systems. The present work can be seen as a complement to the previous results on the stability of multidimensional planar fronts.

For the sake of understanding the mechanism of deep subcriticality and high heterogeneity of neutron fluence rate in time−space on the neutron kinetics of the Accelerator-driven Subcritical Reactor Subcritical Reactor (ADSR) under varied beam transients and neutron spectra. A Monte Carlo homogenization approach for the neutron time−space kinetics of the ADSR is proposed in this study, and the influence mechanism on the kinetic parameters of the ADSR under varied neutron spectra, subcriticality, and beam transients is examined. The results show that the Monte Carlo homogenization for the α eigenvalue mode is more adaptable to the subcriticality characteristics under varied subcriticality; under beam transients, the relative differences in the kinetic parameters of the different modes of the ADSR with fast/thermal spectra increase with the depth of subcriticality, and the differences in neutron generation time for varied modes are larger than those of effective fraction of delayed neutro... [more]

The effect of non-coaxial rotation on the transport of mass subjected to first-order chemical reaction is studied analytically. The effects of thermal radiation, buoyancy, constructive and destructive chemical reactions along with Casson fluid in rotating frame are discussed. Time evolution of primary and secondary velocities, energy and solute particles are analyzed. The behavior of flow under the variation of intensity of magnetic field is also investigated. Evolutionary behavior of primary velocity is opposite to the evolutionary behavior of secondary velocity. The impact of buoyant force on primary velocity is opposite to the role of buoyant force on the secondary velocity. The evolutionary behavior of temperature is also examined and a remarkable enhancement in temperature is noticed. Thermal radiation causes the fluid to be cooled down as heat energy is escaped by thermal radiation. Evolutionary behavior of concentration is also analyzed and an increasing of concentration versus... [more]

In this paper, two main ideas of chemical kinetics are distinguished, i.e., a hierarchy and commensuration. A new class of chemical kinetic models is proposed and defined, i.e., egalitarian kinetic models (EKM). Contrary to hierarchical kinetic models (HKM), for the models of the EKM class, all kinetic coefficients are equal. Analysis of EKM models for some complex chemical reactions is performed for sequences of irreversible reactions. Analytic expressions for acyclic and cyclic mechanisms of egalitarian kinetics are obtained. Perspectives on the application of egalitarian models for reversible reactions are discussed. All analytical results are illustrated by examples.

Hydrate-based technologies (HBTs) have high potential in many fields. The industrial application of HBTs is limited by the low conversion rate of the water into hydrate (RWH), and sodium lignin sulfonate (SLS) has the potential to solve the above problem. In order to make the HBTs in the presence of SLS applied in industry and promote the advances of commercial HBTs, the effect of SLS on the thermodynamic equilibrium hydrate formation pressure (Peq) was investigated for the first time, and a new model (which can predict the Peq) was proposed to quantitatively describe the thermodynamic effect of SLS on the hydrate formation. Then, the effects of pressure and initial SLS concentration on the hydrate formation rate (rR) at different stages in the process of hydrate formation were investigated for the first time to reveal the kinetic effect of SLS on hydrate formation. The experimental results show that SLS caused little negative thermodynamic effect on hydrate formation. The Peq of the e... [more]

Pre-reforming of propane was studied over an industrial nickel-chromium catalyst under pressures of 1 and 5 bar, at a low steam to carbon molar ratio of 1, in the temperature range of 220−380 °C and at flow rates of 4000 and 12,000 h−1. It was shown that propane conversion proceeded more efficiently at low pressure (1 atm) and temperatures above 350 °C. A genetic algorithm was applied to search for kinetic parameters better fitting experimental results in such a wide range of experimental conditions. Power law and Langmuir−Hinshelwood kinetics were considered. It was shown that only Langmuir−Hinshelwood type kinetics correctly described the experimental data and could be used to simulate the process of propane pre-reforming and predict propane conversion under the given reaction conditions. The significance of Langmuir−Hinshelwood kinetics increases under high pressure and temperatures below 350 °C.

