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Records with Subject: Process Design
Showing records 481 to 505 of 2098. [First] Page: 1 17 18 19 20 21 22 23 24 25 Last
Improved FAST Device for Inherent Safety of Oxide-Fueled Sodium-Cooled Fast Reactors
Ahmed Amin E. Abdelhameed, Chihyung Kim, Yonghee Kim
March 28, 2023 (v1)
Keywords: anticipated transients without scram, coolant temperature coefficient, inherent safety, sodium-cooled fast reactors
The floating absorber for safety at transient (FAST) was proposed as a solution for the positive coolant temperature coefficient in sodium-cooled fast reactors (SFRs). It is designed to insert negative reactivity in the case of coolant temperature rise or coolant voiding in an inherently passive way. The use of the original FAST design showed effectiveness in protecting the reactor core during some anticipated transients without scram (ATWS) events. However, oscillation behaviors of power due to refloating of the absorber module in FAST were observed during other ATWS events. In this paper, we propose an improved FAST device (iFAST), in which a constraint is imposed on the sinking (insertion) limit of the absorber module in FAST. This provides a simple and effective solution to the power oscillation problem. Here, we focus on an oxide fuel-loaded SFR that is characterized by a more negative Doppler reactivity coefficient and higher operating temperature than the metallic-loaded SFR cor... [more]
Hydraulic Conductivity of Rock Masses Surrounding Water Curtain Boreholes for Underground Oil Storage Caverns
Qi-Hua Zhang, Qing-Bing Liu, Ai-Jun Su, Yu-Jie Li, Yi-Hu Zhang
March 28, 2023 (v1)
Keywords: hydraulic conductivity, underground storage cavern, water curtain borehole, water injection test
The assessment of the groundwater flow rate around the cavern periphery is a critical requirement for the design of underground water-sealed oil storage caverns and commonly made through seepage analysis, where a reasonable estimation of the hydraulic conductivity of the host rock is the key issue. However, it is a challenge to accurately determine the hydraulic conductivity of natural rock masses owing to their heterogeneous and anisotropic nature. The underground storage cavern project has a unique favorable condition in that there is a water curtain system that can provide considerable hydraulic test data for inferring hydraulic parameters; however, no well-established method has ever been proposed to exploit these data for characterizing heterogeneity in hydraulic conductivity. This study presents a new approach to evaluate the spatial variation of hydraulic conductivity using water curtain borehole data. This approach treats the peripheral region of each borehole as a homogenous u... [more]
Tracking the Adoption of Electric Pressure Cookers among Mini-Grid Customers in Tanzania
Ansila Kweka, Anna Clements, Megan Bomba, Nora Schürhoff, Joseph Bundala, Erick Mgonda, Mattias Nilsson, Elliot Avila, Nigel Scott
March 28, 2023 (v1)
Keywords: electric cooking, electricity, fuel stacking, mini-grids, Tanzania
“Are electric cooking appliances viable clean cooking solutions for mini-grids?” To help answer this question, the Access to Energy Institute (A2EI) set up a pilot project in six different mini-grid locations around Lake Victoria in Tanzania and gave 100 households an electric pressure cooker (EPC) to use in their homes. Each EPC was connected to a smart meter to collect data on how the EPCs were used. The paper presents findings from a study designed around the A2EI pilot project that aims to provide an understanding of cooking practices, the adoption of electric cooking over time, and to assess the potential for electric cooking to substitute traditional cooking fuels. Through collaboration with the Modern Energy Cooking Services (MECS) program, Nexleaf Analytics, and PowerGen, the pilot has generated data on electrical energy consumption from 92 households in six remote areas as well as a comprehensive range of other datasets gathered from 28 households in two of the locations. This... [more]
Thermal Efficiency and Economics of a Boil-Off Hydrogen Re-Liquefaction System Considering the Energy Efficiency Design Index for Liquid Hydrogen Carriers
Minsoo Choi, Wongwan Jung, Sanghyuk Lee, Taehwan Joung, Daejun Chang
March 28, 2023 (v1)
Keywords: boil-off hydrogen, economics, energy efficiency design index, Exergy Efficiency, liquid hydrogen carrier, specific energy consumption
