LAPSE:2023.34567
Published Article
LAPSE:2023.34567
Egalitarian Kinetic Models: Concepts and Results
April 27, 2023
In this paper, two main ideas of chemical kinetics are distinguished, i.e., a hierarchy and commensuration. A new class of chemical kinetic models is proposed and defined, i.e., egalitarian kinetic models (EKM). Contrary to hierarchical kinetic models (HKM), for the models of the EKM class, all kinetic coefficients are equal. Analysis of EKM models for some complex chemical reactions is performed for sequences of irreversible reactions. Analytic expressions for acyclic and cyclic mechanisms of egalitarian kinetics are obtained. Perspectives on the application of egalitarian models for reversible reactions are discussed. All analytical results are illustrated by examples.
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Keywords
acyclic and cyclic mechanisms, egalitarian kinetics, hierarchical kinetics
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Suggested Citation
Constales D, Yablonsky G, Xi Y, Marin G. Egalitarian Kinetic Models: Concepts and Results. (2023). LAPSE:2023.34567
Author Affiliations
Constales D: Department of Electronics and Information Systems, Ghent University, Building S-8, Krijgslaan 281, B-9000 Gent, Belgium [ORCID]
Yablonsky G: Department of Energy, Environmental and Chemical Engineering, McKelvey School of Engineering, Washington University in St. Louis, 1 Brookings Dr., St. Louis, MO 63130, USA [ORCID]
Xi Y: Department of Energy, Environmental and Chemical Engineering, McKelvey School of Engineering, Washington University in St. Louis, 1 Brookings Dr., St. Louis, MO 63130, USA
Marin G: Laboratory for Chemical Technology, Ghent University, Technologiepark 914, B-9052 Gent, Belgium [ORCID]
Yablonsky G: Department of Energy, Environmental and Chemical Engineering, McKelvey School of Engineering, Washington University in St. Louis, 1 Brookings Dr., St. Louis, MO 63130, USA [ORCID]
Xi Y: Department of Energy, Environmental and Chemical Engineering, McKelvey School of Engineering, Washington University in St. Louis, 1 Brookings Dr., St. Louis, MO 63130, USA
Marin G: Laboratory for Chemical Technology, Ghent University, Technologiepark 914, B-9052 Gent, Belgium [ORCID]
Journal Name
Energies
Volume
14
Issue
21
First Page
7230
Year
2021
Publication Date
2021-11-02
ISSN
1996-1073
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Original Submission
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PII: en14217230, Publication Type: Journal Article
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LAPSE:2023.34567
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https://doi.org/10.3390/en14217230
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Apr 27, 2023
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