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Records with Subject: Materials
926. LAPSE:2023.31298
Dynamic State Evaluation Method of Power Transformer Based on Mahalanobis−Taguchi System and Health Index
April 18, 2023 (v1)
Subject: Materials
Keywords: health index, Mahalanobis distance, oil chromatogram, status assessment, transformer
Health status assessment is the key link of transformer-condition-based maintenance. The health status assessment method of power transformers mostly adopts the method based on the health index, which has the problems of multiple parameters of each component and strong subjectivity in the selection of weight value, which is easily causes misjudgment. However, the existing online monitoring system for dissolved gas in transformer oil (DGA) can judge the normal or abnormal state of the transformer according to the gas concentration in a monitoring cycle. Still, there are problems, such as fuzzy evaluation results and inaccurate judgment. This paper proposes a dynamic state evaluation method for power transformers based on the Mahalanobis−Taguchi system. First, the oil chromatography online monitoring time series is used to screen key features using the Mahalanobis−Taguchi system to reduce the problem of excessive parameters of each component. Then, a Mahalanobis distance (MD) calculation... [more]
927. LAPSE:2023.31284
A Triple-Layer Membrane with Hybrid Evaporation and Radiation for Building Cooling
April 18, 2023 (v1)
Subject: Materials
Keywords: building cooling, evaporative cooling, passive cooling, polyethylene aerogel, radiative cooling
Passive cooling for thermal comfort improvement has received extensive attention for its low energy consumption. However, most of the existing passive cooling technologies require a complex system design and supporting equipment, since they cool the ambient air. Herein, we propose a hybrid evaporative and radiative cooling membrane with a hygroscopic hydrogel sandwiched by two layers of a porous polyethylene aerogel (PEA). The hydrogel implements evaporative cooling. Combining the high solar reflection of PEA and the high infrared emissivity of hydrogel, this hybrid membrane also possesses radiative cooling. In addition, the high infrared transmittance and low thermal conductivity of PEA allow direct heat transfer between the hydrogel and human body, instead of the ambient air. Through comparative experiments and theoretical calculations, it is indicated that the net cooling power delivered by the hybrid membrane to the human body is up to 78.45 W m−2, which is much higher than that of... [more]
928. LAPSE:2023.31281
Latent Heat Storage Systems for Thermal Management of Electric Vehicle Batteries: Thermal Performance Enhancement and Modulation of the Phase Transition Process Dynamics: A Literature Review
April 18, 2023 (v1)
Subject: Materials
Keywords: battery system, electric vehicle, Latent Heat Storage, phase change material, thermal management, thermal performance enhancement
Electric vehicles battery systems (EVBS) are subject to complex charging/discharging processes that produce various amount of stress and cause significant temperature fluctuations. Due to the variable heat generation regimes, latent heat storage systems that can absorb significant amounts of thermal energy with little temperature variation are an interesting thermal management solution. A major drawback of organic phase change materials is their low thermal conductivity, which limits the material charging/discharging capacity. This review paper covers recent studies on thermal performance enhancement of PCM thermal management for electric vehicles batteries. A special focus is placed on the constraints related to electric vehicles battery systems, such as mass/volume minimization, integration with other battery thermal management systems, operational temperature range, adaptability to extreme regimes and modulation of the melting/solidification behavior. The main research outcomes are... [more]
929. LAPSE:2023.31237
Precision and Accuracy of Pulse Propagation Velocity Measurement in Power Cables
April 18, 2023 (v1)
Subject: Materials
Keywords: cable diagnostics, measurement accuracy, partial discharge, power cables, pulse propagation, time-domain reflectometry
