Sustainable production of electricity from renewable sources by microorganisms is considered an attractive alternative to energy production from fossil fuels. In recent years, research on microbial fuel cells (MFCs) technology for electricity production has increased. However, there are problems with up-scaling MFCs due to the fairly low power output and high operational costs. One of the approaches to improving energy generation in MFCs is by modifying the existing anode materials to provide more electrochemically active sites and improve the adhesion of microorganisms. The aim of this review is to present the effect of anode modification with carbon compounds, metallic nanomaterials, and polymers and the effect that these modifications have on the structure of the microbiological community inhabiting the anode surface. This review summarizes the advantages and disadvantages of individual materials as well as possibilities for using them for environmentally friendly production of elec... [more]

This study addresses the effect of nanoparticles’ conductivity and surface charge on the dielectric performance of insulating nanofluids. Dispersions of alumina and silicon carbide nanoparticles of similar size (~50 nm) and concentration (0.004% w/w) were prepared in natural ester oil. The stability of the dispersions was explored by dynamic light scattering. AC, positive and negative lightning impulse breakdown voltage, as well as partial discharge inception voltage of the nanofluid samples were measured and compared with the respective properties of the base oil. The obtained results indicate that the addition of SiC nanoparticles can lead to an increase in AC breakdown voltage and also enhance the resistance of the liquid to the appearance of partial discharge. On the other hand, the induction of positive charge from the Al2O3 nanoparticles could be the main factor leading to an improved positive Lightning Impulse Breakdown Voltage and worse performance at negative polarity.

Accurate hysteresis models are necessary for modeling of magnetic components of devices such as transformers and motors. This study presents a hysteresis model with a convenient analytical form, based on hypergeometric functions with one free parameter, built upon a class of parameterized curves. The aim of this work is to explore suitability of the presented model for describing major and minor loops, as well as to demonstrate improved agreement between experimental and modeled hysteresis loops. The procedure for generating first order reversal curves is also discussed. The added parameter, introduced into the model, controls the shape of the model curve, especially near saturation. It can be adjusted to provide better agreement between measured and model curves. The model parameters are nonlinearly dependent; therefore, they are determined in a nonlinear curve fitting procedure. The choice of the initial approximation and a suitable set of constraints for the optimization procedure a... [more]

Na3Ni2BiO6 with Honeycomb structure suffers from poor cycle stability when applied as cathode material for sodium-ion batteries. Herein, the strategy to improve the stability is to substitute Ni and Bi with inactive Ti. Monoclinic Na3Ni2-xBi1-yTix+yO6 powders with different Ti content were successfully synthesized via sol gel method, and 0.3 mol of Ti was determined as a maximum concentration to obtain a phase-pure compound. A solid-solution in the system of O3-NaNi0.5Ti0.5O2 and O3-Na3Ni2BiO6 is obtained when this critical concentration is not exceeded. The capacity of the first desodiation process at 0.1 C of Na3Ni2BiO6 (~93 mAh g−1) decreases with the increasing Ti concentration to ~77 mAh g−1 for Na3Ni2Bi0.9Ti0.1O6 and to ~82 mAh g−1 for Na3Ni0.9Bi0.8Ti0.3O6, respectively. After 100 cycles at 1 C, a better electrochemical kinetics is obtained for the Ti-containing structures, where a fast diffusion effect of Na+-ions is more pronounced. As a result of in operando synchrotron radiat... [more]

Metallic interconnects represent the main component of a solid oxide fuel cell (SOFC) stack in terms of weight and volume. They are typically made of ferritic stainless steel (FSS) coated on the air side. At the stack operating conditions, the interconnect is exposed to a dual atmosphere: air at the cathode side; fuel (a hydrogen-rich mixture) at the anode side. The stacks considered in this study were field operated in reformed natural gas for 5000, 9000 and 20,000 h respectively. The analyzed interconnects are made from CROFER22APU and coated on the air side with Co-Mn base spinel. One interconnect has been studied for each stack by sampling and preparing cross section the inlet and outlet positions. The samples were characterized by SEM-EDXS in order to investigate the evolution of the interconnect at the air side. The interaction between the metal substrate and the coating is investigated highlighting the formation of chromia based thermal grown oxide (at the FSS/coating interface)... [more]

