The determination of chemical composition of lignocellulose biomass by wet chemistry analysis is labor-intensive, expensive, and time consuming. Near infrared (NIR) spectroscopy coupled with multivariate calibration offers a rapid and no-destructive alternative method. The objective of this work is to develop a NIR calibration model for olive tree lignocellulosic biomass as a rapid tool and alternative method for chemical characterization of olive tree pruning over current wet methods. In this study, 79 milled olive tree pruning samples were analyzed for extractives, lignin, cellulose, hemicellulose, and ash content. These samples were scanned by reflectance diffuse near infrared techniques and a predictive model based on partial least squares (PLS) multivariate calibration method was developed. Five parameters were calibrated: Lignin, cellulose, hemicellulose, ash, and extractives. NIR models obtained were able to predict main components composition with R2cv values over 0.5, except f... [more]

Reduced graphene oxide (rGO)/Bi2Te3 nanocomposite powders with different contents of rGO have been synthesized by a one-step in-situ reductive method. Then, rGO/Bi2Te3 nanocomposite bulk materials were fabricated by a hot-pressing process. The effect of rGO contents on the composition, microstructure, TE properties, and carrier transportation of the nanocomposite bulk materials has been investigated. All the composite bulk materials show negative Seebeck coefficient, indicating n-type conduction. The electrical conductivity for all the rGO/Bi2Te3 nanocomposite bulk materials decreased with increasing measurement temperature from 25 °C to 300 °C, while the absolute value of Seebeck coefficient first increased and then decreased. As a result, the power factor of the bulk materials first increased and then decreased, and a power factor of 1340 μWm−1K−2 was achieved for the nanocomposite bulk materials with 0.25 wt% rGO at 150 °C.

It is necessary for polymeric materials to have superior tracking resistance against various stress conditions for outdoor applications. In this study, the effect of nano-sized alumina tri-hydrate (ATH) particles on the tracking resistance of silicone rubber (SiR) is studied. Specimens with filler loadings of 1, 3, 5, 10, and 20 wt % are used for performance characterization. From the inclined plane test (IPT) results, apparent improvement in tracking resistance was achieved by mixing 3 wt % of nano-sized fillers, compared to unfilled specimens. ATH/SiR nanocomposites with 5 wt % loading showed comparable tracking performance to SiO2/SiR microcomposites with 20 wt % loading. For detailed analysis, measurements of surface contact angle (SCA) and surface leakage current, and thermo-gravimetric analysis (TGA) were performed. As the nano-ATH filler concentration increased, both thermal stability and leakage current characteristics were improved. Such results agreed with the tracking resist... [more]

The characteristics of the envelope of a building determine, together with other factors, its consumption of energy. Additionally, the climate zone and insulation material may vary the minimum insulation thickness of walls and roofs, making it different, according to cooling down or warming up the home. Spanish legislation establishes different maximum values for energy demand according to different climate area both for heating and for cooling. This paper presents the results of a study that determines the influence of many variables as the climate zone or the orientation, among others, in the optimization of thickness insulation in residential homes in Spain to reduce the CO2 emissions embodied. To do that, 12 representative cities in Spain corresponding to different climate zones, four orientations, two constructive solutions, and four different configurations of the same house have been combined, for three different hypotheses and four insulation materials, resulting in 4608 cases... [more]

The design of new electrode materials for solid oxide electrochemical cells, which are stable against redox processes as well as exhibiting carbon/sulphur tolerance and high electronic conductivity, is a matter of considerable current interest as a means of overcoming the disadvantages of traditional Ni-containing cermets. In the present work, composite materials having the general formula (1−x)Sr2Mg0.25Ni0.75MoO6−δ + xNiO (where x = 0, 15, 30, 50, 70 and 85 mol.%) were successfully prepared to be utilised in solid oxide fuel cells. A detailed investigation of the thermal, electrical, and microstructural properties of these composites, along with their phase stability in oxidising and reducing atmospheres, was carried out. While possessing low thermal expansion coefficient (TEC) values, the composites having low Ni content (15 mol.%−70 mol.%) did not satisfy the requirement of high electronic conductivity. Conversely, the 15Sr2Mg0.25Ni0.75MoO6−δ + 85NiO samples demonstrated very high e... [more]

