In this study, an asymmetric supercapacitor (ASSC) device is assembled by the deposition and annealing of silver-doped mixed metal oxides on reduced graphene oxide (rGO)/Ni foam and activated carbon (AC) on Ni foam as positive and negative electrodes, respectively. The best performing Ag:MnCoNiO active material is synthesized on rGO/Ni foam using chronopotentiometry combined with heat treatment. The XRD study clearly confirms the crystalline nature of the electrode with MnCo2O4 and MnNi2O4 phases. FT-IR and XPS studies revealed the formation of Ag:MnCoNiO/rGO on Ni foam. SEM images show a thin-film layer of fabricated material on the surface of rGO/Ni foam. The supercapacitor properties were tested in two- and three-electrode configurations, with cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS) experiments in a 6 M KOH aqueous electrolyte. In the three-electrode configuration, reversible faradic reactions can be observed in... [more]

Gas hydrate blockage is a major issue that the production and transportation processes in the oil/gas industry faces. The formation of gas hydrates in pipelines results in significant financial losses and serious safety risks. To tackle the flow assurance issues caused by gas hydrate formation in the pipelines, some physical methods and chemical inhibitors are applied by the oil/gas industry. The physical techniques involve subjecting the gas hydrates to thermal heating and depressurization. The alternative method, on the other hand, relies on injecting chemical inhibitors into the pipelines, which affects gas hydrate formation. Chemical inhibitors are classified into high dosage hydrate inhibitors (thermodynamic hydrate inhibitors (THI)) and low dosage hydrate inhibitors (kinetic hydrate inhibitors (KHI) and anti-agglomerates (AAs)). Each chemical inhibitor affects the gas hydrate from a different perspective. The use of physical techniques (thermal heating and depressurization) to in... [more]

Drying is an extremely energy-intensive process. Superheated steam as a drying medium can improve the energy efficiency of the drying processes. In superheated steam drying, waste heat can be recovered by condensing the exhaust steam or raising its specific enthalpy. Spray drying is widely used in industry, even though its energy efficiency is often low. Substitution of air by superheated steam as a drying medium in a spray dryer may reduce the energy consumption of the drying process by 20−30%; moreover, if excess steam generated by moisture evaporation is upgraded to a higher temperature level and reused for drying, the energy demand could be decreased by even 80%. A literature review showed that superheated steam spray drying was successfully applied for both thermally resistant and a wide range of thermally sensitive materials. Superheated steam drying gives a number of advantages in terms of product properties, i.e., higher particle porosity due to rapid moisture evaporation resul... [more]

This work investigates the thermal−physical and rheological properties of hexagonal boron nitride/carbon nanotubes (hBN/CNTs) applied to reinforce water-based working fluid in a flat plate solar collector (FPSC). The hybrid nanoadditives of hBN and the chemically functionalized CNTs (CF-CNTs) were suspended in distilled water (DW) with a nonionic surfactant. The hybridization ratio between CF-CNTs and hBN was optimized to be 40:60. The thermal efficiency tests on the solar collector were carried out using different volumetric flow rates (2, 3, and 4 L/min) under the ASHRAE-93-2010 standard. The morphological characteristics of the hybrid nanoadditives were evaluated using X-ray diffraction (XRD), ultraviolet−visible spectroscopy (UV−vis), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Different concentrations of hBN/CF-CNTs were added to the water-based working fluid to record the optimal wt.% for maximum enhancement in the FPSC’s effic... [more]

Photovoltaic-thermal (PVT) technologies have demonstrated several attractive features, such as higher power and comparative efficiencies. Improving the thermal recovery from the PVT system would further improve the power output and the efficiency of the PVT system. This paper identifies the best operating factors of nanofluid-based PV thermal/nano-enhanced phase change material using artificial intelligence. The target is the maximization of thermal energy and exergy outputs. The suggested approach combines ANFIS modelling and particle swarm optimization (PSO). Four operating factors are taken into consideration: PCM (phase change material) layer thickness, HTF (heat transfer fluid) mass flow rate, MFNPCM (“mass fraction of nanoparticles in PCM”) and MFNfluid (“mass fraction of nanoparticles in nanofluid”). Using a dataset, an “adaptive neuro-fuzzy inference system” (ANFIS) model has been established for simulating the thermal energy and exergy outputs in terms of the mentioned operati... [more]