For the resonance treatment of a very high temperature reactors (VHTR) fuel with the double heterogeneity, an extension of the pin-based pointwise energy slowing-down method (PSM) was developed and implemented into DeCART. The proposed method, PSM-double heterogeneity (DH), has an improved spherical unit cell model with an explicit tri-structural isotropic (TRISO) model, a matrix layer, and a moderator for reflecting the moderation effect. The moderator volume was analytically derived using the relation of the Dancoff factor and the mean chord length. In the first step, the pointwise homogenized cross-sections for the compact was obtained after solving the slowing down equation for the spherical unit cell. Then, the shielded cross-section for the homogenized fuel compact was generated using the original PSM. The verification calculations were performed for the fuel pins with various packing fractions, compact sizes, TRISO sizes, and fuel temperatures. Additionally, two fuel block probl... [more]

The fluid catalytic cracking (FCC) process is an alternative olefin production technology, with lower CO2 emission and higher energy-saving. This process is used for olefin production by almost 60% of the global feedstocks. Different parameters including the operating conditions, feedstock properties, and type of catalyst can strongly affect the catalytic activity and product distribution. FCC catalysts contain zeolite as an active component, and a matrix, a binder, and a filler to provide the physical strength of the catalyst. Along with the catalyst properties, the FCC unit’s performance also depends on the operating conditions, including the feed composition, hydrocarbon partial pressure, temperature, residence time, and the catalyst-to-oil ratio (CTO). This paper provides a summary of the light olefins production via the FCC process and reviews the influences of the catalyst composition and operating conditions on the yield of light olefins.

Three series of binary metal oxide catalysts containing Ni, Cu, or Co oxides were prepared, fully characterized and tested in CO oxidation. The catalysts, with a constant transition metal loading of 10 wt%, were prepared from metal nitrates and urea mixtures by a microwave-assisted solution combustion method. The RV/OV ratio, corresponding to the stoichiometry of the reactants, calculated from their elemental oxidizing and reducing valences, was varied. In order to modify the redox character of the synthesis medium from the quantity of urea; an excess of urea was used for attaining reducing conditions, while a deficit of urea shifted the medium to oxidizing conditions. Three RV/OV ratios (0.9, 1.0, and 1.1) were selected to elaborate the different binary metal oxide catalysts, nine oxide catalysts were synthesized. Then, the influence of the stoichiometry (RV/OV ratio) on the bulk and surface properties of the binary metal oxide catalysts was investigated. Similarly, the influence of t... [more]

Anaerobic digestion (AD) has undergone many developments since its first appearance. Despite that, there are still some environmental and economical obstacles that are limiting its sustainability. On the other hand, different types of starch have proven their effectiveness in some different applications. Food processing industries are considered one of the largest generators of waste in the environment. With an aid of the response surface methodology (RSM), the proposed study aimed to find an optimised way to overcome the obstacles by studying the impacts of the starch isolated from the potato peels on the biogas produced from the AD of potato peels before and after starch separation. The study found that potato peels represented approximately 12.5% of the potato total weight. The starch has only a slight influence on the quantity of the biogas produced and much lower influences on its quality. This finding suggests further investigation is required on the production of starch bio-base... [more]

Cu/ZnO/Al2O3 catalyst with the addition of tri-promoters (Mn/Nb/Zr) was investigated with respect to their catalytic activity and stability in a prolonged reaction duration in methanol synthesis. Spent catalysts were characterized using N2 adsorption-desorption, FESEM/EDX, TEM, N2O chemisorption, and XPS for their physicochemical properties. The catalyst longevity study was evaluated at two days, seven days, and 14 days at 300 °C, 31.25 bar, 2160 mL/g.hr GHSV, and H2:CO2 at 10:1. The CO2 conversion and methanol yield decreased by about 5.7% and 7.7%, respectively, when the reaction duration was prolonged to 14 days. A slight reduction in catalytic activity under prolonged reaction duration was found due to thermal degradation.

Microalgae are natural resources of intracellular compounds with a wide spectrum of applications in, e.g., the food industry, pharmacy, and biofuel production. The extracellular polymeric substances (EPS) released by microalgal cells are a valuable bioproduct. Polysaccharides, protein, lipids, and DNA are the main constituents of EPS. This review presents the recent advances in the field of the determinants of the synthesis of extracellular polymeric substances by microalgal cells and the EPS structure. Physical and chemical culture conditions have been analyzed to achieve useful insights into the development of a strategy optimizing EPS production by microalgal cells. The application of microalgal EPS for flocculation and mechanisms involved in this process are also discussed in terms of biomass harvesting. Additionally, the ability of EPS to remove toxic heavy metals has been analyzed. With their flocculation and sorption properties, microalgal EPS are a promising bioproduct that can... [more]

The growing demand of microalgal biomass for biofuels, nutraceuticals, cosmetics, animal feed, and other bioproducts has created a strong interest in developing low-cost sustainable cultivation media and methods. Agricultural and food residues represent low-cost abundant and renewable sources of organic carbon that can be valorized for the cultivation of microalgae, while converting them from an environmental liability to an industrial asset. Biochemical treatment of such residues results in the release of various sugars, primarily glucose, sucrose, fructose, arabinose, and xylose along with other nutrients, such as trace elements. These sugars and nutrients can be metabolized in the absence of light (heterotrophic) or the presence of light (mixotrophic) by a variety of microalgae species for biomass and bioproduct production. The present review provides an up-to-date critical assessment of the prospects of various types of agricultural and food residues to serve as algae feedstocks an... [more]

