Oil-based drilling fluid has many advantages, such as stable performance, strong anti-pollution ability, and strong inhibition, and it has been widely used in the world. However, at present, there is no unified evaluation standard for the effect of flushing fluid under this condition, and most of them are based on the flushing effect evaluation of water-based drilling fluid. However, there are few studies on wetting reversal phenomenon, reasonable dosage, and flushing time between oil-based drilling fluid and flushing fluid on the two-phase interface. Therefore, it is necessary to establish a comprehensive evaluation method for the effect of flushing fluid under oil-based drilling fluid, and explore the relationship between the amount of flushing fluid and flushing efficiency, so as to determine the reasonable range of flushing fluid consumption. In this paper, using the existing experimental instruments, a type A oil-based flushing fluid commonly used in oil fields was selected for th... [more]

The performance of redox flow batteries is notably influenced by the electrolyte, especially in slurry-based flow batteries, as it serves as both an ionic conductive electrolyte and a flowing electrode. In this study, carbon additives were introduced to achieve a rechargeable zinc slurry flow battery by minimizing the zinc plating on the bipolar plate that occurs during charging. When no carbon additive was present in the zinc slurry, the discharge current density was 24 mA∙cm−2 at 0.6 V, while the use of carbon additives increased it to up to 38 mA∙cm−2. The maximum power density was also increased from 16 mW∙cm−2 to 23 mW∙cm−2. Moreover, the amount of zinc plated on the bipolar plate during charging decreased with increasing carbon content in the slurry. Rheological investigation revealed that the elastic modulus and yield stress are directly proportional to the carbon content in the slurry, which is beneficial for redox flow battery applications, but comes at the expense of an incre... [more]

In this paper, the feasibility study to develop strain-based seismic design criteria applicable for the components of nuclear power plants are carried out as an alternative rule to the current stress-based criteria. To do this, two acceptance criteria are investigated through the detailed example of an application for the surge line nozzles in a nuclear steam supply system, which are known as one of the seismic fragile components in nuclear power plants. These strain-based seismic design criteria are primarily to prevent two types of failure modes, such as a ductile fracture and a cyclic fatigue-induced damage due to continuous large amplitude cyclic loads during seismic event. Through the example problem, the required procedures are described step-by-step with calculations of an accumulated plastic strain, triaxiality factor by the elasto-plastic seismic analysis using the finite element method. For a precise inelastic seismic analysis, the Chaboche kinematic and Voce isotropic harden... [more]

This paper presents the effect of the impact of moisture in paper insulation used as insulation of transformer windings on its thermal conductivity. Various types of paper (cellulose and aramid) and impregnated (mineral oil, synthetic ester, and natural ester) were tested. The impact of paper and impregnated types on the changes in thermal conductivity of paper insulation caused by an increase in moisture were analyzed. A linear equation, describing the changes in thermal conductivity due to moisture, for various types of paper and impregnated, was developed. The results of measuring the thermal conductivity of paper insulation depending on the temperature are presented. The aim of the study is to develop an experimental database to better understand the heat transport inside transformers to assess aging and optimize their performance.

In this study, enhanced oil recovery (EOR) techniques—namely low salinity and nanofluid EOR—are probed at the nanometer-scale using an atomic force microscope (AFM). Mica substrates were used as model clay-rich rocks while AFM tips were coated to present alkyl (-CH3), aromatic (-C6H5) and carboxylic acid (-COOH) functional groups, to simulate oil media. We prepared brine formulations to test brine dilution and cation bridging effects while selected concentrations (0 to 1 wt%) of hydrophilic SiO2 nanoparticles dispersed in 1 wt% NaCl were used as nanofluids. Samples were immersed in fluid cells and chemical force mapping was used to measure the adhesion force between polar/non-polar moieties to substrates. Adhesion work was evaluated based on force-displacement curves and compared with theories. Results from AFM studies indicate that low salinity waters and nanoparticle dispersions promote nanoscale wettability alteration by significantly reducing three-phase adhesion force and the reve... [more]

