The use of photocatalysis and photoelectrocatalysis is expected to achieve the efficient utilization of solar energy to alleviate and even solve the problems of energy depletion and environmental pfollution. At present, stannous tungstate materials have attracted extensive attention in the fields of photocatalysis and photoelectrocatalysis as favorable candidates for such utilization because of their narrow band gap energy (which is ~1.7 eV for the α phase and ~2.7 eV for the β phase, respectively) and unique band structure (which covers the oxidation and reduction potential of water). However, their practical application is still limited by excessive electron−hole recombination and poor stability. In this review, basic information (crystal and electronic structures) related to photocatalysis and photoelectrocatalysis is presented. Additionally, various strategies to enhance the photocatalytic and photoelectrochemical properties of stannous tungstate materials, such as morphological mo... [more]

Solar cookers can greatly reduce the overall carbon footprint of the cooking done in India. In the present work a funnel-type solar cooker is designed using cardboard. After making the solar cooker it is then analyzed on the various performance metrics namely the figures of merit, efficiency value and Cooker Opto−thermal Ratio (COR) which are dependent parameters. Paraffin wax which is a phase change material (PCM) is also incorporated in the testing process to evaluate the overall improvement in the thermal efficiency of the solar cooker. The time taken to break is also calculated. The experimental results show that the solar cooker is capable of reaching a temperature of 125 °C. From the results it can also be seen that using paraffin wax also offers significant improvement in the overall thermal efficiency. The results are tested on various parts of India considering the major cities such as Chennai, Trivandrum, Kanpur and Delhi with the ANN model, which is a deep learning model. Th... [more]

Power electronic systems have a great impact on modern society. Their applications target a more sustainable future by minimizing the negative impacts of industrialization on the environment, such as global warming effects and greenhouse gas emission. Power devices based on wide band gap (WBG) material have the potential to deliver a paradigm shift in regard to energy efficiency and working with respect to the devices based on mature silicon (Si). Gallium nitride (GaN) and silicon carbide (SiC) have been treated as one of the most promising WBG materials that allow the performance limits of matured Si switching devices to be significantly exceeded. WBG-based power devices enable fast switching with lower power losses at higher switching frequency and hence, allow the development of high power density and high efficiency power converters. This paper reviews popular SiC and GaN power devices, discusses the associated merits and challenges, and finally their applications in power electron... [more]

Nowadays, lithium-ion batteries are one of the most widespread energy storage systems, being extensively employed in a large variety of applications. A significant effort has been made to develop advanced materials and manufacturing processes with the aim of increasing batteries performance and preserving nominal properties with cycling. Nevertheless, mechanical degradation is still a significant damaging mechanism and the main cause of capacity fade and power loss. Lithium ions are inserted and extracted into the lattice structure of active materials during battery operation, causing the deformation of the crystalline lattice itself. Strain mismatches within the different areas of the active material caused by the inhomogeneous lithium-ions concentration induce mechanical stresses, leading ultimately to fracture, fatigue issues, and performance decay. Therefore, a deep understanding of the fracture mechanics in active materials is needed to meet the rapidly growing demand for next-gen... [more]

While Malaysia produces about half of the world’s palm oil and is the largest producer and exporter worldwide, oil palm industries generate large amounts of lignocellulosic biomass waste as a sub-product with no economic market value other than feedstock for energy valorisation. With the aim to increase the sustainability of the sector, in this work we prepare new materials for CO2 capture from palm oil residues (empty fruit bunches and kernels). The biochar is obtained through the carbonisation of the residues and is physically and chemically activated to produce porous materials. The resulting microporous samples have similar properties to other commercial activated carbons, with BET surfaces in the 320−880 m2/g range and pore volumes of 0.1−0.3 cm3·g−1. The CO2 uptake at room temperature for physically activated biochar (AC) was 2.4−3.6 mmolCO2/gAC, whereas the average CO2 uptake for chemically activated biochar was 3.36−3.80 mmolCO2/gAC. The amount of CO2 adsorbed decreased at the... [more]