Microalgae have been considered a promising and sustainable candidate for wastewater treatment and valuable bioproducts, such as feedstocks for food, nutrients, and energy. However, many challenging bottlenecks, such as low biomass productivity, expensive biomass harvesting techniques, and inefficient extraction of biofuels restrict its large-scale commercial production. Symbiotic relationships between microalgae and bacteria, also known as microalgal consortia, have proven to be effective solutions for mitigating technical and economic limitations. The natural and artificial symbiotic microalgal consortia combine microorganisms with various metabolic activities, which leads to valuable biomass production and the removal of nutrients, pharmaceuticals, and personal care products (PPCP) from wastewater. Many microalgal consortia have been applied for various wastewater treatments with reduced energy costs and higher efficiency in recovering valuable resources. In this study we review the... [more]

Herein, we proposed new two-stage processing of blackcurrant pomace toward a value-added, hydrocarbon-rich biocrude fraction. The approach consisted of thermochemical liquefaction of a wet-type organic matter into liquid biocrude followed by its upgrade by thermal and catalytic pyrolysis. Particularly, we put effort into investigating the effect of selected catalysts (ZSM-5 and HY zeolite) on the composition of the volatiles released during the pyrolysis of the biocrude. The latter was obtained through liquefaction of the raw material in the binary solvent system of water and isopropanol. The biocrude yield accounted for ca. 45 wt.% of the initial dry biomass. It was a complex mixture of various component groups with an abundant share of oxygenates, especially carboxylic acids and esters. Thereafter, the biocrude was subjected to a pyrolysis study performed by means of the microscale coupled pyrolysis-gas chromatography-mass spectrometry technique (Py-GC-MS). The dominant components id... [more]

It is well known that over the last 60 years the trend of long-lived greenhouse gas emissions have shown a strong acceleration. There is an increasing concern and a mounting opposition by public opinion to continue with the use of fossil energy. Western countries are presently involved in a so-called energy transition with the objective of abandoning fossil energy for renewable sources. In this connection, hydrogen can play a central role. One of the sustainable ways to produce hydrogen is the use of microalgae which possess two important natural catalysts: photosystem II and hydrogenase, used to split water and to combine protons and electrons to generate gaseous hydrogen, respectively. For about 20 years of study on photobiological hydrogen production, our scientific hopes were based on the application of the sulfur protocol, which indisputably represented a very important advancement in the field of hydrogen production biotechnology. However, as reported in this review, there is inc... [more]

Wastewater (WW) treatment using microalgae has become a growing trend due the economic and environmental benefits of the process. As microalgae need CO2, nitrogen, and phosphorus to grow, they remove these potential pollutants from wastewaters, making them able to replace energetically expensive treatment steps in conventional WW treatment. Unlike traditional sludge, biomass can be used to produce biofuels, biofertilizers, high value chemicals, and even next-generation growth media for “organically” grown microalgal biomass targeting zero-waste policies and contributing to a more sustainable circular bioeconomy. The main challenge in this technology is the techno-economic feasibility of the system. Alternatives such as the isolation of novel strains, the use of native consortia, and the design of new bioreactors have been studied to overcome this and aid the scale-up of microalgal systems. This review focuses on the treatment of urban, industrial, and agricultural wastewaters by microa... [more]

Activated carbons (AC) from lignocellulosic biomass feedstocks are used in a broad range of applications, especially for electrochemical devices such as supercapacitor electrodes. Limited studies of environmental and economic impacts for AC supercapacitor production have been conducted. Thus, this paper evaluated the environmental and economic impacts of AC produced from lignocellulosic biomass for energy-storage purposes. The life cycle assessment (LCA) was employed to quantify the potential environmental impacts associated with AC production via the proposed processes including feedstock establishment, harvest, transport, storage, and in-plant production. A techno-economic model was constructed to analyze the economic feasibility of AC production, which included the processes in the proposed technology, as well as the required facility installation and management. A base case, together with two alternative scenarios of KOH-reuse and steam processes for carbon activation, were evaluat... [more]

is a commercially exploitable source of bioactive compounds and biofuels with potential applications in microalgae-based industries. Despite this, little taxonomical information is available. Therefore, proper identification and characterization are needed for the sustainable utilization of isolated microalgae. In this study, an axenically isolated unicellular green alga from the Geumgang Estuary, Korea was investigated for its morphological, molecular, and biochemical characteristics. The morphological characteristics were typical of G. emersonii. Molecular phylogenetic analysis of the 18S rDNA sequence verified that the isolate belonged to G. emersonii and was subsequently named G. emersonii GEGS21. It was isolated from brackish water, and its optimal growth temperature, salinity, and light intensity were at 28−32 °C, 0 M NaCl, and 130−160 µmol m−2 s−1, respectively. The strain thrived over a range of temperatures (5−40 °C) and withstood up to 0.5 M NaCl. The isolate was rich in omeg... [more]