The analysis of in-cylinder combustion temperatures using flame image processing technology is reliable. This method can accurately, intuitively, and in real time obtain the temperature field distribution law of the combustion flame in the cylinder, so we can more deeply understand the characteristics of the combustion process of internal combustion engines. In this paper, a high-speed charge-coupled device (CCD) camera is used to record an in-cylinder combustion image, which is calculated and corrected according to the principle of three primary color temperature measurement, and the temperature field distribution of the combustion flame in the diesel engine cylinder is analyzed in detail. In addition, the temperature of the typical combustion flame images under the open-cycle and closed cycle conditions is compared by the CMS2002 measurement and MATLAB program, respectively. The results show that the accuracy of the MATLAB program is acceptable in general but not entirely acceptable... [more]

As a treatment method of sewage sludge, the hydrothermal carbonization (HTC) process was adopted in this work. HTC has a great advantage considering the economic efficiency of its process operation due to its reduced energy consumption and production of solid fuel upgraded through the increased fixed carbon and heating value. The ash of sewage sludge, however, contains up to 52.55% phosphate, which degrades the efficiency of the thermochemical conversion process such as pyrolysis, combustion, and gasification by causing slagging. In this study, three kinds of organic acids, i.e., oxalic, tartaric, and citric acid, were selected to eliminate phosphorus from hydrochars produced through the HTC of sewage sludge. The efficiency of the phosphorus removal and the properties of the corresponding HTC hydrochars were analyzed by adding 20 mmoles of organic acids per 1 g of phosphorus in the HTC sample. In addition, the phosphorus reduction effect and the applicability to an upgrading process we... [more]

This paper uses an acoustic emission (AE) test to examine the energy dissipation and liberation of coal and rock fracture due to underground coal excavation. Many dynamic failure events are frequently observed due to underground coal excavation. To establish the quantitative relationship between the dissipated energy and AE energy parameters, the coal and rock fracturing characteristics were clearly observed. A testing method to analyze the stage traits and energy release mechanism from damage to fracture of the unloading coal and rock under uniaxial compressive loading is presented. The research results showed that the relevant mechanical parameter discreteness was too large because the internal structures of the coal and rock were divided into multiple structural units (MSU) by a few main cracks. The AE test was categorized into four stages based on both the axial stress and AE event parameters: initial loading stage, elastic stage, micro-fracturing stage, and post-peak fracturing st... [more]

Biodiesel production has considerably increased in recent decades, generating a surplus of crude glycerol, which is the main drawback for the economy of the process. To overcome this, many scientists have directed their efforts to transform glycerol, which has great potential as a platform molecule, into value-added products. A promising option is the preparation of oxygenate additives for fuel, in particular those obtained by the etherification reaction of glycerol with alcohols or olefins, mainly using heterogeneous catalysis. This review collects up-to-date research findings in the etherification of glycerol, either with isobutene (IB) or tert-Butyl alcohol (TBA), highlighting the best catalytic performances reported. Furthermore, the experimental sets employed for these reactions have been included in the present manuscript. Likewise, the characteristics of the glycerol ethers−(bio)fuel blends as well as their performances (e.g., quality of emissions, technical advantages or disadv... [more]

Spent coffee grounds (SCG) are one of the lignocellulosic biomasses that have gained much attention due to their high potential both in valorization and biomethane production. Previous studies have reported single processes that extract either fatty acids/lignin or biogas. In this study, an integrated physicochemical and biological process was investigated, which sequentially recovers lignin, fatty acid methyl esters (FAME) and biogas from the residue of SCG. The determination of optimal conditions for sequential separation was based on central composite design (CCD) and response surface methodology (RSM). Independent variables adopted in this study were reaction temperature (86.1−203.9 °C), concentration of sulfuric acid (0.0−6.4%v/v) and methanol to SCG ratio (1.3−4.7 mL/g). Under determined optimal conditions of 161.0 °C, 3.6% and 4.7 mL/g, lignin and FAME yields were estimated to be 55.5% and 62.4%, respectively. FAME extracted from SCG consisted of 41.7% C16 and 48.16% C18, which... [more]