This study analyzes the thermodynamic, economic, and regulatory aspects of boil-off hydrogen (BOH) in liquid hydrogen (LH2) carriers that can be re-liquefied using a proposed re-liquefaction system or used as fuel in a fuel cell stack. Five LH2 carriers sailing between two designated ports are considered in a case study. The specific energy consumption of the proposed re-liquefaction system varies from 8.22 to 10.80 kWh/kg as the re-liquefaction-to-generation fraction (R/G fraction) is varied. The economic evaluation results show that the cost of re-liquefaction decreases as the re-liquefied flow rate increases and converges to 1.5 $/kg at an adequately large flow rate. Three energy efficient design index (EEDI) candidates are proposed to determine feasible R/G fractions: an EEDI equivalent to that of LNG carriers, an EEDI that considers the energy density of LH2, and no EEDI restrictions. The first EEDI candidate is so strict that the majority of the BOH should be used as fuel. In the... [more]
Research on the Correction Method of the Capillary End Effect of the Relative Permeability Curve of the Steady State
Yanyan Li, Shuoliang Wang, Zhihong Kang, Qinghong Yuan, Xiaoqiang Xue, Chunlei Yu, Xiaodong Zhang
March 28, 2023 (v1)
Keywords: capillary end effect, relative permeability curve, tight reservoir
Relative permeability curve is a key factor in describing the characteristics of multiphase flow in porous media. The steady-state method is an effective method to measure the relative permeability curve of oil and water. The capillary discontinuity at the end of the samples will cause the capillary end effect. The capillary end effect (CEE) affects the flow and retention of the fluid. If the experimental design and data interpretation fail to eliminate the impact of capillary end effects, the relative permeability curve may be wrong. This paper proposes a new stability factor method, which can quickly and accurately correct the relative permeability measured by the steady-state method. This method requires two steady-state experiments at the same proportion of injected liquid (wetting phase and non-wetting phase), and two groups of flow rates and pressure drop data are obtained. The pressure drop is corrected according to the new relationship between the pressure drop and the core len... [more]
Study on Mineral Compositions of Direct Carbonated Steel Slag by QXRD, TG, FTIR, and XPS
Xue Wang, Wen Ni, Jiajie Li, Siqi Zhang, Keqing Li
March 28, 2023 (v1)
Keywords: Carbon Capture, gypsum, orthogonal test design, steel slag, UCS, XPS
Steel slag CO2 sequestration helps mitigate global warming and decrease the stockpile of steel slag (SS). Through orthogonal design tests and single-factor tests, this paper evaluated the effects of the water/solid mass ratio (w/s), gypsum ratio (G/SS), molding pressure, and curing duration on uniaxial compressive strength (UCS) and CO2 uptake of the compacts. The results indicated that high w/s enhanced both strength and CO2 capture ability. The proper addition of gypsum helps promote UCS increase and CO2 uptake of steel slag. In addition, increasing the molding pressure can significantly improve UCS without reducing CO2 uptake. The optimum conditions in the study were a w/s of 0.20, G/SS of 1/16, and molding pressure of 27 MPa, under which conditions 1 d UCS and CO2 uptake were 55.30 MPa and 12.36%, respectively. Microanalyses showed that gypsum activates mainly mayenite in steel slag. An increase in water addition also increased the hydration and carbonation products greatly, and th... [more]
How to Procure Flexibility Services within the Electricity Distribution System: Lessons from an International Review of Innovation Projects
Karim L. Anaya, Michael G. Pollitt
March 28, 2023 (v1)
Keywords: distribution energy resources, distribution system operators, flexibility services, innovation projects, international review, lessons, procurement, regulation
The aim of this paper is to analyse and evaluate the deployment of smart platforms (operated by distribution system operators—DSOs—or by independent parties) in key jurisdictions that facilitate the trading of flexibility services—primarily by DSOs. We look at key innovation projects/initiatives from seven jurisdictions, including Australia, France, Germany, Great Britain, Japan, The Netherlands and Norway. We have deliberately selected 13 use cases that operate under different regulatory frameworks and market rules, and have been recently implemented (from 2017 onwards). With the selection of key use cases this study seeks to discuss the different smart architecture solutions and main capabilities across different demonstrators and their relationship to business as usual. It also analyses flexibility market designs, identifies main characteristics, and compares different price formation schemes and procurement methods. The value of flexibility for DSOs is also discussed.