The partial discharge (PD) measurement is an important method used in determining the condition of medium- and high-voltage cable insulation. Considering the propagation velocity of PD signals in power cables is necessary for determining the location of PD defects. However, the determination of velocity is not straightforward due to propagation-related attenuation and dispersion, which distorts the PD pulse waveform. This introduces a degree of uncertainty into the pulse velocity as well as the PD source locations determined based on that velocity, which is usually considered to be of constant value in PD analysis. This paper investigates the accuracy of the pulse propagation velocity measurement in power cables. Tests were performed on a medium voltage power cable in a laboratory setting using two sets of PD-specific measurement equipment: a high-frequency current transformer (HFCT) and an IEC 60270-compliant conventional measurement system. The propagation velocities and their statis... [more]
930. LAPSE:2023.31230
Distribution of Rare-Earth Elements in Ashes Produced in the Coal Combustion Process from Power Boilers
April 18, 2023 (v1)
Subject: Materials
Keywords: bottom ash, Coal, critical raw materials, fly ash, rare-earth elements, REY, yttrium
The growing demand for rare-earth elements and yttrium (REY) in modern technologies has resulted in the systematic depletion of primary ores. For this reason, research is being conducted around the world on alternative sources of rare-earth elements, e.g., on the possibilities of recovering REY from coal waste or coal combustion. The article presents the results of comprehensive tests of the fuel—hard coal, and high-temperature HTA ash, fly ash, and bottom ash. Examined samples were taken from a Polish power plant. In the tests, fuel quality parameters were determined in accordance with the standards; microscopic observations in reflected and transmitted light, as well as a scanning electron microscope (SEM/EDS), were used, and chemical and phase composition were determined using ICP-MS and XRD methods, respectively. The distribution of REY between these ashes was analyzed. Their suitability as alternative sources of REY was assessed. The obtained results showed that the process of har... [more]
931. LAPSE:2023.31210
A Review of the Performance Improvement Methods of Phase Change Materials: Application for the Heat Pump Heating System
April 18, 2023 (v1)
Subject: Materials
Keywords: heat pump heating system, performance improvement methods, phase change materials, thermal energy storage
With the development of the economy and society, energy problems have become a great concern. The heat pump-coupled thermal energy storage (TES) system is a potential form of building heating, which can improve the stability of the grid and promote the consumption of renewable energy. Phase change materials (PCMs) are widely used in the field of building heating, but there are still some problems such as unsatisfactory melting points, low thermal conductivity, phase separation, and supercooling, which limit the application of PCMs in heat pump heating systems. Therefore, it is very important to improve PCMs by a performance improvement method. This work first summarizes the classification, advantages and disadvantages of PCMs, and introduces the connection between PCMs and heat pumps. Then, a detailed summary of PCMs applied in heat pump heating systems is presented, and a comprehensive review of the performance improvement methods for PCMs, which include additives, encapsulation, and... [more]
932. LAPSE:2023.31199
A Critical Review on the Thermal Transport Characteristics of Graphene-Based Nanofluids
April 18, 2023 (v1)
Subject: Materials
Keywords: convective heat transfer coefficient, graphene, nanofluids, thermal conductivity, thermophysical properties
Over the past few years, considerable research work has been performed on the graphene-based nano-dispersion for improvement of the thermal conductivity and thermal characteristics of base fluid. Graphene-based dispersion shows the good stability, better enhancement in thermal conductivity, and heat transport behavior compared to the other nano-dispersions drawing significant attention among researchers. This article carries out comprehensive reviews on the heat transport behavior of graphene-based nano-dispersion over the past ten years. Some researchers have carried out the investigations on the various methods adopted for the preparation of graphene-based nano-dispersion, techniques involved in making good dispersion including stability characterizations. There needs to be a better agreement in results reported by the various researchers, which paves the way for further potential research needs. Some researchers studied thermo-physical properties and heat transport behavior of graph... [more]
933. LAPSE:2023.31190
Heat and Moisture Management for Automatic Air Conditioning of a Domestic Household Using FA-ZnO Nanocomposite as Smart Sensing Material