Phase change material can be used as heat transfer fluid in the solar water heating system, which is the latest way to improve thermal efficiency. In this paper, graphene composite paraffin emulsion is used as heat transfer fluid in a solar water heating-phase change material (SWH-PCM) system. By comparing with the traditional solar water heating (SWH) system, the thermal performance characteristics of SWH-PCM system have been investigated experimentally. The SWH-PCM system has higher heat storage than the SWH system. The heat storage of SWH-PCM system and SWH system all increase with the increase of solar irradiance, while the thermal efficiency has the opposite trend. The flow rate has a greater influence on the thermal efficiency of SWH-PCM system than that of the SWH system. With the flow rate of 200 L/h, the thermal efficiency of SWH-PCM system is 14.21% higher than that of the SWH system. In summary, the SWH-PCM system is a promising solar water heating system with high heat stor... [more]

Climate change is one of the most important issues affecting the future of the planet. Then, a lot of resources are being used to actively work on climate change issues and greenhouse gas reduction. Greenhouse gas (GHG) emissions are monitored by each country and reported yearly to the United Nations Framework Convention on Climate Change (UNFCCC). The Intergovernmental Panel on Climate Change (IPCC) published the document entitled “2006 IPCC Guidelines for National Greenhouse Gas Inventories” to provide the calculation rules and the way to inform the UNFCCC of the national GHG emissions. Currently, this document does not give a procedure to calculate the net carbon dioxide emissions to the atmosphere due to the Portland cement clinker production. The purpose of this paper is to get reliable relationships to better calculate the CO2 uptake by ground granulated blast-furnace slag (GGBFS) mortars. The application of this material cured under controlled conditions could help minimize envi... [more]

During biomass storage, some gases can be produced and reach dangerous levels to human health. Among them, carbon monoxide is especially worrying, due to its potentially lethal effects and its contribution to the greenhouse effect. High levels of this gas could be reached, depending on many factors, such as unsuitable ventilation in storage areas or raw material characteristics. The aim of this research study was to assess the levels of CO produced during pellet storage at a laboratory scale, depending on the ventilation conditions (changing the amount of sample and frequency), the pellet characteristics (eucalyptus and cork residue pellets), and variables that influence CO levels. A greater number of pellets (when not ventilated) increased CO levels and discontinuous ventilation did not reduce these levels once the space was isolated again. Cork samples provoked higher CO emissions, possibly due to its higher fat content and surface area, which promotes the interaction between air and... [more]

This paper gives an overview on some state-of-the-art characterization methods of SiO2/4H-SiC interfaces in metal oxide semiconductor field effect transistors (MOSFETs). In particular, the work compares the benefits and drawbacks of different techniques to assess the physical parameters describing the electronic properties and the current transport at the SiO2/SiC interfaces (interface states, channel mobility, trapping phenomena, etc.). First, the most common electrical characterization techniques of SiO2/SiC interfaces are presented (e.g., capacitance- and current-voltage techniques, transient capacitance, and current measurements). Then, examples of electrical characterizations at the nanoscale (by scanning probe microscopy techniques) are given, to get insights on the homogeneity of the SiO2/SiC interface and the local interfacial doping effects occurring upon annealing. The trapping effects occurring in SiO2/4H-SiC MOS systems are elucidated using advanced capacitance and current... [more]

Particles in transformer oil are harmful to the operation of transformers, which can lead to the occurrence of partial discharge and even breakdown. More and more researchers are becoming interested in investigating the effects of particles on the performance of insulation oil. In this paper, a simulation method is provided to explore the motion mechanism and accumulation characteristics of different particles. This is utilized to explain the effects of particle properties on the breakdown strength of mineral oil. Experiments on particle accumulation under DC voltage as well as DC breakdown were carried out. The simulation results are in agreement with the experimental results. Having a DC electrical field with a sufficient accumulation time and initial concentration are advantageous for particle accumulation. Properties of impurities determine the bridge shape, conductivity characteristics, and variation law of DC breakdown voltages. Metal particles and mixed particles play more signi... [more]