Development of Empirical Correlation of Two-Phase Pressure Drop in Moisture Separator Based on Separated Flow Model
Woo-Shik Kim, Jae-Bong Lee, Ki-Hwan Kim
March 28, 2023 (v1)
Keywords: moisture separator, separated model, steam generator, two-phase pressure drop
Pressure drop across the moisture separator installed in the steam generator of a nuclear power plant affects the power generation efficiency, and so accurate pressure drop prediction is important in generator design. In this study, an empirical correlation is proposed for predicting the two-phase pressure drop through a moisture separator. To ensure the applicability of the correlation, a series of two-phase air-water experiments were performed, and the results of the present test and of the benchmark test of high-pressure steam-water were used in developing the correlation. Based on the experimental results, quality, dimensionless superficial velocity, density ratio of the working fluid, and the geometrical factor were considered to be important parameters. The two-phase pressure drop multiplier was expressed in terms of these parameters. The empirical correlation was found to predict the experimental results within a reasonable range.
Ushering in a New Dawn: Demand-Side Local Flexibility Platform Governance and Design in the Finnish Energy Markets
Nayeem Rahman, Rodrigo Rabetino, Arto Rajala, Jukka Partanen
March 28, 2023 (v1)
Keywords: demand-side flexibility, energy platform, Finnish energy markets, flexibility, flexibility service, local flexibility market, platform governance and design, platforms
Energy ecosystems are under a significant transition. Local flexibility marketplaces (LFM) and platforms are argued to have significant potential in contributing to such a transition. The purpose of this study was to answer the following research question: how do market conditions and stakeholders shape emerging LFM platform governance choices? We approached this objective with an exploratory single-case study by conducting ten semi-structured interviews with key stakeholders in the Finnish energy ecosystem. The results of the content and pattern analyses revealed the key challenges to LFM implementation such as the current regulatory treatment of flexibility, high costs of gadget installations, and ensuring sufficient liquidity in the market. In addition, we also demonstrated that despite such barriers, the Finnish ecosystem is largely pragmatic about LFMs’ in its midst. All in all, we contributed to the non-technological streams of LFM literature by developing an exhaustive framework... [more]
Guidelines for Determining the Initial Shape and Specifications of High-Speed AFPM Based on Recent Research
Jae-Beom Kang, Ji-Young Lee, Ji-Heon Lee
March 28, 2023 (v1)
Keywords: air mobility, axial-flux permanent-magnet machine(AFPM), design key issues, dynamic performance limit, high-speed electric machine
This paper presents guidelines for determining the initial shape and specifications of a high-speed axial-flux permanent-magnet (AFPM) machine in a hybrid-electric propulsion system in two steps based on previous studies and product review results related to high-speed AFPMs. In the first step, three characteristics to be considered when designing AFPMs were classified as: electromagnetic, thermal, and mechanical. Then, the factors that should be considered in the design process to satisfy each characteristic were organized. In the second step, “the speed−output power” relationship was defined to predict the limits of applying AFPMs to high-speed applications, allowing an estimation of the limits of the speed range that can be used within the proposed output power.