Biochar is an economical and environmentally friendly “green material” with potential benefits in greenhouse gas emission reduction, soil performance improvement, and environmental restoration. Mixing biochar with clay and using it as a landfill cover can effectively reduce the escape of greenhouse gases into the air, which is important for environmental protection. It is suggested that biochar should be mixed with clay and used as a landfill covering layer. In this study, the shear strength was obtained by direct shear test, and the shear strength characteristics of biochar−clay mixture under the influence of different dry and wet cycles, biochar contents, and moisture conditions were studied. The results show that the shear strength of the biochar−clay mixture in the saturated state decreases with increasing wet and dry cycles, with shear strength decreases ranging from 6% to 19%. The cohesion and internal friction angles of the clays and mixtures show a decreasing trend under wet an... [more]

The aim of this work was to develop hybrid TiO2/ZIF-8 photocatalysts and test their activity for the removal of agricultural pollutants in water. The hybrid photocatalysts were prepared by an innovative method involving hydrothermal synthesis at 150 °C using a mechanochemically synthesized zeolitic imidazolate framework (ZIF-8) and titanium tetraisopropoxide as a titanium dioxide (TiO2) precursor. Three composite photocatalysts with different mass fractions of titanium dioxide (5, 50, and 95 wt%) were synthesized and characterized, and their adsorption and photocatalytic properties investigated for the removal of imidacloprid. The equilibrium adsorption test showed that ZIF-8 is a good adsorbent and can adsorb 65% of the model component under the working conditions used in this work, while the hybrid photocatalysts can adsorb 1−3% of the model component. It is assumed that the adsorption is hindered by the TiO2 layer on the surface of ZIF-8, which blocks the interactions of ZIF-8 and i... [more]

A solid-state cold-spray technique was employed for depositing the copper-coated graphite reinforced copper-based composite coatings on aluminum alloy 6061 T6 substrate under different process parameters. The optimum process parameters of the cold-sprayed coatings were predicted in terms of surface roughness, thickness and adhesion. The surface roughness was measured using a 3D profilometer, the thickness and element constitution were detected by an optical microscope and scanning electron microscope furnished with an energy-dispersive spectral analyzer and the adhesion was detected by the scratch test method. The microstructures of the deposited coatings were also observed by a scanning electron microscope. The results show that when the coating is not oxidized and dense, the copper-coated graphite reinforced copper-based composite coating at 800 °C, 5.5 MPa, possesses the lowest surface roughness, the maximum thickness and the highest adhesion among the cold-sprayed coatings. In addi... [more]

Enhanced oil recovery (EOR) is a crucial technology in the petroleum industry, influenced by several factors, including flooding fluids and methods. The adjustment of injection strategies and the application of vibration stimulation can significantly impact oil recovery, especially residual oil. In this study, we conducted experiments using a glass micromodel to investigate the effect of pulsing water injection on oil recovery. Our results show that when the pulse frequency matches the natural frequency of the micromodel, resonance occurs during the two-phase flow of pulse driving, which causes an increase in the amplitude of oscillation, enhances the mobility of oil, and improves recovery. The efficiency of the kinetic energy of displacement is also improved. However, when the frequency is 3 Hz, the absence of resonance leads to the opposite effect. In addition, we found that a greater amplitude increases the fluidity of oil. These findings have significant implications for the design... [more]

The isolation of single homologs of polyethylene glycol by preparative reversed-phase chromatography is investigated. A thermodynamic model developed accurately previously describes the retention times of individual homologs as function of their size, temperature, and mobile phase composition under linear, diluted conditions. The model is extended to predict limiting retention times for linear gradient operation in preparative applications. Isocratic and gradient-based separations are studied under strongly overloaded conditions. Baseline separation of homologs up to 3000 g/mol is demonstrated. Quantitative production of pure single homologs up to molar weights of 1000 g/mol was performed using an automated setup.