Extreme climate change due to heat-trapping gases, especially carbon dioxide, necessitates its mitigation. In this context, the carbon dioxide sequestration technology of enhanced weathering has for years been investigated, with a possible implementation strategy via alkaline mineral soil amendment being more recently proposed. Candidate materials for enhanced weathering include calcium and magnesium silicates, most notably those belonging to the olivine, pyroxene and serpentine groups of minerals, given their reactivity with CO2 and global availability. When these finely crushed silicate rocks are applied to the soil, the alkaline earth metal cations released during mineral weathering gradually react with carbonate anions and results in the formation of pedogenic carbonates, which, over time, and under the right conditions, can accumulate in the soil. This review paper critically reviews the available literature on alkaline mineral soil amendments and its potential to sequester enough... [more]

The tropical insular region is characterized by a large diversity of microclimates and land/sea contrasts, creating a challenging solar forecasting. Therefore, it is necessary to develop and use performant and robustness forecasting techniques. This paper examines the predictive performance of a novel solar forecasting approach, the multiscale hybrid forecast model (MHFM), as a function of several parameters. The MHFM model is a technique recently used for irradiance forecasting based on a hybrid autoregressive (AR) and neural network (NN) model combined with multiscale decomposition methods. This technique presents a relevant performance for 1 h ahead global horizontal irradiance forecast. The goal of this work is to highlight the strength and limits of this model by assessing the influence of different parameters from a metric error analysis. This study illustrates modeling process performance as a function of daily insolation conditions and testifies the influence of learning data a... [more]

The MgO-CO2 working pair has been regarded as prospective for thermochemical energy storage (TCES) due to its relatively high heat storage capacity, low cost, and wide availability. This study is aimed at the optimization of the molar salt content, α, for the MgO modified with the eutectic mixture of LiNO3 and KNO3 (Li0.42K0.58NO3) which was earlier shown to provide high conversion, Δx, in heat-storage/release processes at 300−400 °C. The composites that have different salt content were prepared and carbonation kinetics was investigated under various conditions (carbonation temperature, Tcarb., is 290−360 °C and CO2 pressure, P(CO2), is 50−101 kPa). Significant accelerating effect was revealed at α ≥ 0.05, and the Δx value was maximized at α = 0.10−0.20. The largest conversion of 0.70 was detected at α = 0.10 and Tcarb. = 350 °C that corresponds to the specific useful heat (Qcomp.) is 1.63 MJ/kg-composite. However, the salt content of 0.20 ensures the high conversion, Δx = 0.63−0.67 an... [more]

Organic carbon (C) and oxygen (O) contained in sewage sludge strongly impact its thermal behavior during pyrolysis treatment. This study was aimed at getting an insight into the decomposition mechanism of organic compounds containing C and O during sludge pyrolysis using thermo-gravimetric Fourier transform infrared spectroscopy (TG-FTIR) and pyrolysis-gas-chromatography/mass spectrometry (Py-GC/MS) and helpfully improving energy conversion of sewage sludge. The temperature domains of transformation were determined and indications of the main compounds produced during each stage were obtained. Results showed that the volatile compounds that evolved after sludge pyrolysis were mainly distributed into six groups: alkenes, aromatic hydrocarbons, alcohols, aldehydes, phenols and carboxylic acids. Comparison in thermal behavior and composition of the evolved volatile compounds were observed. In the low temperature stage (<350 °C), compounds containing O−C=O accounted for the highest prop... [more]

This paper presents findings from an experimental study investigating the secondary atomization of liquid fuel droplets widely used in the heat and power industry exemplified by fuel oil and environmentally promising fuel oil/water emulsion. The scientific novelty comes from the comparative analysis of the critical conditions and integral characteristics of the secondary atomization of the liquid and composite fuels with the greatest potential for power plants. Here, we used two fuel atomization schemes: droplet−droplet collisions in a gas and droplets impinging on a heated solid wall. The temperature of the liquids under study was 80 °C. The velocities before collision ranged from 0.1 m/s to 7 m/s, while the initial droplet sizes varied from 0.3 mm to 2.7 mm. A copper substrate served as a solid wall; its temperature was varied from 20 °C to 300 °C. The main characteristics of droplet interaction were recorded by a high-speed camera. Regime maps were constructed using the experimental... [more]