A seven-rod solar laser head was conceptualized and numerically studied to improve the tracking error compensation capacity and power stability in end-side-pumping schemes. It was composed of a first-stage heliostat−parabolic mirror system, a second-stage fused silica aspheric lens and a third-stage conical pumping cavity, within which seven Nd:YAG rods were mounted. Highly stable solar laser emission, with a power loss inferior to 5% for tracking errors up to ±0.4°, could potentially be enabled with seven 4 mm diameter, 13 mm length rods. The tracking error width at 10% laser power loss was about 1.0°, which is 1.65 times higher than the experimental record, attained by a dual-rod side-pumping prototype. Furthermore, a total multimode laser power of about 41.2 W could also be achieved, corresponding to 23.3 W/m2 collection and 2.5% solar-to-laser power conversion efficiencies, which are 1.65 and 1.36 times higher than those obtained with the dual-rod side-pumping prototype. They are a... [more]

Investigation of shocked materials provides unique information about behavior of substances in extreme thermodynamic conditions. Near surface nuclear tests have induced multiple transformations of affected soils. Examination of nuclear glasses and relics of entrapped minerals provides a unique database on their behavior under an intense temperature flash. In this work, several types of nuclear fallout particles from historic tests at the Semipalatinsk test site are investigated using complementary analytical methods. Distribution of radionuclides in all types of samples is highly heterogeneous; domains with high content of radionuclides are often intermixed with non-active materials. There is no general correlation between chemical composition of the glassy matrix and content of radionuclides. In aerodynamic fallout, the main fraction of radionuclides is trapped in the outer glassy shell. Relics of quartz grains are always devoid of radionuclides, while glass regions of high activity h... [more]

Lithium batteries in the electric vehicles (EVs) reveal that the operating temperature and temperature uniformity within the battery pack significantly affect its performance. An efficient thermal management system is urgently needed to protect the battery module within suitable temperature range. In this study, the composite silica gel (CSG), coupled with cross-structure mini-channel cold plate (MCP) as the cooling system, has been proposed and applied in a battery module, which can provide a reliable method of controlling battery temperature with low energy consumption. The experimental and simulation results reveal that a composite silica gel-based liquid system can control the temperature below 45 °C and maintain the temperature difference within 2 °C at a 3C discharge rate. Besides, the CSG, coupled with the structure of reciprocal chiasma channels for the battery module, presents an optimum temperature-controlling performance among various cooling structures during the charge and... [more]

A commercial three-layer particleboard served as model furniture for testing pretreatment with the oyster mushroom (Pleurotus ostreatus (Jacq.) P. Kumm.) over 9-, 12-, 16-, and 20-week periods based on the effects of reducing the enzymatic resistance of component cellulose. The effects of pretreatment were assessed based on Fourier-transform infrared spectroscopy (FTIR) of the treated particleboards, wherein indexes (peaks and peak ratios) connected with parameters influencing enzymatic cellulose hydrolysis were analysed. The data were analysed in two ways: the measurement of peak heights in both primary spectra and deconvoluted spectra. The peak heights for the determination of the total crystallinity index (TCI) were measured according to narrow and broad baselines. Time and how indexes are calculated were found to be the main factors significantly influencing the values of indexes of pretreatment in most cases. Until week 9, P. ostreatus pretreatment seems to be advantageous for bio... [more]

This paper presents an experimental study on a single tank thermal energy storage (TES) system integrated with a cooking unit. The tank had a capacity of 45 L of oil. The cooking chamber was embedded in the storage tank, thereby eliminating the use of pumps and connecting pipes between the cooking unit and the storage unit. The system was designed to make good physical contact, circumferential and basally, with the cooking pot, to improve the rate of heat transfer. Experimental tests were performed with oil only and oil−rock pebbles as sensible heat storage materials. The charging unit was connected to the TES unit in such a way that it allowed circulation of oil between them during charging, using the thermosiphon principle. An electric heater rated at 800 W 240 V was inserted into the charging unit to charge the system. The thermal performance of the TES systems was evaluated in terms of the charging temperature, heat retention capacity, energy stored and cooking efficiency, and the... [more]