This study proposed a novel continuous roll-forming process of elastomer molds, which can control the deformation of the mold using the rolling belt stack combination method. This study analyzed various rolling belt combinations, assembled the system based on simulation and experimental data according to the deformation requirement design, and obtained a controllable microstructure mold rolling belt with tensile deformation. Mold thickness and microstructure size are key microstructure mold deformation parameters. This study designed and assembled a controllable microstructure mold rolling belt-type imprint molding system and conducted a series of experiments. The impact and application of different experimental system operation procedures and fabrication methods of the auxetic structure rolling belt on replication molding were analyzed. The innovative controllable microstructure mold rolling belt-type imprint replication molding technique proposed in this study had a stable and contro... [more]

Wheat straw is a suitable source material for bioethanol production. Removing lignin and hemicellulose in wheat straw to improve enzymatic hydrolysis efficiency is essential because of its complex structure. Deep eutectic solvents (DESs) have become substitutes for ionic liquids (ILs), with the characteristics of good biocompatibility, simple synthesis procedure and low cost. However, the process of removing lignin and hemicellulose using present DESs requires a high operation temperature or long operation time. Therefore, we studied a novel method under mild conditions for screening a series of novel DESs based on an inorganic base to remove lignin and hemicellulose in wheat straw. In this work, the effect of DES type, the pH of the DESs, the operation temperature and operation time for enhancing enzymatic hydrolysis, and the crystal structure and the chemical structure and surface morphology of wheat straw were investigated. In particular, Na:EG exhibited the most excellent solubilit... [more]

This paper studies the effect of gravity orientation on a heat sink, used to passively cool a thick film resistor, by changing the assembly orientation. Using the same geometry and boundary conditions as in the experimental setup, finite element simulations were conducted to evaluate the accuracy of Siemens Flotherm XT 2021.2 simulation software. In order to determine the influence of heat sink orientation, experimental measurements were performed on the resistor and heat sink temperature using thermocouples. Siemens Simcenter Flotherm XT 2021.2 software (Siemens, Munich, Germany) was used to perform finite element simulation. The influence of the heat sink position was evaluated on two setups, one where the resistor is placed directly on the heat sink using screws, and the second one, where a thermal pad was placed between the resistor and the heat sink. Screws were to clamp the parts in both cases. In total, four experiments and simulations were performed with two assemblies with two... [more]

Over past decades, the green method of synthesizing metal nanoparticles has acquired more attentiveness by scientific consensus because of its industrial and biomedical applications. This study focuses on the anti-proliferative effectiveness of AgNPs synthesized from Rotheca serrata (L.) Steane & Mabb. flower bud extract against the PANC-1 cell line in vitro. Various analytical instruments were utilized to visualize the formation of RsFb-AgNPs, such as UV-Vis spectroscopy, FT-IR, SEM, EDS, TEM, XRD, Zeta potential, and DLS analysis. The biosynthesis of RsFb-AgNPs was observed by a change in color and UV-Vis spectroscopy (415 nm). The FT-IR spectra exhibited the existence of many functional groups. XRD confirmed the crystallinity of the AgNPs. Morphology and elemental mapping were assessed by SEM and EDS analysis. The TEM micrograph revealed spherical-shaped particles with sizes ranging from 12 to 40 nm. Zeta potential and DLS analysis were used to measure surface charge and particle si... [more]

The control difficulty of whole coal cavern groups is greatly increased due to the characteristics of soft rock with low strength, large sections, and the mutual influence of crossed cavern groups. The large section gas storage cavern group is taken as the research background. In this paper, the equivalent circle method is used to solve the loose circle of a rectangular roadway, and numerical calculation is used to obtain the deformation and stress distribution laws of the surrounding rock under the excavation conditions of large section whole coal cavern groups (WCCG). The deformation and failure mechanisms of the surrounding rock are revealed under the linkage impact between large section whole coal cavern groups. The stratified reinforcement ring concept of “long cable-bolt-grouting” (LBG) was proposed for the stability control of surrounding rock in the WCCG. On the roof of whole coal cavern groups, the supporting configuration of a high-strength bolt with a high pre-tightening for... [more]