April 18, 2023 (v1)
Subject: Materials
Keywords: COMSOL multiphysics, four-probe method, humidity sensor, moisture storage function
Prior to the year 2000, air conditioning was not common in many cities throughout the world. However, today, 20 years later, air conditioning is common. This circumstance has a negative impact on the climate. Additionally, the situation regarding energy usage as a result of this is alarming. For a healthy and pleasant livelihood, indoor temperature and air flow must be controlled. False partitions with insulating layers have been used to regulate the temperature inside rooms, but they are unable to regulate the variation in humidity caused by the exchange of water between interior and exterior walls. In this manuscript, we provide a sensory system that can automatically detect relative humidity and temperature. Temperature is sensed at each layer of the false partition using an LM35-based integrated circuit and humidity is detected by an FA−ZnO nano-composite layer through an indoor false partition owing to changes in the material’s resistance. Depending upon the change in resistance b... [more]
934. LAPSE:2023.31189
Effect of Oxygen Vacancy on the Crystallinity and Optical Band Gap in Tin Oxide Thin Film
April 18, 2023 (v1)
Subject: Materials
Keywords: calcination, crystallite size, nanoparticles, optical properties, oxygen vacancies, thin film
Herein, we have prepared tin oxide (SnO2) nanoparticles (NPs), through a co-precipitation method, using SnCl2·2H2O dissolved in distilled water (DW) as a precursor. Then, the prepared NPs were heat treated in a muffle furnace, as a function of temperature, under an open atmosphere. The prepared SnO2 NPs were then re-dispersed in DW, followed by spray casting on a glass substrate, for preparing SnO2 thin films. The average thickness of the fabricated SnO2 thin films was 2.76 µm. We demonstrated a very clear variation in the structural, compositional, and morphological features of the different films (in particular, variation of the density of oxygen vacancies), which altered their electrical and optical properties. Raising the calcination temperature of the SnO2 thin films, from 250 °C to 650 °C, led to a monotonic reduction in the crystallite size, from 10.4 nm to 6.7 nm, and a decrease in the O/Sn ratio, from 5.60 to 4.79. A 14.5% decrease in the O/Sn ratio resulted in a decrease in t... [more]
935. LAPSE:2023.31166
Investigation of Thermal Performance of Ternary Hybrid Nanofluid Flow in a Permeable Inclined Cylinder/Plate
April 18, 2023 (v1)
Subject: Materials
Keywords: cylinder and plate, heat source/sink, inclined geometry, porous medium, ternary nanofluid
This article comprehensively investigates the thermal performance of a ternary hybrid nanofluid flowing in a permeable inclined cylinder/plate system. The study focuses on the effects of key constraints such as the inclined geometry, permeable medium, and heat source/sink on the thermal distribution features of the ternary nanofluid. The present work is motivated by the growing demand for energy-efficient cooling systems in various industrial and energy-related applications. A mathematical model is developed to describe the system’s fluid flow and heat-transfer processes. The PDEs (partial differential equations) are transformed into ODEs (ordinary differential equations) with the aid of suitable similarity constraints and solved numerically using a combination of the RKF45 method and shooting technique. The study’s findings give useful insights into the behavior of ternary nanofluids in permeable inclined cylinder/plate systems. Further, important engineering coefficients such as skin... [more]
936. LAPSE:2023.31159
Characterization of the Temperature Profile near Contact Lines of an Evaporating Sessile Drop
April 18, 2023 (v1)
Subject: Materials
Keywords: Bénard-Marangoni instability, drop evaporation, microscopic fluorescence-based thermometry, temperature measurement
Evaporation of a sessile drop is ubiquitous in nature and has many industrial applications. Despite extensive studies over recent decades, a critical issue, i.e., how temperature varies near contact lines, remains elusive. In this work, we report to date the first direct experimental measurement showing the microscopic temperature distribution near contact lines of an evaporating pinned sessile drop. Using a fluorescence-based thermometry, we find that the temperature at the free interface near contact lines varies drastically along the radial direction, engendering a concentric fringe pattern that evolves over the evaporation lifespan. The formation of such fringe patterns is attributed to a combined mechanism of locally enhanced evaporative cooling at the drop edge and the development of interfacial convective vortices due to Bénard-Marangoni instability. We also study the evaporation dynamics at different initial contact angles and find that the characteristics of this fringe patter... [more]