Using hydrogen energy as an alternative renewable source of fuel is no longer an unrealized dream, it now has real-world application. The influence of nanomaterials on various aspects of hydrogen energy, such as hydrogen production, storage, and safety, is considerable. In this review, we present a brief overview of the nanomaterials that have been used as photocatalysts during hydrogen production. The use of nanomaterials and nanomaterial composites for hydrogen storage is also reviewed. The specific use of graphene and its associated nanocomposites, as well as the milestones reached through its application are elaborated. The need to widen the applicability of graphene and its allied forms for hydrogen energy applications is stressed in the future perspectives. Hydrogen energy is our future hope as an alternative renewable fuel, and graphene has the potential to become the future of hydrogen energy generation.

This review deals with the simulation and optimization of the dry- and wet-torrefaction processes of lignocellulosic biomass. The torrefaction pretreatment regards the production of enhanced biofuels and other materials. Dry torrefaction is a mild pyrolytic treatment method under an oxidative or non-oxidative atmosphere and can improve lignocellulosic biomass solid residue heating properties by reducing its oxygen content. Wet torrefaction usually uses pure water in an autoclave and is also known as hydrothermal carbonization, hydrothermal torrefaction, hot water extraction, autohydrolysis, hydrothermolysis, hot compressed water treatment, water hydrolysis, aqueous fractionation, aqueous liquefaction or solvolysis/aquasolv, or pressure cooking. In the case of treatment with acid aquatic solutions, wet torrefaction is called acid-catalyzed wet torrefaction. Wet torrefaction produces fermentable monosaccharides and oligosaccharides as well as solid residue with enhanced higher heating va... [more]

Fly ash generated in the process of combustion of municipal waste is classified as hazardous waste. Its management today has become a significant problem. One of the methods of safe management of such ash may be using it for the production of concrete as a partial replacement for cement. Using immobilization, the number of hazardous compounds could be limited so that the obtained new material would be safe for the natural environment. Recovery of byproducts—in this case, fly ash—complies with the business models applied in the production cycle in the circular economy model. Such a solution may result in saving energy, limiting CO2 emissions, reducing the use of natural resources, and management of dangerous waste. It should be added that concretes with the addition of hazardous waste would be used for industrial purposes according to the binding legal regulations. This article presents the influence of the addition of fly ash on the selected mechanical properties of concrete. Fly ash f... [more]

Soft actuators have received extensive attention in robotics and smart device applications due to their distinctive dexterity and compliance. Among them, hydraulic soft actuators play an important role in the area because they have much higher specific power and power density than other types such as pneumatic soft actuators. Nevertheless, the deformation of flexible materials in soft actuators brings about inherent hysteresis and nonlinearity, which severely hinders them from producing the desired movement in the presence of advanced control strategies. In this paper, previous research efforts made to enhance the driving capability and actuation efficiency of hydraulic soft actuators are illustrated and analyzed from the three aspects of architecture, materials, and control strategy. Meanwhile, the issues and challenges that have emerged when developing hydraulic soft actuators are discussed. Finally, the potential future development of hydraulic powered soft actuators is discussed.

The development of low-cost electrode materials with enhanced activity and favorable durability for hydrogen evolution reactions (HERs) is a great challenge. MoS2 is an effective electrocatalyst with a unique layered structure. In addition, aluminosilica shells can not only provide more hydroxyl groups but also improve the durability of the catalyst as a protective shell. Herein, we have designed a hard-template route to synthesize porous yolk−shell MoS2@void@Aluminosilica microspheres in a NaAlO2 solution. The alkaline solution can directly etch silica (SiO2) hard templates on the surface of MoS2 microspheres and form a porous aluminosilica outer shell. The electrocatalytic results confirm that the MoS2@void@Aluminosilica microspheres exhibit higher electrocatalytic activity for HERs with lower overpotential (104 mV at the current density of −10 mA cm−2) and greater stability than MoS2 microspheres. The superior electrocatalytic activity of MoS2@void@Aluminosilica microspheres is attr... [more]