The combustible cartridge case has become an integral part of many modern weapons systems. The energetic and burning characteristics of the combustible case can have a significant impact on shot parameters. This paper describes Closed Vessel Tests (CVTs) performed on combustible cartridge case material and presents a method of determining the physical burning law and the linear burning rate of the tested material. The method was verified on the basis of the results of CVT of the felted combustible cartridge case material of a 120 mm tank round. It is shown that, in the case of porous combustible materials, the standard methods of determining the burning rate fail. The porosity of combustible materials greatly increases the burning surface and heat feedback from the burning zone to the unburned structure. These effects significantly increase the burning rate of porous materials. The results of analysis show the strong dependence of the burning rate on pressure. The results of this study... [more]

In recent years, research into autonomous vehicles (AVs) has become highly popular in industrialized nations due to their importance in the future success of smart cities. Research on this mobility technology and the critical elements affecting its development in developing countries, however, has been rather limited. This paper aims to shed light on the most influential elements of AV adoption in developing nations. A structural analysis approach is used, based on the primary qualitative data—that was gathered via an expert-opinion poll utilizing the fuzzy Delphi with a snowballing method and engaging 25 experts in the field in two rounds—, in accordance with the tradition of futurist research. The analysis has led to the identification of 11 key factors, from the initial factor pool of 54, affecting AV adoption in the case study context of Iran. The results of the analysis revealed the following conclusions, that fall under the policy and legislation domain, and present the most sign... [more]

Ferroelectric oxides possess abundant fascinating physical functionalities, such as electro-optic, acousto-optic, and nonlinear optical characteristics, etc. However, most pristine ferroelectric oxides exhibit no efficient luminescent properties due to the indirect and wide bandgap. Rare-earth-doped phosphors demonstrate advantages such as sharp emission bandwidths, large Stokes shift, high photonstability, and low toxicity. The combination of rare-earth ions and ferroelectric oxides has shown great potential in optical sensing, lighting, solar cells, and other applications. Rare-earth-doped ferroelectric oxides exhibit efficient upconversion or downconversion luminescence in the range of ultraviolet (UV) to near-infrared (NIR) regions. In this article, the preparation process of rare-earth-doped ferroelectric oxides and the preparation methods of thin films are introduced. Their recent applications in optical sensing, lighting, and solar cells are highlighted. The review concludes wit... [more]

This paper discusses a mathematical model for airflow through a cross-flow plate heat exchanger. The exhaust air is used to heat the supply air. Three kinds of plates are considered: made of aluminium, copper, and steel. The purpose of this research was to verify which material used to build the plate heat exchangers uses the exhaust air heat more efficiently. The method of the Trefftz function was used to determine approximate solutions to the analysed problem. The results obtained for 1.2 mm-thick plates and for external winter, summer, and spring−autumn temperatures are discussed. The results indicate that if the efficiency and price of the metals are considered, then steel is the best material for the plate heat exchanger. Thanks to the use of thin steel plates and the reduction in air exchange time to a few minutes, a cheap and efficient cross-flow heat exchanger can be obtained.

Energy from biomass is increasingly gaining attention amidst the environmental challenges of coal and fossil fuels. This study investigated the effects of inert gases (N2, CO2, and N2/CO2) on intermediate pyrolysis and product properties from Bambara Groundnut Shells (BGS) (shells from an underutilized crop, which has high nutritional values). N2/CO2 atmosphere roughly represents flue gas. The results showed that the inert gases did not significantly affect the yields of bio-oil, biochar, and syngas. The pH of bio-oil ranged from 5.2−5.8, indicating the minimum presence of acids in bio-oil. The CHNS analysis showed that all bio-oil and biochar had their carbon content within 50.04−60.49 wt.%. The FESEM resulted in a wide range of pore sizes in biochar produced in an N2/CO2 atmosphere. The GC-MS (Gas Chromatography-Mass Spectrometry) analysis revealed the presence of compounds which can be categorized as alkene, acid, benzene derivatives, ketone, phenol derivatives, alcohol, aldehyde, a... [more]