937. LAPSE:2023.31113
The Strike-Slip Fault Effects on Tight Ordovician Reef-Shoal Reservoirs in the Central Tarim Basin (NW China)
April 18, 2023 (v1)
Subject: Materials
Keywords: “sweet spot” exploitation, fractured reservoir, reef-shoal reservoir, strike-slip fault, Tarim
The largest carbonate condensate field in China has been found in the central Tarim Basin. Ordovician carbonate reservoirs are generally attributed to reef-shoal microfacies along a platform margin. However, recent production success has been achieved along the NE-trending strike-slip fault zones that intersect at the platform margin. For this contribution, we analyzed the strike-slip fault effects on the reef-shoal reservoirs by using new geological, geophysical, and production data. Seismic data shows that some NE-trending strike-slip faults intersected the NW-trending platform margin in multiple segments. The research indicated that the development of strike-slip faults has affected prepositional landforms and the subsequent segmentation of varied microfacies along the platform margin. In addition, the strike-slip fault compartmentalized the reef-shoal reservoirs into multiple segments along the extent of the platform margin. We show that fractured reef-shoal complexes are favorable... [more]
938. LAPSE:2023.31082
A Study on the Deformation Mechanism of the Rock Surrounding a Weakly Cemented Cross-Layer Roadway, under Tectonic Stress
April 18, 2023 (v1)
Subject: Materials
Keywords: asymmetric deformation, cross-layer roadway, deformation mechanism, tectonic stress, weakly cemented stratum
Maintaining the stability of the surrounding rock is an important prerequisite in ensuring the safe and efficient construction of underground mines—in particular, the surrounding rock of the cross-layer roadway, which is a combination of different media with different lithologies. Numerical models were established to investigate the effects of the different lateral pressure coefficients (λ), the angle (α) between the roadway and the maximum horizontal principal stress, and typical lithological combinations on the deformation of the surrounding rock of weakly cemented roadways. The main outcomes obtained from our research indicated the following: (1) under the action of tectonic stress, the focus should be on strengthening the roof of the roadway support of the slab, which is conducive to the stability of the surrounding rock; (2) roadway deformation and failure for the cases λ < 1.5 are approximately symmetrically distributed, whereas those for the cases λ > 1.5 are asymmetric; (3) roa... [more]
939. LAPSE:2023.31063
Thermal Interface Materials with Hexagonal Boron Nitride and Graphene Fillers in PDMS Matrix: Thermal and Mechanical Properties
April 18, 2023 (v1)
Subject: Materials
Keywords: curing inhibition, elastomers, graphene, hexagonal boron nitride, mechanical properties, PDMS, thermal interface materials
This work studies the effects of graphene nanoplatelets (GNPs) and hexagonal boron nitride (hBN) on the thermal and mechanical properties of polydimethylsiloxane (PDMS) matrix for use as thermal interface materials (TIMs). Solution mixing of 10 wt% GNPs and 40 wt% hBN with PDMS produced TIMs with through-plane thermal conductivity (TC) of 1.24 W m−1 K−1 showing a 519% increase relative to the neat matrix. A synergistic effect between GNPs and hBN was particularly demonstrated when in samples with 48 wt% total filler content, 8 wt% hBN was replaced by GNPs, and the TC was increased by 33%. The elongation at break of the hBN (40 wt%)/GNP (8 wt%) samples reached 151%, representing a 160% increase when compared to samples with only 40 wt% hBN. Moreover, the shore hardness of samples containing 40 wt% hBN was 68 A, and the introduction of 8 wt% GNPs caused a decrease to 38 A. DSC measurements on samples filled with hBN and GNPs showed a reduction up to 65% in Ultimate Heat of Curing, which... [more]
940. LAPSE:2023.31060
Heterogeneous Catalytic Conversion of Terpenes into Biofuels: An Open Pathway to Sustainable Fuels
April 18, 2023 (v1)
Subject: Materials
Keywords: Biofuels, drop-in fuels, heterogeneous catalysis, terpenes, terpenoids