There Is Plenty of Room inside a Bluff Body: A Hybrid Piezoelectric and Electromagnetic Wind Energy Harvester
Mahmood Al-Riyami, Issam Bahadur, Hassen Ouakad
March 28, 2023 (v1)
Keywords: bluff-body design, hybrid energy harvester, piezoelectric and electromagnetic energy harvester, vortex-induced vibration
In this paper, a piezoelectric and electromagnetic hybrid wind energy harvester is proposed. The general design of the harvester comprises multiple cantilever piezoelectric energy harvesters (PEHs) and electromagnetic energy harvesters (EEHs) embedded inside the bluff body that is attached to the free end of PEHs. This research work investigates utilizing the room inside the bluff body to enclose harvesters to have a more compact and efficient harvesting system. A comprehensive coupled dynamic model of the harvester (HEH) is developed using Lagrange’s formulation. The electromechanical and electromagnetic coupling coefficient equations are derived. The coupled equations of motion are solved analytically and numerically with an exact agreement. A parametric analysis is conducted to study the effect of the design parameters on the overall performance of the harvester in terms of output power and bandwidth. The proposed design evidently presents itself as a promising concept in utilizing... [more]
Performance Analysis of an Experimental Linear Encoder’s Reading Head under Different Mounting and Dynamic Conditions
Donatas Gurauskis, Krzysztof Przystupa, Artūras Kilikevičius, Mikołaj Skowron, Matijošius Jonas, Joanna Michałowska, Kristina Kilikevičienė
March 28, 2023 (v1)
Keywords: grating, measuring scale, moiré effect, optical encoder, reading head
The performance of an optical linear encoder is described and evaluated by certain parameters such as its resolution, accuracy and repeatability. The best encoder for a particular application, just like other sensors, is usually selected according these parameters. There are, however, many side effects that have a direct influence on the optimal operation of an encoder. In order to understand how to minimize these harmful effects, a deeper knowledge of an encoder’s performance and a method for determining these factors are necessary. The main aspects of an encoder’s accuracy, resolution and repeatability are briefly reviewed in this paper. Discussed and developed in previous work, the experimental reading head for a Moiré effect-based optical linear encoder is used for the experimental analysis of the influence of different reading head designs on an encoder’s performance under various mounting inaccuracies and dynamic conditions.
Experimental Study on the Transient Disturbance Characteristics and Influence Factors of Pantograph−Catenary Discharge
Mengzhe Jin, Man Hu, Hao Li, Yixuan Yang, Weidong Liu, Qingyuan Fang, Shanghe Liu
March 28, 2023 (v1)
Keywords: arcing discharge, current pulse, electromagnetic disturbance, experimental investigation, pantograph–catenary, radiation, railway, relative motion
The transient electromagnetic disturbance generated by arcing discharge between the pantograph and catenary can pose a significant risk to the safe operation of electrified railways. In order to better comprehend its properties, a pantograph−catenary discharge generating device is designed to simulate the discharge phenomenon with moving electrodes in this experimental investigation. The effects of the applied voltage, the gap distance, and the relative motion between the pantograph and catenary on the time- and frequency-domain features of the discharge current and electromagnetic field are investigated. The variation trends of pulse peak current, rise time, pulse repetition frequency, maximum amplitude, and characteristic frequency in the radiation spectrum are retrieved under varying experimental settings, and the effect mechanisms are derived from the physics of gas discharge. A dynamic discharge test is conducted in this study in order to further understand the effect of electrode... [more]
Design and Analysis of Novel CO2 Conditioning Process in Ship-Based CCS
Wentao Gong, Eryk Remiezowicz, Philip Loldrup Fosbøl, Nicolas von Solms
March 28, 2023 (v1)
Keywords: Carbon Dioxide Capture, CCS hub Dunkirk, CO2 conditioning, CO2 liquefaction, DMXTM process
In this work, CO2 conditioning processes for ship-based CCS sequestration are modelled using the software APSEN HYSYS V11. This study uses the captured CO2 gas from the 3D project as the feed. The feed stream contains water, H2S, and CO as contaminants. The purification processes for dehydration, desulfurization, and CO removal are reviewed. Two liquefaction approaches, the open-cycle and the closed-cycle liquefaction, are modelled and compared for transport pressures 7 and 15 bar. It is found that the energy requirement of the open-cycle process is higher than that of the closed-cycle liquefaction process. For the closed-cycle design, two refrigerants, ammonia and propane, are considered. Results show that the energy requirement of the process using ammonia is lower than that of propane. When comparing the two transport pressures, it is found that liquefaction at 15 bar requires less energy than 7 bar. On top of that, both refrigerants are unsuited for the liquefaction of CO2 at 7 bar... [more]