In the modern digital world, electronic devices are being widely employed for various applications where thermal performance represents a significant technical challenge due to continued miniaturization, high heat generated in the system, and non-uniform high-temperature causing failure. Phase change materials (PCMs) owing to the immense heat of fusion are primarily considered for thermal management, but their insulating properties hedge their applications in electronics cooling. Nano-enhanced phase change materials (NePCMs) have the ability to improve the thermal conductivity of PCM, decrease system temperature and escalate the operating time of devices. Accordingly, the current study focused on the experimental investigations for the thermal performance of three heat sinks (HS) with different configurations such as a simple heat sink (SHS), a square pin-fins heat sink (SpfHS), and Cu foam integrated heat sink (CufmHS) with various alumina nanoparticles mass concentrations (0.15, 0.20... [more]

As human activities are increasingly exploiting our planet’s scarce resources, managing them has become of primary importance. Specifically, this study examines the management of photovoltaic (PV) waste that is produced when PV modules reach end-of-life (EoL). PV modules contain precious and valuable materials, as well as toxic materials that may be harmful to human health and the environment if not disposed of properly. First, this study aims to review and analyze the current literature in order to gain a deeper understanding of the recycling of PV modules, particularly c-Si modules, which represent the largest market share. In the second part, an analysis is conducted of the energy consumption of these recycling processes using a proposed model based on the full recovery end-of-life photovoltaic (FRELP) process. PV modules manufactured from raw materials and PV modules manufactured from recycled materials are also compared in this section. In addition, improvements are suggested with... [more]

Existing research on the magnetic coupler of unmanned aerial vehicle (UAV) wireless charging systems usually ignores the UAV fuselage, but the fuselage causes eddy current loss and reduces a system’s efficiency. Therefore, aiming at the above problems, this paper proposes a design for a magnetic coupler using nanocrystalline cores to reduce the loss caused by the UAV fuselage. First, the parameters of the asymmetric circular coils were designed for higher mutual inductance. The losses caused by the windings and cores were also calculated. Second, for the loss effect of the carbon fiber fuselage, the fuselage was modeled as an additional coil coupled with both the transmitting and receiving coils. The fact that the eddy current induced by the fuselage leads to efficiency reduction is revealed, which has been generally ignored by previous research. Then, the effect of the nanocrystalline alloy was analyzed based on the magnetic circuit model. An optimized nanocrystalline alloy film was a... [more]

Nonlinear resistive field grading materials are widely used in the electrical and electronic applications, and are usually researched based on the initial nonlinear conductivity characteristics of synthetic materials. However, the long-term stability of these materials are rarely reported. In this paper, the effects of thermal ageing on nonlinear resistive field grading material and the electric field distribution of DC cone spacers are studied. The 30 wt.% SiC/epoxy micro-composites are prepared and are thermally aged at 180 °C for 1080 h. The infrared spectroscopy, dielectric properties, breakdown strength and nonlinear conductivity are measured, respectively. In addition, a simulation model for a cone spacer is built, and the electric field and power dissipation density are calculated. With the increasing thermal ageing time, the relative permittivity and loss tangent increase, and the breakdown strength decreases. Besides, the nonlinear coefficient of nonlinear conductivity almost... [more]

Supercritical carbon dioxide (SC-CO2) is suitable to extract low-polar organics and to assist in the dissolution of pores and fractures in shale. In this work, we investigate the effect of temperature on the structure of five shale samples via high pressure reaction assisted with SC-CO2. Shale samples were analyzed using X-ray diffraction, field emission scanning electron microscopy, and ImageJ software. Due to the extraction of CO2, after Sc-CO2 treatment, carbonate and clay content decreased, while quartz and plagioclase increased slightly, which improved gas and oil flow in microscopic pores and shale cracks. Shale samples showed an increase in surface fracture area as experimental temperature increased. Since Sc-CO2 fluid density and solubility increase with temperature, more organics can be extracted from shale pores and fractures, resulting in newly formed pores and fractures. As a result, the threshold temperature for shale high-temperature Sc-CO2 cracking was confirmed to be 40... [more]