The production and use of terpene-based fuels represents a renewable source of energy in the transportation sector, especially in the aviation sector. The literature on the conversion of terpenes into valuable compounds is not new but has been based on the production of products for cosmetics and pharmaceutics. Several established chemical routes are also a way to develop drop-in fuels. The present work explores all the main chemical processes that can transform terpenes into more valuable fuels or additives, focusing on the use of heterogeneous catalysis, catalyst type, operating conditions, and reaction performance. α-pinene is the most studied catalyst, since it is the main component of turpentine. Isomerization is the most frequently applied chemical pathway used to enhance fuel properties, and a wide group of heterogeneous catalysts have been reported, with sulphonic acid resin catalysts, transition metals, alumina, and silicates being the most used. This work also explores the cu... [more]
941. LAPSE:2023.31046
Experimental Study of Oxygen Depletion Effects on Soot Morphology and Nanostructure in Coflow Diffusion Aviation Fuel (RP-3) Flames
April 17, 2023 (v1)
Subject: Materials
Keywords: aviation fuel (RP-3), morphology, nanostructure, oxygen-depleted combustion
Oxygen concentration is a significant factor affecting soot formation and oxidation. However, there are few studies that have focused on the morphology and nanostructure characteristics of soot in aviation kerosene, oxygen-depleted combustion flames. In the present paper, five coflow flames under initial oxygen volume concentrations of 18.5%, 19%, 20%, 21%, and 23.5% were studied. The pneumatic probe sampling method and high-resolution transmission electron microscopy (HRTEM) analysis were conducted to quantify the morphology and nanostructure parameters, and laser extinction (LE) was applied to determine the soot volume fraction. Among the cases of different oxidizer oxygen concentrations (23.5% to 18.5%), the change in soot volume fraction was quantified, and the degree of graphitization of soot particles, i.e., the maturity, were compared. The results show that the peak value of soot volume fraction of the flames increased by 0.73 ppm as the oxygen concentration increased from 21% t... [more]
942. LAPSE:2023.31023
Synergistic Germanium-Decorated h-BN/MoS2 Heterostructure Nanosheets: An Advanced Electrocatalyst for Energy Storage Applications
April 17, 2023 (v1)
Subject: Materials
Keywords: electrocatalysis, energy storage application, Ge/h-BN/MoS2, hydrogen evolution reaction, layered heterostructure
Increasing concerns about the vulnerability of the world’s energy supply and the necessity to implement sustainable technologies have prompted researchers to develop high-performance electrocatalysts that are affordable and efficient for converting and storing renewable energy. This article reports a facile approach to fabricating two-dimensional (2D) Ge-decorated h-BN/MoS2 heterostructure nanosheets by self-assembly for multiple electrochemical applications such as supercapacitor and hydrogen evolution reactions. The organization of the physical and chemical links between the germanium modulations on the heterostructure of boron nitride/molybdenum sulphide (Ge/h-BN/MoS2) were facilitated to generate more active sites. Furthermore, the asymmetric supercapacitor of Ge-decorated h-BN/MoS2 amplified the capacitance to 558.53 F g−1 at 1 A g−1 current density and 159.19 F g−1 at 10 A g−1, in addition to a retention rate of 85.69% after 2000 cycles. Moreover, the Ge-decorated h-BN/MoS2 catal... [more]
943. LAPSE:2023.31017
Hydromechanical Impacts of CO2 Storage in Coal Seams of the Upper Silesian Coal Basin (Poland)
April 17, 2023 (v1)
Subject: Materials
Keywords: CO2 storage, coal swelling, environmental risk assessment, fault reactivation, horizontal well, hydromechanical simulation, regional stress regime
Deep un-mineable coal deposits are viable reservoirs for permanent and safe storage of carbon dioxide (CO2) due to their ability to adsorb large amounts of CO2 in the microporous coal structure. A reduced amount of CO2 released into the atmosphere contributes in turn to the mitigation of climate change. However, there are a number of geomechanical risks associated with the commercial-scale storage of CO2, such as potential fault or fracture reactivation, microseismic events, cap rock integrity or ground surface uplift. The present study assesses potential site-specific hydromechanical impacts for a coal deposit of the Upper Silesian Coal Basin by means of numerical simulations. For that purpose, a near-field model is developed to simulate the injection and migration of CO2, as well as the coal-CO2 interactions in the vicinity of horizontal wells along with the corresponding changes in permeability and stresses. The resulting effective stress changes are then integrated as boundary cond... [more]