Greenhouse gases such as carbon dioxide and methane cause global warming and consequently climate change. Great efforts are being made to reduce greenhouse gas emissions with the objective of addressing this problem, hence the popularity of technologies conductive to reducing greenhouse gas emissions. CO2 emissions can be reduced by improving the thermal efficiency of combustion engines, for example, by using cogeneration systems. Coal mine methane (CMM) emerges due to mining activities as methane released from the coal and surrounding rock strata. The amount of methane produced is primarily influenced by the productivity of the coal mine and the gassiness of the coal seam. The gassiness of the formation around the coal seam and geological conditions are also important. Methane can be extracted to the surface using methane drainage installations and along with ventilation air. The large amounts of methane captured by methane drainage installations can be used for energy production. Thi... [more]

The measurement of polarization and depolarization currents (PDC) based on time−domain response is an effective method for state assessment of cellulose insulation material in oil-immersed electrical equipment. However, the versatility of the data obtained at different temperatures is limited because of the temperature dependence of the PDC. In this respect, the universal conversion of PDC data at different temperatures is an essential aspect to improve the accuracy of the determination of insulating properties of cellulose materials immersed in the oil. Thus, an innovative temperature conversion method based on polarization time-varying current (PTC, obtained by multiplying the polarization current and time) is proposed in this article. In the current work, the PTC data at different temperatures are obtained from the oil-immersed cellulose pressboards with different moisture. Afterwards, the functional model based on the power series theory is used to simulate the PTC data, through wh... [more]

The research of marine antifouling is mainly conducted from the aspects of chemistry, physics, and biology. In the present work, the movement model of microorganisms along or against the flow direction on the microstructural surface was established. The model of globose algae with a diameter of 5 μm in the near-wall area was simulated by computational fluid dynamics (CFD), and the fluid kinematic characteristics and shear stress distribution over different-sized microstructures and in micropits were compared. Simulation results revealed that the increase of the β value (height to width ratio) was prone to cause vortexes in micropits. In addition, the closer the low-velocity region of the vortex center to the microstructural surface, the more easily the upper fluid of the microstructure slipped in the vortex flow and reduced the microbial attachment. Moreover, the shear stress in the micropit with a height and width of 2 μm was significantly higher than those in others; thus, microbes i... [more]

In this study, a new type of functional hybrid suspension for solar energy conversion and thermal energy storage was prepared by adding carbon nanotube (CNT) and microencapsulated phase-change material (MEPCM) into deionized water. MEPCM with octadecane as the core material and titania (TiO2) as the shell material was synthesized by the sol−gel method. The MEPCMs were spherical particles with diameters of 2−4 μm, and the thickness of the shell was about 100 nm. The MEPCM achieved better thermal stability and thermal conductivity than the pure octadecane due to the TiO2 shell. The melting and solidification latent heats of the MEPCM were about 154.24 and 154.26 J/g, respectively. The encapsulation efficiency of octadecane was calculated to be 65.84%. Most of all, the novel hybrid CNT and MEPCM suspensions exhibited remarkable dispersion stability owing to the stable reticular structure composed of CNT in the suspension. Compared with pure water, the thermal conductivity, specific heat o... [more]

Catalysts consisting of Ru nanoparticles (1 wt%), supported on mesoporous activated carbons (ACs), were prepared and used in the one-pot hydrolytic hydrogenation of cellulose to obtain sorbitol. The carbon materials used as supports are a pristine commercial mesoporous AC (named SA), and two samples derived from it by sulfonation or oxidation treatments (named SASu and SAS, respectively). The catalysts have been thoroughly characterized regarding both surface chemistry and porosity, as well as Ru electronic state and particle size. The amount and type of surface functional groups in the carbon materials becomes modified as a result of the Ru incorporation process, while a high mesopore volume is preserved upon functionalization and Ru incorporation. The prepared catalysts have shown to be very active, with cellulose conversion close to 50% and selectivity to sorbitol above 75%. The support functionalization does not lead to an improvement of the catalysts’ behavior and, in fact, the Ru... [more]