The present study is focused on improving the technology for deep oil sludge processing by pyrolysis methods, considered to be the most promising technology for their environmentally friendly utilization, in which a significant yield of fuel products is expected. The technology developed by the authors of this study is a two-stage process. The first stage, pyrolysis of oil sludge, was investigated in previous papers. A significant yield of non-condensable gases was obtained. This paper presents a study of the second stage of complex deep processing technology—pyrolysis of non-condensable gases (purified propane) using a stirrer with the help of the developed experimental setup. The expected benefit of using the stirrer is improved heat transfer due to circumferential and radial-axial circulation of the gas flow. The effect of a stirrer on the yield of final target decomposition products—H2-containing mixtures and H2 generated during non-catalytic (medium-temperature) and catalytic pyro... [more]

Polyethylene has widely been used in radiative cooling applications because of high transmittance values in the atmospheric window. However, it presents optical and mechanical degradation when exposed to environmental conditions and must be replaced every few months. This paper aims to find an alternative to polyethylene to be used in a unique device, the Radiative Collector and Emitter (RCE), that combines solar collection and night-time radiative cooling. The aging evolution analysis of five cheap and market available plastic films (two low density polyethylene, one high density polyethylene, one polypropylene, and one fluorinated ethylene propylene) exposed to environmental conditions was performed. FT-IR spectra and mechanical traction tests were performed before and after 90 days of exposure to the environment. Results confirm that polyethylene undergoes a degradation process both when it is covered by a glass and when it is uncovered. However, it maintains high average transmitta... [more]

Owing to the shortage of rare-earth magnetic materials, various methods are being examined to reduce the use of magnets. One of these is a consequent pole. The consequent pole model can reduce the use of magnets by 50% using only one pole of the magnet and replacing the other pole with iron. However, the consequent pole has the disadvantage of generating back EMF asymmetry and a high cogging torque. In this study, an intersect magnet consequent pole structure is proposed to overcome the disadvantages of the existing consequent pole. Two methods have been proposed to improve axial leakage magnetic flux caused by the intersect magnet consequent pole structure. Finally, we propose a method to reduce the cogging torque and minimize the use of magnets with the same performance standard. For motor design, two-dimensional and three-dimensional finite element analysis was used, and comparative analysis was performed via simulations for several models. The existing model and the final model wer... [more]

The fracture network of a deep geothermal reservoir forms the place for heat exchange between injected fluid and rock mass with high temperature. The fracture resistance ability of reservoir rocks will affect the formation of fracture-network structure, heat exchange and transmission characteristics, and reservoir mechanical stability. However, there are few reports on the fracture toughness and trajectory prediction of geothermal reservoirs with different depths. In this paper, the modified maximum tangential stress criterion (MMTS) is analyzed. The results show that the experimental data are significantly different from the theoretical estimate of MMTS under the influence of different occurrence depths. It is found that the fracture process zone (FPZ) seriously affects the accuracy of predicting fracture initiation angle and mixed-mode (I+II) fracture toughness by MMTS. The FPZ value, considering the influence of different occurrence depths, is modified, and the accuracy of MMTS in p... [more]

This paper investigates the characteristics of generic dielectric materials and char, which are intended to be used as the fixed bed materials of a non-thermal-plasma (NTP)-based dielectric barrier discharge (DBD) reactor. Such data are very essential when upgrading the fixed bed to a fluidised bed, which may provide further improvement in the production and quality of the producer gas. This measure would eventually cause a better producer gas and effective biomass-based power generation. Pertinent data that are currently available focus on either improving the design requirements of the producer gas or studying the impact of individual dielectric-material-specific applications to produce useful gases by decomposing the polluting gases. Considering that there has only been a meagre attempt to gather this information, this study gains its importance. In this context, the collective electrical behaviour of bed materials viz. quartz-sand, olivine, and char under ambient and higher tempera... [more]