Design and Improvement of SD3-Based Energy Management Strategy for a Hybrid Electric Urban Bus
Kunyu Wang, Rong Yang, Yongjian Zhou, Wei Huang, Song Zhang
March 28, 2023 (v1)
Keywords: action masking, deep reinforcement learning, energy management strategy, hybrid electric urban bus
With the rapid development of machine learning, deep reinforcement learning (DRL) algorithms have recently been widely used for energy management in hybrid electric urban buses (HEUBs). However, the current DRL-based strategies suffer from insufficient constraint capability, slow learning speed, and unstable convergence. In this study, a state-of-the-art continuous control DRL algorithm, softmax deep double deterministic policy gradients (SD3), is used to develop the energy management system of a power-split HEUB. In particular, an action masking (AM) technique that does not alter the SD3′s underlying principles is proposed to prevent the SD3-based strategy from outputting invalid actions that violate the system’s physical constraints. Additionally, the transfer learning (TL) method of the SD3-based strategy is explored to avoid repetitive training of neural networks in different driving cycles. The results demonstrate that the learning performance and learning stability of SD3 are una... [more]
Coupling Chemical Heat Pump with Nuclear Reactor for Temperature Amplification by Delivering Process Heat and Electricity: A Techno-Economic Analysis
Aman Gupta, Piyush Sabharwall, Paul D. Armatis, Brian M. Fronk, Vivek Utgikar
March 28, 2023 (v1)
Keywords: chemical heat pump, industrial thermal processes, nuclear energy, techno-economic, temperature boost
The energy economy is continually evolving in response to socio-political factors in the nature of primary energy sources, their conversions to useful forms, such as electricity and heat, and their utilization in different sectors. Nuclear energy has a crucial role to play in the evolution of energy economy due to its clean and non-carbon-emitting characteristics. A techno-economic analysis was undertaken to establish the viability of selling heat along with electricity for an advanced 100 MWth small modular reactor (SMR) and four nuclear hybrid energy system (NHES) configurations featuring the SMR paired with chemical heat pump (ChHP) systems providing a thermal output ranging from 1 to 50 MWth. Net present value, payback period, discounted cash flow rate of return, and levelized cost of energy were evaluated for these systems for different regions of U.S. reflecting a range of electricity and thermal energy costs. The analysis indicated that selling heat to high temperature industria... [more]
Repowering a Coal Power Unit with Small Modular Reactors and Thermal Energy Storage
Łukasz Bartela, Paweł Gładysz, Jakub Ochmann, Staffan Qvist, Lou Martinez Sancho
March 28, 2023 (v1)
Keywords: molten salt thermal energy storage, retrofit decarbonization, small modular reactors, supercritical steam cycles, techno-economic assessment
In the first months of 2022, there was a sharp turn in the energy policy of the European Union, initially spurred by increasing energy prices and further escalated by Russia’s invasion of the Ukraine. Further transformation of the energy system will likely be accompanied by the gradual abandonment of natural gas from Russia and an increase of renewable and nuclear energy. Such a transition will not only increase energy security, but also accelerate the pace at which greenhouse gas emissions are reduced in Europe. This could be achieved more effectively if some of the new nuclear energy capacity is optimized to play an increased balancing role in the energy system, thus allowing for deeper market penetration of intermittent renewable energy sources with a reduced need for flexible fossil backup power and storage. A double effect of decarbonization can be achieved by investments in nuclear repowering of coal-fired units, with the replacement of coal boiler islands with nuclear reactor sy... [more]
Techno-Economic Analysis of Low Carbon Hydrogen Production from Offshore Wind Using Battolyser Technology
Brian Jenkins, David Squires, John Barton, Dani Strickland, K. G. U. Wijayantha, James Carroll, Jonathan Wilson, Matthew Brenton, Murray Thomson
March 28, 2023 (v1)
Keywords: battolyser, electrolysis, Energy Storage, NPV, stochastic modelling, wind generation
A battolyser is a combined battery electrolyser in one unit. It is based on flow battery technology and can be adapted to produce hydrogen at a lower efficiency than an electrolyser but without the need for rare and expensive materials. This paper presents a method of determining if a battolyser connected to a wind farm makes economic sense based on stochastic modelling. A range of cost data and operational scenarios are used to establish the impact on the NPV and LCOE of adding a battolyser to a wind farm. The results are compared to adding a battery or an electrolyser to a wind farm. Indications are that it makes economic sense to add a battolyser or battery to a wind farm to use any curtailed wind with calculated LCOE at £56/MWh to £58/MWh and positive NPV over a range of cost scenarios. However, electrolysers, are still too expensive to make economic sense.