944. LAPSE:2023.31011
Gas Hydrates Reserve Characterization Using Thermo-Hydro-Mechanical Numerical Simulation: A Case Study of Green Canyon 955, Gulf of Mexico
April 17, 2023 (v1)
Subject: Materials
Keywords: gas hydrate, Gulf of Mexico, thermo-hydro-mechanical modeling
The Gulf of Mexico is a widely explored and producing region for offshore oil and gas resources, with significant submarine methane hydrates. Estimates of hydrate saturation and distribution rely on drilling expeditions and seismic surveys that tend to provide either large-scale estimates or highly localized well data. In this study, hydrate reserve characterization is done using numerical simulation at Green Canyon block 955 (GC955). In addition, coupled thermo-hydro-mechanical (THM) simulation results show that hydrate saturation and geobody distribution are determined by the thermodynamic conditions as well as reservoir structures, stratigraphic differences, and permeability differences. Hydrate formation due to upflow of free gas and dissociation due to gas production and oceanic temperature rise due to climate change are simulated. The abundance of free gas under the hydrate stability zone and favorable pressure and temperature meant little hydrate was depleted from the reservoir.... [more]
945. LAPSE:2023.31004
The Underground Coal Gasification Process in Laboratory Conditions: An Experimental Study
April 17, 2023 (v1)
Subject: Materials
Keywords: efficiency, ex-situ reactor, experiment, material balance, Syngas, underground coal gasification
The underground coal gasification (UCG) process represents a modern and effective coal mining technology that enables coal energy extraction through thermic decomposition. The coal is transformed into syngas by oxidizers (e.g., air, technical oxygen, or water steam) and is injected into a georeactor. The produced syngas is exhausted on the surface, where it is transformed into the desired form of energy. This paper presents an experimental study of two experiments performed in ex-situ reactors. The paper describes the equipment for the UCG process, the physical models of the coal seam, and the analysis of coal. The obtained results from the experiments are presented as the behavior of the temperatures in the coal during the experiment, the syngas composition, and its calorific value. The material balance and effective gasification time of the UCG process were also identified for the individual experiments. The aim was to evaluate the impact of the coal seam model on the gasification pr... [more]
946. LAPSE:2023.31000
Modelling Electroluminescence Emission in Polymeric Material Using Dimensional Analysis Method
April 17, 2023 (v1)
Subject: Materials
Keywords: ageing, dimensional analysis, electroluminescence, insulation, Modelling
The Electroluminescence (EL) technique has garnered significant interest over time for its reliable outcomes that enrich our understanding of the onset of electrical degradation in polymeric material. There is growing interest in combining both the EL technique and space charge measurement methods to obtain a more profound knowledge of the degradation and ageing of insulation. The generation of charge carriers in polymeric materials is widely acknowledged to be a crucial aspect of EL, involving injection, de-trapping, and field dissociation processes. This research investigates the variables that influence how EL emissions behave, including applied voltage or electric field, applied electrical frequency, ageing of material, and selection of materials and gases employed. It was found that these factors can be helpful in predicting the process of electrical ageing in insulation to avoid any catastrophes that may occur. A mathematical approach relating these factors and the intensity of E... [more]
947. LAPSE:2023.30998
Microstructure of Surface Pollutants and Brush-Based Dry Cleaning of a Trough Concentrating Solar Power Station
April 17, 2023 (v1)
Subject: Materials
Keywords: brush-based dry cleaning, concentrating solar power station, deposition mode, microstructure, surface pollutants