The booming electric vehicle industry continues to place higher requirements on power batteries related to economic-cost, power density and safety. The positive electrode materials play an important role in the energy storage performance of the battery. The nickel-rich NCM (LiNiCoMnO2 with x + y + z = 1) materials have received increasing attention due to their high energy density, which can satisfy the demand of commercial-grade power batteries. Prominently, single-crystal nickel-rich electrodes with s unique micron-scale single-crystal structure possess excellent electrochemical and mechanical performance, even when tested at high rates, high cut-off voltages and high temperatures. In this review, we outline in brief the characteristics, problems faced and countermeasures of nickel-rich NCM materials. Then the distinguishing features and main synthesis methods of single-crystal nickel-rich NCM materials are summarized. Some existing issues and modification methods are also discussed... [more]

This study investigates the change in internal stresses of ion nitrided and Cr−CrC ion-plasma-coated 20Kh13 steel samples during the incubation period of the droplet impact erosion. To obtain internal stress values, a method based on measuring the deformation (curvature) of the sample along the surface profiles before and after its modification/coating, as well as during the subsequent droplet impact has been applied. The results suggest that the initial droplet impact on the uncoated, nitrided and coated material leads to a sharp increase in the initial internal stress values. The rate of increase in internal stress decreases with the surface damage development and accumulation. The proposed method of stress evaluation can be used in selecting a criterion for comparing the erosion resistance of a material and a method for modifying its surface.

The mechanical properties of materials deteriorate when hydrogen embrittlement (HE) occurs, seriously threatening the reliability and durability of the hydrogen system. Therefore, it is important to summarize the status and development trends of research on HE. This study reviewed 6676 publications concerned with HE from 1997 to 2022 based on the Web of Science Core Collection. VOSviewer was used to conduct the bibliometric analysis and produce visualizations of the publications. The results showed that the number of publications on HE increased after 2007, especially between 2017 and 2019. Japan was the country with the highest numbers of productive authors and citations of publications, and the total number of citations of Japanese publications was 24,589. Kyushu University was the most influential university, and the total number of citations of Kyushu University publications was 7999. Akiyama was the most prolific and influential author, publishing 88 publications with a total of 2... [more]

We propose a complex sealing compound for increasing the efficiency of shutoff operations based on natural materials processing for materials such as sand, peat, rice, and husks. We studied the influence of mechanical activation processes on the mechanical and rheological properties of the developed sealants. Through mechanochemical activation, sand dissolution in a low-concentrated alkali solution was possible, and gelling the resulting sodium silicate while reinforcing it with undissolved sand particles to obtain a sealant composition. We used this approach to produce a hybrid sealing compound based on activated rice husks with up to 20% biogenic silicon dioxide combined with mechanically activated peat: the maximum shear strain of the hybrid sealant was 27.7 ± 1.7 Pa. We produced hydrogels based on sodium silicate, polyacrylamide, and chromium acetate, reinforced with mechanically activated rice husks. We studied the sealants’ rheological and filtration properties and observed the r... [more]

The characteristics of hydrothermal carbonization hydrochar derived from cattle manure including excrements and lignocellulosic biomass were analyzed. The effects of hydrothermal carbonization were evaluated by varying the reaction temperatures in the range of 180~240 °C. The hydrochars were evaluated with respect to their usefulness as renewable fuels via physicochemical analysis and pyrolysis processes. As reaction temperatures increased, the fractions of fixed carbon in proximate analyses, carbon elements in ultimate analyses, and higher heating values of hydrothermally carbonized biochars increased in correlation with the primary reactions of coalification. Various correlations were derived with the characteristics of hydrochars in order to be utilized for operating and designing HTC reactors for cattle manure. The correlation between the O/C and H/C ratios was deduced on the basis of a van Krevelen diagram. The interaction equation was represented with the increased fraction of HH... [more]