A contemporary challenge for the construction industry is to develop a technology based on natural building materials which at the same time provides high energy efficiency. This paper presents the results of an airtightness test and a thermal imaging study of a detached house built with technology using cross laminated dowelled timber panels. The thermal conductivity coefficients of the wood wool used to insulate the walls and ceiling of the building have also been measured, the linear heat transfer coefficients of the structural nodes have been numerically determined, and calculations have been made regarding the energy efficiency of the building. On the basis of the research, it was found that the air exchange rate in the analyzed building n50 is at the level of 4.77 h−1. Air leaks were also observed in the places of connection of longitudinal walls with the roof and at the junction of window frames with external walls. The experimentally determined thermal conductivity coefficient... [more]

Polyoxometalates (POMs) are polyatomic ions with closed three-dimensional frameworks. Their unique structure contains a large number of redox active sites, making them promising electrocatalysts for electrochemical energy conversion and storage applications. Thus, this paper presents an overview of the use of POMs as electrocatalysts for electrochemical energy conversion and storage devices, such as batteries, supercapacitors, fuel cells, or water electrolyzers. A discussion of the viability of these materials as alternatives to noble metal-based electrocatalysts is made. The current status of these materials to respond to the challenges of converting modern energy systems into more sustainable ones is also envisaged.

The obtainment of spectral radiation characteristics of semitransparent materials mainly includes the use of a theoretical method or experimental method. As the experimental method can better characterize the real radiation transmission results inside the material, it is generally considered more reliable and used as the basis for the verification of theoretical results. In this paper, the absorbing and scattering semitransparent materials are taken as the analysis object to illustrate the research status and future development direction in the field of measurement and identification of spectral radiation characteristics. According to the physical quantities measured and the temperature range, research status is discussed for the spectral radiation characteristic measurements of absorbing and scattering semitransparent materials, which specifically involves the measurement principle, measuring system, measuring physical quantity, identification model and application range. This researc... [more]

The combination of porous material with nonthermal plasma (NTP) technology to reduce the amount of particulate matter emitted from a direct-injection compression-ignition engine was investigated in this study. The investigation aimed at regulating particulate matter under long-term operation. A porous materials filter thickness of 4 mm was installed in the NTP reactor. The common rail diesel engine was fueled with 7%-vol biodiesel fuel (B7), and the experiment was carried out at steady-state conditions at 2000 rpm and indicated mean effective pressure (IMEP) of 6 bar. The effects of NTP high-voltage discharge (e.g., 2, 4, 5, 6, 8, and 10 kV) and the porous filter thickness (e.g., 0, 2, 4, and 6 mm) on particle number size distributions were examined. The protype of combine porous filter and NTP illustrated good particulate removal (>70%) operated with a thickness of 4 mm of porous materials filter and a high voltage of 6 kV under the same power rating.

Evacuated tube solar water heaters are gaining more attention in the present market scenario as compared to conventional collectors. Such collectors are versatile because no solar tracking is required and the operating temperature range is also broad. Comparatively, it is cost-effective and may attain higher thermal efficiency. However, like other collectors, continuous energy supply is sometimes hampered by the intermittent nature of solar radiation. This problem can be partially resolved by using phase change materials (PCM) in the evacuated tube solar collector (ETC). PCMs can store the energy during the sunshine hours, which can be released when solar energy is not available. In the literature, several studies are available pertaining to the use of PCMs in ETC-based solar water heaters. The literature indicates that the integration of PCMs with ETCs has several merits. Nevertheless, systematic, and comprehensive review papers dedicated to such integrated energy storage systems with... [more]