The accumulation of pollutants on the surface of a Concentrating Solar Power (CSP) station reduces the power generation efficiency of the whole power plant, affects electricity output, and decreases sales income; therefore, it is particularly important to develop a reasonable and effective cleaning process. Surface pollutants which have a strong interaction with the cleaning process of power stations can determine the quality of cleaning to a certain extent. In this paper, the pollutants on the surface of a trough CSP station with different usage times were collected and characterized using a scanning electron microscope (SEM), a particle size analyzer (PSA), and a transmission electron microscope (TEM). It was found that most of the surface pollutants were of a fine size and included amorphous particles which mainly resulted from the sedimentation of particles suspended for a short time or particles in the process of atmospheric circulation for a long time. Considering the service lif... [more]
948. LAPSE:2023.30987
Thermomechanical and Thermofluid-Dynamic Coupled Analysis of the Top Cap Region of the Water-Cooled Lithium Lead Breeding Blanket for the EU DEMO Fusion Reactor
April 17, 2023 (v1)
Subject: Materials
Keywords: breeding blanket, coupled analysis, DEMO, thermofluid dynamics, thermomechanics, WCLL BB
In the EU, the Water-Cooled Lithium Lead (WCLL) Breeding Blanket (BB) concept is one of the candidates for the design of the DEMO reactor. From the past campaign of analysis emerged that the thermal-induced stress led to the failure in the verification of the RCC-MRx structural criteria. Hence, in this paper the classic conceptual design approach, based on a pure FEM thermal and structural analysis, is compared to a coupled thermofluid-dynamic/structural one. Even though the coupled approach requires tremendous modelling effort and computational burden, it surely allows determining the thermal field with a higher level of detail than the FEM analysis. Therefore, in this work, the focus is put on the impact of a more detailed thermal field on the DEMO WCLL BB global structural performances, focusing on the Top Cap region of its Central Outboard Blanket segment. The obtained results have allowed confirming the soundness of the design solution of the Top Cap region, except for concerns ar... [more]
949. LAPSE:2023.30967
Effect of Concrete Mix Composition on Greenhouse Gas Emissions over the Full Life Cycle of a Structure
April 17, 2023 (v1)
Subject: Materials
Keywords: carbon footprint, circular economy, decarbonization, demolition process, LCA of building materials
As the need to determine and monitor carbon footprints (CFs) in the construction industry grows and given that concrete is a key construction material in this sector, the authors of the article conducted a carbon footprint analysis of 15 different concrete mixtures. The method for determining the carbon footprint of the entire life cycle of concrete was presented in detail. The authors conducted a comparative analysis of the CF for an example structure made of three significantly different concrete strength classes, in addition to determining the CF for 1 m3 of concrete mix. This analysis showed the need to consider the entire structure and the emissivity associated with the consumption of reinforcing steel when selecting the most favorable solution in terms of greenhouse gas (GHG) emissions. The study revealed that the composition of the concrete mix, primarily the type and amount of cement, has the greatest influence on the carbon footprint. Furthermore, the location and geometry of... [more]
950. LAPSE:2023.30964
A Novel Accelerated Stress Test for a Representative Enhancement of Cathode Degradation in Direct Methanol Fuel Cells
April 17, 2023 (v1)
Subject: Materials
Keywords: accelerated stress test, degradation, direct methanol fuel cell, electrochemical active area loss, electrochemical impedance spectroscopy
Performance decay of direct methanol fuel cells hinders technology competitiveness. The cathode electrochemical surface area loss is known to be a major reason for performance loss and it is mainly affected by cathode potential and dynamics, locally influenced by water and methanol crossover. To mitigate such phenomenon, novel materials and components need to be developed and intensively tested in relevant operating conditions. Thus, the development of representative accelerated stress tests is crucial to reduce the necessary testing time to assess material stability. In the literature, the most diffused accelerated stress tests commonly enhance a specific degradation mechanism, each resulting in limited representativeness of the complex combination and interaction of mechanisms involved during real-life operation. This work proposes a novel accelerated stress test procedure permitting a quantifiable and predictable acceleration of cathode degradation, with the goal of being representa... [more]
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