Removable pressure-sensitive adhesives (PSAs) are used in the production of self-adhesive materials such as protective films, masking tapes or biomedical electrodes. This work presents a new and environmentally friendly method of obtaining this type of adhesive materials, i.e., photochemically induced free radical telomerization. Adhesive binders to removable PSAs, i.e., the photoreactive acrylic telomer syrups (ATS) were prepared from n-butyl acrylate, acrylic acid, and 4-acrylooxybenzophenone. Tetrabromomethane (CBr4) or bromotrichloromethane (CBrCl3) were used as the telogens. ATS was modified with unsaturated polybutadiene resin and a radical photoinitiator. Adhesive compositions were coated onto a carrier and UV cross-linked. The effects of the chemical nature of telomers (i.e., terminal Br or Cl atoms) and their molecular weight (K-value), as well as the cross-linking degree on adhesive properties of PSAs, were studied. It was found that with the increase in telogen content in th... [more]

During the last decades, palladium nanoparticles (Pd(0) NPs) and Pd(II) compounds were shown to be attractive catalysts for fine organic synthesis. Nanostructured Pd(0) or Pd(II) catalysts have a relatively low environmental impact, but, at the same time, they are indispensable for such processes as Suzuki cross-coupling. This paper describes the preparation of Pd(0) or Pd(II) supported/embedded in hyper-cross-linked polystyrene (HPS) and compares their activity in Suzuki cross-coupling between phenylboronic acid and 4-bromoanisole. Obviously, the palladium charge (Pd(0) ↔ Pd(II)) changes continuously during the reaction catalytic cycle. It would seem that the use of the starting palladium in the form of Pd(0) or Pd(II) should not affect the reaction’s kinetic laws for both catalysts, but their special individuality is manifested between them. Nanoparticulate Pd(0) catalysts are stable during the reaction. In contrast, catalysts based on Pd(II) are extremely active in the initial perio... [more]

The application of biopolymers and feasible technologies to obtain sheets is crucial for the large-scale production of food packages and for reducing plastic pollution. Additionally, the inclusion of additives in sheets can affect and improve their properties. This work aimed to incorporate tucumã oil (TO) and TO microparticles produced by spray drying (SD), spray chilling (SC), and their combination (SDC) into extruded cassava starch sheets and to evaluate the effect of such addition on their physical, optical, and mechanical properties. Gum Arabic and vegetable fat were used as wall materials for SD and SC/SDC, respectively. The sheets enriched with tucumã oil (FO) and the microparticles produced by SD, SC and SDC (FSD, FSC, and FSDC, respectively) presented yellow color (hue angle around 90°) and higher opacity (11.6−25.3%) when compared to the control (6.3%). All sheets showed high thickness (1.3−1.8 mm), and the additives reduced the water solubility of the materials (from 27.11%... [more]

A gliding arc plasma source designed for high efficient ignition has been studied with the help of numerical simulation and experiments. A coupled 3D−0D approach has been proposed to model the gliding arc from ignition (the equilibrium stage) to extinguish (the non−equilibrium stage). The model takes the measured discharge morphology, voltage, current, and velocity as inputs, and has been validated by comparing the calculated temperature with experimental results from an independent group. The temporal evolution of the temperature as well as active species, and the effective penetration length of the gliding arc has been studied; the influence of the gliding arc-based plasma igniter on the ignition delay time of a premixed pentane-air gas has also been theoretically analyzed.

In 2019, a coffee chain in Taiwan was found to be mixing relatively cheap Robusta beans into products marketed as 100% Arabica. Many studies show 16-OMC is a remarkable marker to distinguish Robusta from Arabica beans, and nuclear magnetic resonance (NMR) is a convenient and efficient technique for 16-OMC quantification. Here, a 500 MHz NMR was employed to determine the content of 16-OMC in coffee for adulterate evaluation. A total of 118 samples were analyzed including products from the coffee chain, raw materials (single coffee beans), and other commercial products. The contents of 16-OMC in single Robusta beans were between 1005.55 and 3208.32 mg/kg and were absent from single Arabica beans. The surveillance results indicate that 17 out of 47 blend products claiming to contain 100% Arabica had 16-OMC quantifications in the range of 155.74−784.60 mg/kg. Furthermore, all 17 products were produced by the same coffee chain. We confirmed that coffee chain adulterated Arabica with Robusta... [more]

In this study, we prepared chitosan/Fe(III)/deferoxamine nanoparticles with unimodal size distribution (hydrodynamic diameter ca. 250 nm, zeta potential ca. 32 mV). The elaborated nanoparticles are characterized by outstanding in vitro and in vivo antibacterial activity, which exceeds even that of commercial antibiotics ampicillin and gentamicin. Moreover, the nanoparticles are non-toxic. We found that the introduction of iron ions into the chitosan matrix increases the ability of the resulting nanoparticles to disrupt the integrity of the membranes of microorganisms in comparison with pure chitosan. The introduction of deferoxamine into the obtained nanoparticles sharply expands their effect of destruction the bacterial membrane. The obtained antibacterial nanoparticles are promising for further preclinical studies.