Numerical Investigations of a Non-Uniform Stator Dihedral Design Strategy for a Boundary Layer Ingestion (BLI) Fan
Tianyu Pan, Kaikai Shi, Hanan Lu, Zhiping Li, Jian Zhang
March 28, 2023 (v1)
Keywords: BLI fan, boundary layer ingestion, dihedral blade, flow separation, inlet distortion, non-uniform stator design
A distributed propulsion system has the advantage of saving 5−15% fuel burn through ingesting the fuselage boundary layer of an aircraft by fan or compressor. However, due to boundary layer ingestion (BLI), the fan stage will continuously operate under serious inlet distortion. This will lead to a circumferentially non-uniform flow separation distribution on the stator blade suction surface along the annulus, which significantly decreases the fan’s adiabatic efficiency. To solve this problem, a non-uniform stator dihedral design strategy has been developed to explore its potential of improving BLI fan performance. First, the stator full-annulus blade passages were divided into blade dihedral design regions and baseline design regions on the basis of the additional aerodynamic loss distributions caused by BLI inlet distortion. Then, to find the appropriate dihedral design parameters, the full-annulus BLI fan was discretized into several portions according to the rotor blade number and t... [more]
Design of an Anti-Corona Device for HVAC Substation Connectors
Ane Miren Larrea, Manuel De La Hoz, Agurtzane Etxegarai, Angel Javier Mazon, Itxaso Aranzabal
March 28, 2023 (v1)
Keywords: computer-aided manufacturing, connector, corona ring, electric fields, high voltage
One of the aspects to consider during high-voltage (HV) equipment design is the reduction in the probability of corona effect onset. Indeed, the corona effect is related to high electric field values beyond the equipment’s insulation levels and insulation strength, among other factors. This issue can be addressed during the design step, either by modifying the geometry of the electrical device or by including additional elements in the equipment structure to smooth out the voltage gradient along critical regions, such as anti-corona devices. The study of anti-corona devices for HV insulators is well documented, in contrast to substation connectors. Therefore, the present study proposed the design of a novel anti-corona device for HV substation connectors, including a method for the selection of its dimensions. This study shows that the relationship between the dimensional design variables and the critical electrical field on the connector is described by linear and rational functions.... [more]
Power Transmission Lines: Worldwide Research Trends
Francisca Alcayde-García, Esther Salmerón-Manzano, Miguel A. Montero, Alfredo Alcayde, Francisco Manzano-Agugliaro
March 28, 2023 (v1)
Keywords: arc flash, Artificial Intelligence, fault location, half-wave, leakage current, line inspection, lines design, magnetic fields, natural disasters, pattern recognition
The importance of the quality and continuity of electricity supply is increasingly evident given the dependence of the world economy on its daily and instantaneous operation. In turn, the network is made up of power transmission lines. This study has been carried out based on the Scopus database, where all the publications, over 5000 documents, related to the topic of the power transmission lines have been analyzed up to the year 2022. This manuscript aims to highlight the main global research trends in power transmission lines and to detect which are the emerging areas. This manuscript cover three main aspects: First, the main scientific categories of these publications and their temporal trends. Second, the countries and affiliations that contribute to the research and their main research topics. Third, identification of the main trends in the field using the detection of scientific communities by means of the clustering method. The three main scientific categories found were Enginee... [more]
Design and Construction of Foundations for Industrial Facilities in the Areas of Former Post-Mining Waste Dumps
Marian Łupieżowiec, Jarosław Rybak, Zenon Różański, Przemysław Dobrzycki, Witold Jędrzejczyk
March 28, 2023 (v1)
Keywords: coal-waste dumps, foundation on the embankment lands, ground improvement, self-ignition of heaps