Bio-based and natural building materials can support the building sector to reduce its environmental impact. In this study, experimental research was developed to evaluate the performance of giant reed when used as a building thermal insulation. Reed was chosen due to its high availability and close relationship to Portuguese vernacular architecture. The role of the reed’s origin in this context, its physical characteristics and its durability aspects were evaluated. The results showed that the performance of the reed boards was compatible with their use as a thermal insulation material, regardless of the reed’s origin. Denser boards showed better results. Under the favourable conditions related to the reed’s water content, mould growth could occur.

Foam-enhanced oil recovery (EOR) is poised to become one of the most promising tertiary recovery techniques to keep up with the continuously increasing global energy demands. Due to their low sensitivity to gravity and permeability heterogeneities that improve sweep efficiency, foams are the preferred injection fluids over water or gas. Although foam injection has been used in the field to improve oil recovery and control gas mobility, its success is still hindered by several conceptual and operational challenges with regard to its stability and foamability under reservoir conditions. This can be attributed to the insufficient attention given to the mechanisms underlying foam generation and stability at the microscopic level in many studies. For a deeper understanding, this study reviews the most pertinent published works on foam-EOR. The major objective is to provide a broad basis for subsequent laboratory and field applications of foam-EOR. In this work, we highlighted foam classific... [more]

Economic growth and rapid urbanization have resulted in the increase in demand for infrastructure development. To meet this ever increasing demand, conventional construction materials such as concrete are used, which requires an energy intensive process that in turn impacts the environment adversely. Ordinary Portland Cement, being the dominant binder in the industry, contributes around 8% of worldwide annual carbon emissions, and this is expected to reach around 20% by 2050. Population growth has resulted in the significant increase in agro-industrial waste generation during recent years. Inadequate waste management raises a number of environmental concerns. With the growing economy and rising living standards, global raw material consumption is expected to double by 2060. The reutilization of waste materials will aid in their management, while conserving the available resources. Alkali-activated materials (AAM) have recently been introduced as an eco-friendly alternative to conventio... [more]

Standard hydraulic breaking hammers are widely used for crushing oversized blasted materials and concrete structures demolition in industry. These hammers, installed in on-surface working excavators or stationary manipulators at the dumping points of underground conveyors, provide the required limited sizes of bulk materials and enable the safe operation of other equipment (screens, crushers). In parallel, hydraulic hammers have an alternative—fully electric hammers. This paper aims to review existing linear electric motor (LEM) hammers as an energy-saving and eco-friendly solution in industry. Global market analysis is presented with potential branches of LEM hammers. Several aspects for implementation—design optimization, dynamics simulation, machine control, and performance estimation—are considered. Different case studies for LEM-hammer application are given. The preliminary measurements are demonstrated on the electric hammer of Lekatech Company, which is intended for the mining i... [more]

The co-pyrolysis of various biomasses mixed with two types of plastic waste was investigated in this study. Mixture M1 consisted of 30% m/m styrene−butadiene rubber (SBR), 40% m/m polyethylene terephthalate (PET), and 30% m/m polypropylene (PP). M2 consisted of 40% m/m PET, 30% m/m PP, and 30% m/m acrylonitrile−butadiene−styrene copolymer (ABS). The SBR, ABS, and PP used in this study were from the automotive industry, while the PET originated from scrap bottles. Co-pyrolysis was performed using wood biomass, agricultural biomass, and furniture trash. Thermal treatment was performed on samples from room temperature to 400 or 600 °C at a heating rate of 10 °C/min under N2 at a flow rate of 3 dm3/min. Based on the findings of the experiments, an acceptable temperature was found for the fixed-bed pyrolysis of biomass−plastic mixtures with varying ratios, and the raw materials were pyrolyzed under the same conditions. The composition of the derived gaseous fraction was investigated. The co... [more]