The concentralized distribution logistics in cruise-building imported materials (CDL-CIMs) constitute a complex process that requires a high degree of coordination between the multi-link and multi-participator. Delayed delivery, materials damaged, and cost overruns occur because of increasing uncertainties and risks, which may cause disjointedness in cruise construction planning. Therefore, it is essential to conduct a risk assessment of the CDL-CIMs to examine their adverse impacts on cruise construction. Drawing on the advantages of the failure modes and effects analysis (FMEA) method in risk assessment, an effective and efficient model is developed using a novel hybrid method in this paper, namely the rule-based Bayesian network (RBN) and utility function. The approach has its superiorities in dealing with vague and uncertainty risk information. In addition, the risk parameters from multiple perspectives concerning “occurrence likelihood”, “detection”, “delayed schedule”, “damaged q... [more]

To improve the wear resistance of the TMR blade and investigate the effect of nano-La2O3 and Mo on the wear resistance of laser cladding coating. 65Mn blade as the substrate, La2O3, Mo and Mo-La2O3 composite powders were added into Ni60a/SiC composite powder. Using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and the CFT-I surface synthesizer, the phase composition, element distribution and friction and wear properties of the coating were analyzed to obtain the best composition of the composite coating. The results showed that the wear resistance of Mo-La2O3-Ni60a/SiC composite coating was the best. The coating was analyzed by X-ray diffraction and X-ray photoelectron spectroscopy. The coating contained hard phases such as CrB, CrC and Cr7C3, and the element distribution was uniform. It can be seen from the scanning electron microscope that the addition of nano-Mo and La2O3 improves the toughness and compactness of Ni60a/SiC composite coating, and t... [more]

Tailings, with their low utilisation rate and value, pose an urgent problem that needs to be solved. This study focused on foam ceramics and glass granules, which were prepared using gold tailings as the main raw materials, and the prepared microcrystalline foam ceramics were investigated. The optimum sample (S6) of foam ceramics consists of 77 wt% of gold tailings, 6 wt% of talc, 9 wt% of bentonite, 2 wt% of calcite, 0.9 wt% of foaming agent and 0.6% of water reducer. The optimum foaming temperature is 1190 °C, and the holding time is 60 min. The compressive strength and bulk density of the samples are 7.4 MPa and 396.4 kg/m3; nucleation temperature, crystallisation temperature, and crystallisation activation energy of glass particles are 700 °C ± 50 °C, 1100 °C ± 50 °C, and 1572 kJ/mol, respectively. Microanalysis results showed that the crystal phases of foam ceramics were mainly quartz, calcium silicate, and aluminium silicate, and crystallinity increases with increasing gold taili... [more]

Microbial fuel cells (MFCs) are a promising technology that can be applied in a bifunctional process in which wastewater treatment is used for renewable electric power generation. In this study, novel transition metal-modified Keggin-type lacunar polyoxometalate salts (L-POMs) Cs5PMo11M(H2O)O39 (M = Fe, Co), were synthesized and characterized by X-ray diffraction, SEM, EDX, IR, TGA/DSC, and UV-Vis/DSR spectroscopies to be tested, for the first time, as a cathode component in wastewater-fed air chamber MFCs. Both materials were tested in the presence and absence of light to evaluate their photocatalytic behavior. The best performance in terms of electricity production was obtained for the MFC containing the Co-modified POM-based cathode, which showed a maximum power of 418.15 mW/m2 equivalent to 331 mW per cubic meter of treated wastewater, and a maximum COD removal percentage of 97% after 96 h of MFC operation. Co- and Fe-modified POMs had outstanding optical behavior with lower energy... [more]