This article presents the characteristics of the heaps resulting from coal exploitation in terms of the possibility of their development for industrial facilities. The chances of soil improvement and the existing threats were indicated, emphasising the risk of self-ignition. The most effective technologies are dynamic or impulse compaction, which allows deep soil improvement and the obtaining of an appropriately rigid and load-bearing subsoil. The homogeneity of the soil’s mechanical properties that form the subsoil is also essential, which guarantees compliance with the serviceability limit state. A very important aspect of the investment process in the post-mining waste dumps is the risk of auto-ignition of the accumulated material. Considerations and analyses are presented on the example of the implementation of Panatonni service, warehouse, and production halls in Ruda Śląska. The performance of impulse compaction allowed for the safe construction of industrial halls. In particular... [more]
Transesterification Using Ultrasonic Spray of Triolein Containing CaO Particles into Methanol Vapor in a 3-Phase Reactor
Ravisut Vitidsant, Satoshi Kodama, Hidetoshi Sekiguchi
March 28, 2023 (v1)
Keywords: CaO, methanol vapor, three-phase reactor, transesterification, triolein, ultrasonic spraying
Ultrasonic spraying was used in a three-phase reactor to produce small droplets of triolein mixed with CaO as a solid catalyst at temperatures above the boiling point of methanol for enhancement of the transesterification of triolein. Droplets fell in the methanol countercurrent flow and were collected at the bottom of the reactor, followed by circulation to the ultrasonic spray system. The experimental parameters included triolein flow rates of 2.5−9.0 mL/min, reaction temperatures of 70−100 °C, and catalyst contents of 1.0−7.0 wt%. The methanol feed rate was set to be constant. The results suggested that the enhancement was successful after using the three-phase reactor by generating a high contact surface area for the droplets, which was a key factor for determining the performance. Comparing the results with conventional transesterification in the liquid phase using the same CaO at 60 °C, the three-phase reactor produced a methyl ester yield 2−5% higher during the 60 min trial peri... [more]
A Logistic Approach for Kinetics of Isothermal Pyrolysis of Cellulose
Jorge López-Beceiro, Ana María Díaz-Díaz, Ana Álvarez-García, Javier Tarrío-Saavedra, Salvador Naya, Ramón Artiaga
March 28, 2023 (v1)
Keywords: cellulose, degradation, isothermal, kinetics, pyrolysis
A kinetic model is proposed to fit isothermal thermogravimetric data obtained from cellulose in an inert atmosphere at different temperatures. The method used here to evaluate the model involves two steps: (1) fitting of single time-derivative thermogravimetric curves (DTG) obtained at different temperatures versus time, and (2) fitting of the rate parameter values obtained at different temperatures versus temperature. The first step makes use of derivative of logistic functions. For the second step, the dependence of the rate factor on temperature is evaluated. That separation of the curve fitting from the analysis of the rate factor resulted to be very flexible since it proved to work for previous crystallization studies and now for thermal degradation of cellulose.
Optimal Design of a Hydrolysis Sugar Membrane Purification System Using a Superstructure-Based Approach
Chien-Yuan Su, Bo-Yan Ji, Pei-Jung Yu, Ming-Hua Wang, Wei-Chun Hung, Ying-Hsi Chang, Jui-Yuan Lee
March 28, 2023 (v1)
Keywords: bioethanol production, mathematical programming, nanofiltration, network synthesis, salt removal
As an alternative to gasoline, bioethanol can be produced from lignocellulosic biomass through hydrolysis using an ionic solution containing zinc chloride (ZnCl2). This method allows for a high yield of glucose from lignocellulose, but entails the removal of ZnCl2 from the hydrolysate using multiple nanofiltration membranes before the fermentation of glucose. This paper presents a mathematical technique for designing such a multistage membrane separation system. The optimization model for the synthesis of membrane networks is based on a superstructure with all feasible interconnections between the membrane units, and consists of mass balances, logical constraints and product specifications. A case study of the separation of a bagasse hydrolysis solution is used to demonstrate the application of the proposed model. Results show that using both types of nanofiltration membranes allows higher ZnCl2 removal ratios at each membrane unit, hence a decrease in the number of membrane units requ... [more]
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