Bifacial photovoltaic (PV) modules can take advantage of rear-surface irradiance, enabling them to produce more energy compared with monofacial PV modules. However, the performance of bifacial PV modules depends on the irradiance at the rear side, which is strongly affected by the installation setup and environmental conditions. In this study, we experiment with a bifacial PV module and a bifacial PV system by varying the size of the reflective material, vertical installation, temperature mismatch, and concentration of particulate matter (PM), using three testbeds. From our analyses, we found that the specific yield increased by 1.6% when the reflective material size doubled. When the PV module was installed vertically, the reduction of power due to the shadow effect occurred, and thus the maximum current was 14.3% lower than the short-circuit current. We also observed a maximum average surface temperature mismatch of 2.19 °C depending on the position of the modules when they were comp... [more]

In view of the serious threat of gas accumulation in the coal mine goaf and the limitations of the existing gas sealing materials, the orthogonal experiment was developed to study a new type of foamed concrete for mine gas sealing. Dry density, gas permeability, and compressive strength were studied as the material indicators according to the demands of the gas isolation material in the coal mine goaf, and the experimental results showed that foam content was the most important factor. Meanwhile, the optimum mix was selected according to the influence of foam content as well as the engineering requirement. Then two application modes of this foamed concrete for goaf gas isolation were put forward, after which the convection-diffusion model of gas was built by COMSOL Multiphysics (COMSOL Inc., Stockholm, Sweden) to reveal the mechanism of different application modes using the parameters of the new foamed concrete. Simulation results showed that this foamed concrete used as isolating mate... [more]

Rechargeable magnesium (Mg)-based energy storage has attracted extensive attention in electrochemical storage systems with high theoretical energy densities. The Mg metal is earth-abundant and dendrite-free for the anode. However, there is a strong Coulombic interaction between Mg2+ and host materials that often inhibits solid-state diffusion, resulting in a large polarization and poor electrochemical performances. Herein, we develop a Mg−Li hybrid battery using a Mg-metal anode, an FeSe2 powder with uniform size and a morphology utilizing a simple solution-phase method as the counter electrode and all-phenyl-complex/tetrahydrofuran (APC)-LiCl dual-ion electrolyte. In the Li+-containing electrolyte, at a current density of 15 mA g−1, the Mg−Li hybrid battery (MLIB) delivered a satisfying initial discharge capacity of 525 mAh g−1. Moreover, the capacity was absent in the FeSe2|APC|Mg cell. The working mechanism proposed is the “Li+-only intercalation” at the FeSe2 and the “Mg2+ dissolve... [more]

At most of the installations for the mechanical and biological treatment of waste operated in Poland, the 0−80 mm fraction, separated from the municipal waste stream, are completely stored after biostabilization. Such an action does not fit into the EU strategy focused on circular waste management. The purpose of this study was to assess the technical feasibility of recovering the mineral fractions contained in the compost-like-output (CLO) on a technological line designed for glass recovery. The research started in January 2019, lasted for the next 12 months, and covered 29 measurement series. The following two high-energy fractions were separated from the CLO: 10−35 mm light fraction after separation in the air separator (M-1) and 35−80 mm light fraction after separation in the air separator (M-2). The stabilization processing on the glass recovery line allowed for the recovery of two high energy fractions in the total amount of 24.5% of the processed, and it stabilized the product’s... [more]

Climate change has been recognized as a threatening environmental problem around the world. CO2 is considered to be the main component of greenhouse gas. By using solar energy (light energy) as the energy source, photocatalytic conversion is one of the most effective technologies to reveal the clean utilization of CO2. Herein, using sodium tungstate, nickel nitrate, and selenium powder as the main raw materials, the high absorption and utilization of WSe2 for light energy and the high intrinsic conductivity of NiSe2 were combined by a hydrothermal method to prepare NiSe2/WSe2 and hydrazine hydrate as the reductant. Then, high-performance NiSe2/WSe2 photocatalytic material was prepared. The characterization results of XRD, XPS, SEM, specific surface area, and UV-visible spectroscopy show that the main diffraction peak of synthesized NiSe2/WSe2 is sharp, which basically coincides with the standard card. After doping NiSe2, the morphology of WSe2 was changed from a flake shape to smaller... [more]