The present review mainly discusses advanced pretreatment techniques for converting lignocellulosic biomass into hydrogen. The focus of this review is also to acquire knowledge concerning lignocellulosic biomass pretreatment processes and their impact on the efficiency of biohydrogen fermentation. The deconstruction of lignocellulosic biomass is presented using various pretreatment techniques albeit with several advantages and disadvantages, particularly about the interference due to the generated inhibitory compounds is toxic to microbes used for fermentation. The use of an appropriate pretreatment process can make the recalcitrant lignocellulosic biomass substrates amenable for further microbial fermentation to produce hydrogen. Although till date there is no ideal pretreatment step available to develop a cost-effective process for conversion of lignocellulosic materials into fermentable sugars, nanotechnology seem to be a more sustainable approach as compared to the traditional proc... [more]

This article presents a simple and low-cost green synthesized single-layer NiO selective solar absorber nanocoating prepared by spin coating on a Cu substrate at different rotational speeds (RS). The effects of substrate RS on the structural, morphological, chemical, and optical properties of the NiO nanocoatings were thoroughly investigated. The XRD results reveal the formation of pure diffraction peaks indexed to face-centered cubic NiO nanocoatings. SEM confirmed the uniform distribution of the NiO thin films with a nanosphere-like structure and the influence of RS variation on the formation of NiO nanostructures. EDS and XPS confirmed the presence of Ni and O in the green synthesized NiO coatings. AFM showed homogeneous nanopillar-like NiO thin films with the average surface roughness decreasing from 13.6 to 9.06 nm as the RS increased from 700 to 1300 RPM. Raman spectroscopy of the nanocoatings showed normal modes related to longitudinal optical and transverse optical phonons, and... [more]

For wellbore stability issues induced by drilling operations in natural gas hydrate-containing reservoirs, wellbore stability research will focus on the mechanical properties of hydrate reservoirs. According to the content of the research, the response relationship between the hydrate core and the base physical property changes under different engineering parameters is established, and the law of hydrate mechanical property changes with temperature and pressure is studied for various physical properties. According to theoretical research and experimental data, it has been determined that: hydrate core-resolved gas and transverse and longitudinal wave velocity have a positive correlation with saturation and pressure and a negative correlation with temperature; a negative correlation exists between resistivity and saturation. The hydrate core stiffness strength correlates positively with saturation and adversely with temperature. Under the identical strain conditions, when saturation, po... [more]

The existing recycling methods of PHA-based material are ineffective in terms of increasing resource efficiency and the production of high value end-of-life products. Therefore, in this study, a novel approach of acidogenic fermentation was proposed to recycle PHB-based composites reinforced with natural fibers such as cellulose, chitin, chitosan, orange waste, sawdust, soy protein, and starch. The inclusion of cellulose, chitosan, and sawdust improved the impact properties of the composites while other fillers had various effects on the mechanical properties. These three composites and neat PHB were subsequently subjected to biological degradation via acidogenic digestion to determine the possibility of converting PHB-based composites into volatile fatty acids (VFAs). Two different pH levels of 6 and 10 were applied to assess the effect of pH on the bioconversion and inhibition of the methanogenesis. The results showed promising PHB degradation, contributing to considerable VFA produc... [more]

With the rapid development of power electronic techniques and the increasing cost of permanent magnets (PMs) materials, switched reluctance motors (SRMs) have recently gained more attention. However, traditional SRMs have a relatively low torque density. For the sake of increasing the motor torque density, this paper proposes a novel segmental rotor type SRM. The proposed motor adopts hybrid stator poles and concentrated windings in the stator side and a segmental rotor structure in the rotor side, which is completely different from the structures of the traditional SRM. The special structure of the motor shortens the magnetic flux paths of the motor, separates the parts of the magnetic flux paths from one another, and eradicates the magnetic flux reversal in the motor stator in order to improve the electric utilization and output torque density of the motor. Meanwhile, the requirement of the magneto-motive force and the core loss of the motor is also decreased, thereby improving the e... [more]