In the last few decades, microalgae have attracted attention from the scientific community worldwide, being considered a promising feedstock for renewable energy production, as well as for a wide range of high value-added products such as pigments and poly-unsaturated fatty acids for pharmaceutical, nutraceutical, food, and cosmetic markets. Despite the investments in microalgae biotechnology to date, the major obstacle to its wide commercialization is the high cost of microalgal biomass production and expensive product extraction steps. One way to reduce the microalgae production costs is the use of low-cost feedstock for microalgae production. Some wastes contain organic and inorganic components that may serve as nutrients for algal growth, decreasing the culture media cost and, thus, the overall process costs. Most of the research studies on microalgae waste treatment use autotrophic and mixotrophic microalgae growth. Research on heterotrophic microalgae to treat wastes is still sca... [more]

Wet organic wastes are especially troublesome in valorization. Therefore, innovative solutions are still in demand to make valorization feasible. In this study, we tested a new transformation route of a blackcurrant pomace as a high-moisture industrial waste through a series of high-temperature and pressure solvothermal liquefaction experiments. The feedstock was directly converted under near-critical conditions of the binary solvent system (water/2-propanol). The goal was to examine the effect of conversion parameters (temperature, biomass-to-solvent ratio) on the change in the yield of resultant bioproducts, as well as the quality thereof. The experiments were conducted in a batch autoclave at a temperature between 250 and 300 °C. The main product of the transformation was liquid biocrude, which was obtained with the highest yield (ca. 52 wt.%) at 275 °C. The quality of biocrude was examined by ATR-FTIR, GC-MS, and elemental analysis. The ultimate biocrude was a viscous heterogeneous... [more]

Lipases are enzymes that, in aqueous or non-aqueous media, act on water-insoluble substrates, mainly catalyzing reactions on carboxyl ester bonds, such as hydrolysis, aminolysis, and (trans)esterification. Yarrowia lipolytica is a non-conventional yeast known for secreting lipases and other bioproducts; therefore, it is of great interest in various industrial fields. The production of lipases can be carried on solid-state fermentation (SSF) that utilizes solid substrates in the absence, or near absence, of free water and presents minimal problems with microbial contamination due to the low water contents in the medium. Moreover, SSF offers high volumetric productivity, targets concentrated compounds, high substrate concentration tolerance, and has less wastewater generation. In this sense, the present work provides a temporal evolution perspective regarding the main aspects of lipase production in SSF by Y. lipolytica, focusing on the most relevant aspects and presenting the potential... [more]

Alternative splicing (AS) is a regulatory mechanism of post-transcriptional regulation that plays an important role in plant response to abiotic stresses. However, corresponding research involving the mechanism of AS in the nitrogen starvation response of C. reinhardtii is rare. This study performed a comprehensive and systematic analysis of AS events in C. reinhardtii at nine time points (0 h, 10 m, 30 m, 1 h, 6 h, 8 h, 24 h, and 48 h) under nitrogen starvation. It used STAR and rMATS tools to identify and quantify the probability of the AS event happening through the transcriptome high-throughput sequencing data. A total of 5806 AS events in 3500 genes were identified, and the retained intron and skipped exon were considered the main AS types. The genes related to the AS event in nitrogen starvation were mainly involved in spliceosome and transporter and enriched in the citrate cycle and fatty acid degradation pathways. These results suggested that AS may play an important role in th... [more]

Solid-state fermentation (SSF) is part of the pathway to consolidate waste as a relevant alternative for the valorization of organic waste. The objective of SSF is to produce one or several bioproducts of added value from solid substrates. Solid-state fermentation can use a wide variety of organic waste as substrates thus, it is an excellent candidate in the framework of the circular bioeconomy to change the status of waste from feedstock. The development of SSF was boosted in the previous decade by scientific efforts devoted to the production of hydrolytic enzymes. Nowadays, SSF has expanded to other valuable products: biosurfactants, biopesticides, aromas, pigments, and bio-flocculants, among others. This review explores the conditions to obtain the main emerging SSF products and highlight and discuss the challenges related to the scale-up of these processes and the bioproducts downstream, which hamper their further commercialization.