In many heat transfer related applications, there is a need for a stable, constant supply temperature. As a result, the integration of intermittent renewable sources of heat into these processes can prove to be challenging, requiring special temperature smoothing devices or strategies. This study focuses on the application of phase change materials integrated into a double tube heat exchanger as a possible thermal smoothing device. The objective of this study is to evaluate the ability of the exchanger to smoothen out temperature variations within the cold stream outlet while the hot stream is subject to oscillating inlet conditions. A computational fluid dynamics approach is used where a numerical model is developed, validated and then used to model the conjugate heat transfer within the heat exchanger. Four organic phase change materials (PCM) with different phase change temperatures were selected for investigation (myristic, octadecane, eicosane, and wax) to study the relationship b... [more]

The commonly used electrode Pt supported on a carbon (Pt/C) catalyst has demonstrated underperforming electrochemical durability in proton exchange membrane fuel cell (PEMFC) harsh operation conditions, especially in terms of Pt electrochemical instability and carbon corrosion. Gold nanoparticles (AuNPs) are considered one of the best alternative catalysts of PtNPs due to their remarkable selectivity for oxygen reduction reaction (ORR) and electrochemical stability in strong acid conditions, attributes which are ideal for practical PEMFC applications. In this work, we propose a new, facile and low-cost approach to prepare AuNPs supported on reduced graphene oxide nanocompounds (AuNPs/rGO). The morphological and structural properties of the as-prepared AuNPs/rGO were studied using various microscopic and spectroscopic techniques, namely, Raman Spectroscopy, Scanning Electron Microscopy (SEM), Scanning Transmission Electron Microscopy (STEM), X-Ray Diffraction (XRD), Fourier Transform In... [more]

Nowadays, waste thermal energy represents a huge quantity of energy that, in most cases, is unfortunately dispersed rather than recovered. Although it is well known that its recovery could result in a considerable impact reduction of human activities on the environment, it is still a challenging issue. In view of this, absorption chillers and heat pumps, based on the use of porous materials capable of reversibly adsorbing and desorbing water vapor, can be considered among the preferred systems to recover waste thermal energy, especially at medium−low temperatures. This study deals with the preparation and performance of a new generation of advanced adsorbent materials specifically produced as coatings for water adsorption systems driven by low temperature heat sources (around 150 °C). The proposed coating consists of hybrid SAPO-34/polyacrilonitrile microfibers directly deposited on the surface to be coated by means of the electrospinning technique. Their zeolite morphology and concent... [more]

Understanding a partial discharge mechanism at direct current (DC) is an actual research topic that requires both modeling, simulations and measurements. This paper describes an influence of insulating material properties on partial discharges at DC voltage. Modifications of the traditional model reflecting the conditions of partial discharges (PD) inception and post discharge processes at DC voltage have been proposed. The aim was to show the partial discharge mechanisms and draw attention to the role of parameters of insulation materials adjacent to the cavity at DC voltage. The investigations were performed on two kinds of dielectric material used in power cables. Various combinations of specimens were designed to reveal the effect of the material resistivity on the PD activity. Key observations referred to the impact of the void adjacent material resistance on the partial discharge inception voltage threshold at DC voltage. The modified PD model was applied to analyze both inceptio... [more]

In this study, the non-intrusive embedded discrete fracture model (EDFM) in combination with the Oda method are employed to characterize natural fracture networks fast and accurately, by identifying the dominant water flow paths through spatial connectivity analysis. The purpose of this study is to present a successful field case application in which a novel workflow integrates field data, discrete fracture network (DFN), and production analysis with spatial fracture connectivity analysis to characterize dominant flow paths for water intrusion in a field-scale numerical simulation. Initially, the water intrusion of single-well sector models was history matched. Then, resulting parameters of the single-well models were incorporated into the full field model, and the pressure and water breakthrough of all the producing wells were matched. Finally, forecast results were evaluated. Consequently, one of the findings is that wellbore connectivity to the fracture network has a considerable ef... [more]

The integration of thermal energy storage systems (TES) in waste-heat recovery applications shows great potential for energy efficiency improvement. In this study, a 2D mathematical model is formulated to analyze the performance of a two-tank thermochemical heat storage system using metal hydrides pair (Mg2Ni/LaNi5), for high-temperature waste heat recovery. Moreover, the system integrates a phase change material (PCM) to store and restore the heat of reaction of LaNi5. The effects of key properties of the PCM on the dynamics of the heat storage system were analyzed. Then, the TES was optimized using a genetic algorithm-based multi-objective optimization tool (NSGA-II), to maximize the power density, the energy density and storage efficiency simultaneously. The results indicate that the melting point Tm and the effective thermal conductivity of the PCM greatly affect the energy storage density and power output. For the range of melting point Tm = 30−50 °C used in this study, it was sho... [more]

Uranium is one of the strategic minerals used mainly in energetics. The main purpose of uranium mining is to achieve maximum production to meet the rapidly growing demand for energies. It needs to become aware that technological progress in mining processes could significantly reduce the negative impacts associated with environmental, economic, and social risks. Uranium mining is one of the most controversial topics. It is dealt with by many experts and scientists around the world. Various methods and technologies of uranium mining are encountered in professional journals, as well as political or socio-economic decisions based on the impact and importance of the energy potential of uranium deposits, or the environmental impacts of uranium mining. The deposit of Kuriskova is one of the most perspective deposits not only in Slovakia but also in the world. The deposit is located near the town of Kosice (with near 240,000 inhabitants) and near the recreational area of Jahodna in the east o... [more]

Lignocellulosic biomass is a non-edible feedstock that can be used in integrated biorefinery for the production of biochemicals and biofuel. Among lignocellulosic biomass, Cynara cardunculus L. (cardoon) is a promising crop thanks to its low water and fertilizer demand. Organosolv is a chemical treatment that uses numerous organic or aqueous solvent mixtures, and a small amount of acid catalyst, in order to solubilize the lignin and hemicellulose fractions, making the cellulose accessible to hydrolytic enzymes. Lignocellulosic residues of cardoon underwent a two-step treatment process to obtain fermentable glucose. In the first step, the milled biomass was subjected to microwave-assisted extraction using an acidified γ-valerolactone (GVL)/water mixture, yielding a solid cellulose pulp. In the second step, the pre-treated material was hydrolyzed by cellulolytic enzymes to glucose. The first step was optimized by means of a two-level full factorial design. The investigated factors were p... [more]

A radiative cooling device, based on a metamaterial able to mirror solar radiation and emit heat toward the universe by the transparency window of the atmosphere (8−13 µm), reaching and maintaining temperatures below ambient air, without any electricity input (passive), could have a significant impact on energy consumption of buildings and positive effects on the global warming prevention. A similar device is expected to properly work if exposed to the nocturnal sky, but during the daytime, its efficacy could be affected by its own heating under direct sunlight. In scientific literature, there are only few evidences of lab scale devices, acting as passive radiative cooling at daytime, and remaining few degrees below ambient air. This work describes the proof of concept of a daytime passive radiative cooler, entirely developed in ENEA labs, capable to reach well 12 °C under ambient temperature. In particular, the prototypal device is an acrylic box case, filled with noble gas, whose top... [more]

The viability of the sodium-ion batteries as a post-lithium storage technology is strongly tied to the development of high-performance carbonaceous anode materials. This requires screening novel precursors, and tuning their electrochemical properties. Soft carbons as promising anode materials, not only for batteries, but also in hybrid capacitors, have drawn great attention, due to safe operation voltage and high-power properties. Herein, several vinyl polymer-derived soft carbons have been prepared via pyrolysis, and their physicochemical and sodium storage properties have been evaluated. According to the obtained results, vinyl polymers are a promising source for preparation of soft carbon anode materials for sodium-ion battery application. In addition, their applicability towards Li-ion battery and hybrid capacitors (e.g., Li ion capacitors, LICs) has been examined. This work not only contrasts the carbonization products of these polymers with relevant physicochemical characterizati... [more]